CN107245287A - Anti-skidding finish paint of illusion-colour drawn grain and preparation method thereof - Google Patents

Anti-skidding finish paint of illusion-colour drawn grain and preparation method thereof Download PDF

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Publication number
CN107245287A
CN107245287A CN201710618214.9A CN201710618214A CN107245287A CN 107245287 A CN107245287 A CN 107245287A CN 201710618214 A CN201710618214 A CN 201710618214A CN 107245287 A CN107245287 A CN 107245287A
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CN
China
Prior art keywords
illusion
colour
finish paint
skidding
drawn grain
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710618214.9A
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Chinese (zh)
Inventor
李娅
于丽佳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
First New Material Science & Technology Development Co Ltd
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First New Material Science & Technology Development Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to CN201710618214.9A priority Critical patent/CN107245287A/en
Publication of CN107245287A publication Critical patent/CN107245287A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/28Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/346Clay
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of anti-skidding finish paint of illusion-colour drawn grain and preparation method thereof, the non slip surface enamel-cover includes following component by weight percentage:Epoxy resin 20~30%;Thixotropic agents 5~10%;Color stuffing 15~30%;Auxiliary agent 3.5~5%;Color sand particle 10~20%;Curing agent 15~20%.The anti-skidding finish paint is by adding bisphenol A type epoxy resin and modified amine curing agent, then is equipped with the color sand particle of organic resin synthesis, improves the hardness and resistance to marring of epoxy material.Thixotropic agents and color sand particle are equipped with solvent-free system so that after material makes, show color sand particle, while also having uniform concavo-convex paint film, there is a good skid resistance, i.e., it is attractive in appearance and have more excellent physical property.

Description

Anti-skidding finish paint of illusion-colour drawn grain and preparation method thereof
Technical field
The present invention relates to the finish paint field of construction material, more particularly to a kind of anti-skidding finish paint of illusion-colour drawn grain and its preparation side Method.
Background technology
Existing epoxide terrace finish paint has the following disadvantages:Hardness low (pencil hardness 2H)/resistance to marring is poor, uses one section Time easily grows dim, and coefficient of friction is low, and skid resistance is poor, and the VOC and the feature of environmental protection of existing epoxide terrace are poor.
The content of the invention
Based on the problems of prior art, it is an object of the invention to provide a kind of anti-skidding finish paint of illusion-colour drawn grain and its system Preparation Method, can solve that existing epoxide terrace soft, resistance to marring be poor, the problems such as growing dim, construct cumbersome of turning white after paint film abrasion.
The purpose of the present invention is achieved through the following technical solutions:
Embodiment of the present invention provides a kind of anti-skidding finish paint of illusion-colour drawn grain, including following component by weight percentage:
Embodiment of the present invention also provides a kind of preparation method of the anti-skidding finish paint of illusion-colour drawn grain, it is characterised in that for making The standby anti-skidding finish paint of illusion-colour drawn grain of the present invention, comprises the following steps:
Each raw material is taken by the formula of the anti-skidding finish paint of illusion-colour drawn grain of the present invention;
After epoxy resin addition auxiliary agent is well mixed, thixotropic agents and color stuffing are added while stirring, 20 are disperseed at a high speed After minute, below fineness 80um adds color sand particle and stirred mian paint is made;
Curing agent is added into above-mentioned mian paint, the anti-skidding finish paint of illusion-colour drawn grain is made after stirring.
As seen from the above technical solution provided by the invention, the anti-skidding finish paint of illusion-colour drawn grain provided in an embodiment of the present invention And preparation method thereof, its advantage is:
By adding bisphenol A type epoxy resin and modified amine curing agent, then the color sand particle of organic resin synthesis is equipped with, carried The hardness and resistance to marring of high epoxy material.Thixotropic agents and color sand particle are equipped with solvent-free system so that material makes Afterwards, show color sand particle, while also having uniform concavo-convex paint film, there is a good skid resistance, i.e., it is attractive in appearance and have more excellent thing Rationality energy.
Embodiment
With reference to the particular content of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely retouched State, it is clear that described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based on the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, Belong to protection scope of the present invention.
The embodiment of the present invention provides a kind of anti-skidding finish paint of illusion-colour drawn grain, including following component by weight percentage:
In above-mentioned anti-skidding finish paint, resin uses bisphenol A type epoxy resin.
In above-mentioned anti-skidding finish paint, curing agent uses modified fatty amine or modified polyether amine.
In above-mentioned anti-skidding finish paint, thixotropic agents are using bentonite and modified aerosil, and the consumption of each component is by unreal The percentage by weight meter of the total consumption of the color anti-skidding finish paint of drawn grain, be respectively:Bentonite 4~5%, modified aerosil 1~ 5%.
In above-mentioned anti-skidding finish paint, color sand particle uses import organic resin synthetic material.
In above-mentioned anti-skidding finish paint, the auxiliary agent includes:Defoamer, levelling agent and dispersant, the consumption of each component press illusion-colour The percentage by weight meter of the total consumption of the anti-skidding finish paint of drawn grain, be respectively:Defoamer 0.8~1.5%, levelling agent 1.7~2.5%, point Powder 1%.
In above-mentioned anti-skidding finish paint, the color stuffing uses titanium dioxide and filler, and the consumption of each component is anti-skidding by illusion-colour drawn grain The percentage by weight meter of the total consumption of finish paint:Titanium dioxide 0.5~1%, filler 14.5~29%.
The embodiment of the present invention also provides a kind of preparation method of the anti-skidding finish paint of illusion-colour drawn grain, it is characterised in that for preparing The above-mentioned anti-skidding finish paint of illusion-colour drawn grain, comprises the following steps:
Each raw material is taken by the formula of the above-mentioned anti-skidding finish paint of illusion-colour drawn grain;
After epoxy resin addition auxiliary agent is well mixed, thixotropic agents and color stuffing are added while stirring, 20 are disperseed at a high speed After minute, below fineness 80um (to meet production technology index request) adds color sand particle and stirred mian paint is made;
Curing agent is added into above-mentioned mian paint, the anti-skidding finish paint of illusion-colour drawn grain is made after stirring.
The embodiment of the present invention is specifically described in further detail below.
Embodiment 1:
The present embodiment provides a kind of anti-skidding finish paint of illusion-colour drawn grain, including following components, and its percentage by weight is:
(1) mian paint includes:
128 epoxy resin 30%
Color sand particle 13%
Color stuffing:
Titanium dioxide 0.5%
Filler 28%
Thixotropic agents:
Bentonite 4%
Modified aerosil 2%
Auxiliary agent:
Defoamer 0.8%
Levelling agent 1.7%
Dispersant 1%
(2) curing agent:
Modified amine curing agent 19%
After taking the 128 epoxy resin addition auxiliary agent in above-mentioned mian paint well mixed, the swollen of thixotropic agents is added while stirring The titanium dioxide and filler of profit soil and aerosil and color stuffing, after disperseing 20 minutes at a high speed, below fineness 80um, then add Enter color sand particle and stir mian paint is made;
Modified amine curing agent is added into obtained mian paint, finish paint is made after stirring, paint film is prepared with the finish paint, Paint film property is detected by GB/T22374-2008 standards, as a result as follows:
The finish paint that can be seen that the present invention from the above-mentioned paint film calculation of measured data to finish paint made from the present embodiment has high hard Degree, super abrasive and excellent adhesion strength.And construction appearance has the color sand granular sensation of tradition, with artistic effect, Preferably beautify the environment.
Embodiment 2:
The anti-skidding finish paint of illusion-colour drawn grain of the present invention, including following components, by weight percentage for:
(1) mian paint includes:
128 epoxy resin 23.5%
Color sand particle 20%
Auxiliary agent:
Defoamer 1%
Levelling agent 2%
Dispersant 1%
Thixotropic agents:
Bentonite 5%
Modified aerosil 3%
Color stuffing:
Titanium dioxide 0.5%
Filler 29%
(2) curing agent:
Modified amine curing agent 15%
Take 128 resins in above-mentioned auxiliary agent add auxiliary agent it is well mixed after, add while stirring thixotropic agents bentonite and Aerosil, titanium dioxide and filler, after disperseing 20 minutes at a high speed, below fineness 80um adds color sand particle stirring equal It is even that the mian paint is made.
Modified amine curing agent is proportionally added into, paint film is prepared after stirring, paint film property presses GB/T22374-2008 Standard is detected, as a result as follows:
Test event Standard requirement Testing result
Surface drying time ≤6h It is qualified
Do solid work the time ≤48h It is qualified
Pencil hardness ≥2H 4H
Wear-resisting (750g/500r) ≤30mg 14mg
I grade of shock resistance Flawless, nothing comes off It is qualified
Resistance to marring Nail is drawn without white trace It is excellent
Water resistance, 168h It is non-foaming, do not fall off It is qualified
The solution of resistance to 20%NaOH, 72h It is non-foaming, do not fall off It is qualified
Resistance to 10%H2SO4Solution, 48h It is non-foaming, do not fall off It is qualified
VOC(g/L) 60 28.3
Anti-skidding coefficient of friction ≥0.5 1.03
The finish paint that can be seen that the present invention from the above-mentioned paint film calculation of measured data to finish paint made from the present embodiment has high hard Degree, super abrasive, excellent adhesion strength.And construction appearance has the color sand granular sensation of tradition, with artistic effect, more preferably Beautify the environment.
Embodiment 3:
The anti-skidding finish paint of illusion-colour drawn grain of the present invention, including following components, by weight percentage for:
(1) mian paint includes:
128 epoxy resin 28%
Color sand particle 15%
Thixotropic agents:
Bentonite 4%
Modified aerosil 1%
Auxiliary agent:
Defoamer 1.2%
Levelling agent 2.5%
Dispersant 1.0%
Color stuffing:
Titanium dioxide 0.5%
Filler 28.8%
(2) curing agent:
Modified amine curing agent 18%.
After 128 epoxy resin addition auxiliary agent in above-mentioned mian paint is well mixed, the swollen of thixotropic agents is added while stirring The titanium dioxide and filler of profit soil and aerosil and color stuffing, after disperseing 20 minutes at a high speed, below fineness 80um, then add Enter color sand particle and stir the mian paint is made;
Modified amine curing agent is added, finish paint is made after stirring, paint film is prepared with the finish paint, paint film property presses GB/ T22374-2008 standards are detected, as a result as follows:
Test event Standard requirement Testing result
Surface drying time ≤6h It is qualified
Do solid work the time ≤48h It is qualified
Pencil hardness ≥2H 4H
Wear-resisting (750g/500r) ≤30mg 16mg
I grade of shock resistance Flawless, nothing comes off It is qualified
Resistance to marring Nail is drawn without white trace It is excellent
Water resistance, 168h It is non-foaming, do not fall off It is qualified
The solution of resistance to 20%NaOH, 72h It is non-foaming, do not fall off It is qualified
Resistance to 10%H2SO4Solution, 48h It is non-foaming, do not fall off It is qualified
VOC(g/L) 60 30.1
Anti-skidding coefficient of friction ≥0.5 0.86
The finish paint that can be seen that the present invention from the above-mentioned paint film calculation of measured data to finish paint made from the present embodiment has high hard Degree, super abrasive, excellent adhesion strength.And construction appearance has the color sand granular sensation of tradition, with artistic effect, more preferably Beautify the environment.
The finish paint of the present invention improves the hardness of epoxy material and resisted by introducing the color sand particle of organic resin synthesis Scratch resistant, while showing more rich colorful outward appearance;The uniform concaveconvex structure of coating surface, makes it have excellent friction system Number, so as to reach more preferable skidproof effect.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art is in the technical scope of present disclosure, the change or replacement that can be readily occurred in, It should all be included within the scope of the present invention.Therefore, protection scope of the present invention should be with the protection model of claims Enclose and be defined.

Claims (8)

1. a kind of anti-skidding finish paint of illusion-colour drawn grain, it is characterised in that including following component by weight percentage:
2. the anti-skidding finish paint of illusion-colour drawn grain according to claim 1, it is characterised in that the epoxy resin uses bisphenol A-type Epoxy resin.
3. the anti-skidding finish paint of illusion-colour drawn grain according to claim 1, it is characterised in that the curing agent uses modified fatty amine Or modified polyether amine.
4. the anti-skidding finish paint of illusion-colour drawn grain according to claim 1, it is characterised in that the thixotropic agents using bentonite and Modified aerosil, the consumption of each component is based on the percentage by weight of the total consumption of the anti-skidding finish paint of illusion-colour drawn grain, respectively:It is swollen Profit soil 4~5%, modified aerosil 1~5%.
5. the anti-skidding finish paint of illusion-colour drawn grain according to claim 1, it is characterised in that the color sand particle is organic using import Resin composite materials.
6. the anti-skidding finish paint of illusion-colour drawn grain according to any one of claim 1 to 5, it is characterised in that the auxiliary agent includes:Disappear Infusion, levelling agent, dispersant, the consumption of each component is based on the percentage by weight of the total consumption of the anti-skidding finish paint of illusion-colour drawn grain, respectively: Defoamer 0.8~1.5%, levelling agent 1.7~2.5%, dispersant 1%.
7. the anti-skidding finish paint of illusion-colour drawn grain according to any one of claim 1 to 5, it is characterised in that the color stuffing is used Titanium dioxide and filler, the consumption of each component is based on the percentage by weight of the total consumption of the anti-skidding finish paint of illusion-colour drawn grain:Titanium dioxide 0.5~ 1%, filler 14.5~29%.
8. a kind of preparation method of the anti-skidding finish paint of illusion-colour drawn grain, it is characterised in that for preparing any one of claim 1 to 7 institute The anti-skidding finish paint of illusion-colour drawn grain stated, comprises the following steps:
The formula of the anti-skidding finish paint of illusion-colour drawn grain as described in any one of claim 1 to 5 takes each raw material;
After epoxy resin addition auxiliary agent is well mixed, thixotropic agents and color stuffing are added while stirring, it is scattered 20 minutes at a high speed Afterwards, below fineness 80um, adds color sand particle and stirs mian paint is made;
Curing agent is added into above-mentioned mian paint, the anti-skidding finish paint of illusion-colour drawn grain is made after stirring.
CN201710618214.9A 2017-07-26 2017-07-26 Anti-skidding finish paint of illusion-colour drawn grain and preparation method thereof Pending CN107245287A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710618214.9A CN107245287A (en) 2017-07-26 2017-07-26 Anti-skidding finish paint of illusion-colour drawn grain and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201710618214.9A CN107245287A (en) 2017-07-26 2017-07-26 Anti-skidding finish paint of illusion-colour drawn grain and preparation method thereof

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CN107245287A true CN107245287A (en) 2017-10-13

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108948952A (en) * 2018-06-20 2018-12-07 上海维度化工科技有限公司 A kind of solvent-free color sand Self-leveling finishing coat and preparation method thereof
CN109868040A (en) * 2019-03-27 2019-06-11 启东维度化工科技有限公司 The solvent-free anti-skidding finishing coat of one kind and its preparing process
CN110003767A (en) * 2019-03-20 2019-07-12 河北晨阳工贸集团有限公司 A kind of anti-skidding mould proof floor paint of environment-friendly solvent-free and the preparation method and application thereof
CN112358759A (en) * 2020-11-09 2021-02-12 豪冠(上海)国际贸易有限公司 Method for preparing water-based colorful stone-like paint with synthetic sand as main body
CN115029045A (en) * 2022-05-06 2022-09-09 中国船舶重工集团公司第七二五研究所 Preparation method of surface defect finishing material of marine environment composite material

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102127358A (en) * 2010-12-31 2011-07-20 亚士漆(上海)有限公司 Solvent-free picking finish paint
CN103525249A (en) * 2013-10-08 2014-01-22 深圳市威尔地坪材料有限公司 Solvent-free epoxy self-leveling floor paint, preparation method thereof and using method thereof
CN104745047A (en) * 2015-04-22 2015-07-01 广东耐迪化工有限公司 Self-leveling sand color terrace material as well as preparation method and construction method thereof
CN106365508A (en) * 2016-08-29 2017-02-01 福州皇家地坪有限公司 Epoxy color sand coating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102127358A (en) * 2010-12-31 2011-07-20 亚士漆(上海)有限公司 Solvent-free picking finish paint
CN103525249A (en) * 2013-10-08 2014-01-22 深圳市威尔地坪材料有限公司 Solvent-free epoxy self-leveling floor paint, preparation method thereof and using method thereof
CN104745047A (en) * 2015-04-22 2015-07-01 广东耐迪化工有限公司 Self-leveling sand color terrace material as well as preparation method and construction method thereof
CN106365508A (en) * 2016-08-29 2017-02-01 福州皇家地坪有限公司 Epoxy color sand coating

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108948952A (en) * 2018-06-20 2018-12-07 上海维度化工科技有限公司 A kind of solvent-free color sand Self-leveling finishing coat and preparation method thereof
CN110003767A (en) * 2019-03-20 2019-07-12 河北晨阳工贸集团有限公司 A kind of anti-skidding mould proof floor paint of environment-friendly solvent-free and the preparation method and application thereof
CN109868040A (en) * 2019-03-27 2019-06-11 启东维度化工科技有限公司 The solvent-free anti-skidding finishing coat of one kind and its preparing process
CN112358759A (en) * 2020-11-09 2021-02-12 豪冠(上海)国际贸易有限公司 Method for preparing water-based colorful stone-like paint with synthetic sand as main body
CN115029045A (en) * 2022-05-06 2022-09-09 中国船舶重工集团公司第七二五研究所 Preparation method of surface defect finishing material of marine environment composite material

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Application publication date: 20171013