CN107652814A - A kind of water-in-water type artificial granite multicolor finish and preparation method thereof - Google Patents

A kind of water-in-water type artificial granite multicolor finish and preparation method thereof Download PDF

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Publication number
CN107652814A
CN107652814A CN201710942955.2A CN201710942955A CN107652814A CN 107652814 A CN107652814 A CN 107652814A CN 201710942955 A CN201710942955 A CN 201710942955A CN 107652814 A CN107652814 A CN 107652814A
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China
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water
parts
colored paint
type artificial
artificial granite
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CN201710942955.2A
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Chinese (zh)
Inventor
黄宏亭
袁海兵
廖基林
谢志超
张海军
黄冠陪
刘振兴
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Guangdong Huazibuxin Mstar Technology Ltd
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Guangdong Huazibuxin Mstar Technology Ltd
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Priority to CN201710942955.2A priority Critical patent/CN107652814A/en
Publication of CN107652814A publication Critical patent/CN107652814A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04Homopolymers or copolymers of monomers containing silicon
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/29Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of water-in-water type artificial granite multicolor finish and preparation method thereof, is related to technical field of coatings, and the multicolor finish includes basic colored paint, continuous phase and protection glue;The basic colored paint includes following raw material:Dispersant, defoamer, talcum powder, bactericide, propane diols, pH adjusting agent, sodium alginate, hydroxypropyl methyl cellulose, glass bead, coarse whiting, organobentonite, the multifunctional assistants of PAE 206, colorant, ethylene glycol methyl-n-butyl ether, silicone acrylic emulsion, deionized water;The continuous phase includes following raw material:Defoamer, bactericide, hydroxypropyl methyl cellulose, sodium alginate, the multifunctional assistants of PAE 206, ethylene glycol methyl-n-butyl ether, silicone acrylic emulsion, deionized water;The protection glue includes following raw material:Protect rubber powder, deionized water;Coating produced by the present invention has good water-fast, weatherability, and adhesive force is strong, and obdurability is good, and resistance to elevated temperatures and wash-resistant property are excellent, and storge quality is stable, has good artificial granite texture.

Description

A kind of water-in-water type artificial granite multicolor finish and preparation method thereof
Technical field
The invention belongs to technical field of coatings, specifically a kind of water-in-water type artificial granite multicolor finish and its preparation Method.
Background technology
With expanding economy, the progress of society, consumer tends to pursue elegant serious natural beauty for building, outside Wall decoration is decorated frequently with natural granite.However, natural granite figure colour limitednumber, and from great, apply Work bothers, costly, the older hidden danger to come off be present;In addition, prolonged exploitation will also result in the exhausted and ecological ring of resource The destruction in border.Therefore, people develop various artificial granite coating, to reach the effect of lithotome.Wherein, it is water-based more The excellent properties of color coating material and the high simulation quality of stone material assign its wide application field, and water-in-water multicolor coating is using parcel Technology, color grains float on a liquid, and once spraying can obtain abundant colour particles, and imitation stone effect is true to nature.But mesh In place of preceding water-in-water type artificial granite multicolor finish on the market comes with some shortcomings, such as occur interpenetrating and altering color phenomenon, Easily peelable, poor water resistance, storage stability is poor, and easily layering is rotten, and erasibility poor-performing, after influenceing spraying Effect.
The content of the invention
In view of the shortcomings of the prior art, it is an object of the invention to provide a kind of water-in-water type artificial granite multicolor finish and Its preparation method, the coating of preparation have water-tolerant, are not easily stripped, scrubbable advantage.
The present invention proposes a kind of water-in-water type artificial granite multicolor finish, including basic colored paint, continuous phase and Protection glue Liquid;
The basic colored paint includes following raw material:Dispersant, defoamer, talcum powder, bactericide, propane diols, pH regulations Agent, sodium alginate, hydroxypropyl methyl cellulose, glass bead, coarse whiting, organobentonite, PAE-206 multifunctional assistants, color Material, ethylene glycol methyl-n-butyl ether, silicone acrylic emulsion, deionized water;
The continuous phase includes following raw material:Defoamer, bactericide, hydroxypropyl methyl cellulose, sodium alginate, PAE- 206 multifunctional assistants, ethylene glycol methyl-n-butyl ether, silicone acrylic emulsion, deionized water;
The protection glue includes following raw material:Protect rubber powder, deionized water.
Preferably, the mass ratio of the basic colored paint, continuous phase and protection sizing material is 3-4:2-3:1-2.
Preferably, the basic colored paint includes the raw material of following parts by weight:Dispersant 0.4-0.6 parts, defoamer 0.2-0.4 Part, talcum powder 8-10 parts, bactericide 0.1-0.3 parts, propane diols 0.5-1.0 parts, pH adjusting agent 0.2-0.3 parts, sodium alginate 0.1-0.3 parts, hydroxypropyl methyl cellulose 0.3-0.5 parts, glass bead 1-2 parts, coarse whiting 0.5-1 parts, organobentonite 0.2- 0.5 part, PAE-206 multifunctional assistant 0.3-0.5 parts, colorant 2-4 parts, ethylene glycol methyl-n-butyl ether 0.8-1.5 parts, silicone acrylic emulsion 25- 30 parts, deionized water 28-32 parts.
Preferably, the basic colored paint also includes mould inhibitor.
Preferably, the content of mould inhibitor is 0.1-0.3% in the basic colored paint.
Preferably, the continuous phase includes the raw material of following parts by weight:Defoamer 0.1-0.3 parts, bactericide 0.1-0.2 Part, hydroxypropyl methyl cellulose 0.2-0.4 parts, sodium alginate 0.1-0.2 parts, PAE-206 multifunctional assistant 0.2-0.3 parts, Ethylene glycol methyl-n-butyl ether 0.5-0.8 parts, silicone acrylic emulsion 60-80 parts, deionized water 22-26 parts.
Preferably, the protection glue includes following raw material:Protect rubber powder 6-8 parts, deionized water 92-94 parts.
The invention also provides the preparation method of above-mentioned water-in-water type artificial granite multicolor finish, comprise the following steps:
1) prepared by basic colored paint:Dispersant, defoamer, pH adjusting agent, talcum powder, glass bead, coarse whiting are added to In ionized water, be dispersed with stirring 20-30min, then add bactericide, propane diols, silicone acrylic emulsion, PAE-206 multifunctional assistants, Ethylene glycol methyl-n-butyl ether, sodium alginate, hydroxypropyl methyl cellulose, are dispersed with stirring 10-20min, be eventually adding organobentonite and Colorant, 10-20min is dispersed with stirring, basic colored paint is made;
2) prepared by continuous phase:Defoamer, bactericide, hydroxypropyl methyl cellulose, sodium alginate, PAE-206 is multi-functional Auxiliary agent, ethylene glycol methyl-n-butyl ether, silicone acrylic emulsion, deionized water mixing, are dispersed with stirring 20-30min, obtain continuous phase;
3) glue is protected to prepare:Protection rubber powder is added in deionized water, 20-30min is dispersed with stirring, obtains Protection glue Liquid;
4) coating preparation:Basic colored paint is added in protection glue, shearing is uniformly dispersed, and is granulated, and color dot is made, will Color dot is added in continuous phase, is uniformly mixed, and is produced.
Preferably, comprise the following steps:
1) prepared by basic colored paint:Dispersant, defoamer, pH adjusting agent, talcum powder, glass bead, coarse whiting are added to In ionized water, 20-30min is dispersed with stirring with 1500-1700r/min rotating speed, then adds bactericide, propane diols, the breast of silicon third Liquid, PAE-206 multifunctional assistants, ethylene glycol methyl-n-butyl ether, sodium alginate, hydroxypropyl methyl cellulose, with 1200-1500r/min Rotating speed be dispersed with stirring 10-20min, be eventually adding organobentonite and colorant, be dispersed with stirring 10-20min, be made basic color Paint;
2) prepared by continuous phase:Defoamer, bactericide, hydroxypropyl methyl cellulose, sodium alginate, PAE-206 is multi-functional Auxiliary agent, ethylene glycol methyl-n-butyl ether, silicone acrylic emulsion, deionized water mixing, 20- is dispersed with stirring with 700-900r/min rotating speed 30min, obtain continuous phase;
3) glue is protected to prepare:Protection rubber powder is added in deionized water, stirred with 1000-1200r/min rotating speed Scattered 20-30min, obtains protection glue;
4) coating preparation:Basic colored paint is added in protection glue, shearing is uniformly dispersed, and is granulated, and color dot is made, will Color dot is added in continuous phase, is uniformly mixed with 800-1000r/min rotating speed, and it is more to produce water-in-water type artificial granite Color coating material.
Preferably, the viscosity of the water-in-water type artificial granite multicolor finish is 80 ± 3Ku/25 DEG C.
In the present invention using high temperature resistant, weatherability, water resistance excellent performance organosilicon acrylic resin as matrix emulsion so that coating have There are preferable pliability and tack;Using talcum powder as main framework material in basic colored paint, coating can be strengthened in base material The deposition and permeability on surface, it is due to talcum powder layered crystal structure, also with good lubricity and adsorptivity, energy Enough assign coating certain Scratch Resistance energy, cooperateed with coarse whiting and play strengthening action, strengthen the anti-wear performance of coating;Organic bentonite Profit soil not only there is good thickening property, heat-resisting quantity, strong adsorptivity and water resistance, also with good suspension stability with Film forming, improve the settleability of material;The glass bead of addition has good water resistance and weatherability;PAE-206 is multi-functional Auxiliary agent can not only provide high adhesion force, toughness, moreover it is possible to improve the hardness and corrosion resistance of coating;By basic colored paint and Protection glue After liquid mixing granulation, with continuously mixing, water-in-water type artificial granite multicolor finish is made.
Compared with prior art, beneficial effects of the present invention are:Obtained coating has good water-fast, weatherability, attached Put forth effort by force, obdurability is good, and resistance to elevated temperatures and wash-resistant property are excellent, and storge quality is stably not easy layering and gone bad, and coating is not easy Peel off, there is good artificial granite texture, emulator is high, ornamental strong.
Embodiment
Technical scheme is clearly and completely described below in conjunction with embodiment, it is clear that described reality It is only part of the embodiment of the present invention to apply example, rather than whole embodiments.Based on the embodiment in the present invention, this area The every other embodiment that those of ordinary skill is obtained under the premise of creative work is not made, belongs to guarantor of the present invention The scope of shield.
Embodiment 1
The present invention proposes a kind of water-in-water type artificial granite multicolor finish, including basic colored paint, continuous phase and Protection glue Liquid, mass ratio 3:2:1;
The basic colored paint includes following raw material:0.4 part of dispersant, 0.4 part of defoamer, 8 parts of talcum powder, bactericide 0.3 Part, 0.5 part of propane diols, 0.3 part of pH adjusting agent, 0.1 part of sodium alginate, 0.5 part of hydroxypropyl methyl cellulose, glass bead 1 Part, 1 part of coarse whiting, 0.2 part of organobentonite, 0.5 part of PAE-206 multifunctional assistants, 2 parts of colorant, 1.5 parts of ethylene glycol methyl-n-butyl ether, 25 parts of silicone acrylic emulsion, 32 parts of deionized water;
The continuous phase includes following raw material:0.1 part of defoamer, 0.2 part of bactericide, hydroxypropyl methyl cellulose 0.2 Part, 0.2 part of sodium alginate, 0.2 part of PAE-206 multifunctional assistants, 0.8 part of ethylene glycol methyl-n-butyl ether, 60 parts of silicone acrylic emulsion, go from Sub- 26 parts of water;
The protection glue includes following raw material:Protect 6 parts of rubber powder, 94 parts of deionized water.
The invention also provides the preparation method of above-mentioned water-in-water type artificial granite multicolor finish, comprise the following steps:
1) prepared by basic colored paint:Dispersant, defoamer, pH adjusting agent, talcum powder, glass bead, coarse whiting are added to In ionized water, 20min is dispersed with stirring with 1500r/min rotating speed, then adds bactericide, propane diols, silicone acrylic emulsion, PAE- 206 multifunctional assistants, ethylene glycol methyl-n-butyl ether, sodium alginate, hydroxypropyl methyl cellulose, with 1200r/min rotating speed stirring point 10min is dissipated, organobentonite and colorant is eventually adding, is dispersed with stirring 10min, basic colored paint is made;
2) prepared by continuous phase:Defoamer, bactericide, hydroxypropyl methyl cellulose, sodium alginate, PAE-206 is multi-functional Auxiliary agent, ethylene glycol methyl-n-butyl ether, silicone acrylic emulsion, deionized water mixing, are dispersed with stirring 20min with 700r/min rotating speed, obtain continuously Phase;
3) glue is protected to prepare:Protection rubber powder is added in deionized water, is dispersed with stirring with 1000r/min rotating speed 20min, obtain protection glue;
4) coating preparation:Basic colored paint is added in protection glue, shearing is uniformly dispersed, and is granulated, and color dot is made, will Color dot is added in continuous phase, is uniformly mixed with 800r/min rotating speed, produces the more color coatings of water-in-water type artificial granite Material, it is 80 ± 3Ku/25 DEG C to control viscosity.
Embodiment 2
The present invention proposes a kind of water-in-water type artificial granite multicolor finish, including basic colored paint, continuous phase and Protection glue Liquid, mass ratio 3:3:2;
The basic colored paint includes following raw material:0.4 part of dispersant, 0.3 part of defoamer, 9.5 parts of talcum powder, bactericide 0.1 part, 0.2 part of mould inhibitor, 0.8 part of propane diols, 0.2 part of pH adjusting agent, 0.1 part of sodium alginate, hydroxypropyl methyl cellulose 0.4 part, 1.2 parts of glass bead, 0.8 part of coarse whiting, 0.3 part of organobentonite, 0.3 part of PAE-206 multifunctional assistants, colorant 3.5 Part, 1.0 parts of ethylene glycol methyl-n-butyl ether, 27 parts of silicone acrylic emulsion, 31 parts of deionized water;
The continuous phase includes following raw material:0.2 part of defoamer, 0.1 part of bactericide, hydroxypropyl methyl cellulose 0.3 Part, 0.1 part of sodium alginate, 0.3 part of PAE-206 multifunctional assistants, 0.6 part of ethylene glycol methyl-n-butyl ether, 70 parts of silicone acrylic emulsion, go from Sub- 25 parts of water;
The protection glue includes following raw material:Protect 7.5 parts of rubber powder, 92.5 parts of deionized water.
The invention also provides the preparation method of above-mentioned water-in-water type artificial granite multicolor finish, comprise the following steps:
1) prepared by basic colored paint:Dispersant, defoamer, pH adjusting agent, talcum powder, glass bead, coarse whiting are added to In ionized water, 25min is dispersed with stirring with 1600r/min rotating speed, then adds bactericide, propane diols, silicone acrylic emulsion, PAE- 206 multifunctional assistants, ethylene glycol methyl-n-butyl ether, sodium alginate, hydroxypropyl methyl cellulose, with 1300r/min rotating speed stirring point 15min is dissipated, organobentonite and colorant is eventually adding, is dispersed with stirring 15min, basic colored paint is made;
2) prepared by continuous phase:Defoamer, bactericide, hydroxypropyl methyl cellulose, sodium alginate, PAE-206 is multi-functional Auxiliary agent, ethylene glycol methyl-n-butyl ether, silicone acrylic emulsion, deionized water mixing, are dispersed with stirring 25min with 800r/min rotating speed, obtain continuously Phase;
3) glue is protected to prepare:Protection rubber powder is added in deionized water, is dispersed with stirring with 1100r/min rotating speed 25min, obtain protection glue;
4) coating preparation:Basic colored paint is added in protection glue, shearing is uniformly dispersed, and is granulated, and color dot is made, will Color dot is added in continuous phase, is uniformly mixed with 900r/min rotating speed, produces the more color coatings of water-in-water type artificial granite Material, it is 80 ± 3Ku/25 DEG C to control viscosity.
Embodiment 3
The present invention proposes a kind of water-in-water type artificial granite multicolor finish, including basic colored paint, continuous phase and Protection glue Liquid, mass ratio 4:2:2;
The basic colored paint includes following raw material:0.5 part of dispersant, 0.3 part of defoamer, 9 parts of talcum powder, bactericide 0.2 Part, 0.2 part of mould inhibitor, 0.7 part of propane diols, 0.3 part of pH adjusting agent, 0.2 part of sodium alginate, hydroxypropyl methyl cellulose 0.3 Part, 1.5 parts of glass bead, 0.6 part of coarse whiting, 0.4 part of organobentonite, 0.4 part of PAE-206 multifunctional assistants, 3 parts of colorant, second 1.2 parts of glycol methyl-n-butyl ether, 28 parts of silicone acrylic emulsion, 30 parts of deionized water;
The continuous phase includes following raw material:0.1 part of defoamer, 0.1 part of bactericide, hydroxypropyl methyl cellulose 0.3 Part, 0.2 part of sodium alginate, 0.2 part of PAE-206 multifunctional assistants, 0.7 part of ethylene glycol methyl-n-butyl ether, 74 parts of silicone acrylic emulsion, go from Sub- 24 parts of water;
The protection glue includes following raw material:Protect 7 parts of rubber powder, 93 parts of deionized water.
The invention also provides the preparation method of above-mentioned water-in-water type artificial granite multicolor finish, comprise the following steps:
1) prepared by basic colored paint:Dispersant, defoamer, pH adjusting agent, talcum powder, glass bead, coarse whiting are added to In ionized water, 20min is dispersed with stirring with 1650r/min rotating speed, then adds bactericide, propane diols, silicone acrylic emulsion, PAE- 206 multifunctional assistants, ethylene glycol methyl-n-butyl ether, sodium alginate, hydroxypropyl methyl cellulose, with 1400r/min rotating speed stirring point 20min is dissipated, organobentonite and colorant is eventually adding, is dispersed with stirring 15min, basic colored paint is made;
2) prepared by continuous phase:Defoamer, bactericide, hydroxypropyl methyl cellulose, sodium alginate, PAE-206 is multi-functional Auxiliary agent, ethylene glycol methyl-n-butyl ether, silicone acrylic emulsion, deionized water mixing, are dispersed with stirring 20min with 850r/min rotating speed, obtain continuously Phase;
3) glue is protected to prepare:Protection rubber powder is added in deionized water, is dispersed with stirring with 1100r/min rotating speed 30min, obtain protection glue;
4) coating preparation:Basic colored paint is added in protection glue, shearing is uniformly dispersed, and is granulated, and color dot is made, will Color dot is added in continuous phase, is uniformly mixed with 950r/min rotating speed, produces the more color coatings of water-in-water type artificial granite Material, it is 80 ± 3Ku/25 DEG C to control viscosity.
Embodiment 4
The present invention proposes a kind of water-in-water type artificial granite multicolor finish, including basic colored paint, continuous phase and Protection glue Liquid, mass ratio 4:2:2;
The basic colored paint includes following raw material:0.6 part of dispersant, 0.2 part of defoamer, 10 parts of talcum powder, bactericide 0.1 part, 1.0 parts of propane diols, 0.2 part of pH adjusting agent, 0.3 part of sodium alginate, 0.3 part of hydroxypropyl methyl cellulose, glass bead 2 parts, 0.5 part of coarse whiting, 0.5 part of organobentonite, 0.3 part of PAE-206 multifunctional assistants, 4 parts of colorant, ethylene glycol methyl-n-butyl ether 0.8 Part, 30 parts of silicone acrylic emulsion, 28 parts of deionized water, 0.1 part of mould inhibitor;
The continuous phase includes following raw material:0.3 part of defoamer, 0.1 part of bactericide, hydroxypropyl methyl cellulose 0.4 Part, 0.1 part of sodium alginate, 0.3 part of PAE-206 multifunctional assistants, 0.5 part of ethylene glycol methyl-n-butyl ether, 80 parts of silicone acrylic emulsion, go from Sub- 22 parts of water;
The protection glue includes following raw material:Protect 8 parts of rubber powder, 92 parts of deionized water.
The invention also provides the preparation method of above-mentioned water-in-water type artificial granite multicolor finish, comprise the following steps:
1) prepared by basic colored paint:Dispersant, defoamer, pH adjusting agent, talcum powder, glass bead, coarse whiting are added to In ionized water, 30min is dispersed with stirring with 1700r/min rotating speed, then adds bactericide, propane diols, silicone acrylic emulsion, PAE- 206 multifunctional assistants, ethylene glycol methyl-n-butyl ether, sodium alginate, hydroxypropyl methyl cellulose, with 1500r/min rotating speed stirring point 20min is dissipated, organobentonite and colorant is eventually adding, is dispersed with stirring 20min, basic colored paint is made;
2) prepared by continuous phase:Defoamer, bactericide, hydroxypropyl methyl cellulose, sodium alginate, PAE-206 is multi-functional Auxiliary agent, ethylene glycol methyl-n-butyl ether, silicone acrylic emulsion, deionized water mixing, are dispersed with stirring 30min with 900r/min rotating speed, obtain continuously Phase;
3) glue is protected to prepare:Protection rubber powder is added in deionized water, is dispersed with stirring with 1200r/min rotating speed 30min, obtain protection glue;
4) coating preparation:Basic colored paint is added in protection glue, shearing is uniformly dispersed, and is granulated, and color dot is made, will Color dot is added in continuous phase, is uniformly mixed with 1000r/min rotating speed, produces the more color coatings of water-in-water type artificial granite Material, it is 80 ± 3Ku/25 DEG C to control viscosity.
Performance detection is carried out to coating prepared by 1-4 of the embodiment of the present invention.
1st, Water Resistance Test detects:Using cement asbestos board 150 × 70 × (4-6) mm as test plate (panel) base material, first with 120 μm Bar uniform coating, after drying 4h, continue to be conserved in 23 ± 2 DEG C, the environment of humidity 50 ± 2% with 80 μm of bar films, test plate (panel) 7 days, edge sealing, sealing are carried out to test plate (panel), are then soaked in test plate (panel) in 23 ± 2 DEG C of deionized water, slant setting, is tried The 2/3 of plate length is soaked into water, soak 4 days, take out test plate (panel), blotted with filter paper, observe and check test plate (panel) whether have loss of gloss, Phenomena such as wrinkling, come off, getting rusty.
2nd, abrasion resistance testing inspection:, as test plate (panel) base material, used using without cement asbestos board 430 × 150 × (3-6) mm 120 μm of bar uniform coatings, after drying 4h, continue with 80 μm of bar films, test plate (panel) is in 23 ± 2 DEG C, the environment of humidity 50 ± 2% Test plate (panel), is then fixed on testing stand, installs brush, brush is naturally drooped by middle maintenance 7 days, and 0.2% laundry is added dropwise Powder solution 0.2mL starts washability instrument, each second, 0.2% washing powder was added dropwise in about 0.04mL speed in the pilot region of test plate (panel) Solution.Scrub 1.5-2cm among ester test plate (panel) and expose ground in region, rinsed well with running water, write down scouring number.
3rd, adhesion test detects:Using cement asbestos board 150 × 70 × (4-6) mm as test plate (panel) base material, with 80 μm of lines Rod uniform coating, after drying 4h, test plate (panel) conserves 7 days in 23 ± 2 DEG C, the environment of humidity 50 ± 2%, model is placed on hard Cutting test is carried out on straight object plane, cutting section edge coating dropping situations is observed, is divided into 6 grades;Wherein, 0 grade, cutting Edge is completely smooth, and none lattice comes off;1 grade, there is a little disbonding in the intersection of otch, but cross-cut area is by shadow Sound can not be significantly greater than 5%;2 grades, there are coating shedding, impacted cross-cut in otch infall and/or along notching edge Area is significantly greater than 5%, but can not be significantly greater than 15%;3 grades, coating is partly or entirely come off along cut edge with big fragment, And/or 15% is significantly greater than in grid different parts upper part or whole peelings, impacted cross-cut area, but can not Significantly greater than 35%;4 grades, coating peels off along the big fragment in cut edge, and/or some grid parts or all comes off, by The cross-cut area of influence is significantly greater than 35%, but can not be significantly greater than 65%;5 grades, the degree of peeling is more than 4 grades.
The coating property of table 1 detects
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
Water resistance It is without exception It is without exception It is without exception It is without exception
Abrasion resistance/time 3100 3250 3500 3200
Adhesive force/level 1 0 0 0
From table 1 it follows that the water-resistant coating prepared in 1-4 of the embodiment of the present invention is good, immersion is taken out equal after 4 days Phenomena such as without wrinkling, coming off.It is strong with matrix material adhesive force for building coating, it is not easily stripped, and washability number is high Up to 3500 times.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, nothing By from the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by institute Attached claim rather than described above limit, it is intended that will fall in the implication and scope of the equivalency of claim All changes include in the present invention.

Claims (10)

1. a kind of water-in-water type artificial granite multicolor finish, it is characterised in that including basic colored paint, continuous phase and protection glue;
The basic colored paint includes following raw material:Dispersant, defoamer, talcum powder, bactericide, propane diols, pH adjusting agent, marine alga Sour sodium, hydroxypropyl methyl cellulose, glass bead, coarse whiting, organobentonite, PAE-206 multifunctional assistants, colorant, ethylene glycol Methyl-n-butyl ether, silicone acrylic emulsion, deionized water;
The continuous phase includes following raw material:Defoamer, bactericide, hydroxypropyl methyl cellulose, sodium alginate, PAE-206 are more Function additive, ethylene glycol methyl-n-butyl ether, silicone acrylic emulsion, deionized water;
The protection glue includes following raw material:Protect rubber powder, deionized water.
2. water-in-water type artificial granite multicolor finish according to claim 1, it is characterised in that the basic colored paint, company The continuous mass ratio mutually with protection sizing material is 3-4:2-3:1-2.
3. water-in-water type artificial granite multicolor finish according to claim 1, it is characterised in that the basic colored paint includes The raw material of following parts by weight:Dispersant 0.4-0.6 parts, defoamer 0.2-0.4 parts, talcum powder 8-10 parts, bactericide 0.1-0.3 Part, propane diols 0.5-1.0 parts, pH adjusting agent 0.2-0.3 parts, sodium alginate 0.1-0.3 parts, hydroxypropyl methyl cellulose 0.3- 0.5 part, glass bead 1-2 parts, coarse whiting 0.5-1 parts, organobentonite 0.2-0.5 parts, PAE-206 multifunctional assistants 0.3-0.5 Part, colorant 2-4 parts, ethylene glycol methyl-n-butyl ether 0.8-1.5 parts, silicone acrylic emulsion 25-30 parts, deionized water 28-32 parts.
4. water-in-water type artificial granite multicolor finish according to claim 3, it is characterised in that the basic colored paint also wraps Include mould inhibitor.
5. water-in-water type artificial granite multicolor finish according to claim 4, it is characterised in that prevent in the basic colored paint Mould dose of content is 0.1-0.3%.
6. water-in-water type artificial granite multicolor finish according to claim 1, it is characterised in that the continuous phase include with The raw material of lower parts by weight:Defoamer 0.1-0.3 parts, bactericide 0.1-0.2 parts, hydroxypropyl methyl cellulose 0.2-0.4 parts, marine alga Sour sodium 0.1-0.2 parts, PAE-206 multifunctional assistant 0.2-0.3 parts, ethylene glycol methyl-n-butyl ether 0.5-0.8 parts, silicone acrylic emulsion 60-80 Part, deionized water 22-26 parts.
7. water-in-water type artificial granite multicolor finish according to claim 1, it is characterised in that the protection glue includes Following raw material:Protect rubber powder 6-8 parts, deionized water 92-94 parts.
8. based on the preparation method of the water-in-water type artificial granite multicolor finish described in claim 1-7 any one, its feature It is, comprises the following steps:
1) prepared by basic colored paint:Dispersant, defoamer, pH adjusting agent, talcum powder, glass bead, coarse whiting are added to deionization In water, 20-30min is dispersed with stirring, then adds bactericide, propane diols, silicone acrylic emulsion, PAE-206 multifunctional assistants, ethylene glycol Methyl-n-butyl ether, sodium alginate, hydroxypropyl methyl cellulose, are dispersed with stirring 10-20min, are eventually adding organobentonite and colorant, stir Scattered 10-20min is mixed, basic colored paint is made;
2) prepared by continuous phase:By defoamer, bactericide, hydroxypropyl methyl cellulose, sodium alginate, PAE-206 multifunctional assistants, Ethylene glycol methyl-n-butyl ether, silicone acrylic emulsion, deionized water mixing, are dispersed with stirring 20-30min, obtain continuous phase;
3) glue is protected to prepare:Protection rubber powder is added in deionized water, 20-30min is dispersed with stirring, obtains protection glue;
4) coating preparation:Basic colored paint is added in protection glue, shearing is uniformly dispersed, and is granulated, and color dot is made, by color dot plus Enter into continuous phase, be uniformly mixed, produce.
9. the preparation method of water-in-water type artificial granite multicolor finish according to claim 8, it is characterised in that including with Lower step:
1) prepared by basic colored paint:Dispersant, defoamer, pH adjusting agent, talcum powder, glass bead, coarse whiting are added to deionization In water, 20-30min is dispersed with stirring with 1500-1700r/min rotating speed, then add bactericide, propane diols, silicone acrylic emulsion, PAE-206 multifunctional assistants, ethylene glycol methyl-n-butyl ether, sodium alginate, hydroxypropyl methyl cellulose, with turning for 1200-1500r/min Speed is dispersed with stirring 10-20min, is eventually adding organobentonite and colorant, is dispersed with stirring 10-20min, and basic colored paint is made;
2) prepared by continuous phase:By defoamer, bactericide, hydroxypropyl methyl cellulose, sodium alginate, PAE-206 multifunctional assistants, Ethylene glycol methyl-n-butyl ether, silicone acrylic emulsion, deionized water mixing, are dispersed with stirring 20-30min with 700-900r/min rotating speed, must connect Continuous phase;
3) glue is protected to prepare:Protection rubber powder is added in deionized water, is dispersed with stirring with 1000-1200r/min rotating speed 20-30min, obtain protection glue;
4) coating preparation:Basic colored paint is added in protection glue, shearing is uniformly dispersed, and is granulated, and color dot is made, by color dot plus Enter into continuous phase, be uniformly mixed with 800-1000r/min rotating speed, produce water-in-water type artificial granite multicolor finish.
10. the preparation method of water-in-water type artificial granite multicolor finish according to claim 9, it is characterised in that described The viscosity of water-in-water type artificial granite multicolor finish is 80 ± 3Ku/25 DEG C.
CN201710942955.2A 2017-10-11 2017-10-11 A kind of water-in-water type artificial granite multicolor finish and preparation method thereof Pending CN107652814A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108624181A (en) * 2018-06-01 2018-10-09 陕西五岳松航空新材料有限公司 A kind of rock color coating material and preparation method thereof
CN109777231A (en) * 2019-03-01 2019-05-21 福州居家逸涂料科技有限公司 A kind of illusion-colour pearly-lustre water-water paint and preparation method thereof
CN110527384A (en) * 2019-09-10 2019-12-03 北京莱恩斯新材料科技有限公司 Application of the expanded and vitrified small ball in water burnt-in sand base paint, water burnt-in sand base paint, preparation method and water burnt-in sand coating
CN111826040A (en) * 2020-07-02 2020-10-27 广东嘉宝莉科技材料有限公司 Water-in-water multicolor paint with strong layering sense and capable of being coated in batches and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107129735A (en) * 2017-06-08 2017-09-05 广东东艺宝建材有限公司 A kind of artificial granite speckle multicolor finish of waterproof and heat-insulating and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107129735A (en) * 2017-06-08 2017-09-05 广东东艺宝建材有限公司 A kind of artificial granite speckle multicolor finish of waterproof and heat-insulating and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108624181A (en) * 2018-06-01 2018-10-09 陕西五岳松航空新材料有限公司 A kind of rock color coating material and preparation method thereof
CN109777231A (en) * 2019-03-01 2019-05-21 福州居家逸涂料科技有限公司 A kind of illusion-colour pearly-lustre water-water paint and preparation method thereof
CN110527384A (en) * 2019-09-10 2019-12-03 北京莱恩斯新材料科技有限公司 Application of the expanded and vitrified small ball in water burnt-in sand base paint, water burnt-in sand base paint, preparation method and water burnt-in sand coating
CN111826040A (en) * 2020-07-02 2020-10-27 广东嘉宝莉科技材料有限公司 Water-in-water multicolor paint with strong layering sense and capable of being coated in batches and preparation method thereof

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Application publication date: 20180202