CN108276906A - A kind of anti-fouling agent for anti-skidding Dali stone ceramic tile - Google Patents
A kind of anti-fouling agent for anti-skidding Dali stone ceramic tile Download PDFInfo
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- CN108276906A CN108276906A CN201810022517.9A CN201810022517A CN108276906A CN 108276906 A CN108276906 A CN 108276906A CN 201810022517 A CN201810022517 A CN 201810022517A CN 108276906 A CN108276906 A CN 108276906A
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- Prior art keywords
- ceramic tile
- component
- skidding
- fouling agent
- dali stone
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1618—Non-macromolecular compounds inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1637—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
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Abstract
The invention discloses a kind of anti-fouling agent for anti-skidding Dali stone ceramic tile, the anti-fouling agent includes component A and B component, and the weight ratio of the component A and B component is 0.5:1~4.0:1, the component A is organic siliconresin, and the B component is nanometer bleeding agent.Anti-fouling agent disclosed by the invention for anti-skidding Dali stone ceramic tile can not only improve the non-skid property of Dali stone ceramic tile, and may be implemented persistently antifouling, while not influence the surface decoration effect of Dali stone ceramic tile again.
Description
Technical field
The present invention relates to a kind of anti-fouling agents for anti-skidding Dali stone ceramic tile.
Background technology
With economic continuous development and the raising of domestic level, people for interior decoration visual effect and
The requirement of properties of product is more stringent.Dali stone ceramic tile imitates natural marble lines, and good visual effect is presented, meets
Pursuit of the people for lithotome U.S..But Dali stone ceramic tile also needs to be safeguarded in use, for example make
The brick for making spot penetrate into brick body destruction ceramic tile because of the consumption of stain-proofing layer need to be prevented with after a period of time in surface smear protective layer
Face effect.Therefore, the anti-fouling effect of Dali stone ceramic tile is paid attention to by consumers in general.
The smooth surface that Dali stone ceramic tile is formed in polishing process in meeting jettisoning sintering process, to expose pore
And micro-crack, being easy the sundries such as adsorbent solid particle, liquid causes brick face contaminated.Most of glaze mirror polish on the market now
Brick is all to improve brick face glossiness and antifouling capacity to be filled micro-crack and pore to reach using wax water.But wax water
The protective film wearability being formed by curing is poor, is easily damaged after repeatedly scrubbing, and ceramic tile surface antifouling capacity is lost.
Chinese patent 201610880415.1 discloses a kind of preparation process of antifouling anti-skid brick, by brick face coating adhesive
Liquid solution forms one layer of waterproof membrane to play anti-fouling effect after its drying.Anti-dirtying liquid ingredient used in the patent is Silicon Containing Hydrogen
Oil, alkali resistance is very poor, is easy to be corroded by alkaline cleaner in cleaning；Silica gel solution is also easy to be ground after being immersed in water
Damage is fallen, and causes antifouling capacity not lasting.
Chinese patent 201410185232.9 discloses a kind of clean bright technique of coloured polished brick, antifouling by being coated in brick face
Liquid and silicone oil carry out sealed porosity and reach antifouling purpose.Anti-dirtying liquid used in the patent is mixed by silicon dioxide gel and water-soluble mill base
It forms, water-soluble mill base keeps its color consistent with ceramic tile according to ceramic tile color to adjust formula, produces the porcelain of different colours every time
Brick will replace mill base and cleaning container, complex process；Simultaneously when producing the ceramic tile of color complexity, the configuration of water-soluble mill base and
Coating will be the insurmountable problem of this method, be unfavorable for producing the glaze polished bricks of multiple color.
Dali stone ceramic tile refers to having natural marble texture true to nature, color, penetrating and texture a kind of tile product,
Superior function with natural marble decorative effect true to nature and ceramic tile.It is compared to other ceramic tile categories, Dali stone ceramic tile
It must assure that again while chasing superior practical performance on the decorative effects such as texture, color, penetrating, texture and feel completely
Reach the vivid effect of natural marble, so other ceramic tile categories will be significantly larger than by promoting the difficulty of the practicality energy.
Invention content
For the unabiding problem of anti-dirtying liquid anti-fouling effect at present on the market, the purpose of the present invention is to provide a kind of use
In the anti-fouling agent of anti-skidding Dali stone ceramic tile.Organic siliconresin itself in the anti-fouling agent has certain non-skid property, receives simultaneously
Rice anti-fouling agent can be furnished with the transparent stain-proofing layer of discontinuous pit in ceramic tile surface cure component.Therefore, anti-fouling agent can not only carry
The non-skid property of high marble ceramic tile, and may be implemented persistently antifouling, while not influencing the incrustation of Dali stone ceramic tile again
Effect.
To achieve the above object, the technical solution adopted in the present invention is：It is a kind of to be used for the antifouling of anti-skidding Dali stone ceramic tile
Agent, the anti-fouling agent include component A and B component, and the weight ratio of the component A and B component is 0.5:1~4.0:1, the A groups
It is divided into organic siliconresin, the B component is nanometer bleeding agent.
Preferably, the weight ratio of the component A and B component is 0.8:1~3.0:1.It is highly preferred that the component A and B groups
The weight ratio divided is 2:1.
Preferably, the organic siliconresin is by poly- alkyl organic resin, poly- aryl organic siliconresin, polyoxyethylene alkyl aryl base
One or more of organic siliconresin mixing composition.The organic siliconresin can form hydrophobic protective film on brick surface.It is more excellent
Selection of land, the organic siliconresin are by poly- alkyl organic resin, poly- aryl organic siliconresin and polyoxyethylene alkyl aryl Ji Youjiguishu
Fat mixing composition.Preferably, the poly- alkyl organic resin, poly- aryl organic siliconresin and polyoxyethylene alkyl aryl Ji Youjiguishu
Weight ratio is 1:1:2.
Preferably, the nanometer bleeding agent is inorganic nano dispersion liquid.The nanometer bleeding agent can be repaired, fill polishing
And after corrosion process ceramic tile surface micro-crack and pore, prevent dunghill penetrate into wherein；Also, nanometer bleeding agent can be anti-
Sliding treated ceramic tile surface ceramic simultaneously forms the fine and close transparent stain-proofing layer that discontinuous shallow pits is distributed with.
Preferably, the anti-skidding Dali stone ceramic tile is the porcelain handled by surface corrosion or enamel polished bricks.
Preferably, the solid content of the B component is 5~20%.Preferably, the solid content of the B component is 9~18%.
Most preferably, the solid content of the B component is 16%.
The preparation method of anti-fouling agent of the present invention is to be uniformly mixed component A and B component can be obtained.
The thinking and key problem in technology of the present invention is the nano inorganic in organic siliconresin small molecule and B component in component A
Particle can effectively penetrate into the micro-crack and pore on brick surface, and both final formed by crosslinking curing transparent has
The ceramic stain-proofing layer of tridimensional network, the stain-proofing layer have the abrasion resistance and hardness of ceramics, may be implemented it is lasting antifouling, and
And it can effectively promote the non-skid property of Dali stone ceramic tile with very strong hydrophobicity；In addition, by controlling A, B component
The adhesion of anti-fouling agent is adjusted in different proportion, the marble porcelain with shallow pits after making it preferably be fitted in anti-skidding processing
Brick surface forms the fine and close stain-proofing layer that shallow pits is equally distributed with, keeps the effect of anti-skidding processing.
Compared with prior art, the beneficial effects of the present invention are：
Anti-fouling agent of the present invention for anti-skidding Dali stone ceramic tile can not only improve the non-skid property of Dali stone ceramic tile,
And may be implemented persistently it is antifouling, promote the competitiveness of product；The original property indices of ceramic tile are not influenced, such as texture, color
Damp, penetrating, texture；Cost is relatively low, with material environmental protection, will not generate pollution to ambient enviroment.
Specific implementation mode
With reference to embodiments further the present invention will be described, but present disclosure be not limited solely to it is following
Embodiment.Following embodiment is to be coated with the present invention through identical anti-skidding corrosion treatment condition treated marble ceramic tile surface
Anti-fouling agent.
Embodiment 1
Anti-fouling agent of the present invention is coated on the marble ceramic tile surface after anti-skidding corrosion treatment by wax-polishing machine, wherein group
It is 0.8 to divide the weight ratio of A, B:1, component A is poly- methylsiloxane resin, and it is 9% that B component nano inorganic, which disperses fluid solid content,.
Using the anti-fouling agent treated anti-skidding Dali stone ceramic tile, the coefficient of sliding friction is 0.73, by GB/T3810.7
Regulation to examine wear-resisting grade be 4 grades, it is 5 grades to examine antifouling grade by the regulation of GB/T3810.14, and Mohs' hardness is 5 grades.And
The performances such as texture, color and luster, the penetrating, texture of the Dali stone ceramic tile do not have significant change.
Embodiment 2
Anti-fouling agent is coated on the marble ceramic tile surface after anti-skidding corrosion treatment by wax-polishing machine, wherein component A, B
Weight ratio is 3:1, component A is poly- ethyl organic siliconresin and poly- aryl organic siliconresin, weight ratio 1:1, B component is received
It is 18% that meter Wu Ji, which disperses fluid solid content,.
Using the anti-fouling agent treated anti-skidding Dali stone ceramic tile, the coefficient of sliding friction is 0.76, by GB/T3810.7
Regulation to examine wear-resisting grade be 5 grades, it is 5 grades to examine antifouling grade by the regulation of GB/T3810.14, and Mohs' hardness is 6 grades.And
The performances such as texture, color and luster, the penetrating, texture of the Dali stone ceramic tile do not have significant change.
Embodiment 3
Anti-fouling agent is coated on the marble ceramic tile surface after anti-skidding corrosion treatment by wax-polishing machine, wherein component A, B
Weight ratio is 2, and component A is poly- ethyl organic siliconresin, poly- aryl organic siliconresin and the mixing of polyoxyethylene alkyl aryl base organic siliconresin
It forms, weight ratio 1:1:2, it is 16% that B component nano inorganic, which disperses fluid solid content,.
Using the anti-fouling agent treated anti-skidding Dali stone ceramic tile, the coefficient of sliding friction is 0.78, by GB/T3810.7
Regulation to examine wear-resisting grade be 5 grades, it is 5 grades to examine antifouling grade by the regulation of GB/T3810.14, and Mohs' hardness is 6 grades.And
The performances such as texture, color and luster, the penetrating, texture of the Dali stone ceramic tile do not have significant change, the anti-fouling agent best results of the embodiment.
Comparative example 1
Anti-fouling agent is coated on the marble ceramic tile surface after anti-skidding corrosion treatment by wax-polishing machine, wherein component A, B
Weight ratio is 0.3, and component A is poly- aryl organic siliconresin, and it is 24% that B component nano inorganic, which disperses fluid solid content,.
Using the anti-fouling agent treated anti-skidding Dali stone ceramic tile, the coefficient of sliding friction is 0.51, by GB/T3810.7
Regulation to examine wear-resisting grade be 3 grades, it is 3 grades to examine antifouling grade by the regulation of GB/T3810.14, and Mohs' hardness is 4 grades.And
The performances such as texture, color and luster, the penetrating, texture of the Dali stone ceramic tile significantly decrease.
Comparative example 2
Anti-fouling agent is coated on the marble ceramic tile surface after anti-skidding corrosion treatment by wax-polishing machine, wherein component A, B
Weight ratio is 6:1, component A is that poly- alkyl organic resin and polyoxyethylene alkyl aryl base organic siliconresin mix, weight ratio
It is 1:1, it is 3% that B component nano inorganic, which disperses fluid solid content,.
Using the anti-fouling agent treated anti-skidding Dali stone ceramic tile, the coefficient of sliding friction is 0.55, by GB/T3810.7
Regulation to examine wear-resisting grade be 2 grades, it is 3 grades to examine antifouling grade by the regulation of GB/T3810.14, and Mohs' hardness is 3 grades.And
The performances such as texture, color and luster, the penetrating, texture of the Dali stone ceramic tile significantly decrease.
Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than is protected to the present invention
The limitation of range is protected, although being explained in detail to the present invention with reference to preferred embodiment, those skilled in the art should
Understand, technical scheme of the present invention can be modified or replaced equivalently, without departing from the essence of technical solution of the present invention
And range.
Claims (10)
1. a kind of anti-fouling agent for anti-skidding Dali stone ceramic tile, which is characterized in that the anti-fouling agent includes component A and B component, institute
The weight ratio for stating component A and B component is 0.5:1~4.0:1, the component A is organic siliconresin, and the B component is oozed for nanometer
Saturating agent.
2. being used for the anti-fouling agent of anti-skidding Dali stone ceramic tile as described in claim 1, which is characterized in that the component A and B component
Weight ratio be 0.8:1~3.0:1.
3. being used for the anti-fouling agent of anti-skidding Dali stone ceramic tile as described in claim 1, which is characterized in that the component A and B component
Weight ratio be 2:1.
4. being used for the anti-fouling agent of anti-skidding Dali stone ceramic tile as described in claim 1, which is characterized in that the organic siliconresin is
By one or more of poly- alkyl organic resin, poly- aryl organic siliconresin, polyoxyethylene alkyl aryl base organic siliconresin mixing group
At.
5. being used for the anti-fouling agent of anti-skidding Dali stone ceramic tile as claimed in claim 4, which is characterized in that the organic siliconresin is
It is made of the mixing of poly- alkyl organic resin, poly- aryl organic siliconresin and polyoxyethylene alkyl aryl base organic siliconresin.
6. being used for the anti-fouling agent of anti-skidding Dali stone ceramic tile as claimed in claim 5, which is characterized in that the poly- alkyl organic
The weight ratio of resin, poly- aryl organic siliconresin and polyoxyethylene alkyl aryl Ji Youjiguishu is 1:1:2.
7. being used for the anti-fouling agent of anti-skidding Dali stone ceramic tile as described in claim 1, which is characterized in that the nanometer bleeding agent is
Inorganic nano dispersion liquid.
8. being used for the anti-fouling agent of anti-skidding Dali stone ceramic tile as described in claim 1, which is characterized in that the anti-skidding marble porcelain
Brick is the porcelain handled by surface corrosion or enamel polished bricks.
9. being used for the anti-fouling agent of anti-skidding Dali stone ceramic tile as described in claim 1, which is characterized in that consolidating for the B component contains
Amount is 5~20%.
10. being used for the anti-fouling agent of anti-skidding Dali stone ceramic tile as claimed in claim 9, which is characterized in that consolidating for the B component contains
Amount is 9~18%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810022517.9A CN108276906A (en) | 2018-01-10 | 2018-01-10 | A kind of anti-fouling agent for anti-skidding Dali stone ceramic tile |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810022517.9A CN108276906A (en) | 2018-01-10 | 2018-01-10 | A kind of anti-fouling agent for anti-skidding Dali stone ceramic tile |
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| CN108276906A true CN108276906A (en) | 2018-07-13 |
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| CN201810022517.9A Pending CN108276906A (en) | 2018-01-10 | 2018-01-10 | A kind of anti-fouling agent for anti-skidding Dali stone ceramic tile |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110229022A (en) * | 2019-07-27 | 2019-09-13 | 广东特地陶瓷有限公司 | A kind of antibacterial mosquito dispersing ceramic tile and preparation method thereof |
| CN111303766A (en) * | 2020-04-26 | 2020-06-19 | 苏州佩托斯光学材料有限公司 | Optical panel nano anti-fouling agent and spraying method thereof |
| CN112745704A (en) * | 2019-10-31 | 2021-05-04 | 佛山市东鹏陶瓷有限公司 | High-gloss antiskid material and preparation method thereof |
| CN114249609A (en) * | 2021-12-06 | 2022-03-29 | 清远市简一陶瓷有限公司 | Preparation method of low-gloss antifouling brick |
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| CN2850906Y (en) * | 2005-10-08 | 2006-12-27 | 佛山欧神诺陶瓷有限公司 | Antifouling ceramic tile |
| CN1944348A (en) * | 2006-02-06 | 2007-04-11 | 霍镰泉 | Method for preparing silicon dioxide anti-pollution layer of polished glazed tile surface |
| CN105131831A (en) * | 2015-10-19 | 2015-12-09 | 广东富多新材料股份有限公司 | Stone material surface anti-fouling paint and method of applying same to marble surface for preventing fouling |
| CN106747658A (en) * | 2016-12-05 | 2017-05-31 | 广东纳德新材料有限公司 | Repairing agent for ceramic tiles and preparation method thereof |
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2018
- 2018-01-10 CN CN201810022517.9A patent/CN108276906A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2850906Y (en) * | 2005-10-08 | 2006-12-27 | 佛山欧神诺陶瓷有限公司 | Antifouling ceramic tile |
| CN1944348A (en) * | 2006-02-06 | 2007-04-11 | 霍镰泉 | Method for preparing silicon dioxide anti-pollution layer of polished glazed tile surface |
| CN105131831A (en) * | 2015-10-19 | 2015-12-09 | 广东富多新材料股份有限公司 | Stone material surface anti-fouling paint and method of applying same to marble surface for preventing fouling |
| CN106747658A (en) * | 2016-12-05 | 2017-05-31 | 广东纳德新材料有限公司 | Repairing agent for ceramic tiles and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110229022A (en) * | 2019-07-27 | 2019-09-13 | 广东特地陶瓷有限公司 | A kind of antibacterial mosquito dispersing ceramic tile and preparation method thereof |
| CN112745704A (en) * | 2019-10-31 | 2021-05-04 | 佛山市东鹏陶瓷有限公司 | High-gloss antiskid material and preparation method thereof |
| CN111303766A (en) * | 2020-04-26 | 2020-06-19 | 苏州佩托斯光学材料有限公司 | Optical panel nano anti-fouling agent and spraying method thereof |
| CN114249609A (en) * | 2021-12-06 | 2022-03-29 | 清远市简一陶瓷有限公司 | Preparation method of low-gloss antifouling brick |
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Application publication date: 20180713 |