CN107265860A - A kind of celadon antibacterial glaze water and preparation method thereof - Google Patents
A kind of celadon antibacterial glaze water and preparation method thereof Download PDFInfo
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- CN107265860A CN107265860A CN201710598379.4A CN201710598379A CN107265860A CN 107265860 A CN107265860 A CN 107265860A CN 201710598379 A CN201710598379 A CN 201710598379A CN 107265860 A CN107265860 A CN 107265860A
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- glaze
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- celadon
- antibacterial
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
- C03C2204/02—Antibacterial glass, glaze or enamel
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- Engineering & Computer Science (AREA)
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- General Chemical & Material Sciences (AREA)
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- Nanotechnology (AREA)
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a kind of celadon antibacterial glaze water and preparation method thereof, the celadon antibacterial glaze water is 1 by mass ratio:05 0.8 glaze and water composition, the following parts by weight component composition of glaze：30 40 parts of little Mei glaze soil, 20 30 parts of small stream mouthful glaze soil, 15 25 parts of Zhou village glaze soil, 8 15 parts of potassium feldspar, 36 parts of aluminum oxide, eight all 8 12 parts of 35 parts of fluorite and nano antibacterial agent.Celadon antibacterial glaze water provided by the present invention, with the addition of nano antibacterial agent, can be uniformly dispersed in glaze water, both with antibiotic effect, and not influence the decentralization of glaze water, and made celadon ware surface is smooth, while the intensity of glaze layer can be improved.
Description
Technical field
The invention belongs to celadon preparing technical field, and in particular to a kind of celadon antibacterial glaze water and preparation method thereof.
Background technology
Celadon is one of traditional category of China's porcelain, and celadon is muddy with porcelain exquisiteness, lucid and lively smooth, the moulding dignity of lines
Piao, color and luster are pure and bright-colored famous, are referred to as " flower of porcelain ".Why celadon is the ceramics occurred earliest, is former with enamel frit makeing
Material interwoveness.All contain more or less irony in natural enamel frit makeing raw material, and in the sintering procedure of ceramics, these iron
A part for matter can be reduced into ferrous iron, so that different tones are presented in glaze.Celadon have that " blue or green as beautiful, bright such as mirror, sound is such as
The good reputation of " flower of porcelain " of single sonorous stone ", its is wide in variety, and glaze colours is colourful, but most characteristic product surely belongs to cracked ice pattern celadon, because
Its cracking special in appearance and exquisite glaze colours, win the favor of successive dynasties collector.
Celadon ware has the advantages that graceful, safe and environment-friendly as water appliance, therefore deep is favored by people.It is existing
Celadon ware does not have antibiotic effect, therefore develops a kind of celadon antibacterial glaze water as urgent problem to be solved.
The content of the invention
The invention provides a kind of celadon antibacterial glaze water, nano antibacterial agent is with the addition of, can be uniformly dispersed in glaze water, both had
There is antibiotic effect, and do not influence the decentralization of glaze water, made celadon ware surface is smooth, while the intensity of glaze layer can be improved.
The technical proposal for solving the technical problem of the invention is：
A kind of celadon antibacterial glaze water, the celadon antibacterial glaze water is 1 by mass ratio:05-0.8 glaze and water composition, the glaze
Expect following parts by weight component composition：30-40 parts of little Mei glaze soil, small stream mouthful 20-30 parts of glaze soil, 15-25 parts of Zhou village glaze soil, potassium feldspar
8-15 parts, 3-6 parts of aluminum oxide, eight all fluorite 3-5 parts and 8-12 parts of nano antibacterial agents；
The nano antibacterial agent is prepared by following methods：Surfactant and zinc nitrate are added into silver nitrate aqueous solution, in
1200-1500r/min stirrings are lower well mixed, continue to stir and add silica, continue after stirring 30-50 minutes, add
Foaming agent, after stirring 8-10 minutes, by foam tiling in a reservoir, after 60-80 DEG C is dried in vacuo 12 hours, collects powder,
Grinding, crosses and nano antibacterial agent is obtained after 80 mesh sieves.
Using the amphiphilic character of surfactant, by coated with silica in silver nitrate and nitric acid zinc surface, add
Foaming agent foam, using the principle at interface, the nanometer that silicon dioxide carried silver nitrate and zinc nitrate are formed at foam interface is micro-
Grain, as nano antibacterial agent.
Preferably, described surfactant is hexadecyltrimethylammonium chloride or cetyl trimethyl bromination
Ammonium.
Preferably, the mass concentration of described silver nitrate aqueous solution is 15-20%.
Preferably, described silver nitrate aqueous solution, zinc nitrate, surfactant, the quality of silica and foaming agent
Than for 1：0.1-0.2：0.03-0.05：0.2-0.3：0.05-0.1, the consumption of silica influences it in silver nitrate and zinc nitrate
The cladding density on surface, it is excessive in the cladding density of silver nitrate and nitric acid zinc surface if the consumption of silica is excessive so that
The antibacterial effect of antiseptic is not good；If the consumption of silica is too small, in the cladding density mistake of silver nitrate and nitric acid zinc surface
It is small, silver nitrate can be caused too fast oxidized in use and antibacterial effect is lost.
Preferably, described foaming agent is 1 by mass ratio:0.2-0.4 sodium xylene sulfonate and petroleum ether composition, is adopted
It can cause the big and stable foam of solution formation diameter with the foaming agent of the formula.
Invention also provides a kind of preparation method of celadon antibacterial glaze water, the preparation method is：(1) to nitric acid
Surfactant and zinc nitrate are added in the silver-colored aqueous solution, it is lower well mixed in 1200-1500r/min stirrings, continue to stir and add
Enter silica, continue after stirring 30-50 minutes, add foaming agent, after stirring 8-10 minutes, by foam tiling in a reservoir,
After 60-80 DEG C is dried in vacuo 12 hours, powder is collected, grinding is crossed and nano antibacterial agent is obtained after 80 mesh sieves；
(2) by little Mei glaze soil 30-40 parts by weight, small stream mouthful glaze soil 20-30 parts by weight, Zhou village glaze soil 15-25 parts by weight, potassium feldspar
8-15 parts by weight, aluminum oxide 3-6 parts by weight, eight all fluorite 3-5 parts by weight and nano antibacterial agent 8-12 parts by weight are well mixed, and
It is 1.5-2 by mass ratio:1:0.5-1 ballstone, glaze and water add in ball-grinding machine that ball milling is after 30-50 hours, iron removal by filtration
Celadon antibacterial glaze water needed for obtaining.
Preferably, described surfactant is hexadecyltrimethylammonium chloride or cetyl trimethyl bromination
Ammonium.
Preferably, the mass concentration of described silver nitrate aqueous solution is 15-20%.
Preferably, described silver nitrate aqueous solution, zinc nitrate, surfactant, the quality of silica and foaming agent
Than for 1：0.1-0.2：0.03-0.05：0.2-0.3：0.05-0.1.
Preferably, described foaming agent is 1 by mass ratio:0.2-0.4 sodium xylene sulfonate and petroleum ether composition.
Beneficial effects of the present invention are：
Celadon antibacterial glaze water provided by the present invention, containing nano antibacterial agent, the nano antibacterial agent is silicon dioxide carried nitre
Sour silver and zinc nitrate, it is scattered in nanoscale, with preferable antibacterial effect, while can be dispersed in glaze water, made celadon
Porcelain surface is smooth, while the intensity of glaze layer can be improved.
Embodiment
The present invention is described in further detail with reference to embodiments.This specific embodiment is only the solution to the present invention
Release, it is not limitation of the present invention, those skilled in the art can be as needed to this reality after this specification is read
Apply example and make the modification without creative contribution, but as long as all being protected in scope of the presently claimed invention by Patent Law
Shield.
Embodiment 1
(1) 125g hexadecyltrimethylammonium chlorides and 50g zinc nitrates are added into 500g 20wt% silver nitrate aqueous solutions, in
1300r/min stirrings are lower well mixed, continue to stir and add 125g silica, continue after stirring 40 minutes, add 23g bis-
Toluenesulfonic acid sodium salt and 7g petroleum ethers, after stirring 10 minutes, by foam tiling in a reservoir, after 60 DEG C are dried in vacuo 12 hours,
Powder is collected, grinding is crossed and 225g nano antibacterial agents are obtained after 80 mesh sieves.
(2) by little Mei glaze soil 300g, small stream mouthful glaze soil 250g, Zhou village glaze soil 200g, potassium feldspar 100g, aluminum oxide 50g, eight
All fluorite 40g and 80g nano antibacterial agents, and be 1.5 by mass ratio:1:0.8 ballstone, glaze and water adds ball in ball-grinding machine
Mill is after 40 hours, and iron removal by filtration obtains glaze water.；
Embodiment 2
(1) 100g cetyl trimethylammonium bromides and 75g zinc nitrates are added into 500g 15wt% silver nitrate aqueous solutions, in
1200r/min stirrings are lower well mixed, continue to stir and add 100g silica, continue after stirring 50 minutes, add 210g
Sodium xylene sulfonate and 40g petroleum ethers, after stirring 9 minutes, by foam tiling in a reservoir, are dried in vacuo 12 hours in 70 DEG C
Afterwards, powder is collected, grinding is crossed and 194.5g nano antibacterial agents are obtained after 80 mesh sieves.
(2) by little Mei glaze soil 350g, small stream mouthful glaze soil 200g, Zhou village glaze soil 150g, potassium feldspar 150g, aluminum oxide 60g, eight
All fluorite 30g and 100g nano antibacterial agents, and be 1.8 by mass ratio:1:0.5 ballstone, glaze and water is added in ball-grinding machine
After ball milling 30 hours, iron removal by filtration obtains glaze water.
Embodiment 3
(1) 150g cetyl trimethylammonium bromides and 100g zinc nitrates are added into 500g 18wt% silver nitrate aqueous solutions, in
1500r/min stirrings are lower well mixed, continue to stir and add 150g silica, continue after stirring 350 minutes, add
35.5g sodium xylene sulfonates and 14.5g petroleum ethers, after stirring 8 minutes, by foam tiling in a reservoir, in 80 DEG C of vacuum drying
After 12 hours, powder is collected, grinding is crossed and 211.5g nano antibacterial agents are obtained after 80 mesh sieves.
(2) by little Mei glaze soil 400g, small stream mouthful glaze soil 300g, Zhou village glaze soil 250g, potassium feldspar 80g, aluminum oxide 30g, eight all
Fluorite 50g and 120g nano antibacterial agent, and be 2 by mass ratio:1:1 ballstone, glaze and water adds ball milling 30 in ball-grinding machine
After hour, iron removal by filtration obtains glaze water.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
Any modifications, equivalent substitutions and improvements made within refreshing and principle etc., should be included in the scope of the protection.
Claims (10)
1. a kind of celadon antibacterial glaze water, it is characterised in that the celadon antibacterial glaze water is 1 by mass ratio:05-0.8 glaze and
Water is constituted, the following parts by weight component composition of glaze：30-40 parts of little Mei glaze soil, small stream mouthful 20-30 parts of glaze soil, Zhou village glaze soil
15-25 parts, 8-15 parts of potassium feldspar, 3-6 parts of aluminum oxide, eight all fluorite 3-5 parts and 8-12 parts of nano antibacterial agents；
The nano antibacterial agent is prepared by following methods：Surfactant and zinc nitrate are added into silver nitrate aqueous solution, in
1200-1500r/min stirrings are lower well mixed, continue to stir and add silica, continue after stirring 30-50 minutes, add
Foaming agent, after stirring 8-10 minutes, by foam tiling in a reservoir, after 60-80 DEG C is dried in vacuo 12 hours, collects powder,
Grinding, crosses and nano antibacterial agent is obtained after 80 mesh sieves.
2. celadon antibacterial glaze water as claimed in claim 1, it is characterised in that described surfactant is cetyl front three
Ammonium chloride or cetyl trimethylammonium bromide.
3. celadon antibacterial glaze water as claimed in claim 1, it is characterised in that the mass concentration of described silver nitrate aqueous solution is
15-20%。
4. celadon antibacterial glaze water as claimed in claim 1, it is characterised in that described silver nitrate aqueous solution, zinc nitrate, surface
The mass ratio of activating agent, silica and foaming agent is 1：0.1-0.2：0.03-0.05：0.2-0.3：0.05-0.1.
5. celadon antibacterial glaze water as claimed in claim 1, it is characterised in that described foaming agent is 1 by mass ratio:0.2-
0.4 sodium xylene sulfonate and petroleum ether composition.
6. prepare the method for the celadon antibacterial glaze water described in claim 1, it is characterised in that the preparation method is：
(1) surfactant and zinc nitrate are added into silver nitrate aqueous solution, it is equal in the lower mixing of 1200-1500r/min stirrings
Even, continuation is stirred and adds silica, is continued after stirring 30-50 minutes, is added foaming agent, after stirring 8-10 minutes, will steep
Foam tiling in a reservoir, after 60-80 DEG C is dried in vacuo 12 hours, collects powder, grinding is crossed and nano-antibacterial is obtained after 80 mesh sieves
Agent；
(2) by little Mei glaze soil 30-40 parts by weight, small stream mouthful glaze soil 20-30 parts by weight, Zhou village glaze soil 15-25 parts by weight, potassium feldspar
8-15 parts by weight, aluminum oxide 3-6 parts by weight, eight all fluorite 3-5 parts by weight and nano antibacterial agent 8-12 parts by weight are well mixed, and
It is 1.5-2 by mass ratio:1:0.5-1 ballstone, glaze and water add in ball-grinding machine that ball milling is after 30-50 hours, iron removal by filtration
Celadon antibacterial glaze water needed for obtaining.
7. the preparation method of celadon antibacterial glaze water as claimed in claim 6, it is characterised in that the surface described in step (1)
Activating agent is hexadecyltrimethylammonium chloride or cetyl trimethylammonium bromide.
8. the preparation method of celadon antibacterial glaze water as claimed in claim 6, it is characterised in that the nitric acid described in step (1)
The mass concentration of the silver-colored aqueous solution is 15-20%.
9. the preparation method of celadon antibacterial glaze water as claimed in claim 6, it is characterised in that the nitric acid described in step (1)
The silver-colored aqueous solution, zinc nitrate, surfactant, the mass ratio of silica and foaming agent are 1：0.1-0.2：0.03-0.05：0.2-
0.3：0.05-0.1.
10. the preparation method of celadon antibacterial glaze water as claimed in claim 6, it is characterised in that the foaming described in step (1)
Agent is 1 by mass ratio:0.2-0.4 sodium xylene sulfonate and petroleum ether composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710598379.4A CN107265860A (en) | 2017-07-21 | 2017-07-21 | A kind of celadon antibacterial glaze water and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710598379.4A CN107265860A (en) | 2017-07-21 | 2017-07-21 | A kind of celadon antibacterial glaze water and preparation method thereof |
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| CN201710598379.4A Pending CN107265860A (en) | 2017-07-21 | 2017-07-21 | A kind of celadon antibacterial glaze water and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107986622A (en) * | 2017-11-17 | 2018-05-04 | 龙泉市宝溪先明瓷厂 | A kind of plum green color glaze and preparation method thereof |
| CN108249761A (en) * | 2018-03-22 | 2018-07-06 | 福建省德化县中国白陶瓷有限责任公司 | A kind of Chinese red glaze water and its preparation method and application |
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| CN101100397A (en) * | 2006-12-30 | 2008-01-09 | 江苏高淳陶瓷股份有限公司 | Technique for preparing antibiotic stoneware tableware |
| CN101486593A (en) * | 2008-01-15 | 2009-07-22 | 泉州斯达纳米科技发展有限公司 | Preparation and use method of silver nano ceramic glaze water antibacterial additive |
| CN101611718A (en) * | 2009-07-27 | 2009-12-30 | 浙江大学 | A kind of dragon spring celadon antibacterial agent and application thereof |
| CN104876646A (en) * | 2015-05-26 | 2015-09-02 | 绥阳县华夏陶瓷有限责任公司 | Anti-bacterial glaze and preparation method thereof |
| CN106167391A (en) * | 2016-06-12 | 2016-11-30 | 龙泉瓯江青瓷有限公司 | Longquan celadon reinforced porcelain processing technology |
-
2017
- 2017-07-21 CN CN201710598379.4A patent/CN107265860A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101100397A (en) * | 2006-12-30 | 2008-01-09 | 江苏高淳陶瓷股份有限公司 | Technique for preparing antibiotic stoneware tableware |
| CN101486593A (en) * | 2008-01-15 | 2009-07-22 | 泉州斯达纳米科技发展有限公司 | Preparation and use method of silver nano ceramic glaze water antibacterial additive |
| CN101611718A (en) * | 2009-07-27 | 2009-12-30 | 浙江大学 | A kind of dragon spring celadon antibacterial agent and application thereof |
| CN104876646A (en) * | 2015-05-26 | 2015-09-02 | 绥阳县华夏陶瓷有限责任公司 | Anti-bacterial glaze and preparation method thereof |
| CN106167391A (en) * | 2016-06-12 | 2016-11-30 | 龙泉瓯江青瓷有限公司 | Longquan celadon reinforced porcelain processing technology |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107986622A (en) * | 2017-11-17 | 2018-05-04 | 龙泉市宝溪先明瓷厂 | A kind of plum green color glaze and preparation method thereof |
| CN108249761A (en) * | 2018-03-22 | 2018-07-06 | 福建省德化县中国白陶瓷有限责任公司 | A kind of Chinese red glaze water and its preparation method and application |
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Application publication date: 20171020 |