CN107268337A - 一种高透光纤维玻面纸及其制备方法 - Google Patents

一种高透光纤维玻面纸及其制备方法 Download PDF

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CN107268337A
CN107268337A CN201710554016.0A CN201710554016A CN107268337A CN 107268337 A CN107268337 A CN 107268337A CN 201710554016 A CN201710554016 A CN 201710554016A CN 107268337 A CN107268337 A CN 107268337A
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parts
coating
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余振华
余耀
张莹
詹建波
李赓
谢姣
郑晗
余婷婷
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China Tobacco Yunnan Industrial Co Ltd
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Abstract

本发明公开了一种高透光纤维玻面纸,包括硫酸纸,在所述硫酸纸的两侧依次涂布有底涂层、二次涂层和保护层,所述底涂层由二氧化碳共聚物多元醇80份、二异氰酸酯18份、扩链交联剂22份和亲水扩链剂14份制得;所述二次涂层由改性聚氨酯丙烯酸50份、UV光油26份、香味缓释微胶囊7份、醋酸乙酯16份、白矿油0.3份和染料10份制得;所述保护层由羟乙基纤维素醚27份、十二烷基硫酸钠2份、聚丙烯酰胺4份和三乙醇胺6份制得;该种高透光纤维玻面纸使纤维的透光性和表面平滑度显著提高,且经过双面处理后的纸张,表面平滑度大于210秒,同时该工艺制备方法简单,应用范围广泛。

Description

一种高透光纤维玻面纸及其制备方法
技术领域
本发明属于包装材料技术领域,具体涉及一种透光性强、表面平滑度高的高透光纤维玻面纸及其制备方法。
背景技术
目前,硫酸纸(也称为描图纸)是市场上具有透光性质的唯一纸张,其主要应用于描图、转印制版和局限性印刷。硫酸纸是由细微的植物纤维通过相互交织,在潮湿状态下经过游离打浆、不施胶、不加填料、抄纸工艺后,置于浓度为72%的浓硫酸中浸泡2~3s,用清水洗涤,并加以甘油处理、干燥后所形成的薄膜型纸张。通过该方法制备得到的硫酸纸质地坚实、致密且呈半透明状,但其表面却很粗糙、平整度差,平滑度一般小于90秒。将硫酸纸用于包装印刷时存在色彩还原性差、无法适应细网点印刷、条码识别清晰度不足等缺陷,导致其在印刷领域的应用受到很大的局限;同时由于硫酸纸表面纯纤维结构较为疏松,也大大降低了其透光性能,无法使其包装制品呈现应有的透明度。
发明内容
有鉴于此,本发明的目的是提供一种具有高透光性和平滑度的高透光纤维玻面纸。
为解决上述技术问题,本发明的技术方案是:
一种高透光纤维玻面纸,包括硫酸纸,在所述硫酸纸的两侧依次涂布有底涂层、二次涂层和保护层,所述底涂层由二氧化碳共聚物多元醇80份、二异氰酸酯18份、扩链交联剂22份和亲水扩链剂14份制得;所述二次涂层由改性聚氨酯丙烯酸50份、UV光油26份、香味缓释微胶囊7份、醋酸乙酯16份、白矿油0.3份和染料10份制得;所述保护层由羟乙基纤维素醚27份、十二烷基硫酸钠2份、聚丙烯酰胺4份和三乙醇胺6份制得。
进一步的,所述一种高透光纤维玻面纸的制备方法,包括以下步骤:
1)选取面密度为160g/m2,厚度为0.04mm的硫酸纸作为基底层,备用;
2)取二氧化碳共聚物多元醇80份、二异氰酸酯18份、扩链交联剂22份和亲水扩链剂14份放入搅拌釜内,然后以100-110r/min的速度搅拌20-30min,制得底涂层涂料,备用;
3)通过210线/吋的网纹辊将步骤2)制得的底涂层涂料均匀涂布于步骤1)选取的硫酸纸的表面,底涂层涂料的涂布量为9-10g/m2,得到底层涂层,备用;
4)取改性聚氨酯丙烯酸50份、UV光油26份、香味缓释微胶囊7份、醋酸乙酯16份、白矿油0.3和染料10份放入搅拌釜内,然后以100-110r/min的速度搅拌20-30min,使得改性聚氨酯丙烯酸、UV光油、香味缓释微胶囊、醋酸乙酯、白矿油和染料混合后的粘度为55Pa.S,制得二次涂层涂料,备用;
5)通过210线/吋的陶瓷网纹辊将步骤4)制得的二次涂层涂料均匀涂布于步骤3)得到的底层涂层上,二次涂层涂料的涂布量为6-7g/m2,得到二次涂层,备用;
6)通过镀铬镜面钢辊以70m/s的速度,在压力9kgf下对步骤5)得到的二次涂层进行整平修饰,然后通过功率为280毫焦耳的UV油专用紫外线灯对经过表面整饰的二次涂层烘烤5秒,使其表面形成UV固化膜,得到二次涂层UV固化膜,备用;
7)取羟乙基纤维素醚27份、十二烷基硫酸钠2份、聚丙烯酰胺4份和三乙醇胺6份放入搅拌釜内,然后以100-110r/min的速度搅拌20-30min,制得保护层涂料,备用;
8)通过180线/吋的网纹辊将步骤7)制得的保护层涂料均匀涂布于步骤6)得到的二次涂层UV固化膜的表面,保护层涂料的涂布量为7-8g/m2,即得本发明的高透光纤维玻面纸。
本发明的有益效果为:本发明的高透光纤维玻面纸采用密度为160g/m2,厚度为0.04mm硫酸纸做基层,在硫酸纸的两侧依次涂布有由二氧化碳共聚物多元醇、二异氰酸酯、扩链交联剂和亲水扩链剂制成的底涂层、由改性聚氨酯丙烯酸份、UV光油、香味缓释微胶囊、醋酸乙酯、白矿油和染料制成的二次涂层和由羟乙基纤维素醚、十二烷基硫酸钠、聚丙烯酰胺和三乙醇胺制成的保护层,使纤维的透光性和表面平滑度显著提高,且经过双面处理后的纸张,表面平滑度大于210秒,同时该工艺制备方法简单,解决了硫酸纸用于包装印刷时,所存在得色彩还原性差、无法适应细网点印刷、条码识别清晰度不足等缺陷,应用范围广泛。
附图说明
图1为本发明高透光纤维玻面纸的整体结构示意图。
图中:1-硫酸纸,2-底涂层,3-二次涂层,4-保护层。
具体实施方式
以下结合附图及实施例对本发明作进一步详细说明,应当理解,实施例仅用于说明和解释本发明,并不用于限定本发明。
如附图1所示,本实施例中所述的高透光纤维玻面纸,以面密度为160g/m2,厚度为0.04mm的硫酸纸1为基底层,在所述硫酸纸1的两侧依次涂布有底涂层2、二次涂层3和保护层4;所述底涂层2由二氧化碳共聚物多元醇80份、二异氰酸酯18份、扩链交联剂22份和亲水扩链剂14份制得,所述保护层4由羟乙基纤维素醚27份、十二烷基硫酸钠2份、聚丙烯酰胺4份和三乙醇胺6份制得,所述二次涂层3由改性聚氨酯丙烯酸50份、UV光油26份、香味缓释微胶囊7份、醋酸乙酯16份、白矿油0.3份和染料10份制得。
实施例1
一种高透光纤维玻面纸,包括硫酸纸,在所述硫酸纸的两侧依次涂布有底涂层、二次涂层和保护层,所述底涂层由二氧化碳共聚物多元醇80份、二异氰酸酯18份、扩链交联剂22份和亲水扩链剂14份制得;所述二次涂层由改性聚氨酯丙烯酸50份、UV光油26份、香味缓释微胶囊7份、醋酸乙酯16份、白矿油0.3份和染料10份制得;所述保护层由羟乙基纤维素醚27份、十二烷基硫酸钠2份、聚丙烯酰胺4份和三乙醇胺6份制得。
一种高透光纤维玻面纸的制备方法,包括以下步骤:
1)选取面密度为160g/m2,厚度为0.04mm的硫酸纸作为基底层,备用;
2)取二氧化碳共聚物多元醇80份、二异氰酸酯18份、扩链交联剂22份和亲水扩链剂14份放入搅拌釜内,然后以100r/min的速度搅拌30min,制得底涂层涂料,备用;
3)通过210线/吋的网纹辊将步骤2)制得的底涂层涂料均匀涂布于步骤1)选取的硫酸纸的表面,底涂层涂料的涂布量为10g/m2,得到底层涂层,备用;
4)取改性聚氨酯丙烯酸50份、UV光油26份、香味缓释微胶囊7份、醋酸乙酯16份、白矿油0.3和染料10份放入搅拌釜内,然后以100r/min的速度搅拌30min,使得改性聚氨酯丙烯酸、UV光油、香味缓释微胶囊、醋酸乙酯、白矿油和染料混合后的粘度为55Pa.S,制得二次涂层涂料,备用;
5)通过210线/吋的陶瓷网纹辊将步骤4)制得的二次涂层涂料均匀涂布于步骤3)得到的底层涂层上,二次涂层涂料的涂布量为7g/m2,得到二次涂层,备用;
6)通过镀铬镜面钢辊以70m/s的速度,在压力9kgf下对步骤5)得到的二次涂层进行整平修饰,然后通过功率为280毫焦耳的UV油专用紫外线灯对经过表面整饰的二次涂层烘烤5秒,使其表面形成UV固化膜,得到二次涂层UV固化膜,备用;
7)取羟乙基纤维素醚27份、十二烷基硫酸钠2份、聚丙烯酰胺4份和三乙醇胺6份放入搅拌釜内,然后以100r/min的速度搅拌30min,制得保护层涂料,备用;
8)通过180线/吋的网纹辊将步骤7)制得的保护层涂料均匀涂布于步骤6)得到的二次涂层UV固化膜的表面,保护层涂料的涂布量为7g/m2,即得本发明的高透光纤维玻面纸。
实施例2
一种高透光纤维玻面纸,包括硫酸纸,在所述硫酸纸的两侧依次涂布有底涂层、二次涂层和保护层,所述底涂层由二氧化碳共聚物多元醇80份、二异氰酸酯18份、扩链交联剂22份和亲水扩链剂14份制得;所述二次涂层由改性聚氨酯丙烯酸50份、UV光油26份、香味缓释微胶囊7份、醋酸乙酯16份、白矿油0.3份和染料10份制得;所述保护层由羟乙基纤维素醚27份、十二烷基硫酸钠2份、聚丙烯酰胺4份和三乙醇胺6份制得。
一种高透光纤维玻面纸的制备方法,包括以下步骤:
1)选取面密度为160g/m2,厚度为0.04mm的硫酸纸作为基底层,备用;
2)取二氧化碳共聚物多元醇80份、二异氰酸酯18份、扩链交联剂22份和亲水扩链剂14份放入搅拌釜内,然后以110r/min的速度搅拌20min,制得底涂层涂料,备用;
3)通过210线/吋的网纹辊将步骤2)制得的底涂层涂料均匀涂布于步骤1)选取的硫酸纸的表面,底涂层涂料的涂布量为9g/m2,得到底层涂层,备用;
4)取改性聚氨酯丙烯酸50份、UV光油26份、香味缓释微胶囊7份、醋酸乙酯16份、白矿油0.3和染料10份放入搅拌釜内,然后以110r/min的速度搅拌20min,使得改性聚氨酯丙烯酸、UV光油、香味缓释微胶囊、醋酸乙酯、白矿油和染料混合后的粘度为55Pa.S,制得二次涂层涂料,备用;
5)通过210线/吋的陶瓷网纹辊将步骤4)制得的二次涂层涂料均匀涂布于步骤3)得到的底层涂层上,二次涂层涂料的涂布量为6g/m2,得到二次涂层,备用;
6)通过镀铬镜面钢辊以70m/s的速度,在压力9kgf下对步骤5)得到的二次涂层进行整平修饰,然后通过功率为280毫焦耳的UV油专用紫外线灯对经过表面整饰的二次涂层烘烤5秒,使其表面形成UV固化膜,得到二次涂层UV固化膜,备用;
7)取羟乙基纤维素醚27份、十二烷基硫酸钠2份、聚丙烯酰胺4份和三乙醇胺6份放入搅拌釜内,然后以110r/min的速度搅拌20min,制得保护层涂料,备用;
8)通过180线/吋的网纹辊将步骤7)制得的保护层涂料均匀涂布于步骤6)得到的二次涂层UV固化膜的表面,保护层涂料的涂布量为8g/m2,即得本发明的高透光纤维玻面纸。
本发明的有益效果为:本发明的高透光纤维玻面纸采用密度为160g/m2,厚度为0.04mm硫酸纸做基层,在硫酸纸的两侧依次涂布有由二氧化碳共聚物多元醇、二异氰酸酯、扩链交联剂和亲水扩链剂制成的底涂层、由改性聚氨酯丙烯酸份、UV光油、香味缓释微胶囊、醋酸乙酯、白矿油和染料制成的二次涂层和由羟乙基纤维素醚、十二烷基硫酸钠、聚丙烯酰胺和三乙醇胺制成的保护层,使纤维的透光性和表面平滑度显著提高,且经过双面处理后的纸张,表面平滑度大于210秒,同时该工艺制备方法简单,解决了硫酸纸用于包装印刷时,所存在得色彩还原性差、无法适应细网点印刷、条码识别清晰度不足等缺陷,应用范围广泛。
以上所述仅为本发明的优选实施例而已,并不用于限制本发明,尽管参照前述实施例对本发明进行了详细的说明,对于本领域的技术人员来说,其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换,凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。

Claims (2)

1.一种高透光纤维玻面纸,包括硫酸纸,其特征在于:在所述硫酸纸的两侧依次涂布有底涂层、二次涂层和保护层,所述底涂层由二氧化碳共聚物多元醇80份、二异氰酸酯18份、扩链交联剂22份和亲水扩链剂14份制得;所述二次涂层由改性聚氨酯丙烯酸50份、UV光油26份、香味缓释微胶囊7份、醋酸乙酯16份、白矿油0.3份和染料10份制得;所述保护层由羟乙基纤维素醚27份、十二烷基硫酸钠2份、聚丙烯酰胺4份和三乙醇胺6份制得。
2.如权利要求1所述的一种高透光纤维玻面纸的制备方法,其特征在于:包括以下步骤:
1)选取面密度为160g/m2,厚度为0.04mm的硫酸纸作为基底层,备用;
2)取二氧化碳共聚物多元醇80份、二异氰酸酯18份、扩链交联剂22份和亲水扩链剂14份放入搅拌釜内,然后以100-110r/min的速度搅拌20-30min,制得底涂层涂料,备用;
3)通过210线/吋的网纹辊将步骤2)制得的底涂层涂料均匀涂布于步骤1)选取的硫酸纸的表面,底涂层涂料的涂布量为9-10g/m2,得到底层涂层,备用;
4)取改性聚氨酯丙烯酸50份、UV光油26份、香味缓释微胶囊7份、醋酸乙酯16份、白矿油0.3和染料10份放入搅拌釜内,然后以100-110r/min的速度搅拌20-30min,使得改性聚氨酯丙烯酸、UV光油、香味缓释微胶囊、醋酸乙酯、白矿油和染料混合后的粘度为55Pa.S,制得二次涂层涂料,备用;
5)通过210线/吋的陶瓷网纹辊将步骤4)制得的二次涂层涂料均匀涂布于步骤3)得到的底层涂层上,二次涂层涂料的涂布量为6-7g/m2,得到二次涂层,备用;
6)通过镀铬镜面钢辊以70m/s的速度,在压力9kgf下对步骤5)得到的二次涂层进行整平修饰,然后通过功率为280毫焦耳的UV油专用紫外线灯对经过表面整饰的二次涂层烘烤5秒,使其表面形成UV固化膜,得到二次涂层UV固化膜;
7)取羟乙基纤维素醚27份、十二烷基硫酸钠2份、聚丙烯酰胺4份和三乙醇胺6份放入搅拌釜内,然后以100-110r/min的速度搅拌20-30min,制得保护层涂料,备用;
8)通过180线/吋的网纹辊将步骤7)制得的保护层涂料均匀涂布于步骤6)得到的二次涂层UV固化膜的表面,保护层涂料的涂布量为7-8g/m2,即得本发明的高透光纤维玻面纸。
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