CN112358759A - Method for preparing water-based colorful stone-like paint with synthetic sand as main body - Google Patents
Method for preparing water-based colorful stone-like paint with synthetic sand as main body Download PDFInfo
- Publication number
- CN112358759A CN112358759A CN202011240415.8A CN202011240415A CN112358759A CN 112358759 A CN112358759 A CN 112358759A CN 202011240415 A CN202011240415 A CN 202011240415A CN 112358759 A CN112358759 A CN 112358759A
- Authority
- CN
- China
- Prior art keywords
- parts
- paint
- colorful
- water
- preparing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a method for preparing water-based colorful stone-like paint with synthetic sand as a main body, which comprises the following steps: step one, preparing synthetic sand: step two, a formula of the black line paint with the integrated bottom surface is as follows: step three, preparing a formula of the colorful dispersed phase colored paint: step four: preparation of a multicolor continuous phase formula: step five: preparing a formula of the colorful finished paint: the prepared stone paint is prepared by firstly adopting conventional putty to carry out base layer treatment, then brushing a black line paint with a bottom surface by a wool roller, and then spraying a colorful finished paint by an LPHV spray gun. The invention adopts artificial synthetic sand to replace natural quartz sand, saves resources, has simple process production and various material properties concentrated on black line paint and water-based colorful stone-like coating main materials containing the synthetic sand; the construction process is reduced, the construction efficiency is improved, the construction cost is reduced, the decorative effect is higher, and the service life is longer.
Description
Technical Field
The invention relates to the technical field of synthetic sand, in particular to a method for preparing water-based colorful stone-like paint taking synthetic sand as a main body.
Background
In recent years, the mainstream products in the building coating market and the building coating varieties with the most extensive application are mainly sand wall-shaped coatings of a sand-containing system, and account for more than 80 percent of the total amount of the current exterior wall building coating market; the sand used by the product is a natural quartz sand material, belongs to a resource product, is a consumable and non-renewable resource material, and has great and profound influence on ecological environment. In the sand wall-shaped paint series, the sand-containing colorful building paint is also used as the most fire-retardant paint variety at present, the decorative effect of the paint is as good as that of granite stone of a fire board, the load and the decorative process of the wall body are greatly improved, and the cost per square of the wall body is greatly reduced; the most main filling material and aggregate in the material are white quartz sand which is also a resource product, the production and processing are rough, the energy consumption is high during the processing, and the dust pollution is serious.
In recent years, the mainstream products for outdoor wall decoration are various sand wall-like coatings, and the coatings are received by the market due to the characteristics of high cost performance, high coating strength, long service life and the like. The water-based sand-containing colorful stone-like paint has higher and higher use ratio in recent three years, which is a trend and application trend, but the use ratio is limited due to higher square decoration price caused by the problems of high unit price and use amount; the decorative effect of the product in the current market is different from that of the natural stone paint, so that the natural stone paint is not effectively replaced, and the potential market is huge; and the filling main material in the water-based colorful imitation stone is also a natural stone resource material, and has serious damage to the ecological environment.
Disclosure of Invention
The invention aims to provide a method for preparing water-based colorful stone-like paint with synthetic sand as a main body, so as to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme:
the invention also provides a preparation method of the water-based colorful stone-like paint taking the synthetic sand as a main body, which comprises the following steps:
step one, preparing synthetic sand: 300-350 parts of aqueous epoxy solid agent, 1.5-3.0 parts of emulsified silicone oil foam inhibitor, 1.5-3.0 parts of organic silicon defoaming agent, 5.0-10.0 parts of block grafting dispersion wetting agent, 75.0-100 parts of rutile titanium dioxide, 50.0-75.0 parts of heavy calcium, 50-75 parts of barium sulfate, 5.0-8.0 parts of polyurethane thickener and 1000 parts of water are sequentially fed into a stirrer to be stirred to form a group A, 90-95 parts of epoxy emulsion and 5-10 parts of AGE special diluent are mixed to form a group B, and the weight ratio of A: b, fully mixing according to the ratio of 3.5-4.0:1.0, and then forming synthetic sand by adopting an extrusion molding granulation mode;
step two, a formula of the black line paint with the integrated bottom surface is as follows: 300 parts of 250-containing organic solvent, 2.0-3.0 parts of emulsified silicone oil defoaming agent, 1.5-3.0 parts of ethyl hydroxyethyl cellulose ether, 3.0-5.0 parts of polycarboxylic acid sodium salt dispersant, 4.0-6.0 parts of polyacrylic ammonium salt dispersant, 2.0-3.0 parts of alkylphenol polyoxyethylene ether nonionic wetting agent, 15-20 parts of propylene glycol, 125 parts of iron oxide black powder, 50-75 parts of superfine kaolin, 50-75 parts of superfine wollastonite, 125 parts of heavy calcium carbonate, 50-75 parts of superfine talcum powder, 150 parts of 100-containing organic solvent high Tg styrene-acrylic emulsion, 150 parts of 125-containing organic solvent high Tg emulsion, 2.0-3.0 parts of benzene green sodium formate preservative and 2.0-3.0 parts of sodium carbonate PH regulator;
step three, preparing a formula of the colorful dispersed phase colored paint: sequentially feeding 450 parts of water, 0.8-1.5 parts of polyacrylic acid sodium salt dispersing agent, 2.0-3.0 parts of emulsified silicone oil foam inhibitor, 1.5-2.0 parts of polyethylene polyamine high-temperature preservative, 5-10 parts of titanium dioxide, 8-12 parts of methyl ethyl hydroxyethyl cellulose, 1-1.5 parts of sodium carbonate PH regulator, 2.0-3.0 parts of alcohol ester dodecafilming auxiliary agent, 4.0-6.0 parts of propylene glycol, 150 parts of inorganic grafting modified acrylic emulsion, 45-50 parts of 10% carob bean gum protective colloid and the synthetic sand obtained in the first step of 250-300 into a mixer for stirring to obtain the colorful dispersed phase color paint;
step four: preparation of a multicolor continuous phase formula: adding 420 parts of 380-fold water, 2.0-3.0 parts of sodium chloride high-efficiency preservative, 0.8-1.2 parts of organic modified bentonite, 10-12 parts of propylene glycol, 1.0-2.0 parts of silicone emulsion defoamer, 2.0-3.0 parts of sodium carbonate PH regulator, 5.0-7.0 parts of alcohol ester dodecafilming auxiliary agent and 600 parts of matte hydroxyl modified polyacrylic acid PMMA graft emulsion 550-fold in sequence into a reaction kettle, and stirring for 20-30min to obtain a colorful continuous phase;
step five: preparing a formula of the colorful finished paint: mixing and stirring 250 parts of long carob bean gum 5% multicolor protection glue 200-; the prepared stone paint is prepared by firstly adopting conventional putty to carry out base layer treatment, then brushing a black line paint with a bottom surface by a wool roller, and then spraying a colorful finished paint by an LPHV spray gun.
Preferably, the aqueous epoxy solid agent is one of aliphatic diamine, polyamine, aromatic polyamine and dicyandiamide; the block grafting dispersion wetting agent is a polyoxypropylene block polymer.
Preferably, the inorganic graft modified acrylic emulsion in the formula of the multicolor disperse phase colored paint is fed into a magnetic stirrer by adopting the acrylic emulsion, then 1-2 parts of trimethyl benzoyl-diphenyl phosphine oxide are added to prepare a graft solution, then nano titanium dioxide accounting for 10-20% of the total amount of the acrylic emulsion is added, and then proton irradiation is adopted for 10-20min, wherein the irradiation power is 200-300W.
Preferably, the modification method of the organically modified bentonite comprises the following steps: adding bentonite into tetraethylenepentamine solution, reacting at 70-80 deg.C for 20-30min, adding silane coupling agent KH560, stirring for 20-30min at a rotation speed of 100-.
Preferably, the rare earth is lanthanum chloride, and the mass ratio of the lanthanum chloride to the bentonite is 1-3: 20.
Preferably, the mass ratio of the lanthanum chloride to the bentonite is 1: 10.
Preferably, the organic enhancer comprises the following raw materials in parts by weight: 4-5 parts of chitosan, 1-3 parts of vinyl polydimethylsiloxane, 2-6 parts of polyethylene glycol and 5-10 parts of acetone.
Preferably, the organic enhancer comprises the following raw materials in parts by weight: 4.5 parts of chitosan, 2 parts of vinyl polydimethylsiloxane, 4 parts of polyethylene glycol and 7.5 parts of acetone.
Preferably, the matte hydroxyl modified polyacrylic acid PMMA grafted emulsion is obtained by adding PMMA and azobisisobutyronitrile into an aqueous matte hydroxyl acrylic resin in an ethanol solution medium and reacting.
Compared with the prior art, the invention has the following beneficial effects:
(1) the invention adopts artificial synthetic sand to replace natural quartz sand, saves resources, has simple process production and various material properties concentrated on black line paint and water-based colorful stone-like coating main materials containing the synthetic sand; the construction process is reduced, the construction efficiency is improved, the construction cost is reduced, the decorative effect is higher, and the service life is longer.
(2) Under the construction of the water-based multicolor paint, the conventional water-based multicolor stone-like paint is a system combination and respectively consists of a water-based closed bottom, a water-based line paint, a multicolor matching middle coat, a water-based multicolor stone-like main material and a water-based finish coat varnish, and the technical route of the system adopts 'synthetic sand' to replace 'natural quartz sand', so that the damage to the production environment and resources is avoided, meanwhile, the specific gravity of the water-based multicolor stone-like paint is reduced, the suspension property of color points is improved, the color point spreadability is increased, and the use area of the water-based multicolor stone-like paint is increased; the performance of the water-based colorful main material is improved to reduce the construction of water-based finish varnish, and the water-based seal primer, the line paint and the matched middle coat base color are integrated together to reduce the use of various materials and the reduction of processes, so the water-based colorful main material under a new process route needs to have more excellent performance to meet the requirements of outdoor use and long-term use.
(3) The invention requires the colored spot paint to have excellent adhesive force and water resistance, adopts the inorganic graft modified acrylic emulsion with high resistance and high strength, the self-made modified bentonite and the multicolor protection glue solution to carry out reasonable compatibility, and meets the requirement that the colored paint can keep the state of the colored paint for a long time without gelling and hardening under the state of multicolor protection package to ensure that the colored paint has excellent adhesive force; the water-based sand-containing colorful stone-like coating of the system mainly needs to consider the coverage rate, the use cost and the simple construction property of the colored paint in construction, so that the coating system has higher requirements on the using amount of the colored paint, and the using amounts of the colored paint, the colorful protective glue and the colorful continuous phase have absolute influences on the storage stability and the water resistance of the system.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below with reference to specific embodiments, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1:
the method for manufacturing the water-based colorful stone-like paint with the synthetic sand as the main body comprises the following steps:
step one, preparing synthetic sand: 300 parts of aqueous epoxy solid agent, 1.5 parts of emulsified silicone oil foam inhibitor, 1.5 parts of organic silicon defoaming agent, 5.0 parts of block grafting dispersion wetting agent, 75.0 parts of rutile titanium dioxide, 50.0 parts of heavy calcium, 50 parts of barium sulfate, 5.0 parts of polyurethane thickener and 1000 parts of water are sequentially fed into a stirrer to be stirred to form a group A, 90 parts of epoxy emulsion and 5 parts of AGE special diluent are mixed to form a group B, and the weight ratio of A: b, fully mixing according to the ratio of 3.5:1.0, and then forming synthetic sand by adopting an extrusion molding granulation mode;
step two, a formula of the black line paint with the integrated bottom surface is as follows: 250 parts of water, 2.0 parts of emulsified silicone oil defoaming agent, 1.5 parts of ethyl hydroxyethyl cellulose ether, 3.0 parts of polycarboxylic acid sodium salt dispersant, 4.0 parts of polyacrylic acid ammonium salt dispersant, 2.0 parts of alkylphenol polyoxyethylene ether nonionic wetting agent, 15 parts of propylene glycol, 100 parts of iron oxide black powder, 50 parts of superfine kaolin, 55 parts of superfine wollastonite, 100 parts of heavy calcium carbonate, 50 parts of superfine talcum powder, 100 parts of high Tg styrene-acrylic emulsion, 125 parts of anti-salting primer high Tg emulsion, 2.0 parts of sodium benzoate green preservative and 2.0 parts of sodium carbonate PH regulator;
step three, preparing a formula of the colorful dispersed phase colored paint: sequentially feeding 420 parts of water, 0.8 part of sodium polyacrylate dispersant, 2.0 parts of emulsified silicone oil foam inhibitor, 1.5 parts of polyethylene polyamine high-temperature preservative, 5 parts of titanium dioxide, 8 parts of methyl ethyl hydroxyethyl cellulose, 1 part of sodium carbonate pH regulator, 2.0 parts of alcohol ester dodecafilming auxiliary agent, 4.0 parts of propylene glycol, 150 parts of inorganic graft modified acrylic emulsion, 45-10% carob bean gum protective colloid and 250 steps of synthetic sand into a mixer for stirring to obtain colorful dispersed phase color paint;
step four: preparation of a multicolor continuous phase formula: sequentially adding 380 parts of water, 2.0 parts of sodium chloride efficient preservative, 0.8 part of organic modified bentonite, 10 parts of propylene glycol, 1.0 part of emulsified silicone oil defoaming agent, 2.0 parts of sodium carbonate pH regulator, 5.0 parts of alcohol ester dodecafilming aid and 550 parts of matte hydroxyl modified polyacrylic acid PMMA grafted emulsion into a reaction kettle, and stirring for 20min to obtain a colorful continuous phase;
step five: preparing a formula of the colorful finished paint: mixing and stirring 200 parts of carob bean 5% colorful protective glue, 0.5 part of EHEC cellulose, 600 parts of colorful dispersed phase colored paint, 200 parts of colorful continuous phase and 2 parts of gum arabic thickener for 20min to obtain colorful finished paint; the prepared stone paint is prepared by firstly adopting conventional putty to carry out base layer treatment, then brushing a black line paint with a bottom surface by a wool roller, and then spraying a colorful finished paint by an LPHV spray gun.
The aqueous epoxy solid agent of the embodiment is one of aliphatic diamine, polyamine, aromatic polyamine and dicyandiamide; the block grafting dispersion wetting agent is a polyoxypropylene block polymer.
In the formula of the multicolor dispersed phase colored paint of the embodiment, the inorganic graft modified acrylic emulsion is fed into a magnetic stirrer by adopting the acrylic emulsion, then 1 part of trimethyl benzoyl-diphenyl phosphine oxide is added to prepare a graft solution, then nano titanium dioxide accounting for 10% of the total amount of the acrylic emulsion is added, and then proton irradiation is carried out for 10min, wherein the irradiation power is 200W.
The modification method of the organically modified bentonite in this example is as follows: adding bentonite into tetraethylenepentamine solution, reacting at 70 deg.C for 20min, adding silane coupling agent KH560, stirring for 20min at 100r/min, and adding rare earth and organic enhancer.
The rare earth in this example is lanthanum chloride, and the mass ratio of lanthanum chloride to bentonite is 1: 20.
The organic enhancer of the embodiment comprises the following raw materials in parts by weight: 4 parts of chitosan, 1 part of vinyl polydimethylsiloxane, 2 parts of polyethylene glycol and 5 parts of acetone.
The matte hydroxyl modified polyacrylic acid PMMA grafted emulsion is obtained by adding PMMA and azobisisobutyronitrile into aqueous matte hydroxyl acrylic resin in an ethanol solution medium and reacting.
Example 2:
the method for manufacturing the water-based colorful stone-like paint with the synthetic sand as the main body comprises the following steps:
step one, preparing synthetic sand: feeding 350 parts of aqueous epoxy solid agent, 3.0 parts of emulsified silicone oil foam inhibitor, 3.0 parts of organic silicon defoaming agent, 10.0 parts of block grafting dispersion wetting agent, 100 parts of rutile titanium dioxide, 75.0 parts of heavy calcium, 75 parts of barium sulfate, 8.0 parts of polyurethane thickener and 1000 parts of water into a stirrer in sequence for stirring to form a group A, mixing 95 parts of epoxy emulsion and 10 parts of AGE special diluent to form a group B, and mixing A: b, fully mixing according to the ratio of 4.0:1.0, and then forming synthetic sand by adopting an extrusion molding granulation mode;
step two, a formula of the black line paint with the integrated bottom surface is as follows: 300 parts of water, 3.0 parts of emulsified silicone oil defoaming agent, 3.0 parts of ethyl hydroxyethyl cellulose ether, 5.0 parts of polycarboxylic acid sodium salt dispersing agent, 6.0 parts of polyacrylic acid ammonium salt dispersing agent, 3.0 parts of alkylphenol polyoxyethylene ether nonionic wetting agent, 20 parts of propylene glycol, 125 parts of iron oxide black powder, 75 parts of superfine kaolin, 75 parts of superfine wollastonite, 125 parts of heavy calcium carbonate, 75 parts of superfine talcum powder, 150 parts of high Tg styrene-acrylic emulsion, 150 parts of anti-salting primer high Tg emulsion, 3.0 parts of sodium benzoate green preservative and 3.0 parts of sodium carbonate PH regulator;
step three, preparing a formula of the colorful dispersed phase colored paint: feeding 450 parts of water, 1.5 parts of sodium polyacrylate dispersant, 3.0 parts of emulsified silicone oil foam inhibitor, 2.0 parts of polyethylene polyamine high-temperature preservative, 10 parts of titanium dioxide, 12 parts of methyl ethyl hydroxyethyl cellulose, 1.5 parts of sodium carbonate pH regulator, 3.0 parts of alcohol ester dodecafilming auxiliary agent, 6.0 parts of propylene glycol, 200 parts of inorganic graft modified acrylic emulsion, 50 parts of 10% carob bean gum protective colloid and the synthetic sand obtained in the first step into a mixer in sequence for stirring to obtain the multicolor dispersed phase color paint;
step four: preparation of a multicolor continuous phase formula: sequentially adding 420 parts of water, 3.0 parts of sodium chloride efficient preservative, 1.2 parts of organic modified bentonite, 12 parts of propylene glycol, 2.0 parts of emulsified silicone oil defoamer, 3.0 parts of sodium carbonate PH regulator, 7.0 parts of alcohol ester dodecafilming aid and 600 parts of matte hydroxyl modified polyacrylic acid PMMA grafted emulsion into a reaction kettle, and stirring for 20-30min to obtain a colorful continuous phase;
step five: preparing a formula of the colorful finished paint: mixing and stirring 250 parts of carob bean 5% colorful protective glue, 0.8 part of EHEC cellulose, 650 parts of colorful dispersed phase colored paint, 250 parts of colorful continuous phase and 8 parts of gum arabic thickener for 30min to obtain colorful finished paint; the prepared stone paint is prepared by firstly adopting conventional putty to carry out base layer treatment, then brushing a black line paint with a bottom surface by a wool roller, and then spraying a colorful finished paint by an LPHV spray gun.
The aqueous epoxy solid agent of the embodiment is one of aliphatic diamine, polyamine, aromatic polyamine and dicyandiamide; the block grafting dispersion wetting agent is a polyoxypropylene block polymer.
In the formula of the multicolor dispersed phase colored paint of the embodiment, the inorganic graft modified acrylic emulsion is fed into a magnetic stirrer by adopting the acrylic emulsion, then 2 parts of trimethyl benzoyl-diphenyl phosphine oxide are added to prepare a graft solution, then nano titanium dioxide accounting for 20% of the total amount of the acrylic emulsion is added, and then proton irradiation is carried out for 20min, wherein the irradiation power is 300W.
The modification method of the organically modified bentonite in this example is as follows: adding bentonite into tetraethylenepentamine solution, reacting at 80 deg.C for 30min, adding silane coupling agent KH560, stirring for 30min at 200r/min, and adding rare earth and organic enhancer.
The rare earth in this example is lanthanum chloride, and the mass ratio of lanthanum chloride to bentonite is 3: 20.
The organic enhancer of the embodiment comprises the following raw materials in parts by weight: 5 parts of chitosan, 3 parts of vinyl polydimethylsiloxane, 6 parts of polyethylene glycol and 10 parts of acetone.
The matte hydroxyl modified polyacrylic acid PMMA grafted emulsion is obtained by adding PMMA and azobisisobutyronitrile into aqueous matte hydroxyl acrylic resin in an ethanol solution medium and reacting.
Example 3:
the method for manufacturing the water-based colorful stone-like paint with the synthetic sand as the main body comprises the following steps:
step one, preparing synthetic sand: 325 parts of aqueous epoxy solid agent, 1.75 parts of emulsified silicone oil foam inhibitor, 1.75 parts of organic silicon defoaming agent, 7.5 parts of block grafting dispersion wetting agent, 75.0-100 parts of rutile titanium dioxide, 50.0-75.0 parts of heavy calcium, 62.5 parts of barium sulfate, 6.5 parts of polyurethane thickener and 1000 parts of water are sequentially fed into a stirrer to be stirred to form a group A, 92.5 parts of epoxy emulsion and 7.5 parts of AGE special diluent are mixed to form a group B, and the weight ratio of A: b, fully mixing according to the ratio of 3.75:1.0, and then forming synthetic sand by adopting an extrusion molding granulation mode;
step two, a formula of the black line paint with the integrated bottom surface is as follows: 275 parts of water, 2.5 parts of silicone emulsion defoaming agent, 1.75 parts of ethyl hydroxyethyl cellulose ether, 3.25 parts of polycarboxylic acid sodium salt dispersant, 5 parts of polyacrylic acid ammonium salt dispersant, 2.5 parts of alkylphenol polyoxyethylene ether nonionic wetting agent, 17.5 parts of propylene glycol, 112.5 parts of iron oxide black powder, 62.5 parts of superfine kaolin, 62 parts of superfine wollastonite, 112 parts of heavy calcium carbonate, 62 parts of superfine talcum powder, 125 parts of high Tg styrene-acrylic emulsion, 137 parts of salting-out resistant primer high Tg emulsion, 2.5 parts of sodium benzoate green preservative and 2.5 parts of sodium carbonate pH regulator;
step three, preparing a formula of the colorful dispersed phase colored paint: 435 parts of water, 0.95 part of sodium polyacrylate dispersant, 2.0-3.0 parts of emulsified silicone oil foam inhibitor, 1.75 parts of polyethylene polyamine high-temperature preservative, 5-10 parts of titanium dioxide, 8-12 parts of methyl ethyl hydroxyethyl cellulose, 1.25 parts of sodium carbonate pH regulator, 2.5 parts of alcohol ester dodecafilming aid, 5 parts of propylene glycol, 175 parts of inorganic graft modified acrylic emulsion, 47.5 parts of 10% carob bean gum protective colloid and 275 steps I synthetic sand are sequentially fed into a mixer to be stirred, so that the multi-color dispersed phase paint is obtained;
step four: preparation of a multicolor continuous phase formula: adding 400 parts of water, 2.5 parts of sodium chloride efficient preservative, 1.0 part of organic modified bentonite, 11 parts of propylene glycol, 1.5 parts of emulsified silicone oil defoamer, 2.5 parts of sodium carbonate pH regulator, 6 parts of alcohol ester dodecafilming aid and 575 parts of matte hydroxyl modified polyacrylic acid PMMA grafted emulsion into a reaction kettle in sequence, and stirring for 25min to obtain a colorful continuous phase;
step five: preparing a formula of the colorful finished paint: mixing 225 parts of carob bean gum 5% colorful protective glue, 0.7 part of EHEC cellulose, 625 parts of colorful dispersed phase colored paint, 225 parts of colorful continuous phase and 5 parts of gum arabic thickener, and stirring for 25min to obtain colorful finished paint; the prepared stone paint is prepared by firstly adopting conventional putty to carry out base layer treatment, then brushing a black line paint with a bottom surface by a wool roller, and then spraying a colorful finished paint by an LPHV spray gun.
The aqueous epoxy solid agent of the embodiment is one of aliphatic diamine, polyamine, aromatic polyamine and dicyandiamide; the block grafting dispersion wetting agent is a polyoxypropylene block polymer.
In the formula of the multicolor dispersed phase colored paint of the embodiment, the inorganic graft modified acrylic emulsion is fed into a magnetic stirrer by adopting the acrylic emulsion, then 1.5 parts of trimethyl benzoyl-diphenyl phosphine oxide are added to prepare a graft solution, then nano titanium dioxide accounting for 15 percent of the total amount of the acrylic emulsion is added, and then proton irradiation is adopted for 15min, wherein the irradiation power is 250W.
The modification method of the organically modified bentonite in this example is as follows: adding bentonite into tetraethylenepentamine solution, reacting at 705 deg.C for 25min, adding silane coupling agent KH560, stirring for 20-30min at 150r/min, and adding rare earth and organic enhancer.
The rare earth in this example is lanthanum chloride, and the mass ratio of lanthanum chloride to bentonite is 1: 10.
The organic enhancer of the embodiment comprises the following raw materials in parts by weight: 4.5 parts of chitosan, 2 parts of vinyl polydimethylsiloxane, 4 parts of polyethylene glycol and 7.5 parts of acetone.
The matte hydroxyl modified polyacrylic acid PMMA grafted emulsion is obtained by adding PMMA and azobisisobutyronitrile into aqueous matte hydroxyl acrylic resin in an ethanol solution medium and reacting.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art.
Claims (9)
1. A method for manufacturing water-based colorful stone-like paint with synthetic sand as a main body is characterized by comprising the following steps:
step one, preparing synthetic sand: 300-350 parts of aqueous epoxy solid agent, 1.5-3.0 parts of emulsified silicone oil foam inhibitor, 1.5-3.0 parts of organic silicon defoaming agent, 5.0-10.0 parts of block grafting dispersion wetting agent, 75.0-100 parts of rutile titanium dioxide, 50.0-75.0 parts of heavy calcium, 50-75 parts of barium sulfate, 5.0-8.0 parts of polyurethane thickener and 1000 parts of water are sequentially fed into a stirrer to be stirred to form a group A, 90-95 parts of epoxy emulsion and 5-10 parts of AGE special diluent are mixed to form a group B, and the weight ratio of A: b, fully mixing according to the ratio of 3.5-4.0:1.0, and then forming synthetic sand by adopting an extrusion molding granulation mode;
step two, a formula of the black line paint with the integrated bottom surface is as follows: 300 parts of 250-containing organic solvent, 2.0-3.0 parts of emulsified silicone oil defoaming agent, 1.5-3.0 parts of ethyl hydroxyethyl cellulose ether, 3.0-5.0 parts of polycarboxylic acid sodium salt dispersant, 4.0-6.0 parts of polyacrylic ammonium salt dispersant, 2.0-3.0 parts of alkylphenol polyoxyethylene ether nonionic wetting agent, 15-20 parts of propylene glycol, 125 parts of iron oxide black powder, 50-75 parts of superfine kaolin, 50-75 parts of superfine wollastonite, 125 parts of heavy calcium carbonate, 50-75 parts of superfine talcum powder, 150 parts of 100-containing organic solvent high Tg styrene-acrylic emulsion, 150 parts of 125-containing organic solvent high Tg emulsion, 2.0-3.0 parts of benzene green sodium formate preservative and 2.0-3.0 parts of sodium carbonate PH regulator;
step three, preparing a formula of the colorful dispersed phase colored paint: sequentially feeding 450 parts of water, 0.8-1.5 parts of polyacrylic acid sodium salt dispersing agent, 2.0-3.0 parts of emulsified silicone oil foam inhibitor, 1.5-2.0 parts of polyethylene polyamine high-temperature preservative, 5-10 parts of titanium dioxide, 8-12 parts of methyl ethyl hydroxyethyl cellulose, 1-1.5 parts of sodium carbonate PH regulator, 2.0-3.0 parts of alcohol ester dodecafilming auxiliary agent, 4.0-6.0 parts of propylene glycol, 150 parts of inorganic grafting modified acrylic emulsion, 45-50 parts of 10% carob bean gum protective colloid and the synthetic sand obtained in the first step of 250-300 into a mixer for stirring to obtain the colorful dispersed phase color paint;
step four: preparation of a multicolor continuous phase formula: adding 420 parts of 380-fold water, 2.0-3.0 parts of sodium chloride high-efficiency preservative, 0.8-1.2 parts of organic modified bentonite, 10-12 parts of propylene glycol, 1.0-2.0 parts of silicone emulsion defoamer, 2.0-3.0 parts of sodium carbonate PH regulator, 5.0-7.0 parts of alcohol ester dodecafilming auxiliary agent and 600 parts of matte hydroxyl modified polyacrylic acid PMMA graft emulsion 550-fold in sequence into a reaction kettle, and stirring for 20-30min to obtain a colorful continuous phase;
step five: preparing a formula of the colorful finished paint: mixing and stirring 250 parts of long carob bean gum 5% multicolor protection glue 200-; the prepared stone paint is prepared by firstly adopting conventional putty to carry out base layer treatment, then brushing a black line paint with a bottom surface by a wool roller, and then spraying a colorful finished paint by an LPHV spray gun.
2. The method for preparing an aqueous colorful stone-like paint with synthetic sand as a main body according to claim 1, wherein the aqueous epoxy solid agent is one of aliphatic diamine, polyamine, aromatic polyamine and dicyandiamide; the block grafting dispersion wetting agent is a polyoxypropylene block polymer.
3. The method for preparing an aqueous colorful stone-like paint with synthetic sand as the main body according to claim 1, wherein the acrylic emulsion modified by inorganic grafting in the colorful dispersed phase color paint formula is fed into a magnetic stirrer by adopting acrylic emulsion, then 1-2 parts of trimethyl benzoyl-diphenyl phosphine oxide are added to prepare a grafting solution, then nano titanium dioxide with 10-20% of the total amount of the acrylic emulsion is added, and then proton irradiation is carried out for 10-20min with the irradiation power of 200-300W.
4. The method for preparing the waterborne multicolor stone-like paint taking the synthetic sand as the main body according to the claim 1, wherein the modification method of the organic modified bentonite comprises the following steps: adding bentonite into tetraethylenepentamine solution, reacting at 70-80 deg.C for 20-30min, adding silane coupling agent KH560, stirring for 20-30min at a rotation speed of 100-.
5. The method for preparing the water-based colorful stone-like paint taking the synthetic sand as the main body as claimed in claim 4, wherein the rare earth is lanthanum chloride, and the mass ratio of the lanthanum chloride to the bentonite is 1-3: 20.
6. The method for manufacturing the water-based colorful stone-like paint taking the synthetic sand as the main body according to claim 4, wherein the mass ratio of the lanthanum chloride to the bentonite is 1: 10.
7. The method for manufacturing the water-based colorful stone-like paint taking the synthetic sand as the main body according to claim 4, wherein the organic reinforcing agent comprises the following raw materials in parts by weight: 4-5 parts of chitosan, 1-3 parts of vinyl polydimethylsiloxane, 2-6 parts of polyethylene glycol and 5-10 parts of acetone.
8. The method for manufacturing the water-based colorful stone-like paint taking the synthetic sand as the main body according to claim 7, wherein the organic reinforcing agent comprises the following raw materials in parts by weight: 4.5 parts of chitosan, 2 parts of vinyl polydimethylsiloxane, 4 parts of polyethylene glycol and 7.5 parts of acetone.
9. The method for preparing a water-based colorful stone-like paint with synthetic sand as a main body according to claim 1, wherein the matte hydroxyl modified polyacrylic acid PMMA graft type emulsion is prepared by adding PMMA and azobisisobutyronitrile into water-based matte hydroxyl acrylic resin in an ethanol solution medium and reacting.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011240415.8A CN112358759A (en) | 2020-11-09 | 2020-11-09 | Method for preparing water-based colorful stone-like paint with synthetic sand as main body |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011240415.8A CN112358759A (en) | 2020-11-09 | 2020-11-09 | Method for preparing water-based colorful stone-like paint with synthetic sand as main body |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112358759A true CN112358759A (en) | 2021-02-12 |
Family
ID=74510107
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011240415.8A Pending CN112358759A (en) | 2020-11-09 | 2020-11-09 | Method for preparing water-based colorful stone-like paint with synthetic sand as main body |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112358759A (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1995084A (en) * | 2005-12-29 | 2007-07-11 | 电子科技大学 | Organic polymer graft modified nanometer titanium dioxide preparation method |
| CN103525249A (en) * | 2013-10-08 | 2014-01-22 | 深圳市威尔地坪材料有限公司 | Solvent-free epoxy self-leveling floor paint, preparation method thereof and using method thereof |
| CN104261711A (en) * | 2014-09-23 | 2015-01-07 | 合肥工业大学 | Artificial colored sand and preparation method thereof |
| CN104692687A (en) * | 2015-02-09 | 2015-06-10 | 沈阳真石源涂料科技有限公司 | Windblown sand dyeing method |
| CN107245287A (en) * | 2017-07-26 | 2017-10-13 | 富思特新材料科技发展股份有限公司 | Anti-skidding finish paint of illusion-colour drawn grain and preparation method thereof |
| CN109517516A (en) * | 2018-11-20 | 2019-03-26 | 广西大学 | A kind of cerium bentonite modified watersoluble polyurethane paint and preparation method thereof |
| CN111607274A (en) * | 2020-06-04 | 2020-09-01 | 豪冠(上海)国际贸易有限公司 | Preparation method of cover-free stain-resistant weather-resistant water-based multicolor building coating |
| CN111675841A (en) * | 2020-06-30 | 2020-09-18 | 洛阳聚环新材料科技有限公司 | Resin-based artificial colored sand and preparation method thereof |
-
2020
- 2020-11-09 CN CN202011240415.8A patent/CN112358759A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1995084A (en) * | 2005-12-29 | 2007-07-11 | 电子科技大学 | Organic polymer graft modified nanometer titanium dioxide preparation method |
| CN103525249A (en) * | 2013-10-08 | 2014-01-22 | 深圳市威尔地坪材料有限公司 | Solvent-free epoxy self-leveling floor paint, preparation method thereof and using method thereof |
| CN104261711A (en) * | 2014-09-23 | 2015-01-07 | 合肥工业大学 | Artificial colored sand and preparation method thereof |
| CN104692687A (en) * | 2015-02-09 | 2015-06-10 | 沈阳真石源涂料科技有限公司 | Windblown sand dyeing method |
| CN107245287A (en) * | 2017-07-26 | 2017-10-13 | 富思特新材料科技发展股份有限公司 | Anti-skidding finish paint of illusion-colour drawn grain and preparation method thereof |
| CN109517516A (en) * | 2018-11-20 | 2019-03-26 | 广西大学 | A kind of cerium bentonite modified watersoluble polyurethane paint and preparation method thereof |
| CN111607274A (en) * | 2020-06-04 | 2020-09-01 | 豪冠(上海)国际贸易有限公司 | Preparation method of cover-free stain-resistant weather-resistant water-based multicolor building coating |
| CN111675841A (en) * | 2020-06-30 | 2020-09-18 | 洛阳聚环新材料科技有限公司 | Resin-based artificial colored sand and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111849258B (en) | Stone-like paint and preparation method thereof | |
| CN102627902B (en) | Nanometer reinforced aqueous acrylic acid modified epoxy primer-topcoat anticorrosion paint coating and preparation method thereof | |
| CN102433052B (en) | Aqueous polyurethane modified silicon-acrylate multifunctional waterproof heat-insulation elastic paint and preparation method thereof | |
| CN103849280B (en) | Preparation method of ultra-stable high-weather-resistance water-in-water granite-like multicolor paint | |
| CN110903721A (en) | Colorful sand-in-water coating and preparation method thereof | |
| CN107513325B (en) | A kind of weather-proof epoxy thickness slurry anticorrosive paint and preparation method thereof | |
| CN102643586A (en) | High-solid-content quick-drying water-based white primer and preparation method thereof | |
| CN112812603A (en) | Primer-free odor-free anti-fouling art coating and preparation method thereof | |
| CN108485362A (en) | A kind of aqueous polyurethane heat-reflecting heat-insulating exterior coating and preparation method thereof | |
| CN104946058A (en) | Energy-saving type building outer wall coating | |
| CN101967329A (en) | Water-based colorful imitation marble paint | |
| CN111875291A (en) | Spraying texture paint resisting spraying and floating and preparation process thereof | |
| CN106854051A (en) | A kind of texture paint and preparation method thereof | |
| CN114015268A (en) | Inorganic nano ceramic fiber heat-insulating flame-retardant coating | |
| CN106752559A (en) | A kind of environment-friendly type building water paint and preparation method thereof | |
| CN107286803A (en) | The environment-friendly type aqueous protective paint of engineering derrick crane and preparation method | |
| CN102443335A (en) | Epoxy flooring coating for computer machine room | |
| CN108178965A (en) | A kind of aqueous epoxy resins antirust paint and preparation method thereof | |
| CN112358759A (en) | Method for preparing water-based colorful stone-like paint with synthetic sand as main body | |
| CN107353848A (en) | A kind of preparation method of the environment-friendly water-based water proof building fluid sealant of weather resistant | |
| CN115286945A (en) | Compound inorganic resin, preparation method and single-component micro-cement artistic coating | |
| CN102181196A (en) | Water-in-water colorful stone simulated paint | |
| CN107880684A (en) | A kind of water paint of environment friendly corrosion protection and preparation method thereof | |
| CN107955501A (en) | A kind of water paint and preparation method thereof | |
| CN111607274A (en) | Preparation method of cover-free stain-resistant weather-resistant water-based multicolor building coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |