CN107424919A - A kind of low Damage Medium grid and preparation method thereof - Google Patents

A kind of low Damage Medium grid and preparation method thereof Download PDF

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Publication number
CN107424919A
CN107424919A CN201710335407.3A CN201710335407A CN107424919A CN 107424919 A CN107424919 A CN 107424919A CN 201710335407 A CN201710335407 A CN 201710335407A CN 107424919 A CN107424919 A CN 107424919A
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Prior art keywords
barrier layer
layer
metal
passivation layer
grid
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Inventor
王元刚
冯志红
吕元杰
宋旭波
谭鑫
周幸叶
徐鹏
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CETC 13 Research Institute
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CETC 13 Research Institute
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/41Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions
    • H01L29/423Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions not carrying the current to be rectified, amplified or switched
    • H01L29/42312Gate electrodes for field effect devices
    • H01L29/42316Gate electrodes for field effect devices for field-effect transistors
    • H01L29/4232Gate electrodes for field effect devices for field-effect transistors with insulated gate
    • H01L29/42364Gate electrodes for field effect devices for field-effect transistors with insulated gate characterised by the insulating layer, e.g. thickness or uniformity
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • H01L21/28008Making conductor-insulator-semiconductor electrodes
    • H01L21/28017Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
    • H01L21/28247Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon passivation or protection of the electrode, e.g. using re-oxidation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/778Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface
    • H01L29/7786Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface with direct single heterostructure, i.e. with wide bandgap layer formed on top of active layer, e.g. direct single heterostructure MIS-like HEMT
    • H01L29/7787Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface with direct single heterostructure, i.e. with wide bandgap layer formed on top of active layer, e.g. direct single heterostructure MIS-like HEMT with wide bandgap charge-carrier supplying layer, e.g. direct single heterostructure MODFET

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Drying Of Semiconductors (AREA)
  • Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)

Abstract

The invention discloses a kind of low Damage Medium grid and preparation method thereof, it is related to semiconductor high-frequency power device and high tension apparatus technical field;Including being followed successively by substrate, channel layer, barrier layer and passivation layer from top to bottom, source metal and leakage metal are located at device both sides, grid metal is located between source metal and leakage metal, dry etching passivation layer is until barrier layer first, then in etching position deposit grid metal, barrier layer is provided between barrier layer and passivation layer, as etch stop layer;Etching technics damage device surface is avoided, reduces grid leak electricity, improves the yield rate of Dielectric.

Description

A kind of low Damage Medium grid and preparation method thereof
Technical field
The present invention relates to semiconductor high-frequency power device and high tension apparatus technical field.
Background technology
Dielectric combination field plate can effectively improve device electric breakdown strength, be widely used in microwave power and high pressure field. Document:The performance comparision of 0.25 μm of Dielectric and non-Dielectric PHEMT is analyzed, device manufacture and application, and 2009,36(7): 658-660 compared for Dielectric and non-Dielectric PHEMT device electric breakdown strengths, as shown in Figure 1.As can be seen from Figure 1:Dielectric PHEMT ON states breakdown voltage is apparently higher than non-medium gate device.
Dielectric group III-nitride HEMT(HEMT)Structure is as shown in Fig. 2 conventional preparation method For:One layer of passivation layer is deposited first, and then ICP etches grid position passivation layer, finally evaporates grid metal, forms Dielectric.
Typical media grid preparation method etching grid position passivation layer can damage potential barrier layer surface, cause grid leak electricity increase etc. no Good influence.
The content of the invention
The technical problem to be solved in the present invention is to be directed to above-mentioned the deficiencies in the prior art, there is provided a kind of low Damage Medium grid and Its preparation method, etching technics damage device surface is avoided, grid leak will not be caused electric, improve the yield rate of Dielectric.
In order to solve the above technical problems, the technical solution used in the present invention is:Including being followed successively by substrate, ditch from top to bottom Channel layer, barrier layer and passivation layer, source metal and leakage metal are located at device both sides, and grid metal is located between source metal and leakage metal, Dry etching passivation layer is until barrier layer, then deposits grid metal in etching position first.It is characterized in that:The barrier layer with Barrier layer is provided between passivation layer), as etch stop layer.
Preferably, barrier layer is one layer.
Preferably, barrier layer is two layers, respectively the first barrier layer and the second barrier layer.
Preferably, grid metal runs through cut-off passivation layer through cut-off passivation layer, or grid metal(6)With barrier layer or pass through Wear cut-off passivation layer and the first barrier layer.
Preferably, passivation layer is Si3N4, barrier layer Al2O3
Preferably, the first barrier layer thickness d1 scopes are:1nm≤d1≤10μm.
Preferably, the second barrier layer thickness d2 scopes are:1nm≤d2≤10μm.
A kind of preparation method of low Damage Medium grid, it is characterised in that:Step includes:
(1), obtain substrate, channel layer and barrier layer successively with metal organic chemical vapor deposition;
(2), deposited by electron beam evaporation obtain source metal and leakage metal, and carry out high temperature rapid thermal annealing;
(2), on barrier layer obtain barrier layer with atomic layer deposition strategy;
(3), over the barrier layer with gas ions enhancing chemical vapour deposition technique obtain passivation layer;
(4), with dry etching passivation layer, and the condition of dry etching passivation layer can not etching barrier layer(8);Or dry etching After passivation layer, rewetting method corrosion barrier layer;
(5), deposited by electron beam evaporation obtain grid metal, that is, be made low Damage Medium grid.
Preferably, step(4)The method of middle dry etching passivation layer is:Set using sense coupling Standby, the plasma dry formed using sulfur hexafluoride gas carves passivation layer Si3N4
It is using beneficial effect caused by above-mentioned technical proposal:The present invention is simple in construction, passivation layer and barrier layer it Between increase barrier layer, avoid etching technics damage device surface, grid leak will not be caused electric, reduce grid leak electricity and grid metal/partly lead Body interface state, improve device electric breakdown strength and reliability;Improve the yield rate of Dielectric.
Brief description of the drawings
Fig. 1 is that Dielectric and non-Dielectric ON state breakdown voltage compare;
Fig. 2 is the structural representation of prior art;
Fig. 3 is the structural representation of one embodiment of the invention;
Fig. 4 is the structural representation of another embodiment of the present invention;
Fig. 5 is the inventive method step(2)- step(3)Schematic diagram;
Fig. 6 is the inventive method step(4)The schematic diagram of Etch Passivation;
Fig. 7 is the inventive method step(4)The schematic diagram of corrosion barrier layer.
In figure:1st, substrate;2nd, channel layer;3rd, barrier layer;4th, source metal;5th, metal is leaked;6th, passivation layer;7th, grid metal;8、 Barrier layer;8.1st, the first barrier layer;8.2nd, the second barrier layer.
Embodiment
The present invention is further detailed explanation with reference to the accompanying drawings and detailed description.
With Dielectric group III-nitride HEMT ((High Electron Mobility Transistor), high electronics moves Shifting rate transistor) exemplified by illustrate.
Embodiment 1:
As shown in figure 3, be a kind of one embodiment of low Damage Medium grid of the present invention and preparation method thereof,
Including being followed successively by substrate 1 and channel layer 2 from top to bottom;Both ends on channel layer 2 are respectively equipped with source metal 4 and leakage metal 5; Barrier layer 3 and passivation layer 6 are sequentially provided with from top to bottom on channel layer 2 and between source metal 4 and leakage metal 5, are set on passivation layer 6 There is grid metal 7, and grid metal 7 is through cut-off passivation layer 6;It is characterized in that:Resistance is provided between the barrier layer 3 and passivation layer 6 Barrier 8.
Barrier layer 8 is provided between barrier layer 3 and passivation layer 6, barrier layer 8 can make will not be to resistance in Etch Passivation 6 Barrier 8 is performed etching, and then device surface is protected, and grid leak will not be caused electric, improve the yield rate of Dielectric.
As illustrated in figs. 5-7, a kind of preparation method of low Damage Medium grid, it is characterised in that:Step includes:
(1), obtain substrate, channel layer and barrier layer successively with metal organic chemical vapor deposition;
(2), deposited by electron beam evaporation obtain source metal and leakage metal, and carry out high temperature rapid thermal annealing;
(2), on barrier layer obtain barrier layer with atomic layer deposition strategy;
(3), over the barrier layer with gas ions enhancing chemical vapour deposition technique obtain passivation layer;
(4), with dry etching passivation layer, and the condition of dry etching passivation layer can not etching barrier layer(8);Or dry etching After passivation layer, rewetting method corrosion barrier layer;
(5), deposited by electron beam evaporation obtain grid metal, that is, be made low Damage Medium grid.
Embodiment 2:
As the Dielectric structure in embodiment 1 is identical with preparation method, barrier layer 8 is one layer.The thickness d scope of barrier layer 8 is: 1nm≤d≤10 μm, optimum range are 1nm≤d≤20nm.
Embodiment 3:
As the Dielectric structure in embodiment 1 is identical with preparation method.
As shown in figure 4, barrier layer 8 is two layers, respectively the first barrier layer 8.1 and the second barrier layer 8.2.
The scope of first barrier layer, 8.1 thickness d 1 is:1nm≤d1≤10 μm, optimum range are 1nm≤d1≤20nm.
The scope of second barrier layer, 8.2 thickness d 2 is:1nm≤d2≤10 μm, optimum range are 1nm≤d2≤20nm.
The safer Etch Passivation 6 of two layers of energy of barrier layer 8.
Embodiment 4:
As the Dielectric structure in embodiment 1 is identical with preparation method.
Grid metal 7 is through cut-off passivation layer 6.
Embodiment 5:
As the Dielectric structure in embodiment 1 is identical with preparation method.
Grid metal 7 is through cut-off passivation layer 6 and barrier layer 8.
Embodiment 6:
As the Dielectric structure in embodiment 1 is identical with preparation method.
Through cut-off passivation layer 6 and first barrier layer 8.1.
Whether grid metal 7 does not influence through use of the barrier layer 8 on Dielectric.
Embodiment 7:
As the Dielectric structure in embodiment 1 is identical with preparation method.
Passivation layer 6 is Si3N4, barrier layer 8 is Al2O3
Step(4)The method of middle dry etching passivation layer 6 is:Using inductively coupled plasma etching equipment I CP, use Sulfur hexafluoride SF6The Si for the plasma dry etch passivation layer 6 that gas is formed3N4, the condition can not etching barrier layer 8 Al2O3
Evaporation obtains grid metal 7 on passivation layer 6, and grid metal 7 fills up the indentation, there of the passivation layer 6 of etching.
Embodiment 8:
As the Dielectric structure in embodiment 1 is identical with preparation method.There is two layers of barrier layer 8.
Passivation layer 6 is SiO2, the first barrier layer 8.1 is Al2O3, the second barrier layer 8.2 is hafnium oxide HfO2
Step(4)The method of middle dry etching passivation layer 6 is:Using inductively coupled plasma etching equipment I CP, use Sulfur hexafluoride SF6The plasma dry that gas is formed carves the SiO of passivation layer 62, the condition can not etching barrier layer 8 Al2O3。 Barrier layer 8 retains as medium under grid.
Evaporation obtains grid metal 7 on passivation layer 6, and grid metal 7 fills up the indentation, there of the passivation layer 6 of etching.
The scope of first barrier layer, 8.1 thickness d 1 is:1nm≤d1≤10 μm, optimum range are 1nm≤d1≤20nm.
The scope of second barrier layer, 8.2 thickness d 2 is:1nm≤d2≤10 μm, optimum range are 1nm≤d2≤20nm.
Embodiment 9:
As the Dielectric structure in embodiment 1 is identical with preparation method.
Passivation layer 6 is Si3N4, barrier layer 8 is Al2O3
Step(4)The method of middle dry etching passivation layer 6 is:Using inductively coupled plasma etching equipment I CP, use Sulfur hexafluoride SF6The plasma dry that gas is formed carves the Si of passivation layer 63N4, the condition can not etching barrier layer 8 Al2O3
Then wet etching barrier layer Al is utilized2O3
Evaporation obtains grid metal 7 on passivation layer 6, and grid metal 7 fills up passivation layer 6 and the barrier layer 8 of corrosion of etching Indentation, there.
Embodiment 10:
As the Dielectric structure in embodiment 1 is identical with preparation method.There is two layers of barrier layer 8.
Passivation layer 6 is SiO2, the first barrier layer 8.1 is Al2O3, the second barrier layer 8.2 is hafnium oxide HfO2
Step(4)The method of middle dry etching passivation layer 6 is:Using inductively coupled plasma etching equipment I CP, use Sulfur hexafluoride SF6The plasma dry that gas is formed carves the SiO of passivation layer 62, the condition can not etching barrier layer 8 Al2O3
The first barrier layer of wet etching 8.1.
Evaporation obtains grid metal 7 on passivation layer 6, and grid metal 7 fills up the barrier layer 8.1 of passivation layer 6 and first of etching Indentation, there.
Embodiment 11:
As the Dielectric structure in embodiment 1 is identical with preparation method.There is two layers of barrier layer 8.
Passivation layer 6 is SiO2, the first barrier layer 8.1 is Al2O3, the second barrier layer 8.2 is hafnium oxide HfO2
Step(4)The method of middle dry etching passivation layer 6 is:Using inductively coupled plasma etching equipment I CP, use Sulfur hexafluoride SF6The plasma dry that gas is formed carves the SiO of passivation layer 62, the condition can not etching barrier layer 8 Al2O3
Wet etching the first barrier layer 8.1 and the second barrier layer 8.2.
Evaporation obtains grid metal 7 on passivation layer 6, and grid metal 7 fills up the passivation layer 6 of etching, the first barrier layer 8.1 and the The indentation, there on two barrier layers 8.2.
Passivation layer 6 and barrier layer 8 are the medium beyond present invention description, or passivation layer 6 and the choosing of the growth technique of barrier layer 8 Prepared with the method beyond PECVD, LPCVD either present invention such as ALD description or the dry etching of passivation layer 6 is from the present invention Condition and equipment beyond description, the either corrosion of barrier layer 8 are stopped from the condition beyond present invention description or wet etching The corrodible either not corrodible or device architecture of condition of layer 8 is from the device junction beyond the present invention description such as Si bases MOS Structure, or change the pattern of grid, but these changes all should be fallen within the scope of the hereto appended claims.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention All any modification, equivalent and improvement made within refreshing and principle etc., should be included in the scope of the protection.

Claims (9)

1. a kind of low Damage Medium grid, including substrate is followed successively by from top to bottom(1), channel layer(2), barrier layer(3)And passivation layer (6), source metal(4)With leakage metal(5)Positioned at device both sides, grid metal(7)Positioned at source metal(4)With leakage metal(5)Between, it is first First dry etching passivation layer(6)Until barrier layer(3), then in etching position deposit grid metal(7);It is characterized in that:It is described Barrier layer(3)With passivation layer(6)Between be provided with barrier layer(8), as etch stop layer.
A kind of 2. low Damage Medium grid according to claim 1, it is characterised in that the barrier layer(8)For one layer.
A kind of 3. low Damage Medium grid according to claim 1, it is characterised in that the barrier layer(8)For two layers, respectively For the first barrier layer(8.1)With the second barrier layer(8.2).
A kind of 4. low Damage Medium grid according to claim 1 or 3, it is characterised in that the grid metal(7)Through cut-off Passivation layer(6), or grid metal(7)Through cut-off passivation layer(6)And barrier layer(8)Or through cut-off passivation layer(6)With first Barrier layer(8.1).
A kind of 5. low Damage Medium grid according to claim 1, it is characterised in that the passivation layer(6)For Si3N4, stop Layer(8)For Al2O3
A kind of 6. low Damage Medium grid according to claim 3, it is characterised in that first barrier layer(8.1)Thickness d 1 Scope is:1nm≤d1≤10μm.
A kind of 7. low Damage Medium grid according to claim 3, it is characterised in that second barrier layer(8.2)Thickness d 2 Scope is:1nm≤d2≤10μm.
A kind of 8. preparation method of low Damage Medium grid according to any one of claim 1-7, it is characterised in that:Step Including:
(1), with metal organic chemical vapor deposition obtain substrate successively(1), channel layer(2)And barrier layer(3);
(2), deposited by electron beam evaporation obtain source metal(4)With leakage metal(5), and carry out high temperature rapid thermal annealing;
(2), in barrier layer(3)On with atomic layer deposition strategy obtain barrier layer(8);
(3), on barrier layer(8)On with gas ions enhancing chemical vapour deposition technique obtain passivation layer(6);
(4), with dry etching passivation layer(6), and dry etching passivation layer(6)Condition can not etching barrier layer(8);It is or dry Method Etch Passivation(6)Afterwards, rewetting method corrosion barrier layer(8);
(5), deposited by electron beam evaporation obtain grid metal(7), that is, low Damage Medium grid are made.
A kind of 9. preparation method of low Damage Medium grid according to claim 8, it is characterised in that the step(4)In do Method Etch Passivation(6)Method be:Using sense coupling equipment, using sulfur hexafluoride gas formed etc. Gas ions dry method carves passivation layer(6)Si3N4
CN201710335407.3A 2017-05-12 2017-05-12 A kind of low Damage Medium grid and preparation method thereof Pending CN107424919A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108133961A (en) * 2017-12-20 2018-06-08 成都海威华芯科技有限公司 A kind of GaN_HEMT device preparation methods based on aluminum nitride barrier layers
CN108376706A (en) * 2018-01-11 2018-08-07 北京华碳科技有限责任公司 A kind of GaN base HEMT device and its manufacturing method
WO2022052001A1 (en) * 2020-09-10 2022-03-17 苏州晶湛半导体有限公司 Enhanced semiconductor structure and manufacturing method therefor
US20220208992A1 (en) * 2020-12-29 2022-06-30 Vanguard International Semiconductor Corporation Semiconductor device and method of forming the same

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CN101414627A (en) * 2008-12-01 2009-04-22 西安电子科技大学 Insulated gate type source-leakage composite field plate transistor with high electron mobility and preparing method thereof
CN103797581A (en) * 2011-07-18 2014-05-14 埃皮根股份有限公司 Method for growing iii-v epitaxial layers and semiconductor structure
CN105977147A (en) * 2016-07-29 2016-09-28 中国电子科技集团公司第十三研究所 Damage-free automatic-terminating etching method for nano-gate preparation

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CN1906765A (en) * 2004-01-16 2007-01-31 克里公司 Nitride-based transistors with a protective layer and a low-damage recess and methods of fabrication thereof
US20070018199A1 (en) * 2005-07-20 2007-01-25 Cree, Inc. Nitride-based transistors and fabrication methods with an etch stop layer
CN101414627A (en) * 2008-12-01 2009-04-22 西安电子科技大学 Insulated gate type source-leakage composite field plate transistor with high electron mobility and preparing method thereof
CN103797581A (en) * 2011-07-18 2014-05-14 埃皮根股份有限公司 Method for growing iii-v epitaxial layers and semiconductor structure
CN105977147A (en) * 2016-07-29 2016-09-28 中国电子科技集团公司第十三研究所 Damage-free automatic-terminating etching method for nano-gate preparation

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108133961A (en) * 2017-12-20 2018-06-08 成都海威华芯科技有限公司 A kind of GaN_HEMT device preparation methods based on aluminum nitride barrier layers
CN108376706A (en) * 2018-01-11 2018-08-07 北京华碳科技有限责任公司 A kind of GaN base HEMT device and its manufacturing method
WO2022052001A1 (en) * 2020-09-10 2022-03-17 苏州晶湛半导体有限公司 Enhanced semiconductor structure and manufacturing method therefor
US20220208992A1 (en) * 2020-12-29 2022-06-30 Vanguard International Semiconductor Corporation Semiconductor device and method of forming the same
US11450764B2 (en) * 2020-12-29 2022-09-20 Vanguard International Semiconductor Corporation Semiconductor device and method of forming the same

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Application publication date: 20171201