CN107382327A - 陶瓷3d打印浆料的制备及应用 - Google Patents

陶瓷3d打印浆料的制备及应用 Download PDF

Info

Publication number
CN107382327A
CN107382327A CN201710849400.3A CN201710849400A CN107382327A CN 107382327 A CN107382327 A CN 107382327A CN 201710849400 A CN201710849400 A CN 201710849400A CN 107382327 A CN107382327 A CN 107382327A
Authority
CN
China
Prior art keywords
ceramic
preparation
hours
premixed liquid
added
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710849400.3A
Other languages
English (en)
Other versions
CN107382327B (zh
Inventor
周宏志
邢占文
戴宪光
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SUZHOU JIANGNAN JIAJIE ELECTROMECHANICAL TECHNOLOGY RESEARCH INSTITUTE Co Ltd
Z RAPID TECHNOLOGIES Co Ltd
Suzhou Academy of Xian Jiaotong University
Original Assignee
SUZHOU JIANGNAN JIAJIE ELECTROMECHANICAL TECHNOLOGY RESEARCH INSTITUTE Co Ltd
Z RAPID TECHNOLOGIES Co Ltd
Suzhou Academy of Xian Jiaotong University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SUZHOU JIANGNAN JIAJIE ELECTROMECHANICAL TECHNOLOGY RESEARCH INSTITUTE Co Ltd, Z RAPID TECHNOLOGIES Co Ltd, Suzhou Academy of Xian Jiaotong University filed Critical SUZHOU JIANGNAN JIAJIE ELECTROMECHANICAL TECHNOLOGY RESEARCH INSTITUTE Co Ltd
Priority to CN201710849400.3A priority Critical patent/CN107382327B/zh
Publication of CN107382327A publication Critical patent/CN107382327A/zh
Application granted granted Critical
Publication of CN107382327B publication Critical patent/CN107382327B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/632—Organic additives
    • C04B35/634—Polymers
    • C04B35/63404—Polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B35/63424—Polyacrylates; Polymethacrylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00—Materials specially adapted for additive manufacturing
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/447—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on phosphates, e.g. hydroxyapatite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/602—Making the green bodies or pre-forms by moulding
    • C04B2235/6026—Computer aided shaping, e.g. rapid prototyping

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Composite Materials (AREA)
  • Producing Shaped Articles From Materials (AREA)

Abstract

本发明涉及增材制造技术领域，本发明公开了一种陶瓷3D打印浆料的制备及应用，首先，将质量百分比为单体的1.5～3%光引发剂加入到丙烯酸酯单体中，磁力搅拌分散使其完全溶解得到预混液1；其次，将质量百分比为陶瓷粉末的0.3～2%分散剂加入到预混液1后，将质量百分比含量70～85%的陶瓷粉末加入，球磨1～3小时，全部粉末加入后球磨6小时，使各组分混合均匀，获得预混液2；最后，将质量百分比0.5～2%的触变剂加入预混液2,磁力搅拌0.5～2小时,静置2～4小时，得到陶瓷浆料。本发明能够实现陶瓷浆料的输送、刮平，并最终实现致密度高的陶瓷制品制备。

Description

陶瓷3D打印浆料的制备及应用
技术领域
本发明涉及增材制造技术领域，具体涉及一种陶瓷3D打印浆料的制备及应用。
背景技术
陶瓷材料具有强度高、耐磨、耐腐蚀等优异性能，在航空航天、石油化工、生物医用等领域应用广泛。传统的成形工艺是开模后将陶瓷浆料干燥成为坯体，再进行高温烧结得到陶瓷制品。这种成形方法受开模限制，制约陶瓷制品复杂化的发展。
近年来发展的各种3D打印成形技术使陶瓷成形实现了无模化生产。其中，1990年代中期法国利摩日大学开发了针对陶瓷坯体的光固化3D打印成形工艺，将单体、光引发剂、分散剂、陶瓷粉末配置成粘度较低、固含量较高的浆料，基于光固化成形设备利用紫外光引发单体发生聚合反应，固化形成陶瓷坯体，再经过后续脱脂和烧结获得最终的陶瓷制品。该成形工艺能够获得致密度高、结构复杂的陶瓷制品，成为陶瓷3D打印成形的代表性工作。
国内对于陶瓷工件光固化3D打印所用陶瓷浆料方面，西安交通大学的李涤尘等人开发了亚甲基双丙烯酸胺、分散剂、光引发剂制备的水基光固化陶瓷浆料，并借助振镜驱动的激光束完成每个陶瓷样品切面的快速成形。结合其设备的成形能力，该类浆料粘度较小，固含量较低。而较低的固含量将对最终陶瓷工件的致密度和强度带来影响，因此该类浆料不能满足高质量陶瓷坯体的制造需求。
当提高陶瓷浆料固含量之后，其粘度较大，在3D打印过程中容易造成局部缺损或模型发生损坏。因此，如何获得固含量相对较高、流动性较好的陶瓷浆料，成为提高光固化3D打印陶瓷制品质量、拓展其应用领域的关键。
发明内容
为解决上述技术问题，我们提出了一种陶瓷3D打印浆料的制备及应用，通过在浆料中添加一定量的触变剂，将高固含量陶瓷浆料的粘度调节至合适范围，以利于进行光固化成形，同时保证最终烧结致密度和强度要求。
为达到上述目的，本发明的技术方案如下：
陶瓷3D打印浆料的制备，其包括如下步骤：
首先，将质量百分比为单体的1.5～3%光引发剂加入到丙烯酸酯单体中，磁力搅拌分散使其完全溶解得到预混液1；其次，将质量百分比为陶瓷粉末的0.3～2%分散剂加入到预混液1后，将质量百分比含量70～85%的陶瓷粉末分成多等份逐次加入，每次球磨1～3小时，全部粉末加入后球磨6小时，使各组分混合均匀，获得预混液2；最后，将质量百分比0.5～2%的触变剂加入预混液2,磁力搅拌0.5～2小时,静置2～4小时，得到陶瓷浆料。
优选的，所述陶瓷粉末是Al2O3、ZrO2、HAP、TCP中一种。
优选的，所述光引发剂是光引发剂184和光引发剂651中任一个。
优选的，所述分散剂是分散剂655和分散剂670中任一个。
优选的，所述触变剂是触变剂BYK410。
为了实现上述目的，本发明还提出了一种陶瓷3D打印浆料的制备应用，其具体包括如下：
1)将CAD三维陶瓷部件模型导入陶瓷3D打印机进行分层处理，并将上述陶瓷浆料置于料槽中，采用光固化成形方法制备陶瓷坯体；
2)将上述制备陶瓷坯体脱脂、烧结：其中脱脂要求温度为450～600度，保温1.5～3小时；其中烧结要求温度为1250～1650度，保温1.5～3小时，制得陶瓷制品。
通过上述技术方案，本发明以弥补现有陶瓷3D打印浆料的不足为目的，通过添加合适比例的触变剂，使高固含量的浆料具备恰当触变性，使之在光固化成形过程中能够实现陶瓷浆料的输送、刮平，并最终实现致密度高的陶瓷制品制备。
附图说明
为了更清楚地说明本发明实施例的技术方案，下面将对实施例描述中所需要使用的附图作简单地介绍，显而易见地，下面描述中的附图仅仅是本发明的一些实施例，对于本领域普通技术人员来讲，在不付出创造性劳动的前提下，还可以根据这些附图获得其他的附图。
图1为本发明实施例所公开的一种陶瓷3D打印浆料的制备及应用的流程图。
具体实施方式
下面将结合本发明实施例中的附图，对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
下面结合示意图对本发明的具体实施方式作进一步详细的说明。
参照图1，陶瓷3D打印浆料的制备及应用的流程图
1）制备陶瓷浆料：首先，将质量百分比为单体的1.5～3%光引发剂加入到丙烯酸酯单体中，磁力搅拌分散使其完全溶解得到预混液1；其次，将质量百分比为陶瓷粉末的0.3～2%分散剂加入到预混液1后，将质量百分比含量70～85%的陶瓷粉末分成多等份逐次加入，每次球磨1～3小时，全部粉末加入后球磨6小时，使各组分混合均匀，获得预混液2；最后，将质量百分比0.5～2%的触变剂加入预混液2,磁力搅拌0.5～2小时,静置2～4小时，得到陶瓷浆料；
2)将CAD三维陶瓷部件模型导入陶瓷3D打印机进行分层处理，并将上述陶瓷浆料置于料槽中，采用光固化成形方法制备陶瓷坯体；
3)将上述制备陶瓷坯体脱脂、烧结：其中脱脂要求温度为450～600度，保温1.5～3小时；其中烧结要求温度为1250～1650度，保温1.5～3小时，制得陶瓷制品。
实施例1
陶瓷3D打印浆料的制备及应用按以下步骤进行：
（1）制备陶瓷浆料
将1g光引发剂184加入到50g丙烯酸酯单体中，磁力搅拌分散使其完全溶解得到预混液1；
其次，将2.4g分散剂655加入到预混液1后，将260g Al2O3陶瓷粉末分成多等份，逐次加入，每次球磨1小时，全部粉末加入后球磨6小时，使各组分混合均匀，获得预混液2；
最后，将3.1g触变剂BYK410加入预混液2,磁力搅拌1小时,静置2小时得到陶瓷浆料。
（2）将CAD三维陶瓷部件模型导入陶瓷3D打印机进行分层处理，并将上述陶瓷浆料置于料槽中，采用光固化成形方法制备陶瓷坯体；
（3）脱脂：温度为550度，保温1.5小时；
（4）烧结：温度为1650度，保温1.5小时，制得陶瓷制品。
实施例2
陶瓷3D打印浆料的制备及应用按以下步骤进行：
（1）制备陶瓷浆料
将0.75g光引发剂651加入到50g丙烯酸酯单体中，磁力搅拌分散使其完全溶解得到预混液1；
其次，将2g分散剂670加入到预混液1后，将200g ZrO2陶瓷粉末分成多等份，逐次加入，每次球磨2小时，全部粉末加入后球磨6小时，使各组分混合均匀，获得预混液2；
最后，将1.25g触变剂BYK410加入预混液2,磁力搅拌1.5小时,静置2小时，得到陶瓷浆料。
（2）将CAD三维陶瓷部件模型导入陶瓷3D打印机进行分层处理，并将上述陶瓷浆料置于料槽中，采用光固化成形方法制备陶瓷坯体；
（3）脱脂：温度为550度，保温2小时；
（4）烧结：温度为1450度，保温2小时，制得陶瓷制品。
实施例3
陶瓷3D打印浆料的制备及应用按以下步骤进行：
（1）制备陶瓷浆料
将1.4g光引发剂651加入到70g丙烯酸酯单体中，磁力搅拌分散使其完全溶解得到预混液1；
其次，将6.3g分散剂670加入到预混液1后，将210g HAP或TCP陶瓷粉末分成多等份，逐次加入，每次球磨2小时，全部粉末加入后球磨6小时，使各组分混合均匀，获得预混液2；
最后，将4.9g触变剂BYK410加入预混液2,磁力搅拌2小时,静置2小时，得到陶瓷浆料。
（2）将CAD三维陶瓷部件模型导入陶瓷3D打印机进行分层处理，并将上述陶瓷浆料置于料槽中，采用光固化成形方法制备陶瓷坯体；
（3）脱脂：温度为600度，保温3小时；
（4）烧结：温度为1450度，保温3小时，制得陶瓷制品。
以上所述的仅是本发明的优选实施方式，应当指出，对于本领域的普通技术人员来说，在不脱离本发明创造构思的前提下，还可以做出若干变形和改进，这些都属于本发明的保护范围。

Claims (7)

1.陶瓷3D打印浆料的制备，其特征在于，其包括如下步骤：首先，将质量百分比为单体的1.5～3%光引发剂加入到丙烯酸酯单体中，磁力搅拌分散使其完全溶解得到预混液1；其次，将质量百分比为陶瓷粉末的0.3～2%分散剂加入到预混液1后， 将质量百分比含量70～85%的陶瓷粉末分成多等份，逐次加入，每次球磨1～3小时，全部粉末加入后球磨6小时，使各组分混合均匀，获得预混液2；最后，将质量百分比0.5～2%的触变剂加入预混液2,磁力搅拌0.5～2小时,静置2～4小时，得到陶瓷浆料。
2.根据权利要求1所述的陶瓷3D打印浆料的制备，其特征在于，所述陶瓷粉末为Al2O3、ZrO2、HAP、TCP中一种。
3.根据权利要求1所述的陶瓷3D打印浆料的制备，其特征在于，所述光引发剂是光引发剂184、光引发剂651中一种。
4.根据权利要求1所述的陶瓷3D打印浆料的制备，其特征在于，所述分散剂是分散剂655、分散剂670中一种。
5.根据权利要求1所述的陶瓷3D打印浆料的制备，其特征在于，所述触变剂是触变剂BYK410。
6.根据权利要求1-5所述的陶瓷3D打印浆料的应用，其应用于3D打印机上制备陶瓷制品，其特征在于，其包括如下步骤：
将CAD三维陶瓷部件模型导入3D打印机进行分层处理，并将上述陶瓷浆料置于料槽中，采用光固化成形方法制备陶瓷坯体；
将上述制备陶瓷胚体脱脂、烧结：其中脱脂要求温度为450～600度，保温1.5～3小时；其中烧结要求温度为1250～1650度，保温1.5～3小时，制得陶瓷制品。
7.根据权利要求6所述的陶瓷3D打印浆料的应用，其特征在于，所述3D打印机是陶瓷3D打印机。
CN201710849400.3A 2017-09-20 2017-09-20 陶瓷3d打印浆料的制备及应用 Active CN107382327B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710849400.3A CN107382327B (zh) 2017-09-20 2017-09-20 陶瓷3d打印浆料的制备及应用

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710849400.3A CN107382327B (zh) 2017-09-20 2017-09-20 陶瓷3d打印浆料的制备及应用

Publications (2)

Publication Number Publication Date
CN107382327A true CN107382327A (zh) 2017-11-24
CN107382327B CN107382327B (zh) 2020-02-21

Family

ID=60350932

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710849400.3A Active CN107382327B (zh) 2017-09-20 2017-09-20 陶瓷3d打印浆料的制备及应用

Country Status (1)

Country Link
CN (1) CN107382327B (zh)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109535333A (zh) * 2018-10-11 2019-03-29 南方科技大学 一种光敏树脂及其制备方法和陶瓷浆料、3d打印制品
CN110304930A (zh) * 2019-07-29 2019-10-08 中国科学院空间应用工程与技术中心 一种用于微重力环境制造使用的软物质材料及其制备方法
CN110330329A (zh) * 2019-04-03 2019-10-15 武汉理工大学 一种用于立体光刻成型的触变性陶瓷膏体材料及其制备方法
CN113208750A (zh) * 2021-05-15 2021-08-06 江苏京科智镕新材料科技有限公司 基于立体光刻3d打印的透光性渐变牙冠及制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105198449A (zh) * 2015-09-16 2015-12-30 广东工业大学 一种光固化成型的高致密陶瓷的制备方法
CN105837216A (zh) * 2016-03-22 2016-08-10 西安铂力特激光成形技术有限公司 一种陶瓷零件的制备方法
CN106278201A (zh) * 2016-08-27 2017-01-04 景德镇陶瓷大学 一种直接成型3d陶瓷打印用瘠性陶瓷粉体浆料及其制备方法和应用
US20170107388A1 (en) * 2015-10-19 2017-04-20 Electronics For Imaging, Inc. Radiation-curable inkjet ink for application to glass, ceramic, or metal
CN107382312A (zh) * 2017-07-11 2017-11-24 宁波匠心快速成型技术有限公司 一种3d打印用陶瓷浆料的制备方法及其3d打印成型方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105198449A (zh) * 2015-09-16 2015-12-30 广东工业大学 一种光固化成型的高致密陶瓷的制备方法
US20170107388A1 (en) * 2015-10-19 2017-04-20 Electronics For Imaging, Inc. Radiation-curable inkjet ink for application to glass, ceramic, or metal
CN105837216A (zh) * 2016-03-22 2016-08-10 西安铂力特激光成形技术有限公司 一种陶瓷零件的制备方法
CN106278201A (zh) * 2016-08-27 2017-01-04 景德镇陶瓷大学 一种直接成型3d陶瓷打印用瘠性陶瓷粉体浆料及其制备方法和应用
CN107382312A (zh) * 2017-07-11 2017-11-24 宁波匠心快速成型技术有限公司 一种3d打印用陶瓷浆料的制备方法及其3d打印成型方法

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109535333A (zh) * 2018-10-11 2019-03-29 南方科技大学 一种光敏树脂及其制备方法和陶瓷浆料、3d打印制品
CN110330329A (zh) * 2019-04-03 2019-10-15 武汉理工大学 一种用于立体光刻成型的触变性陶瓷膏体材料及其制备方法
CN110330329B (zh) * 2019-04-03 2022-06-03 武汉理工大学 一种用于立体光刻成型的触变性陶瓷膏体材料及其制备方法
CN110304930A (zh) * 2019-07-29 2019-10-08 中国科学院空间应用工程与技术中心 一种用于微重力环境制造使用的软物质材料及其制备方法
CN113208750A (zh) * 2021-05-15 2021-08-06 江苏京科智镕新材料科技有限公司 基于立体光刻3d打印的透光性渐变牙冠及制备方法

Also Published As

Publication number Publication date
CN107382327B (zh) 2020-02-21

Similar Documents

Publication Publication Date Title
CN107382327A (zh) 陶瓷3d打印浆料的制备及应用
CN107129283A (zh) 一种光固化3d打印用高固相含量陶瓷浆料及其制备工艺
CN103881461B (zh) 彩色腻子粉及其制备方法
CN107540352A (zh) 3d打印氧化铝增韧陶瓷浆料的制备及应用
CN104002061B (zh) 一种高性能高稳定纳米焊锡膏及其制备方法
CN108275979B (zh) 一种用于光固化3d打印的陶瓷材料、陶瓷件及其制备方法
CN107573007A (zh) 硫氧镁胶凝材料工艺品的制备方法及硫氧镁胶凝材料
CN106278201A (zh) 一种直接成型3d陶瓷打印用瘠性陶瓷粉体浆料及其制备方法和应用
CN110128116A (zh) 一种光固化用陶瓷浆料及其制备方法
CN102321421A (zh) 一种皱纹粉末涂料
CN106747523A (zh) 低铁莫来石砖及其制造方法
CN110483008A (zh) 一种用于光固化3d打印陶瓷的浆料及其陶瓷产品制备方法
CN104803619A (zh) 地质聚合物组合物及地质聚合物材料
CN105731960A (zh) 一种石膏基砂浆
CN107352999A (zh) 一种3d打印用无机物粉末激光烧结性能的模拟测试方法
CN111635156A (zh) 一种3d打印建筑材料骨料的制备方法
CN106810268A (zh) 一种基于选择性激光烧结的陶瓷3d打印材料及其制备方法
CN102942377A (zh) 一种改性膨润土陶瓷坯体增强剂及其制作方法和使用方法
CN101204830B (zh) 用于陶瓷注浆成型的改进的石膏模具及其制作方法
CN115925421B (zh) 一种光固化3d打印的力致发光陶瓷及其制备方法与应用
CN108503360B (zh) Lsm块体材料的制备方法
JP2021133667A (ja) 積層造形用水硬性組成物及びその製造方法、積層体及びその製造方法、並びに二液型水硬性材料
CN103421415A (zh) 一种通过紫外光固化的亲水铝箔涂料及其制备方法
IT201800020080A1 (it) Miscela cementizia per stampante 3D, a prestazioni migliorate, e relativo uso in detta stampante
CN105016725A (zh) 一种陶瓷插芯专用陶瓷颗粒及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB02 Change of applicant information
CB02 Change of applicant information

Address after: 215223 No. 13 Tongan West Road, Wujiang District, Jiangsu, Suzhou

Applicant after: Suzhou Zhong Rui Zhi Chuang 3D Polytron Technologies Inc

Applicant after: Suzhou Jiangnan Jiajie Electromechanical Technology Research Institute Co., Ltd.

Applicant after: Suzhou Academy of Xi'an Jiaotong University

Address before: 215223 No. 13 Tongan West Road, Wujiang District, Jiangsu, Suzhou

Applicant before: Z Rapid Technologies Co., Ltd.

Applicant before: Suzhou Jiangnan Jiajie Electromechanical Technology Research Institute Co., Ltd.

Applicant before: Suzhou Academy of Xi'an Jiaotong University

GR01 Patent grant
GR01 Patent grant