CN107348512A - It is a kind of to avoid rare sugar method of easy caramelization and overgenerous Maillard reaction in food processing - Google Patents

It is a kind of to avoid rare sugar method of easy caramelization and overgenerous Maillard reaction in food processing Download PDF

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Publication number
CN107348512A
CN107348512A CN201710670095.1A CN201710670095A CN107348512A CN 107348512 A CN107348512 A CN 107348512A CN 201710670095 A CN201710670095 A CN 201710670095A CN 107348512 A CN107348512 A CN 107348512A
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Prior art keywords
caramelization
rare
food processing
overgenerous
easy
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方明
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Hefei Cambridge Trade Ltd Co
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Hefei Cambridge Trade Ltd Co
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Priority to CN201710670095.1A priority Critical patent/CN107348512A/en
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/10Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
    • A23L33/125Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives containing carbohydrate syrups; containing sugars; containing sugar alcohols; containing starch hydrolysates
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Mycology (AREA)
  • Nutrition Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)

Abstract

The present invention provides the method for avoiding rare sugar that caramelization and Maillaid braun reaction easily occur in food processing.Present invention sodium alginate bonds PURE WHEY and rare sugar, forms particle, is protected glycoprotein structure, high temperature resistant so that rare sugar can avoid easy caramelization and overgenerous Maillard reaction during food processing and storage.One layer of sodium alginate, trehalose, calcium lactate film are coated again in particle surface in addition, calcium lactate improves the intensity of sodium alginate, prevent in premature collapse, L arabinoses or Tagatose can be transported to specified intestines and stomach, in the presence of human body acid, rapid disintegration, discharges L arabinoses or Tagatose, blocks absorption of the human body to sucrose, glucose.The cladding of outer layer strengthens rare sugared protective effect, can both prevent caramelization at low temperature, can bear more than 200 DEG C of high temperature again, resist the performance enhancement of Maillaid braun reaction.

Description

One kind avoids rare sugar easy caramelization and overgenerous U.S. in food processing The method of Maillard reaction
Technical field
The present invention relates to food processing field, more particularly to one kind to avoid rare sugar caramelization easy in food processing With the method for overgenerous Maillard reaction.
Background technology
With the development of science and technology, rare sugar is more and more applied to make functional food processing, such as dieletic foodstuff, subtract Fertile food etc..L-arabinose therein, Tagatose are approved as new resource food via defending planning commission(New raw-food material), its The distinctive function of blocking sucrose and glucose absorption, more and more applied to dieletic foodstuff, weight reduction product.L- is Arabic The most representational physiological action of sugar is selectively to influence the invertase in small intestine, so as to suppress the absorption of sucrose.According to report Road, 2% L-arabinose is added in sucrose, the absorption of 40% sucrose can be suppressed, while blood glucose value is lacked rise about 50%.Tagatose have lower calorific value, zero glycemic index, blood glucose passivation, without carious tooth, prebiotic function and antioxygen Change the excellent nutritive peculiarities such as activity.
But overgenerous Maillard reaction easily occurs for L-arabinose, caramelization and mistake easily occur for Tagatose In strong Maillard reaction.With Tagatose caramelization and overgenerous Maillard reaction easily occur for L-arabinose, Cause product brown stain to have influence on the quality of product, make cold working food under normal temperature, caramelization will occur after one day --- Change colour, gradually become partially red, Maillard reaction more serious-brown stain in hot-working, quickly become dark brown, this results in heat The product of processing is also under-done, and surface color is not in continuation.
The second phase positive phoenix Liu Xing honor of primary track occasion Lv of volume 37 in 2011 is kindly helped secure the success of written by good fortune《The more recent application of L-arabinose is entered Exhibition》) in 2_1.5L- arabinoses in bakery using " ... in addition, due to L-arabinose Maillard reaction it is strong ' Will be influenceed after addition baked product flavor and color ' therefore need to study related process and formula, to balance L- Arab The influence of the overgenerous Maillard reaction of sugar.
Tagatose (D- Tagatose) is a kind of naturally occurring rare monose, is the ketose form of galactolipin, fructose Epimer.Sweet taste characteristic is similar to sucrose, and caused heat is only 1/3rd of sucrose, so being referred to as low Caloric sweeteners.Tagatose have lower calorific value, zero glycemic index, blood glucose passivation, without carious tooth, prebiotics make With with the excellent nutritive peculiarity such as antioxidation activity, glass transition temperature 15 DEG C relatively stable to heat, easily crystallization, hygroscopicity is low, protects It is moist strong.Acid resistance is strong, stable in the range of pH2 ~ 7.Caramelization and Maillaid braun reaction easily occurs.Natural tower lattice Sugar is primarily present in the dairy products such as yogurt, milk powder.
Sodium alginate is that the accessory substance after iodine and mannitol is extracted from the sea-tangle or sargassum of brown algae, its molecule by Beta-D-mannuronic acid(β-D-mannuronic, M)With α-L- guluronic acids(α-L-guluronic, G)Press(1→4)Key connects Connect and form, be a kind of natural polysaccharide, there is stability, dissolubility, viscosity and security needed for pharmaceutical preparation auxiliary material.Alginic acid Sodium is widely applied in food industry and field of medicaments.
Sodium alginate is used as the adhesive of tablet, and alginic acid is used as the disintegrant of fast-release tablet.However, sodium alginate is to piece The influence of agent property depends in prescription the amount being put into, and in some cases, sodium alginate can promote the disintegration of tablet.Sea Mosanom can add during granulation, rather than add in the form of a powder after granulation, and such manufacturing process is simpler It is single.Compared with using starch, made mechanical strength in blocks is bigger.
Whey protein powder is the precious protein come out using advanced technologies from milk separation and Extraction, with its purity it is high, Absorptivity is high, amino acid forms most reasonable etc. many advantages and pushed away as " king of albumen ".
Lactalbumin not only easily digests, but also has high biological value, efficient rate, high protein effect ratio and usury It is the fine work in protein with rate.In all essential amino acids containing needed by human body, its amino acid compositional model and skeletal muscle Amino acid compositional model it is almost completely the same, extremely easily absorbed by human body.
Calcium lactate, molecular formula:(CH3CHOHCOO)2Ca•5H2O molecular weight:308.3.For white particle or powder, it is no different Taste, mouth gustation are bitter.Micro- have efflorescence properties, is soluble in hot water, is soluble in hot water into transparent or slightly turbid solution, cold water solubility compared with It is low, insoluble in ethanol, chloroform and ether.The Ph values of the aqueous solution are 6.0~7.0.With solubility is high, dissolution velocity is fast, biology Utilization rate is high, in good taste, is widely used in the fields such as dairy products, beverage, health care of food product.
The application of L-arabinose, Tagatose in field of food at present is a lot, but easily occur caramelization and Maillaid braun reaction, mouthfeel, color and luster of food etc. are influenceed, it is necessary to be improved.
The content of the invention
The defects of the object of the invention is exactly to make up prior art, there is provided one kind avoids rare sugar easy in food processing The method of caramelization and Maillaid braun reaction occurs.
The present invention is achieved by the following technical solutions:
A kind of method for avoiding rare sugar that caramelization and Maillaid braun reaction easily occur in food processing, rare sugar add Work step is suddenly:
First, heart material processed
(1)Rare sugared quality is detected, the rare sugar is L-arabinose, Tagatose or both mixture;
(2)Sodium alginate is dissolved in water, the 1-2wt% aqueous solution is made, PURE WHEY is added, stirs, add rare sugar and stir Mix and be formed uniformly slurry;The weight/mass percentage composition of each raw material is in slurry:Sodium alginate 1-1.3wt%, PURE WHEY 30- 40wt%, rare sugared 15-20wt%, surplus is water;
(3)Slurry is spray-dried, gel powder is made;
2nd, cladding processed
(4)Sodium alginate is dissolved with water, the 3-3.5wt% aqueous solution is made, adds trehalose while stirring, stirs, adds Enter the calcium lactate aqueous solution, stir, obtain viscous paste;The weight/mass percentage composition of each raw material is in viscous paste:Alginic acid Sodium 3-3.5wt%, trehalose 40-50wt%, calcium lactate 0.5-1wt%, surplus are water;
3rd, synthesize
(5)Viscous paste is sprayed on the gel powder, pellet is made, produces the rare sugar processed.
The temperature of water used is 30 DEG C~35 DEG C, and pH value is 6.0~7.0.
The particle diameter of the gel powder is 60-70 microns.
The particle diameter of the pellet is 120-150 microns.
The trehalose is aqueous 20-30wt% powder.
Step(3)Drying mode for spray drying, step(5)The spraying is spraying drying.
The concentration of the calcium lactate aqueous solution is 0.5-1wt%.
The rare sugared purposes that gained processes is added in the hot and cold process of starch food products, rare to protect Sugar, avoid that caramelization and Maillaid braun reaction easily occurs.
It is an advantage of the invention that:Present invention sodium alginate bonds PURE WHEY and rare sugar, forms particle, makes sugar Protein structure is protected, high temperature resistant so that rare sugar can avoid strong Mei Lade during food processing and storage Reaction.One layer of sodium alginate, calcium lactate film are coated again in particle surface in addition, and calcium lactate improves the intensity of calcium alginate, prevents Only in premature collapse, L-arabinose, Tagatose or both polymer can be transported to specified intestines and stomach, in the effect of human body acid Under, rapid disintegration, L-arabinose or Tagatose are discharged, block absorption of the human body to sucrose or glucose sugar.The bag of outer layer Covering strengthens rare sugared protective effect, can both prevent caramelization, can bear more than 200 DEG C of high temperature again, resists The performance enhancement of Maillard reaction.
Trehalose that the present invention uses, PURE WHEY, sodium alginate, calcium lactate, are conventional supplementary material, and through overfeeding Product industry widely practice and clinical verification;Preparation method used is conventional method and normal temperature environment, simple to operate It is easily mastered and obtains controllable quality.
The method of the present invention improves stability of the rare sugar in food processing early, middle, late stage, avoids and caramel easily occurs Change reaction and Maillaid braun reaction, can be used for making food processing and be added in raw material.By adding product institute of the present invention The either thermally processed foods or cold working cake of production are made, obtain good outward appearance and color and luster, people are enjoying U.S. While taste, place that intestines and stomach that and can enough allows the polymer of rare sugared L-arabinose, Tagatose or both to reach are specified, Sucrose, glucose absorption are blocked, suppresses the occurrence and development of postprandial hyperglycemia, promotes health, can more allow the new resources such as rare sugar Food preferably benefits masses.
Embodiment
The present invention is described further with reference to specific embodiment, but protection scope of the present invention is not limited in This:
Embodiment 1
First, heart material processed
(1)Detect the quality of L-arabinose;
(2)Sodium alginate is dissolved in water, the 1wt% aqueous solution is made, PURE WHEY is added, stirs, it is Arabic to add L- Sugar, stir to form slurry;The weight/mass percentage composition of each raw material is in slurry:Sodium alginate 1.1wt%, PURE WHEY 30wt%, L-arabinose 15wt%, surplus are water;5Kg slurry is made;
(3)Slurry is spray-dried, the gel powder of 60-70 microns is made;
2nd, cladding processed
(4)Sodium alginate is dissolved with water, the 3wt% aqueous solution is made, adds trehalose while stirring, stirs, is added The 1wt% calcium lactate aqueous solution, stirs, obtains viscous paste;The weight/mass percentage composition of each raw material is in viscous paste:Sea Mosanom 3wt%, trehalose 45wt%, calcium lactate 0.6wt%, surplus are water;10Kg viscous paste is made;
3rd, synthesize
(5)Viscous paste spraying is dried on the gel powder, the pellet of 120-150 microns is made, produces what is processed L-arabinose.
The temperature of water used is 35 DEG C, pH value 7.0.
The trehalose is aqueous 20wt% powder.
A, biscuit(Finished product PH7.0)
Control group:Flour, sucrose, L-arabinose, auxiliary material, through overbaking, biscuit is made.As a result:Gross distortion after coming out of the stove, face Color depth is black, and the brown stain of Maillard reaction is serious, there is bitter taste, can not eat;
Test group:L-arabinose that flour, sucrose, embodiment 1 obtain, other auxiliary materials, through overbaking, biscuit is made.As a result: Anatomic shape, it is golden yellow, crispy in taste, belong to normal biscuit, have no the brown stain serious problems of Maillard reaction.
B, cake class-mung bean cake(Finished product PH7.0)
Control group:Mung bean flour, sucrose, L-arabinose, auxiliary material, using cold working, mung bean cake is made.
As a result:Mung bean cake color change is partially red after three days.
Test group:The L-arabinose that mung bean flour, sucrose, embodiment 1 obtain, auxiliary material, using cold working, mung bean is made Cake.
As a result:Color and luster is still glossy after 15 days, there is appetite sense.
Embodiment 2
First, heart material processed
(1)Detect the quality of Tagatose;
(2)Sodium alginate is dissolved in water, the 2wt% aqueous solution is made, PURE WHEY is added, stirs, adds Tagatose stirring It is formed uniformly slurry;The weight/mass percentage composition of each raw material is in slurry:Sodium alginate 1.1wt%, PURE WHEY 30wt%, tower lattice Sugared 15wt%, surplus are water;5Kg slurry is made;
(3)Slurry is spray-dried, the gel powder of 60-70 microns is made;
2nd, cladding processed
(4)Sodium alginate is dissolved with water, the 3wt% aqueous solution is made, adds trehalose while stirring, stirs, is added The 1wt% calcium lactate aqueous solution, stirs, obtains viscous paste;The weight/mass percentage composition of each raw material is in viscous paste:Sea Mosanom 3wt%, trehalose 45wt%, calcium lactate 0.6wt%, surplus are water;10Kg viscous paste is made;
3rd, synthesize
(5)Viscous paste spraying is dried on the gel powder, the pellet of 120-150 microns is made, produces what is processed Tagatose.
The temperature of water used is 35 DEG C, pH value 7.0.
The trehalose is aqueous 20-30wt% powder.
Experimental data:
A, biscuit(Finished product pH7.0)
Control group:Flour, sucrose, Tagatose, auxiliary material, through overbaking, biscuit is made.As a result:Half the time is baked to seriously to become Shape, color is pitch black, and the brown stain of Maillard reaction is serious, and biscuit is not baked, there is bitter taste, can not eat;
Test group:Tagatose that flour, sucrose, embodiment 2 obtain, other auxiliary materials, through overbaking, biscuit is made.As a result:Shape It is attractive in appearance, it is golden yellow, crispy in taste, belong to normal biscuit, have no the brown stain serious problems of Maillard reaction.
B, cake class-mung bean cake(Finished product pH7.0)
Control group:Mung bean flour, sucrose, Tagatose, auxiliary material, using cold working, mung bean cake is made.
As a result:Mung bean cake color change is partially red after one day.
Test group:The Tagatose that mung bean flour, sucrose, embodiment 2 obtain, auxiliary material, using cold working, mung bean cake is made.
As a result:Color and luster is still glossy after 30 days, there is appetite sense.
Pass through Experimental Comparison, either hot-working or cold working cake, it was confirmed that product of the present invention avoid L- I Uncle's sugar, Tagatose easy caramelization and overgenerous Maillard reaction in food processing, by adding product of the present invention The either thermally processed foods or cold working cake of made production, obtain good outward appearance and color and luster.

Claims (8)

1. a kind of avoid rare sugar method of easy caramelization and overgenerous Maillard reaction in food processing, it is special Sign is that rare sugared procedure of processing is:
First, heart material processed
(1)Detect rare sugared quality;The rare sugar is L-arabinose, Tagatose or both mixture;
(2)Sodium alginate is dissolved in water, the 1-2wt% aqueous solution is made, PURE WHEY is added, stirs, add rare sugar and stir Mix and be formed uniformly slurry;The weight/mass percentage composition of each raw material is in slurry:Sodium alginate 1-1.3wt%, PURE WHEY 30- 40wt%, rare sugared 15-20wt%, surplus is water;
(3)By slurry drying, gel powder is made;
2nd, cladding processed
(4)Sodium alginate is dissolved with water, the 3-3.5wt% aqueous solution is made, adds trehalose while stirring, stirs, adds Enter the calcium lactate aqueous solution, viscous paste is obtained after stirring;The weight/mass percentage composition of each raw material is in viscous paste:Sodium alginate 3- 3.5wt%, trehalose 40-50wt%, calcium lactate 0.5-1wt%, surplus are water;
3rd, synthesize
(5)Viscous paste is sprayed on the gel powder, pellet is made, produces the rare sugar processed.
2. rare sugar easy caramelization and overgenerous Maillard reaction in food processing are avoided as claimed in claim 1 Method, it is characterised in that the temperature of water used be 30 DEG C~35 DEG C, pH value be 6.0~7.0.
3. avoid rare sugared caramelization easy in food processing and overgenerous U.S. rad anti-as claimed in claim 1 The method answered, it is characterised in that the particle diameter of the gel powder is 60-70 microns.
4. rare sugar easy caramelization and overgenerous Maillard reaction in food processing are avoided as claimed in claim 1 Method, it is characterised in that the particle diameter of the pellet is 120-150 microns.
5. avoid rare sugared caramelization easy in food processing and overgenerous U.S. rad anti-as claimed in claim 1 The method answered, it is characterised in that the trehalose is aqueous 20-30wt% powder.
6. avoid rare sugared caramelization easy in food processing and overgenerous U.S. rad anti-as claimed in claim 1 The method answered, it is characterised in that step(3)Drying mode for spray drying, step(5)The spraying is spraying drying.
7. avoid rare sugared caramelization easy in food processing and overgenerous U.S. rad anti-as claimed in claim 1 The method answered, it is characterised in that the concentration of the calcium lactate aqueous solution is 0.5-1wt%.
8. avoiding the method for rare sugar Maillard reaction strong in food processing as claimed in claim 1, its feature exists In the rare sugared purposes that gained processes is added in the hot and cold process of starch food products, to protect rare sugar, is kept away Exempt from easy caramelization and overgenerous Maillard reaction in food processing.
CN201710670095.1A 2017-08-08 2017-08-08 It is a kind of to avoid rare sugar method of easy caramelization and overgenerous Maillard reaction in food processing Pending CN107348512A (en)

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CN110839707A (en) * 2018-08-21 2020-02-28 内蒙古伊利实业集团股份有限公司 Normal-temperature low-acid gel type milk-containing dessert capable of preventing browning and preparation method thereof

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Application publication date: 20171117