CN110003767A - A kind of anti-skidding mould proof floor paint of environment-friendly solvent-free and the preparation method and application thereof - Google Patents
A kind of anti-skidding mould proof floor paint of environment-friendly solvent-free and the preparation method and application thereof Download PDFInfo
- Publication number
- CN110003767A CN110003767A CN201910212921.7A CN201910212921A CN110003767A CN 110003767 A CN110003767 A CN 110003767A CN 201910212921 A CN201910212921 A CN 201910212921A CN 110003767 A CN110003767 A CN 110003767A
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- China
- Prior art keywords
- environment
- mould proof
- friendly solvent
- floor paint
- free
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses anti-skidding mould proof floor paints of a kind of environment-friendly solvent-free and the preparation method and application thereof, and by weight percentage, raw material includes following components: epoxy resin 30~60%, color sand 30~50%, auxiliary agent 1~4%, curing agent 5~20%.The anti-skidding mould proof floor paint of environment-friendly solvent-free provided by the invention not only remains existing floor tile advantage easy for construction, and accomodation ground is made to have color sand effect, decorative surface, skid resistance and artistry, opposite toilet often with the color unicity of floor tile, there are seam, shelter evil people and countenance evil practices, ground is easily sliding and poor waterproof properties the disadvantages of, have a very significant increase.
Description
Technical field
The present invention relates to floor paint fields, more particularly to a kind of anti-skidding mould proof floor paint of environment-friendly solvent-free and its preparation side
Method and application.
Background technique
As the improvement of people's living standards, people constantly pursue on the surface decoration materials such as toilet, kitchen, balcony
It is superior, as bright as a sixpence vitrified tile, floor tile are largely selected, fashion, noble purpose are had reached.However, these flooring boards
Once material is moist or ponding, and the accidents such as be easy to slip in active procedure, in the bathroom, especially soapsuds,
Under the effects of shower cream, shampoo, it is easier to which slip accident.
Currently, ordinary toilet floor treatment in the market is still to be laid with based on floor tile, although easy for construction, price is just
Preferably, but the color of floor tile it is single, there are seam, easily shelter evil people and countenance evil practices, ground is easily sliding and poor waterproof properties, and the later period be difficult to clean up it is dry
Only, it is difficult to renovate.
Therefore, anti-skidding, the mould proof problem for how improving accomodation ground, has caused the concern of people.
Summary of the invention
Technical problem to be solved by the present invention lies in provide a kind of anti-skidding mould proof floor paint of environment-friendly solvent-free and its preparation
Method and application make floor paint on the basis of keeping original floor tile feature easy for construction, increase the mould proof of ground, skid resistance,
Artistic effect, the feature of environmental protection, and reduce construction cost.
To achieve the above object, the present invention provides following schemes:
The present invention provides a kind of anti-skidding mould proof floor paint of environment-friendly solvent-free, by weight percentage, raw material include below at
Point:
Preferably, the epoxy resin is bisphenol A epoxide resin.
Preferably, the color sand is suspension lightweight circle color sand.Suspension lightweight color sand can float on the upper layer of floor paint, and one
Aspect enhances antiskid effect, and enhancing is decorative, on the other hand, can increase the weatherability of terrace.
Preferably, the partial size of the suspension lightweight circle color sand is 120-200 mesh.
Preferably, the curing agent is polyamide.It is highly preferred that the curing agent is polyamide YD8216,
The curing agent contains admittedly for 100%, is free of organic volatile, and the feature of environmental protection is good, and after mixing with epoxy resin, curing rate is fast, solidifies
Hardness is high, obdurability is good, chemical resistance is strong, and compact in paint film after solidification, and gap is not present, and bacterium can not adhere to and life
It deposits, there is good anti-mold effect.
Preferably, the auxiliary agent includes dispersing agent, defoaming agent and rheology modifier.It is highly preferred that dispersing agent is
BYK104S, defoaming agent BYK-141, rheology modifier BYK-410.Rheology modifier BYK-410 is by being precipitated the crystallization bodily form
Its thixotropy is realized at tridimensional network, also provides for superior anti-settling, resist sagging performance.When environment-friendly solvent-free is anti-skidding
When mould proof floor paint stores, rheology modifier BYK-410 is held suspension lightweight circle color sand using tridimensional network, effectively
It prevents from settling, while viscosity rises, and when construction, due to the shearing force certain to system, the net of rheology modifier BYK-410
Shape is destructurized, and viscosity declines rapidly, can reach construction requirement, and after shearing force disappears, this reticular structure is in several seconds
It can establish, suspension lightweight circle color sand can be made not settle and can be uniformly distributed in system.
The present invention also provides the preparation method of the anti-skidding mould proof floor paint of the environment-friendly solvent-free, the preparation method packet
It includes: epoxy resin and auxiliary agent being added in dispersion machine, stirs evenly, then color sand is added in dispersion machine, be uniformly mixed,
Component A is formed, curing agent is added in component A, the anti-skidding mould proof floor paint of the environment-friendly solvent-free is uniformly mixing to obtain.
Preferably, after epoxy resin and auxiliary agent being added to dispersion machine, the revolving speed of dispersion machine is adjusted to 800-
The revolving speed of dispersion machine is adjusted to 400-600rpm after color sand is added by 1000rpm.Be added color sand after, can not high speed dispersion, prevent
Only the structure of suspension lightweight circle color sand is destroyed.
The present invention provides the anti-skidding mould proof floor paint of environment-friendly solvent-free and is preparing toilet, balcony, in the terrace of kitchen
Application.
It is uniform to produce fluidised form using suspension lightweight circle color sand, simultaneously using the auxiliary agent of control color sand sedimentation by the present invention
The anti-skidding mould proof floor paint of environment-friendly solvent-free house ornamentation use in toilet, construction technology identical with traditional terrace, produce paint film cause
The naked leakage of close, part color sand in surface of the paint film, reach the anti-skidding synergy with anti-ponding, mildew proof, while it is again easy to clean
Floor paint assigns film simultaneously with the texture of art, and properties are very comprehensive.
Bisphenol A epoxide resin contains function monomer, and amido therein can reduce or eliminate the organic contamination in air
Object, therefore toilet air quality can be improved.Adjuvant used and curing agent is environment-friendly materials in the present invention, will not be to body
Harm is generated, and construction cost is lower.
Be added suspension lightweight circle color sand floor paint do not contain any dyestuff, have nontoxic, tasteless, wear-resisting, waterproof,
Anti-corrosion, anticorrosive, acid and alkali-resistance, it is uprising shine, the features such as lucuriant in design, tone is soft, three-dimensional sense is strong, cohesive force is strong, non-discolouring, i.e.,
Make to change colour by the flushing of the liquid such as shampoo, bath foam.The addition of color sand makes floor paint have stronger gas permeability,
Enhance the anti-mold effect of floor paint.
Specific embodiment
It is clearly and completely described below in conjunction with the technical solution in the embodiment of the present invention, it is clear that described reality
Applying example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is general
Logical technical staff every other embodiment obtained without making creative work belongs to what the present invention protected
Range.
In order to make the foregoing objectives, features and advantages of the present invention clearer and more comprehensible, With reference to embodiment
The present invention is described in further detail.
Embodiment 1-6
By weight percentage, including following component:
The preparation method of the anti-skidding mould proof floor paint of embodiment 1-6 environment-friendly solvent-free: according to it is described proportion by epoxy resin with
Auxiliary agent is added in dispersion machine, is adjusted the revolving speed of dispersion machine, is stirred under 800-1000rpm revolving speed, will then be suspended
Lightweight circle color sand is added in dispersion machine, is sufficiently mixed uniformly under 400-600rpm revolving speed, is formed component A；By curing agent plus
Enter into component A, stirs to obtain the anti-skidding mould proof floor paint of the environment-friendly solvent-free.
Environmentally friendly auxiliary agent in embodiment 1-6 includes dispersing agent, defoaming agent, rheology modifier, and wherein dispersing agent is
BYK104S, defoaming agent BYK-141, rheology modifier BYK-410, environment friendly curing agent are polyamide YD8216,
The composition and ratio of the anti-skidding mould proof floor paint of embodiment 1-6 environment-friendly solvent-free are shown in Table 1.
The component of comparative example 1-3 is shown in Table 1.The curing agent of comparative example 1 is diethylenetriamine, the rheology modifier of comparative example 2
For fumed silica, other auxiliary agents are same as Example 1.
Comparative example 3 is to add the floor paint of low dose of color sand, remaining component is same as Example 1.
Table 1
Paint film property is tested, paint film property is tested according to GB/T22374-2008 terrace coating material, as a result such as table 2
It is shown.
Table 2
Above-mentioned testing result shows that paint film intensity prepared by the present invention is high, and wearability is good, and paint film property reaches GB/
T22374-2008 related request.The curing agent of comparative example 1 changes, and the rheology modifier of comparative example 2 changes, terrace
The anti-skid wearable performance of paint has to be declined to a certain degree, a degree of blistering, peeling phenomenon occurs.It is main used in the present invention
Agent and auxiliary agent produce synergistic effect, enhance the anti-skidding fungicidal properties of floor paint, and comparative example 3 is to add the ground of low dose of color sand
Level ground paint, anti-skid factor significantly reduce.
The fungicidal properties of testing example 1-6 and comparative example 1-3: it according to HG/T 3950-2007, is examined using method for adhering film
The coating fungicidal properties is surveyed, embodiment 1-6 reaches six kinds of Candida albicans and aspergillus niger etc. the comprehensive mould suppression rates of killing as the result is shown
It is respectively as follows: 99.9% and 99.9% to 0 grade, while to the suppression rate of killing of staphylococcus aureus and Escherichia coli, 1-3 pairs of comparative example
Six kinds of Candida albicans and aspergillus niger etc. the comprehensive moulds suppression rates of killing are respectively II grade, II grade and not up to standard, to Staphylococcus aureus
The suppression rate of killing of bacterium and Escherichia coli is respectively as follows: 60.5% and 64.4%, 55.5% and 54.4%, 50.5% and 47.4%.
Workability test is done, is found: compared with traditional toilet floor tile, art effect of this product rich in cubic appearance
Fruit, it is mould proof, antiskid effect is excellent.
Bisphenol A type epoxy resin is due to its special construction, and under the irradiation of sunlight, phenyl ring is easily converted to quinoid knot
Structure makes paint film turn yellow, and is also easy to produce powder phenomenon-tion.The light that bisphenol A type epoxy resin can be improved in the color sand of addition large dosage is stablized
Property, powder phenomenon-tion will not occur prolonged application, so that the floor paint is achieved the effect that photostability, even if when long
Between use, color will not change.It is existing that within 3 years use time dusting does not occur for the floor paint of embodiment 1-6
As slight dusting occurs in 6 months for the floor paint of comparative example 3, and powder phenomenon-tion is serious in 12 months.
In the selection of auxiliary agent, using the auxiliary agent of environment-friendly solvent-free, common solvent type epoxy finishing coat construction gas is avoided
Highly seasoned, the defect of big, the serious damage construction personnel's health of toxicity has reached the requirement of environmental protection.
Embodiment described above is only that preferred embodiment of the invention is described, and is not carried out to the scope of the present invention
It limits, without departing from the spirit of the design of the present invention, those of ordinary skill in the art make technical solution of the present invention
Various changes and improvements, should all fall into claims of the present invention determine protection scope in.
Claims (9)
1. a kind of anti-skidding mould proof floor paint of environment-friendly solvent-free, which is characterized in that by weight percentage, raw material include below at
Point:
2. the anti-skidding mould proof floor paint of environment-friendly solvent-free according to claim 1, which is characterized in that the epoxy resin is double
Phenol A epoxy resin.
3. the anti-skidding mould proof floor paint of environment-friendly solvent-free according to claim 1, which is characterized in that the color sand is to suspend gently
Matter circle color sand.
4. the anti-skidding mould proof floor paint of environment-friendly solvent-free according to claim 3, which is characterized in that the suspension lightweight is round
The partial size of color sand is 120-200 mesh.
5. the anti-skidding mould proof floor paint of environment-friendly solvent-free according to claim 1, which is characterized in that the curing agent is polyamides
Polyimide resin.
6. the anti-skidding mould proof floor paint of environment-friendly solvent-free according to claim 1, which is characterized in that the auxiliary agent includes dispersion
Agent, defoaming agent and rheology modifier.
7. the preparation method of the anti-skidding mould proof floor paint of environment-friendly solvent-free described in claim 1, which is characterized in that by epoxy resin
It is added in dispersion machine, stirs evenly with auxiliary agent, then color sand is added in dispersion machine, be uniformly mixed, form component A, it will
Curing agent is added in component A, is uniformly mixing to obtain the anti-skidding mould proof floor paint of the environment-friendly solvent-free.
8. the preparation method of the anti-skidding mould proof floor paint of environment-friendly solvent-free according to claim 7, which is characterized in that by epoxy
After resin and auxiliary agent are added to dispersion machine, the revolving speed of dispersion machine is adjusted to 800-1000rpm, after color sand is added, by dispersion machine
Revolving speed be adjusted to 400-600rpm.
9. the application of the anti-skidding mould proof floor paint of environment-friendly solvent-free described in claim 1, which is characterized in that the environment-friendly solvent-free
Anti-skidding mould proof floor paint is preparing toilet, balcony, the application in the terrace of kitchen.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910212921.7A CN110003767A (en) | 2019-03-20 | 2019-03-20 | A kind of anti-skidding mould proof floor paint of environment-friendly solvent-free and the preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910212921.7A CN110003767A (en) | 2019-03-20 | 2019-03-20 | A kind of anti-skidding mould proof floor paint of environment-friendly solvent-free and the preparation method and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110003767A true CN110003767A (en) | 2019-07-12 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910212921.7A Withdrawn CN110003767A (en) | 2019-03-20 | 2019-03-20 | A kind of anti-skidding mould proof floor paint of environment-friendly solvent-free and the preparation method and application thereof |
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| CN (1) | CN110003767A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114262560A (en) * | 2021-11-12 | 2022-04-01 | 海洋化工研究院有限公司 | Light corrosion-resistant anti-slip coating and construction method thereof |
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| CN101210149A (en) * | 2007-12-21 | 2008-07-02 | 浙江中成建工集团有限公司 | Antiskid ventilating epoxide terrace paint |
| WO2008147079A1 (en) * | 2007-05-31 | 2008-12-04 | Sang Yang Kim | Epoxy resin mortar composition and coating method on the surface of the concrete |
| CN102108235A (en) * | 2010-12-31 | 2011-06-29 | 亚士漆(上海)有限公司 | Solvent type epoxy picking finish coat |
| CN102127358A (en) * | 2010-12-31 | 2011-07-20 | 亚士漆(上海)有限公司 | Solvent-free picking finish paint |
| CN107245287A (en) * | 2017-07-26 | 2017-10-13 | 富思特新材料科技发展股份有限公司 | Anti-skidding finish paint of illusion-colour drawn grain and preparation method thereof |
-
2019
- 2019-03-20 CN CN201910212921.7A patent/CN110003767A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008147079A1 (en) * | 2007-05-31 | 2008-12-04 | Sang Yang Kim | Epoxy resin mortar composition and coating method on the surface of the concrete |
| CN101210149A (en) * | 2007-12-21 | 2008-07-02 | 浙江中成建工集团有限公司 | Antiskid ventilating epoxide terrace paint |
| CN102108235A (en) * | 2010-12-31 | 2011-06-29 | 亚士漆(上海)有限公司 | Solvent type epoxy picking finish coat |
| CN102127358A (en) * | 2010-12-31 | 2011-07-20 | 亚士漆(上海)有限公司 | Solvent-free picking finish paint |
| CN107245287A (en) * | 2017-07-26 | 2017-10-13 | 富思特新材料科技发展股份有限公司 | Anti-skidding finish paint of illusion-colour drawn grain and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114262560A (en) * | 2021-11-12 | 2022-04-01 | 海洋化工研究院有限公司 | Light corrosion-resistant anti-slip coating and construction method thereof |
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Application publication date: 20190712 |
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