CN107249735A - 包含改性剂的碳载催化剂和制备碳载催化剂的方法 - Google Patents
包含改性剂的碳载催化剂和制备碳载催化剂的方法 Download PDFInfo
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- CN107249735A CN107249735A CN201580076612.1A CN201580076612A CN107249735A CN 107249735 A CN107249735 A CN 107249735A CN 201580076612 A CN201580076612 A CN 201580076612A CN 107249735 A CN107249735 A CN 107249735A
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- Prior art keywords
- supported catalyst
- carbon
- carbon supported
- niobium
- platinum
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 160
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 151
- 239000003054 catalyst Substances 0.000 title claims abstract description 128
- 238000000034 method Methods 0.000 title claims abstract description 40
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 39
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 154
- 239000000203 mixture Substances 0.000 claims abstract description 91
- 229910052751 metal Inorganic materials 0.000 claims abstract description 76
- 239000002184 metal Substances 0.000 claims abstract description 76
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 74
- 239000010955 niobium Substances 0.000 claims abstract description 57
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 50
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract description 50
- -1 metals compound Chemical class 0.000 claims abstract description 45
- 239000010936 titanium Substances 0.000 claims abstract description 35
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 34
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 26
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910000765 intermetallic Inorganic materials 0.000 claims abstract description 17
- 229910000484 niobium oxide Inorganic materials 0.000 claims abstract description 16
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 claims abstract description 16
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 8
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 8
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052737 gold Inorganic materials 0.000 claims abstract description 7
- 239000010931 gold Substances 0.000 claims abstract description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 5
- 239000010941 cobalt Substances 0.000 claims abstract description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052802 copper Inorganic materials 0.000 claims abstract description 5
- 239000010949 copper Substances 0.000 claims abstract description 5
- 229910003455 mixed metal oxide Inorganic materials 0.000 claims abstract description 5
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 5
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 5
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims abstract description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 4
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 4
- 239000011651 chromium Substances 0.000 claims abstract description 4
- 229910052742 iron Inorganic materials 0.000 claims abstract description 4
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract description 4
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 4
- 229910052707 ruthenium Inorganic materials 0.000 claims abstract description 4
- 229910052706 scandium Inorganic materials 0.000 claims abstract description 4
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 4
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000007789 gas Substances 0.000 claims description 59
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 59
- 239000002245 particle Substances 0.000 claims description 30
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 28
- 239000013067 intermediate product Substances 0.000 claims description 23
- 239000002243 precursor Substances 0.000 claims description 20
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- 150000002739 metals Chemical class 0.000 claims description 19
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 12
- 239000000446 fuel Substances 0.000 claims description 12
- 239000001301 oxygen Substances 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 12
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- 238000004140 cleaning Methods 0.000 claims description 9
- 238000001556 precipitation Methods 0.000 claims description 7
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 6
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- 239000003638 chemical reducing agent Substances 0.000 claims description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 5
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- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 4
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- 238000009835 boiling Methods 0.000 claims description 2
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- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical class CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 2
- OGHBATFHNDZKSO-UHFFFAOYSA-N propan-2-olate Chemical compound CC(C)[O-] OGHBATFHNDZKSO-UHFFFAOYSA-N 0.000 claims description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 2
- 150000001805 chlorine compounds Chemical group 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 64
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical class CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 56
- 239000007787 solid Substances 0.000 description 53
- 239000007921 spray Substances 0.000 description 49
- 229910052757 nitrogen Inorganic materials 0.000 description 32
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- 238000000151 deposition Methods 0.000 description 15
- 238000010438 heat treatment Methods 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 13
- 238000000634 powder X-ray diffraction Methods 0.000 description 13
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 12
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 12
- 239000001257 hydrogen Substances 0.000 description 12
- 229910052739 hydrogen Inorganic materials 0.000 description 12
- 238000009826 distribution Methods 0.000 description 10
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- NWAHZABTSDUXMJ-UHFFFAOYSA-N platinum(2+);dinitrate Chemical compound [Pt+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O NWAHZABTSDUXMJ-UHFFFAOYSA-N 0.000 description 8
- 238000013019 agitation Methods 0.000 description 7
- 239000012298 atmosphere Substances 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 7
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 230000002902 bimodal effect Effects 0.000 description 6
- 239000003792 electrolyte Substances 0.000 description 6
- 150000002431 hydrogen Chemical class 0.000 description 6
- 239000002244 precipitate Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 125000004429 atom Chemical group 0.000 description 5
- 229910052738 indium Inorganic materials 0.000 description 5
- 239000003607 modifier Substances 0.000 description 5
- ZKATWMILCYLAPD-UHFFFAOYSA-N niobium pentoxide Chemical compound O=[Nb](=O)O[Nb](=O)=O ZKATWMILCYLAPD-UHFFFAOYSA-N 0.000 description 5
- 238000004062 sedimentation Methods 0.000 description 5
- 238000003980 solgel method Methods 0.000 description 5
- LCKIEQZJEYYRIY-UHFFFAOYSA-N Titanium ion Chemical compound [Ti+4] LCKIEQZJEYYRIY-UHFFFAOYSA-N 0.000 description 4
- OBOYOXRQUWVUFU-UHFFFAOYSA-N [O-2].[Ti+4].[Nb+5] Chemical compound [O-2].[Ti+4].[Nb+5] OBOYOXRQUWVUFU-UHFFFAOYSA-N 0.000 description 4
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- 241000209094 Oryza Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000001186 cumulative effect Effects 0.000 description 3
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- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
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- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 229910002844 PtNi Inorganic materials 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N SnO2 Inorganic materials O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
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- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 2
- CWLKHIHGOBVTMS-UHFFFAOYSA-N ethanol;niobium(5+) Chemical compound [Nb+5].CCO CWLKHIHGOBVTMS-UHFFFAOYSA-N 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
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- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 2
- HRGDZIGMBDGFTC-UHFFFAOYSA-N platinum(2+) Chemical compound [Pt+2] HRGDZIGMBDGFTC-UHFFFAOYSA-N 0.000 description 2
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- 238000005245 sintering Methods 0.000 description 2
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- PBCFLUZVCVVTBY-UHFFFAOYSA-N tantalum pentoxide Inorganic materials O=[Ta](=O)O[Ta](=O)=O PBCFLUZVCVVTBY-UHFFFAOYSA-N 0.000 description 2
- 229910002058 ternary alloy Inorganic materials 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- GDSOZVZXVXTJMI-SNAWJCMRSA-N (e)-1-methylbut-1-ene-1,2,4-tricarboxylic acid Chemical compound OC(=O)C(/C)=C(C(O)=O)\CCC(O)=O GDSOZVZXVXTJMI-SNAWJCMRSA-N 0.000 description 1
- LLYXJBROWQDVMI-UHFFFAOYSA-N 2-chloro-4-nitrotoluene Chemical compound CC1=CC=C([N+]([O-])=O)C=C1Cl LLYXJBROWQDVMI-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 101100116420 Aedes aegypti DEFC gene Proteins 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
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- 229940045985 antineoplastic platinum compound Drugs 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
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- WBLJAACUUGHPMU-UHFFFAOYSA-N copper platinum Chemical compound [Cu].[Pt] WBLJAACUUGHPMU-UHFFFAOYSA-N 0.000 description 1
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- PNCDAXYMWHXGON-UHFFFAOYSA-N ethanol;niobium Chemical compound [Nb].CCO.CCO.CCO.CCO.CCO PNCDAXYMWHXGON-UHFFFAOYSA-N 0.000 description 1
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- 229910052750 molybdenum Inorganic materials 0.000 description 1
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- HFLAMWCKUFHSAZ-UHFFFAOYSA-N niobium dioxide Inorganic materials O=[Nb]=O HFLAMWCKUFHSAZ-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- JRTYPQGPARWINR-UHFFFAOYSA-N palladium platinum Chemical compound [Pd].[Pt] JRTYPQGPARWINR-UHFFFAOYSA-N 0.000 description 1
- YHBDIEWMOMLKOO-UHFFFAOYSA-I pentachloroniobium Chemical compound Cl[Nb](Cl)(Cl)(Cl)Cl YHBDIEWMOMLKOO-UHFFFAOYSA-I 0.000 description 1
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- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/925—Metals of platinum group supported on carriers, e.g. powder carriers
- H01M4/926—Metals of platinum group supported on carriers, e.g. powder carriers on carbon or graphite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
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| PCT/EP2015/080752 WO2016102440A1 (en) | 2014-12-22 | 2015-12-21 | Carbon supported catalyst comprising a modifier and process for preparing the carbon supported catalyst |
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| EP (1) | EP3237110A1 (enExample) |
| JP (1) | JP6671376B2 (enExample) |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108745373A (zh) * | 2018-06-15 | 2018-11-06 | 南京大学 | 一种贵金属合金/碳材料负载型催化剂的制备方法 |
| CN111883791A (zh) * | 2020-06-17 | 2020-11-03 | 江苏大学 | 三金属铂钯铬直接乙醇燃料电池催化剂的制备方法 |
| CN111939893A (zh) * | 2020-08-11 | 2020-11-17 | 江苏集萃安泰创明先进能源材料研究院有限公司 | 一种储氢材料用复合催化剂及其制备方法 |
| CN113113623A (zh) * | 2021-03-26 | 2021-07-13 | 中国科学技术大学 | 碳负载的铂基金属间化合物纳米材料合成方法及其电催化应用 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9873107B2 (en) * | 2014-03-18 | 2018-01-23 | Basf Se | Process for the production of a carbon supported catalyst |
| US10886540B2 (en) * | 2015-12-14 | 2021-01-05 | Indiana University Research And Technology Corporation | Systems and methods of graphene supported catalysts |
| US11110433B2 (en) | 2016-03-18 | 2021-09-07 | Basf Se | Metal-doped tin oxide for electrocatalysis applications |
| KR102569084B1 (ko) | 2016-10-28 | 2023-08-22 | 바스프 에스이 | 산화 주석 상에 지지된 귀금속 산화물을 포함하는 전기촉매 조성물 |
| KR102093824B1 (ko) * | 2018-05-02 | 2020-03-26 | 한국과학기술연구원 | 탄소-담지 백금-전이금속 합금 나노입자 촉매의 제조방법 |
| KR102141396B1 (ko) * | 2018-08-24 | 2020-08-05 | 한국과학기술연구원 | 탄소-담지 백금-전이금속 합금 나노입자 촉매의 제조방법 |
| JP6904371B2 (ja) * | 2019-02-08 | 2021-07-14 | 株式会社豊田中央研究所 | Ｐｔ−Ｌｎナノ粒子、並びに、Ｐｔ−Ｌｎナノ粒子複合体及びその製造方法 |
| US20210104752A1 (en) * | 2019-10-02 | 2021-04-08 | Robert Bosch Gmbh | Catalyst support materials for fuel cells |
| KR102421057B1 (ko) * | 2019-11-20 | 2022-07-15 | 건국대학교 산학협력단 | 전기증착법을 이용한 금속 유기 골격체와 층상 이중 수산화물 복합체 제조 방법 |
| CN114512617A (zh) * | 2020-11-17 | 2022-05-17 | 京东方科技集团股份有限公司 | 一种发光器件、显示装置和发光器件的制作方法 |
| KR20220091754A (ko) * | 2020-12-24 | 2022-07-01 | 현대자동차주식회사 | 인터메탈릭 촉매 및 이의 제조 방법 |
| KR20220103288A (ko) * | 2021-01-15 | 2022-07-22 | 현대자동차주식회사 | 인터메탈릭 촉매 및 이의 제조 방법 |
| CN112921344B (zh) * | 2021-01-19 | 2022-06-10 | 华南理工大学 | 一种氧化锡-氯氧化铋复合颗粒及其制备方法和应用 |
| CN116020503B (zh) * | 2021-10-25 | 2024-08-30 | 中国石油化工股份有限公司 | 用于烃类选择氧化的成型钒磷氧化物催化剂及其制备方法和顺酐的制备方法 |
| CN117486746B (zh) * | 2023-12-21 | 2024-04-05 | 禾工(广州)材料科技股份有限公司 | 一种十八烷基油酸酰胺的制备方法 |
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| JP2011222132A (ja) * | 2010-04-02 | 2011-11-04 | Hitachi Ltd | 電極触媒材料およびその製造方法 |
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2015
- 2015-12-21 US US15/538,457 patent/US20180006313A1/en not_active Abandoned
- 2015-12-21 EP EP15817306.2A patent/EP3237110A1/en not_active Withdrawn
- 2015-12-21 WO PCT/EP2015/080752 patent/WO2016102440A1/en not_active Ceased
- 2015-12-21 CN CN201580076612.1A patent/CN107249735A/zh active Pending
- 2015-12-21 KR KR1020177020312A patent/KR20170100581A/ko not_active Ceased
- 2015-12-21 JP JP2017533948A patent/JP6671376B2/ja active Active
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| CN1957492A (zh) * | 2004-05-25 | 2007-05-02 | Lg化学株式会社 | 钌－铑合金电极催化剂和包括该催化剂的燃料电池 |
| CN101024495A (zh) * | 2006-02-23 | 2007-08-29 | 三星Sdi株式会社 | 碳纳米管、含它的担载催化剂及采用该催化剂的燃料电池 |
| CN102668200A (zh) * | 2009-09-22 | 2012-09-12 | 巴斯夫欧洲公司 | 用于燃料电池的具有金属氧化物掺杂的催化剂 |
| EP2413406A2 (en) * | 2010-07-28 | 2012-02-01 | Hitachi, Ltd. | Catalyst material and method of manufacturing the same |
| CN102593472A (zh) * | 2011-01-13 | 2012-07-18 | 三星电子株式会社 | 催化剂、制法、燃料电池、电极及锂空气电池 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108745373A (zh) * | 2018-06-15 | 2018-11-06 | 南京大学 | 一种贵金属合金/碳材料负载型催化剂的制备方法 |
| CN111883791A (zh) * | 2020-06-17 | 2020-11-03 | 江苏大学 | 三金属铂钯铬直接乙醇燃料电池催化剂的制备方法 |
| CN111939893A (zh) * | 2020-08-11 | 2020-11-17 | 江苏集萃安泰创明先进能源材料研究院有限公司 | 一种储氢材料用复合催化剂及其制备方法 |
| CN113113623A (zh) * | 2021-03-26 | 2021-07-13 | 中国科学技术大学 | 碳负载的铂基金属间化合物纳米材料合成方法及其电催化应用 |
Also Published As
| Publication number | Publication date |
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| US20180006313A1 (en) | 2018-01-04 |
| EP3237110A1 (en) | 2017-11-01 |
| WO2016102440A1 (en) | 2016-06-30 |
| JP6671376B2 (ja) | 2020-03-25 |
| JP2018507097A (ja) | 2018-03-15 |
| KR20170100581A (ko) | 2017-09-04 |
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