CN107986622A - A kind of plum green color glaze and preparation method thereof - Google Patents

A kind of plum green color glaze and preparation method thereof Download PDF

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Publication number
CN107986622A
CN107986622A CN201711142929.8A CN201711142929A CN107986622A CN 107986622 A CN107986622 A CN 107986622A CN 201711142929 A CN201711142929 A CN 201711142929A CN 107986622 A CN107986622 A CN 107986622A
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parts
glaze
soil
green color
plum green
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Chinese (zh)
Inventor
陈克萍
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Longquan City Bao Xi First Porcelain Factory
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Longquan City Bao Xi First Porcelain Factory
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/32Burning methods
    • C04B33/34Burning methods combined with glazing
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The present invention relates to a kind of ceramic technology field, more particularly to a kind of plum green color glaze and preparation method thereof.The plum green color glaze is by major ingredient and auxiliary material in mass ratio 56:1 composition, the major ingredient are formed by the Raw material processing of following parts by weight:Profound 15 25 parts of the glaze soil of Huangshi, 10 15 parts of organobentonite, 20 30 parts of little Mei glaze soil, 20 30 parts of small stream mouth glaze soil, 15 25 parts of Zhou village glaze soil, 5 10 parts of kaolin, the auxiliary material is formed by the Raw material processing of following parts by weight:20 40 parts of Cab-O-sil, 6 12 parts of soda ash, 10 18 parts of feldspar powder, 10 ~ 15 parts of aluminium hydroxide, 58 parts of zinc oxide, 8 12 parts of calcium carbonate, 68 parts of borax, 26 parts of potassium carbonate, 6 10 parts of barium sulfate.The new plum green color glaze raw material selection is reasonable, temperature-controllable of cooking, and high yield rate, product homogeneity is good, and processing controllability is good.

Description

A kind of plum green color glaze and preparation method thereof
Technical field
The present invention relates to a kind of ceramic technology field, more particularly to a kind of plum green color glaze and preparation method thereof.
Background technology
Longquan, Zhejiang Province brother's kiln is one of Chinese five big kilns of Song Dynasty, its produce plum green glaze porcelain ware by generation treasure.Zhejiang The preparation process of Jiang Longquan brother's kilns is:Celadon product is different with the shrinking percentage of tire using glaze in the cooling procedure after burning till, glaze Irregular texture is cracked into, forms the celadon product of exquisiteness.
But plum green color glaze glaze of the prior art selection is harsh, and firing temperature is difficult to control, yield rate is low during klining, quality Influenced greatly by processing qualification, homogeneity is poor, therefore urgently develops a kind of new plum green color glaze.
The content of the invention
A kind of deficiency it is an object of the present invention to the plum green color glaze for solving the prior art, there is provided new plum Cyan glaze, the new plum green color glaze raw material selection is reasonable, firing temperature is controllable, and high yield rate, product homogeneity is good, and processing can Control property is good.
The second object of the present invention is to provide a kind of preparation method of new plum green color glaze.
The third object of the present invention is to provide a kind of secret color glaze porcelain being process using the new plum green color glaze.
The technical solution adopted by the present invention to solve the technical problems is:
A kind of plum green color glaze, the plum green color glaze is by major ingredient and auxiliary material 5-6 in mass ratio:1 composition, the major ingredient is by following The Raw material processing of parts by weight forms:15-25 parts of Huangshi profound glaze soil, 10-15 parts of organobentonite, 20-30 parts of little Mei glaze soil, small stream Mouthful 20-30 parts of glaze soil, 15-25 parts of Zhou village glaze soil, 5-10 parts of kaolin, the auxiliary material by the Raw material processing of following parts by weight and Into:20-40 parts of Cab-O-sil, 6-12 parts of soda ash, 10-18 parts of feldspar powder, 10 ~ 15 parts of aluminium hydroxide, 5-8 parts of zinc oxide, carbonic acid 8-12 parts of calcium, 6-8 parts of borax, 2-6 parts of potassium carbonate, 6-10 parts of barium sulfate.
Preferably, the plum green color glaze is by major ingredient and auxiliary material in mass ratio 6:1 composition, the major ingredient is by following parts by weight Raw material processing form:Profound 20 parts of the glaze soil of Huangshi, 12 parts of organobentonite, 25 parts of little Mei glaze soil, 25 parts of small stream mouth glaze soil, Zhou village 20 parts of glaze soil, 8 parts of kaolin, the auxiliary material is formed by the Raw material processing of following parts by weight:30 parts of Cab-O-sil, 10 parts of soda ash are long 12 parts of mountain flour, 12 parts of aluminium hydroxide, 6 parts of zinc oxide, 10 parts of calcium carbonate, 6 parts of borax, 4 parts of potassium carbonate, 8 parts of barium sulfate.
A kind of preparation method of plum green color glaze, the preparation method step are as follows:
(1)The profound glaze soil of the Huangshi of formula ratio, organobentonite, little Mei glaze soil, small stream mouth glaze soil, Zhou village glaze soil and kaolin are mixed Conjunction obtains major ingredient;
(2)By the Cab-O-sil of formula ratio, soda ash, feldspar powder, aluminium hydroxide, zinc oxide, calcium carbonate, borax, potassium carbonate and sulfuric acid Barium is mixed to get auxiliary material;
(3)Major ingredient and auxiliary material are mixed in proportion, mixture is mixed with ballstone, water 1 ﹕ 0.8-0.9 of 1.3-1.5 ﹕ in mass ratio, is filled Glaze slip is obtained after dividing grinding;
(4), in 750~850 DEG C of biscuitings, it will be cooled down after secret color glaze porcelain body drying;
(5)By step(3)Glaze slip to be modulated into water content be 30-35%, interior glaze is applied to the color glaze porcelain billet body using glaze method is swung, Then outer glaze is applied to color glaze porcelain billet body using dipping in glaze method;
(6)Color glaze porcelain billet body after glazing is fired by glaze, obtains plum green color glaze.
Preferably, step(6)Described in be fired by glaze and include evaporation stage, reduction phase successively, into porcelain stage and holding stage,
The temperature of the evaporation stage is 400-480 DEG C;
The temperature of the reduction phase is 950-1000 DEG C;
The temperature into the porcelain stage is 1080-1150 DEG C;
The temperature of the holding stage is 1080-1150 DEG C, 5-8min.
The beneficial effects of the invention are as follows:The new plum green color glaze raw material selection is reasonable, temperature-controllable of cooking, yield rate Height, product homogeneity is good, and processing controllability is good.
Embodiment
Below by specific embodiment, technical scheme is described in further detail.
Embodiment 1:
A kind of plum green color glaze, the plum green color glaze is by major ingredient and auxiliary material in mass ratio 5:1 composition, the major ingredient is by following heavy The Raw material processing of amount part forms:Profound 15 parts of the glaze soil of Huangshi, 10 parts of organobentonite, 20 parts of little Mei glaze soil, 20 parts of small stream mouth glaze soil, 15 parts of Zhou village glaze soil, 5 parts of kaolin, the auxiliary material is formed by the Raw material processing of following parts by weight:20 parts of Cab-O-sil, soda ash 6 Part, 10 parts of feldspar powder, 10 parts of aluminium hydroxide, 5 parts of zinc oxide, 8 parts of calcium carbonate, 6 parts of borax, 2 parts of potassium carbonate, barium sulfate 6 Part;
Its preparation methods steps are as follows:
(1)The profound glaze soil of the Huangshi of formula ratio, organobentonite, little Mei glaze soil, small stream mouth glaze soil, Zhou village glaze soil and kaolin are mixed Conjunction obtains major ingredient;
(2)By the Cab-O-sil of formula ratio, soda ash, feldspar powder, aluminium hydroxide, zinc oxide, calcium carbonate, borax, potassium carbonate and sulfuric acid Barium is mixed to get auxiliary material;
(3)Major ingredient and auxiliary material are mixed in proportion, mixture is mixed with 1 ﹕ 0.8 of ballstone, water 1.3 ﹕ in mass ratio, after being fully ground Obtain glaze slip;
(4), in 750-780 DEG C of biscuiting, it will be cooled down after secret color glaze porcelain body drying;
(5)By step(3)Glaze slip be modulated into water content as 30%, interior glaze is applied to the color glaze porcelain billet body using glaze method is swung, so Outer glaze is applied to color glaze porcelain billet body using dipping in glaze method afterwards;
(6)Color glaze porcelain billet body after glazing is fired by glaze, obtains plum green color glaze, step(6)Described in be fired by glaze and include successively Evaporation stage, reduction phase, into porcelain stage and holding stage,
The temperature of the evaporation stage is 400-420 DEG C;
The temperature of the reduction phase is 950-980 DEG C;
The temperature into the porcelain stage is 1080-1100 DEG C;
The temperature of the holding stage is 1080-1100 DEG C, 8min.
Embodiment 2:
A kind of plum green color glaze, the plum green color glaze is by major ingredient and auxiliary material in mass ratio 6:1 composition, the major ingredient is by following heavy The Raw material processing of amount part forms:Profound 25 parts of the glaze soil of Huangshi, 15 parts of organobentonite, 30 parts of little Mei glaze soil, 30 parts of small stream mouth glaze soil, 25 parts of Zhou village glaze soil, 10 parts of kaolin, the auxiliary material is formed by the Raw material processing of following parts by weight:40 parts of Cab-O-sil, soda ash 12 Part, 18 parts of feldspar powder, 15 parts of aluminium hydroxide, 8 parts of zinc oxide, 12 parts of calcium carbonate, 8 parts of borax, 6 parts of potassium carbonate, barium sulfate 10 Part, magnetic order mesoporous 15 parts of nickel ferrite based magnetic loaded.
Its preparation methods steps are as follows:
(1)The profound glaze soil of the Huangshi of formula ratio, organobentonite, little Mei glaze soil, small stream mouth glaze soil, Zhou village glaze soil and kaolin are mixed Conjunction obtains major ingredient;
(2)By the Cab-O-sil of formula ratio, soda ash, feldspar powder, aluminium hydroxide, zinc oxide, calcium carbonate, borax, potassium carbonate and sulfuric acid Barium is mixed to get auxiliary material;
(3)Major ingredient and auxiliary material are mixed in proportion, mixture is mixed with 1 ﹕ 0.9 of ballstone, water 1.5 ﹕ in mass ratio, after being fully ground Obtain glaze slip;
(4), in 820~850 DEG C of biscuitings, it will be cooled down after secret color glaze porcelain body drying;
(5)By step(3)Glaze slip be modulated into water content as 35%, interior glaze is applied to the color glaze porcelain billet body using glaze method is swung, so Outer glaze is applied to color glaze porcelain billet body using dipping in glaze method afterwards;
(6)Color glaze porcelain billet body after glazing is fired by glaze, obtains plum green color glaze, step(6)Described in be fired by glaze and include successively Evaporation stage, reduction phase, into porcelain stage and holding stage,
The temperature of the evaporation stage is 460-480 DEG C;
The temperature of the reduction phase is 980-1000 DEG C;
The temperature into the porcelain stage is 1130-1150 DEG C;
The temperature of the holding stage is 1130-1150 DEG C, 5min.
Embodiment 3:
A kind of plum green color glaze, the plum green color glaze is by major ingredient and auxiliary material in mass ratio 6:1 composition, the major ingredient is by following heavy The Raw material processing of amount part forms:Profound 20 parts of the glaze soil of Huangshi, 12 parts of organobentonite, 25 parts of little Mei glaze soil, 25 parts of small stream mouth glaze soil, 20 parts of Zhou village glaze soil, 8 parts of kaolin, the auxiliary material is formed by the Raw material processing of following parts by weight:30 parts of Cab-O-sil, soda ash 10 Part, 12 parts of feldspar powder, 12 parts of aluminium hydroxide, 6 parts of zinc oxide, 10 parts of calcium carbonate, 6 parts of borax, 4 parts of potassium carbonate, barium sulfate 8 Part, magnetic order mesoporous 10 parts of nickel ferrite based magnetic loaded.
Its preparation methods steps are as follows:
(1)The profound glaze soil of the Huangshi of formula ratio, organobentonite, little Mei glaze soil, small stream mouth glaze soil, Zhou village glaze soil and kaolin are mixed Conjunction obtains major ingredient;
(2)By the Cab-O-sil of formula ratio, soda ash, feldspar powder, aluminium hydroxide, zinc oxide, calcium carbonate, borax, potassium carbonate and sulfuric acid Barium is mixed to get auxiliary material;
(3)Major ingredient and auxiliary material are mixed in proportion, mixture is mixed with 1 ﹕ 0.85 of ballstone, water 1.4 ﹕ in mass ratio, is fully ground After obtain glaze slip;
(4), in 800-820 DEG C of biscuiting, it will be cooled down after secret color glaze porcelain body drying;
(5)By step(3)Glaze slip be modulated into water content as 32%, interior glaze is applied to the color glaze porcelain billet body using glaze method is swung, so Outer glaze is applied to color glaze porcelain billet body using dipping in glaze method afterwards;
(6)Color glaze porcelain billet body after glazing is fired by glaze, obtains plum green color glaze, step(6)Described in be fired by glaze and include successively Evaporation stage, reduction phase, into porcelain stage and holding stage,
The temperature of the evaporation stage is 450-460 DEG C;
The temperature of the reduction phase is 980-990 DEG C;
The temperature into the porcelain stage is 1110-1120 DEG C;
The temperature of the holding stage is 1110-1120 DEG C, 6min.
The plum green color glaze raw material of embodiment 1-3 selects reasonable, temperature-controllable of cooking, and high yield rate, product homogeneity is good, It is good to process controllability.Embodiment described above is a kind of preferable scheme of the present invention, not makees any shape to the present invention Limitation in formula, also has other variations and remodeling on the premise of without departing from the technical solution described in claim.

Claims (4)

1. a kind of plum green color glaze, it is characterised in that the plum green color glaze is by major ingredient and auxiliary material 5-6 in mass ratio:1 composition, The major ingredient is formed by the Raw material processing of following parts by weight:15-25 parts of Huangshi profound glaze soil, 10-15 parts of organobentonite, little Mei 20-30 parts of glaze soil, 20-30 parts of small stream mouth glaze soil, 15-25 parts of Zhou village glaze soil, 5-10 parts of kaolin, the auxiliary material is by following parts by weight Raw material processing form:20-40 parts of Cab-O-sil, 6-12 parts of soda ash, 10-18 parts of feldspar powder, 10 ~ 15 parts of aluminium hydroxide, oxidation 5-8 parts of zinc, 8-12 parts of calcium carbonate, 6-8 parts of borax, 2-6 parts of potassium carbonate, 6-10 parts of barium sulfate.
A kind of 2. plum green color glaze according to claim 1, it is characterised in that:The plum green color glaze is by major ingredient and auxiliary material In mass ratio 6:1 composition, the major ingredient are formed by the Raw material processing of following parts by weight:Profound 20 parts of the glaze soil of Huangshi, organobentonite 12 parts, 25 parts of little Mei glaze soil, 25 parts of small stream mouth glaze soil, 20 parts of Zhou village glaze soil, 8 parts of kaolin, the auxiliary material is by following parts by weight Raw material processing forms:30 parts of Cab-O-sil, 10 parts of soda ash, 12 parts of feldspar powder, 12 parts of aluminium hydroxide, 6 parts of zinc oxide, calcium carbonate 10 Part, 6 parts of borax, 4 parts of potassium carbonate, 8 parts of barium sulfate.
A kind of 3. preparation method of the plum green color glaze described in claim 1 or 2, it is characterised in that:The preparation method step It is as follows:
(1)The profound glaze soil of the Huangshi of formula ratio, organobentonite, little Mei glaze soil, small stream mouth glaze soil, Zhou village glaze soil and kaolin are mixed Conjunction obtains major ingredient;
(2)By the Cab-O-sil of formula ratio, soda ash, feldspar powder, aluminium hydroxide, zinc oxide, calcium carbonate, borax, potassium carbonate and sulfuric acid Barium is mixed to get auxiliary material;
(3)Major ingredient and auxiliary material are mixed in proportion, mixture is mixed with ballstone, water 1 ﹕ 0.8-0.9 of 1.3-1.5 ﹕ in mass ratio, is filled Glaze slip is obtained after dividing grinding;
(4), in 750~850 DEG C of biscuitings, it will be cooled down after secret color glaze porcelain body drying;
(5)By step(3)Glaze slip to be modulated into water content be 30-35%, interior glaze is applied to the color glaze porcelain billet body using glaze method is swung, Then outer glaze is applied to color glaze porcelain billet body using dipping in glaze method;
(6)Color glaze porcelain billet body after glazing is fired by glaze, obtains plum green color glaze.
4. the preparation method of plum green color glaze according to claim 1, it is characterised in that:Step(6)Described in glaze firing according to It is secondary including evaporation stage, reduction phase, into porcelain stage and holding stage,
The temperature of the evaporation stage is 400-480 DEG C;
The temperature of the reduction phase is 950-1000 DEG C;
The temperature into the porcelain stage is 1080-1150 DEG C;
The temperature of the holding stage is 1080-1150 DEG C, 5-8min.
CN201711142929.8A 2017-11-17 2017-11-17 A kind of plum green color glaze and preparation method thereof Pending CN107986622A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108640514A (en) * 2018-06-25 2018-10-12 浙江东度文化创意有限公司 Secret color glaze layer of celadon of sustained-release antibacterial and preparation method thereof
CN108675635A (en) * 2018-06-25 2018-10-19 浙江东度文化创意有限公司 A kind of secret color glaze of celadon and preparation method thereof
CN108706871A (en) * 2018-06-25 2018-10-26 浙江东度文化创意有限公司 Can generating negative ions glaze and preparation method thereof
CN109608045A (en) * 2019-02-18 2019-04-12 青田县南方陶瓷原料有限公司 A kind of wear-resisting high-hardness ceramic glaze and preparation method thereof
CN109704578A (en) * 2019-02-18 2019-05-03 青田县南方陶瓷原料有限公司 A kind of antibacterial ceramic glaze and preparation method thereof that glaze is clear
CN111559865A (en) * 2020-07-07 2020-08-21 广东民洁卫浴有限公司 Colored glaze and preparation method thereof
CN114409373A (en) * 2022-01-05 2022-04-29 丽水学院 She-family-element-containing celadon and preparation method thereof
CN115594402A (en) * 2022-12-15 2023-01-13 箭牌家居集团股份有限公司(Cn) Sanitary ceramic glaze, preparation method thereof and sanitary ceramic product

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CN103466938A (en) * 2013-08-09 2013-12-25 申英良 Soft-light colored glass, and preparation method and use thereof
CN105399329A (en) * 2015-07-17 2016-03-16 郑峰 Preparation method and glaze material of celadon secret color glaze
CN105753322A (en) * 2016-03-13 2016-07-13 浙江天丰陶瓷有限公司 Medium-temperature plum green glaze and medium-temperature plum green Longquan celadon
CN106167391A (en) * 2016-06-12 2016-11-30 龙泉瓯江青瓷有限公司 Longquan celadon reinforced porcelain processing technology
CN107265860A (en) * 2017-07-21 2017-10-20 龙泉市宏鑫瓷业有限公司 A kind of celadon antibacterial glaze water and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN103466938A (en) * 2013-08-09 2013-12-25 申英良 Soft-light colored glass, and preparation method and use thereof
CN105399329A (en) * 2015-07-17 2016-03-16 郑峰 Preparation method and glaze material of celadon secret color glaze
CN105753322A (en) * 2016-03-13 2016-07-13 浙江天丰陶瓷有限公司 Medium-temperature plum green glaze and medium-temperature plum green Longquan celadon
CN106167391A (en) * 2016-06-12 2016-11-30 龙泉瓯江青瓷有限公司 Longquan celadon reinforced porcelain processing technology
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108640514A (en) * 2018-06-25 2018-10-12 浙江东度文化创意有限公司 Secret color glaze layer of celadon of sustained-release antibacterial and preparation method thereof
CN108675635A (en) * 2018-06-25 2018-10-19 浙江东度文化创意有限公司 A kind of secret color glaze of celadon and preparation method thereof
CN108706871A (en) * 2018-06-25 2018-10-26 浙江东度文化创意有限公司 Can generating negative ions glaze and preparation method thereof
CN109608045A (en) * 2019-02-18 2019-04-12 青田县南方陶瓷原料有限公司 A kind of wear-resisting high-hardness ceramic glaze and preparation method thereof
CN109704578A (en) * 2019-02-18 2019-05-03 青田县南方陶瓷原料有限公司 A kind of antibacterial ceramic glaze and preparation method thereof that glaze is clear
CN109608045B (en) * 2019-02-18 2021-12-07 青田县南方玻纤原料有限公司 Wear-resistant high-hardness ceramic glaze and preparation method thereof
CN109704578B (en) * 2019-02-18 2021-12-07 青田县南方玻纤原料有限公司 Antibacterial ceramic glaze with clear glaze surface and preparation method thereof
CN111559865A (en) * 2020-07-07 2020-08-21 广东民洁卫浴有限公司 Colored glaze and preparation method thereof
CN114409373A (en) * 2022-01-05 2022-04-29 丽水学院 She-family-element-containing celadon and preparation method thereof
CN115594402A (en) * 2022-12-15 2023-01-13 箭牌家居集团股份有限公司(Cn) Sanitary ceramic glaze, preparation method thereof and sanitary ceramic product

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Application publication date: 20180504