CN107382468A - A kind of coating plants essential oil walks quickly and keeps away planting matrix of insect and preparation method thereof - Google Patents

A kind of coating plants essential oil walks quickly and keeps away planting matrix of insect and preparation method thereof Download PDF

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Publication number
CN107382468A
CN107382468A CN201710621048.8A CN201710621048A CN107382468A CN 107382468 A CN107382468 A CN 107382468A CN 201710621048 A CN201710621048 A CN 201710621048A CN 107382468 A CN107382468 A CN 107382468A
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China
Prior art keywords
essential oil
insect
plant
extraction
stalk
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CN201710621048.8A
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Chinese (zh)
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不公告发明人
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Hefei Xinwen Agricultural Technology Co Ltd
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Hefei Xinwen Agricultural Technology Co Ltd
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Priority to CN201710621048.8A priority Critical patent/CN107382468A/en
Publication of CN107382468A publication Critical patent/CN107382468A/en
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D1/00—Fertilisers containing potassium
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G24/00—Growth substrates; Culture media; Apparatus or methods therefor
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A01N25/10—Macromolecular compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/36—Rutaceae [Rue family], e.g. lime, orange, lemon, corktree or pricklyash
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00—Fertilisers characterised by their form
    • C05G5/30—Layered or coated, e.g. dust-preventing coatings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

Abstract

Planting matrix of insect and preparation method thereof is walked quickly and kept away the invention discloses a kind of coating plants essential oil, is made up of the raw material of following parts by weight：Chinese prickly ash wood leaf 45 ~ 65, the fresh material 20 ~ 30 of other plant tissue, 80% ~ 90% petroleum ether aqueous solution 30 ~ 50, beta cyclodextrin 10 ~ 20, rape stalk 60 ~ 100, peat soil 45 ~ 70, banana skin 20 ~ 35, EM bacteria agent 1 ~ 2, plant ash 5 ~ 10, dry cow dung 40 ~ 50, powdered rice hulls 5 ~ 10, attapulgite 20 ~ 45, vermiculite granule 20 ~ 30, haydite 15 ~ 25, spent pulping liquor 15 ~ 30 and appropriate water.Using matrix structure frame of the stalk as plantation, fermentation of organic material is added, forms loose crop cultivation body, itself has good air permeable effect, has the function that good plant source insect is walked quickly and kept away, has more preferable durability by the essential oil crude extract wrapped.

Description

A kind of coating plants essential oil walks quickly and keeps away planting matrix of insect and preparation method thereof
Technical field
The invention belongs to the technology field of plantation, and in particular to a kind of plantation for being coated with plants essential oil and walking quickly and keeping away insect Matrix and preparation method thereof.
Background technology
Modern agricultural planting is a big Important Economic strategy and policy of various countries, but the disease on thing followed crops The incidence of insect pest also more and more higher, along with the unreasonable use of agricultural chemicals, not only soil, lake and air are by different journeys The influence of degree, the various insects to harm the crops also play the suitable resistance to the action of a drug, chemicals is applied to the difficulty of crops More and more higher is spent, the use of agricultural chemicals, which is more or less in the product of crops, has residual, is detrimental to health, with people couple How valuing for health, make the incidence of pest and disease damage reduce, while reduces the use of chemicals, turns into current unavoidable Major issue.
Before pest and disease damage generation, fundamentally prevent the generation of insect, show the essential oil of pepper wood to evil by research Worm has fabulous effect of walking quickly and keeping away, and pepper wood is Rutaceae xanthoxylum, because pepper wood complete stool has strong pepper fragrance, itself Rare pest and disease damage (only accidental anthracnose and aphid at present), and periphery plant also rare pest and disease damage.But applied to agricultural Aspect, effect is general, one side extract single effect, targetedly can only have effect to some insects, its secondary amounts is less simultaneously And the extraction of essential oil thing of plant is applied to the preventing and treating of insect by the scheme of neither one system, so invention is wanted to add other concentration Insect walks quickly and keeps away plant extracts and pepper wood is used cooperatively, while extends action time and the effect of extract using protective agent.
Studied by the extraction to pepper wood blade, it is found that essential oil contains substantial amounts of expelling parasite, desinsection, sterilization component, wherein Most effective composition is limonene（0.18%）And methyl cinnamate（More than 85%）.There is powerful antibacterial to live for limonene and australene Property, growth, the breeding of a variety of pathogens can be suppressed.There is limonene obvious repellent and poisoning to live to mosquito and other insects Property, australene has cytotoxicity to mosquito.Alpha-terpineol is respectively provided with stronger antibacterial to gram-negative bacteria and gram positive bacteria and lived Property, the synthesis of bacterial nucleic acid and the expression of soluble protein can be suppressed by cell membrane and cell leakage change.Menthol And menthol material has certain repellent effect to aedes albopictus.The acetal compound of citronellal is to Anopheles sinensis, white Line yellow-fever mosquito, Culex pipiens pallens show comparatively ideal repellent activity.
The content of the invention
In order to improve the insect pest effect of cultivation matrix, invention is sprayed using the stalk of crops as carrier on the surface of stalk The derived essential oil of the insect pest effect of plant extract is applied, then is wrapped up with analogs such as cyclodextrin, natural preventive is played and reduces disease pest The effect that evil occurs, realized particular by following method：
A kind of planting matrix for being coated with plants essential oil and walking quickly and keeping away insect, is made up of the raw material of following parts by weight：Chinese prickly ash wood leaf 45 ~ 65, The fresh material 20 ~ 30 of other plant tissue, 80% ~ 90% petroleum ether aqueous solution 30 ~ 50, beta-schardinger dextrin 10 ~ 20, rape stalk 60 ~ 100, Peat soil 45 ~ 70, banana skin 20 ~ 35, EM bacteria agent 1 ~ 2, plant ash 5 ~ 10, dry cow dung 40 ~ 50, powdered rice hulls 5 ~ 10, attapulgite 20 ~ 45, vermiculite granule 20 ~ 30, haydite 15 ~ 25, spent pulping liquor 15 ~ 30 and appropriate water；
The fresh material of other plant tissue is made up of the raw material of following parts by weight：Eucalyptus leaves 10 ~ 15, Mikania micrantha 5 ~ 10, Folium Meliae 20 ~ 30, orange peel 15 ~ 25 and jackfruit pomace 10 ~ 20.
A kind of preparation method for being coated with plants essential oil and walking quickly and keeping away the planting matrix of insect, this method include following steps,
（1）Chinese prickly ash wood leaf and the fresh material of other plant are mixed, dries the material by way of lyophilized, ground 100 ~ 140 mesh sieves, by solid-liquid ratio 1:4 ~ 6 ratio is added portionwise in 80% ~ 90% petroleum ether aqueous solution, passes through ultrasonic cell disruption instrument 5 ~ 10min is acted on, then 45 ~ 65 DEG C of constant temperature stands 2 ~ 3h of extraction, and recovery petroleum ether solvent is evaporated under reduced pressure after the completion of extraction, is obtained Rough extraction of essential oil thing.
（2）Beta-schardinger dextrin and enough water are mixed into saturation, added（1）Described rough extraction of essential oil thing mixes Close, rape stalk rolled into crushings, discharge water 30 ~ 40h of middle immersion, after the completion of drying to water content 30 ~ 45%, be put into foregoing mix Close in liquid, 5 ~ 10 DEG C of low temperature, 15 ~ 25h of placement, after the completion of pull rape stalk out, dried under the conditions of 60 ~ 80 DEG C.
（3）Mixing peat soil, banana skin and other following residual components being not directed to, add EM bacteria agent fermentation maturity, complete Into rear high-temp steam sterilizing and ball milling is into slurry, adds vermiculite granule and haydite, fermentation slurry is wrapped in particle table after stirring Face.
（4）Finally will（2）The stalk in（3）Gained compound mixes, and keeps water content 30 ~ 40%.
By testing and screening, using pepper wood leaf as major ingredient, it is auxiliary incidentally to add some plant tissues rich in insect resistace Material：Eucalyptus leaves, Mikania micrantha, Folium Meliae, orange peel and jackfruit pomace composition, are freezed, ground 80 ~ 120 mesh by low-temp low-pressure The powder of sieve, the granularity of material is smaller, the progress of easier extraction process, then by the powder of grinding and organic solvent 80% ~ The 90% petroleum ether aqueous solution presses solid-liquid ratio 1:After 4 ~ 6 ratio mixing, 5 ~ 10min is acted in ultrasonic cell disruption instrument, it is permanent 45 ~ 65 DEG C of temperature stands 2 ~ 3h of extraction, is evaporated under reduced pressure recovery petroleum ether using Rotary Evaporators after the completion of extraction, petroleum ether solvent can Reuse.For solvent while extraction essential oil, other active components of plants also can be by a certain degree of extraction, other Material includes some terpenoids, derivative of fatty acid, alkaloid, flavone compound and nitrogen-containing compound indoles etc., While by ultrasonic disruption, cell release content, the progress of extraction step is preferably carried out.The extract so obtained Essential oil not only containing emphasis of the present invention extraction, the cell extract of various fresh plant tissues is also included, improve crop to evil Worm walks quickly and keeps away effect, while is advantageous to the growth of plant.
Although the Extracts from Plant Recourses of extraction has good repellent effect to insect more than, belongs to organic matter after all Category, itself belong to the material of structure class, once destructurized, its due effect can also be affected, particularly one Denier is exposed in natural environment, it is easy to is neutralized by rugged environment, most importantly this extract is a kind of to walk quickly and keep away Reach insect-pest effect, if its action effect effective time under natural environment is too short, estimated effect well will not had Fruit, thus invention by it using the stalk of crops as carrier, be made a kind of matrix of plantation, rather than fertilizer directly applies fertilizer like that Mode is shed in big field.
Allow extract to be lumped together with the matrix planted, crop field or nursery are together discharged into itself as a unit Or the preparation in small sections of a vegetable plot, because prior plant extracts is just blended with matrix, belong to the combination of unified system, so less Can be by environment too much influence.Invention is coated with the essence oil lamp vegetable active extract of extraction using beta-schardinger dextrin as coating agent, Its action time and effect can preferably be played.
The object fixed using stalk as extraction of essential oil liquid and beta-schardinger dextrin mixing and absorption, one side stalk belong to organic Matter, it will not be polluted when as planting matrix, while stalk short texture, the reservoir storage under dampness is high, After suctioning extraction of essential oil liquid and beta-schardinger dextrin mixed liquor, extraction of essential oil thing is just fixed in drying process, and last stalk can be made For the structure-steel framing of matrix, keep matrix to breathe freely, prevent hardened, prevent that germ and pest and disease damage are also of great advantage for matrix.
Beneficial effects of the present invention：Using matrix structure frame of the stalk as plantation, fermentation of organic material is added, is formed loose Crop cultivation body, can be as nursery, small sections of a vegetable plot or potted plant planting matrix, itself have good air permeable effect, simultaneously Plant extract extraction of essential oil composition is secured using beta-schardinger dextrin as parcel composition in the inside of stalk and surface, is had good The effect that plant source insect is walked quickly and kept away, there is more preferable durability by the essential oil crude extract wrapped.
Embodiment
Embodiment 1
A kind of planting matrix for being coated with plants essential oil and walking quickly and keeping away insect, by following weight（Kg）Raw material be made：Chinese prickly ash wood leaf 50, its The fresh material 25 of his plant tissue, 80% ~ 90% petroleum ether aqueous solution 40, beta-schardinger dextrin 15, rape stalk 75, peat soil 55, banana skin 25th, EM bacteria agent 1, plant ash 8, dry cow dung 45, powdered rice hulls 6, attapulgite 30, vermiculite granule 25, haydite 20, the and of spent pulping liquor 20 Appropriate water；
The fresh material of other plant tissue is by following weight（Kg）Raw material be made：Eucalyptus leaves 12, Mikania micrantha 8, Folium Meliae 26, tangerine Skin 20 and jackfruit pomace 15.
A kind of preparation method for being coated with plants essential oil and walking quickly and keeping away the planting matrix of insect, this method include following steps,
（1）Chinese prickly ash wood leaf and the fresh material of other plant are mixed, the material, ground 120 mesh are dried by way of lyophilized Sieve, by solid-liquid ratio 1:5 ratio is added portionwise in the 80% petroleum ether aqueous solution, acts on 6min by ultrasonic cell disruption instrument, so 50 DEG C of constant temperature stands extraction 3h afterwards, and recovery petroleum ether solvent is evaporated under reduced pressure after the completion of extraction, obtains rough extraction of essential oil thing.
（2）Beta-schardinger dextrin and enough water are mixed into saturation, added（1）Described rough extraction of essential oil thing mixes Close, rape stalk rolled into crushings, discharge water middle immersion 35h, after the completion of drying to water content 30%, be put into foregoing mixed liquor, 6 DEG C of low temperature placement 20h, after the completion of pull rape stalk out, dried under the conditions of 60 DEG C.
（3）Mixing peat soil, banana skin and other following residual components being not directed to, add EM bacteria agent fermentation maturity, complete Into rear high-temp steam sterilizing and ball milling is into slurry, adds vermiculite granule and haydite, fermentation slurry is wrapped in particle table after stirring Face.
（4）Finally will（2）The stalk in（3）Gained compound mixes, and keeps water content 30%.
Test group is set, the coating plants essential oil of the present invention is walked quickly and kept away to system of the planting matrix for shepherd's purse nursery of insect It is standby, matrix is laid on the table soil of small sections of a vegetable plot, 5 ~ 10cm of thickness.
Control group is set, in the planting matrix used, the unlocked rough extraction of essential oil thing of stalk of addition, other compositions It is consistent with the matrix of the present invention with preparation method, management all same of the later stage for shepherd's purse.
As a result：The shepherd's purse pest and disease damage incidence of test group plantation is low, and continuation is good, examines the quality of plantation shepherd's purse, examination It is more preferable to test the nutrient of group, is not detected by residues of pesticides, it is more healthy.

Claims (2)

  1. A kind of 1. planting matrix for being coated with plants essential oil and walking quickly and keeping away insect, it is characterised in that：It is made up of the raw material of following parts by weight：Flower Green pepper wood leaf 45 ~ 65, the fresh material 20 ~ 30 of other plant tissue, 80% ~ 90% petroleum ether aqueous solution 30 ~ 50, beta-schardinger dextrin 10 ~ 20, rape Stalk 60 ~ 100, peat soil 45 ~ 70, banana skin 20 ~ 35, EM bacteria agent 1 ~ 2, plant ash 5 ~ 10, dry cow dung 40 ~ 50, powdered rice hulls 5 ~ 10th, attapulgite 20 ~ 45, vermiculite granule 20 ~ 30, haydite 15 ~ 25, spent pulping liquor 15 ~ 30 and appropriate water；
    The fresh material of other plant tissue is made up of the raw material of following parts by weight：Eucalyptus leaves 10 ~ 15, Mikania micrantha 5 ~ 10, Folium Meliae 20 ~ 30, orange peel 15 ~ 25 and jackfruit pomace 10 ~ 20.
  2. 2. a kind of preparation method for being coated with plants essential oil and walking quickly and keeping away the planting matrix of insect, its feature exist according to claim 1 In：This method includes following steps,
    （1）Chinese prickly ash wood leaf and the fresh material of other plant are mixed, dries the material by way of lyophilized, ground 100 ~ 140 mesh sieves, by solid-liquid ratio 1:4 ~ 6 ratio is added portionwise in 80% ~ 90% petroleum ether aqueous solution, passes through ultrasonic cell disruption instrument 5 ~ 10min is acted on, then 45 ~ 65 DEG C of constant temperature stands 2 ~ 3h of extraction, and recovery petroleum ether solvent is evaporated under reduced pressure after the completion of extraction, is obtained Rough extraction of essential oil thing；
    （2）Beta-schardinger dextrin and enough water are mixed into saturation, added（1）Described rough extraction of essential oil thing mixing, will Rape stalk rolls crushing, and discharge water 30 ~ 40h of middle immersion, after the completion of dry to water content 30 ~ 45%, be put into foregoing mixed liquor In, 5 ~ 10 DEG C of low temperature, 15 ~ 25h of placement, after the completion of pull rape stalk out, dried under the conditions of 60 ~ 80 DEG C；
    （3）Mixing peat soil, banana skin and other following residual components being not directed to, add EM bacteria agent fermentation maturity, after the completion of Simultaneously ball milling into slurry, adds vermiculite granule and haydite, fermentation slurry is wrapped in particle surface after stirring high-temp steam sterilizing；
    （4）Finally will（2）The stalk in（3）Gained compound mixes, and keeps water content 30 ~ 40%.
CN201710621048.8A 2017-07-27 2017-07-27 A kind of coating plants essential oil walks quickly and keeps away planting matrix of insect and preparation method thereof Withdrawn CN107382468A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109479666A (en) * 2018-11-21 2019-03-19 安徽泓森高科林业股份有限公司 A kind of seedling medium of the leaf containing chinaberry and preparation method thereof
CN112979219A (en) * 2021-03-16 2021-06-18 浙江理工大学 Porous carbon fiber material with photo-thermal and joule-thermal essential oil controlled release functions and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103613468A (en) * 2013-11-25 2014-03-05 青岛东颐锦禾农业科技有限公司 Preparation method of vegetable seedling raising matrix
CN105993682A (en) * 2016-05-23 2016-10-12 合肥信文农业科技有限公司 Sweet cherry seedling transplanting antibacterial seedling-strengthening substrate, and preparation method thereof
CN106007966A (en) * 2016-05-23 2016-10-12 合肥信文农业科技有限公司 Nanometer reinforced seaweed culture medium capable of improving red kiwi fruit transplantation survival rate and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103613468A (en) * 2013-11-25 2014-03-05 青岛东颐锦禾农业科技有限公司 Preparation method of vegetable seedling raising matrix
CN105993682A (en) * 2016-05-23 2016-10-12 合肥信文农业科技有限公司 Sweet cherry seedling transplanting antibacterial seedling-strengthening substrate, and preparation method thereof
CN106007966A (en) * 2016-05-23 2016-10-12 合肥信文农业科技有限公司 Nanometer reinforced seaweed culture medium capable of improving red kiwi fruit transplantation survival rate and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109479666A (en) * 2018-11-21 2019-03-19 安徽泓森高科林业股份有限公司 A kind of seedling medium of the leaf containing chinaberry and preparation method thereof
CN112979219A (en) * 2021-03-16 2021-06-18 浙江理工大学 Porous carbon fiber material with photo-thermal and joule-thermal essential oil controlled release functions and preparation method thereof
CN112979219B (en) * 2021-03-16 2022-08-23 浙江理工大学 Porous carbon fiber material with photo-thermal and joule-thermal essential oil controlled release functions and preparation method thereof

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