CN107245339A - A kind of weeding composite for being used to adjust soil ph - Google Patents
A kind of weeding composite for being used to adjust soil ph Download PDFInfo
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- CN107245339A CN107245339A CN201710618733.5A CN201710618733A CN107245339A CN 107245339 A CN107245339 A CN 107245339A CN 201710618733 A CN201710618733 A CN 201710618733A CN 107245339 A CN107245339 A CN 107245339A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
- A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
- A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2109/00—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE pH regulation
Abstract
The invention discloses a kind of weeding composite for being used to adjust soil ph, its raw material includes Controlled-release filler, soil acid-base conditioning agent, silica gel, tourmaline powder, flyash, sepiolite powder, n-hexadecyl trimethylamine, bromide sixteen alkyls pyridine, polymetaphosphate sodium, hexa, carboxymethyl cellulose, na-montmorillonite, atrazine, metribuzin, Acetochlor, sodium bentonite, nicosulfuron, neopelex, lauryl sodium sulfate, glycerine, butyl acetate, potassium dihydrogen phosphate and sodium tetraborate.The weeding composite of the present invention has excellent sustained release performance, can realize the high-effect high-quality release of weeding medicine, improves the efficiency and quality of weeding, and can carry out acid-base balance regulation to soil, optimizes soil property.
Description
Technical field
It is combined the present invention relates to the technical field of weeding material, more particularly to a kind of weeding for being used to adjust soil ph
Material.
Background technology
Weeding material of the prior art is mostly pharmaceutically dosage form, and weeding is carried out by way of sprinkling, and medicament is being entered
It is easy to damage the acid-base property of soil after soil so that alkalization of soils or acidifying, is unfavorable for the growth of soil crop,
The heavy damage acid-base balance of soil, so needing badly, exploitation is a kind of to be used to adjust the weeding composite of soil ph to solve
Certainly the problems of the prior art.
The content of the invention
To solve technical problem present in background technology, the present invention proposes a kind of weeding for being used to adjust soil ph
Composite, with excellent sustained release performance, can realize the high-effect high-quality release of weeding medicine, improve the efficiency of weeding
And quality, and acid-base balance regulation can be carried out to soil, optimize soil property.
A kind of weeding composite for being used to adjust soil ph proposed by the present invention, its raw material includes by weight：
20-50 parts of Controlled-release filler, 15-25 parts of soil acid-base conditioning agent, 5-15 parts of silica gel, 2-6 parts of tourmaline powder, 1-5 parts of flyash, sea
3-6 parts of afrodite powder, 1-3 parts of n-hexadecyl trimethylamine, 2-5 parts of bromide sixteen alkyls pyridine, 2-6 parts of polymetaphosphate sodium, six
3-5 parts of methenamine, 4-8 parts of carboxymethyl cellulose, 2-5 parts of na-montmorillonite, 3-6 parts of atrazine, 1-5 parts of metribuzin, second
Careless amine 4-6 parts, 3-6 parts of sodium bentonite, 2-5 parts of nicosulfuron, 3-6 parts of neopelex, lauryl sodium sulfate
2-4 parts, 1-4 parts of glycerine, 2-5 parts of butyl acetate, 1-6 parts of potassium dihydrogen phosphate, 4-8 parts of sodium tetraborate.
Preferably, the raw material of Controlled-release filler includes by weight：15-25 parts of attapulgite, 4-8 parts of hydrochloric acid solution, shell gather
3-6 parts of sugar juice, 2-5 parts of sodium alginate, 1-5 parts of disodium hydrogen phosphate, 4-8 parts of calcium nitrate solution, 3,5- dihydroxy-benzoic acids 3-6
Part, 2-8 parts of octylame.
Preferably, Controlled-release filler is prepared by following technique：Attapulgite is soaked in hydrochloric acid solution, stirred at room temperature
Mix, suction filtration, wash, dry, grinding sieving is cooled to room temperature and obtains material a；Chitosan solution and sodium alginate are mixed equal
It is even, salt acid for adjusting pH is then added, disodium hydrogen phosphate, calcium nitrate solution and the mixing of 3,5- dihydroxy-benzoic acid is subsequently added into equal
Even, stirring then heats up, and is incubated, and is subsequently added into material a and octylame is well mixed, stirring, with acetone precipitation, solid is filtered, washed
Wash, then dissolved with distilled water, dialysed, freeze-drying obtains Controlled-release filler.
Preferably, Controlled-release filler is prepared by following technique：Attapulgite is soaked into 10-20min in hydrochloric acid solution,
At room temperature 20-40min, suction filtration, washing, in 100-110 DEG C of dry 2-4h, ground 180- are stirred in 650-850r/min rotating speeds
220 mesh sieves, are cooled to room temperature and obtain material a；Chitosan solution and sodium alginate are well mixed, salt acid for adjusting pH is then added
To 3-4, it is subsequently added into disodium hydrogen phosphate, calcium nitrate solution and 3,5- dihydroxy-benzoic acid and is well mixed, in 650-850r/min
Rotating speed stirs 20-40min, is then warming up to 25-35 DEG C, is incubated 2-3h, is subsequently added into material a and octylame is well mixed, in
450-550r/min rotating speeds stir 15-35min, with acetone precipitation, and then solid filtering, washing are dissolved with distilled water, and dialyse 2-
4d, freeze-drying, obtains Controlled-release filler.
Preferably, the raw material of soil acid-base conditioning agent includes by weight：4-9 parts of pyrolkigneous liquid, 2-5 parts of orange peel, mushroom bran 3-6
Part, 1-4 parts of humic acid, 2-6 parts of oyster shell powder, 1-5 parts of kaolin powder, 3-6 parts of talcum powder, 2-5 parts of dolomite rock powder, take stone flour 1-
3 parts, 6-12 parts of deionized water, 4-8 parts of cetyl trimethylammonium bromide, 3-5 parts of acrylic acid amides, 4-8 parts of polyvinyl alcohol, sulphur
Sour calcium 2-5 parts, 1-5 parts of magnesium sulfate, 3-6 parts of ammonium molybdate, 2-5 parts of Boratex, diammonium hydrogen phosphate and 2-4 parts of ammonium dihydrogen phosphate, lemon
3-6 parts of potassium of lemon acid, 1-4 parts of acetum, 2-6 parts of glutaraldehyde.
Preferably, soil acid-base conditioning agent is prepared by following technique：By pyrolkigneous liquid, orange peel, mushroom bran, humic acid, male
Oyster shells, kaolin powder, talcum powder, dolomite rock powder, to take stone flour, deionized water and cetyl trimethylammonium bromide mixing equal
It is even, stir, washing, suction filtration is dried, be cooled to room temperature, grinding sieving obtains material A, acrylic acid acyl is then added into material A
Amine, polyvinyl alcohol, calcium sulfate, magnesium sulfate, ammonium molybdate, Boratex, diammonium hydrogen phosphate and ammonium dihydrogen phosphate and potassium citrate mixing
Uniformly, heat up, insulation is subsequently added into acetum and is well mixed, stirring, and then addition is well mixed, stands, is subsequently added into penta
Dialdehyde is well mixed, and is washed to neutrality, is dried, is cooled to room temperature and obtains soil acid-base conditioning agent.
Preferably, soil acid-base conditioning agent is prepared by following technique：By pyrolkigneous liquid, orange peel, mushroom bran, humic acid, male
Oyster shells, kaolin powder, talcum powder, dolomite rock powder, to take stone flour, deionized water and cetyl trimethylammonium bromide mixing equal
It is even, 20-40min is stirred in 650-850r/min rotating speeds, washing, suction filtration, in 80-90 DEG C of dry 1-3h, is cooled to room temperature, grinds
Cross 110-130 mesh sieves and obtain material A, acrylic acid amides, polyvinyl alcohol, calcium sulfate, magnesium sulfate, molybdenum are then added into material A
Sour ammonium, Boratex, diammonium hydrogen phosphate and ammonium dihydrogen phosphate and potassium citrate are well mixed, are warming up to 80-120 DEG C, are incubated 2-4h,
It is subsequently added into acetum to be well mixed, 20-40min is stirred in 1500-2500r/min rotating speeds, then adds and be well mixed, it is quiet
.5-1.5h is set to 0, glutaraldehyde is subsequently added into and is well mixed, be washed to neutrality, in 85-95 DEG C of dry 2-4h, be cooled to room temperature and obtain
Soil acid-base conditioning agent.
A kind of weeding composite for being used to adjust soil ph of the present invention, its raw material includes Controlled-release filler, soil
It is acid-base modifier, silica gel, tourmaline powder, flyash, sepiolite powder, n-hexadecyl trimethylamine, bromide sixteen alkyls pyridine, many
Sodium hexametaphosphate, hexa, carboxymethyl cellulose, na-montmorillonite, atrazine, metribuzin, Acetochlor, Na-bentonite
Soil, nicosulfuron, neopelex, lauryl sodium sulfate, glycerine, butyl acetate, potassium dihydrogen phosphate and four boron
Sour sodium.Wherein, Controlled-release filler is stirred, suction filtration at room temperature by the way that attapulgite is soaked in hydrochloric acid solution, is washed, and is dried, is ground
Honed sieve, is cooled to room temperature and obtains material a；Chitosan solution and sodium alginate are well mixed, salt acid for adjusting pH is then added,
It is subsequently added into disodium hydrogen phosphate, calcium nitrate solution and 3,5- dihydroxy-benzoic acid well mixed, stirring then heats up, and is incubated, connects
Addition material a and octylame is well mixed, stirring, with acetone precipitation, then solid filtering, washing are dissolved, thoroughly with distilled water
Analysis, freeze-drying, obtains Controlled-release filler, in the weeding composite for applying to the present invention, can effectively improve weeding additive
Release efficiency and quality.Wherein, soil acid-base conditioning agent is prepared by following technique：By pyrolkigneous liquid, orange peel, mushroom bran, corruption
Grow acid, oyster shell powder, kaolin powder, talcum powder, dolomite rock powder, expense stone flour, deionized water and cetyl trimethylammonium bromide
It is well mixed, stir, washing, suction filtration is dried, be cooled to room temperature, grinding sieving obtains material A, third is then added into material A
Enoic, polyvinyl alcohol, calcium sulfate, magnesium sulfate, ammonium molybdate, Boratex, diammonium hydrogen phosphate and ammonium dihydrogen phosphate and citric acid
Potassium is well mixed, and is heated up, and is incubated, and is subsequently added into acetum and is well mixed, and then stirring adds well mixed, standing, then
Add glutaraldehyde to be well mixed, be washed to neutrality, dry, be cooled to room temperature and obtain soil acid-base conditioning agent, apply to the present invention
Weeding composite in, can realize and soil acidity or alkalinity is controlled, it is to avoid soil it is peracid or cross alkalize, optimize soil
Structure, is able to ensure that the health of soil environment while realizing weeding.The weeding composite of the present invention has excellent delay
Performance is released, the high-effect high-quality release of weeding medicine can be realized, the efficiency and quality of weeding is improved, and soil can be entered
Row acid-base balance is adjusted, and optimizes soil property.
Embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent substitution etc. are in this hair
In bright protection domain.
In embodiment, the parts by weight of Controlled-release filler can for 20 parts, 25 parts, 30 parts, 35 parts, 40 parts, 45 parts, 50
Part；The parts by weight of soil acid-base conditioning agent can for 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts,
24 parts, 25 parts；The parts by weight of silica gel can for 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15
Part；The parts by weight of tourmaline powder can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The parts by weight of flyash can for 1 part, 2 parts, 3 parts,
4 parts, 5 parts；The parts by weight of sepiolite powder can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；N-hexadecyl three
The parts by weight of methylamine can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts；The parts by weight of bromide sixteen alkyls pyridine can for 2 parts,
2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of polymetaphosphate sodium can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；
The parts by weight of hexa can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of carboxymethyl cellulose can be 4
Part, 5 parts, 6 parts, 7 parts, 8 parts；The parts by weight of na-montmorillonite can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；
The parts by weight of atrazine can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of metribuzin can be 1
Part, 2 parts, 3 parts, 4 parts, 5 parts；The parts by weight of Acetochlor can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The weight of sodium bentonite
It can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts to measure part；The parts by weight of nicosulfuron can for 2 parts, 2.5 parts, 3
Part, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of neopelex can for 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts,
5.5 parts, 6 parts；The parts by weight of lauryl sodium sulfate can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The parts by weight of glycerine
It can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The parts by weight of butyl acetate can for 2 parts, 2.5 parts, 3 parts,
3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of potassium dihydrogen phosphate can for 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4
Part, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of sodium tetraborate can for 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7
Part, 7.5 parts, 8 parts.
Embodiment 1
A kind of weeding composite for being used to adjust soil ph proposed by the present invention, its raw material includes by weight：
35 parts of Controlled-release filler, 20 parts of soil acid-base conditioning agent, 10 parts of silica gel, 4 parts of tourmaline powder, 3 parts of flyash, 4.5 parts of sepiolite powder,
2 parts of n-hexadecyl trimethylamine, 3.5 parts of bromide sixteen alkyls pyridine, 4 parts of polymetaphosphate sodium, 4 parts of hexa, carboxylic
6 parts of methylcellulose, 3.5 parts of na-montmorillonite, 4.5 parts of atrazine, 3 parts of metribuzin, 5 parts of Acetochlor, sodium bentonite 4.5
Part, 3.5 parts of nicosulfuron, 4.5 parts of neopelex, 3 parts of lauryl sodium sulfate, 2.5 parts of glycerine, butyl acetate
3.5 parts, 3.5 parts of potassium dihydrogen phosphate, 6 parts of sodium tetraborate.
Controlled-release filler is prepared by following technique：20 parts of attapulgites are soaked in 6 parts of hydrochloric acid solutions by weight
15min, stirs 30min in 750r/min rotating speeds at room temperature, and suction filtration is washed, in 105 DEG C of dry 3h, ground 200 mesh sieve is cold
But material a is obtained to room temperature；4.5 parts of chitosan solutions and 3.5 parts of sodium alginates are well mixed, salt acid for adjusting pH is then added
To 3.5, it is subsequently added into 3 parts of disodium hydrogen phosphates, 6 parts of calcium nitrate solutions and 4.5 parts of 3,5- dihydroxy-benzoic acids and is well mixed, in
750r/min rotating speeds stir 30min, are then warming up to 30 DEG C, are incubated 2.5h, be subsequently added into material a and 5 parts of octylames are well mixed,
25min is stirred in 500r/min rotating speeds, with acetone precipitation, then solid filtering, washing are dissolved with distilled water, and dialyse 3d, freezing
Dry, obtain Controlled-release filler.
Soil acid-base conditioning agent is prepared by following technique：By weight by 6.5 parts of pyrolkigneous liquid, 3.5 parts of orange peels, 4.5
Part mushroom bran, 2.5 parts of humic acid, 4 parts of oyster shell powders, 3 parts of kaolin powder, 4.5 parts of talcum powder, 3.5 parts of dolomite rock powders, 2 parts take stone
Powder, 9 parts of deionized waters and 6 parts of cetyl trimethylammonium bromides are well mixed, and are stirred 30min in 750r/min rotating speeds, are washed,
Suction filtration, in 85 DEG C of dry 2h, is cooled to room temperature, ground 120 mesh sieve obtains material A, and 4 parts of propylene are then added into material A
Sour acid amides, 6 parts of polyvinyl alcohol, 3.5 parts of calcium sulfate, 3 parts of magnesium sulfate, 4.5 parts of ammonium molybdates, 3.5 parts of Boratexes, 3 parts of phosphoric acid hydrogen two
Ammonium and 4.5 parts of ammonium dihydrogen phosphates and potassium citrate are well mixed, are warming up to 100 DEG C, are incubated 3h, are subsequently added into 2.5 parts of acetic acid molten
Liquid is well mixed, and 30min is stirred in 2000r/min rotating speeds, is then added well mixed, standing 1h, is subsequently added into 4 parts of glutaraldehydes
It is well mixed, neutrality is washed to, in 90 DEG C of dry 3h, room temperature is cooled to and obtains soil acid-base conditioning agent.
Embodiment 2
A kind of weeding composite for being used to adjust soil ph proposed by the present invention, its raw material includes by weight：
20 parts of Controlled-release filler, 25 parts of soil acid-base conditioning agent, 5 parts of silica gel, 6 parts of tourmaline powder, 1 part of flyash, 6 parts of sepiolite powder, just
1 part of hexadecyl trimethylamine, 5 parts of bromide sixteen alkyls pyridine, 2 parts of polymetaphosphate sodium, 5 parts of hexa, carboxymethyl
4 parts of cellulose, 5 parts of na-montmorillonite, 3 parts of atrazine, 5 parts of metribuzin, 4 parts of Acetochlor, 6 parts of sodium bentonite, nicosulfuron 2
Part, 6 parts of neopelex, 2 parts of lauryl sodium sulfate, 4 parts of glycerine, 2 parts of butyl acetate, 6 parts of potassium dihydrogen phosphate,
4 parts of sodium tetraborate.
Controlled-release filler is prepared by following technique：15 parts of attapulgites are soaked in 8 parts of hydrochloric acid solutions by weight
10min, stirs 20min in 850r/min rotating speeds at room temperature, and suction filtration is washed, in 110 DEG C of dry 2h, ground 220 mesh sieve is cold
But material a is obtained to room temperature；3 parts of chitosan solutions and 5 parts of sodium alginates are well mixed, salt acid for adjusting pH are then added to 3,
It is subsequently added into 5 parts of disodium hydrogen phosphates, 4 parts of calcium nitrate solutions and 6 parts of 3,5- dihydroxy-benzoic acids to be well mixed, turns in 650r/min
Speed stirring 40min, is then warming up to 25 DEG C, is incubated 3h, is subsequently added into material a and 2 parts of octylames are well mixed, turn in 550r/min
Speed stirring 15min, with acetone precipitation, then solid filtering, washing are dissolved with distilled water, and dialysed 4d, and freeze-drying is delayed
Release filler.
Soil acid-base conditioning agent is prepared by following technique：By weight by 4 parts of pyrolkigneous liquid, 5 parts of orange peels, 3 parts of mushroom brans,
4 parts of humic acid, 2 parts of oyster shell powders, 5 parts of kaolin powder, 3 parts of talcum powder, 5 parts of dolomite rock powders, 1 part take stone flour, 12 parts of deionizations
Water and 4 parts of cetyl trimethylammonium bromides are well mixed, and 20min, washing, suction filtration, in 90 DEG C are stirred in 850r/min rotating speeds
Dry 1h, be cooled to room temperature, ground 130 mesh sieve obtains material A, then added into material A 3 parts of acrylic acid amides, 8 parts gather
Vinyl alcohol, 2 parts of calcium sulfate, 5 parts of magnesium sulfate, 3 parts of ammonium molybdates, 5 parts of Boratexes, 2 parts of diammonium hydrogen phosphates and 6 parts of ammonium dihydrogen phosphates and
Potassium citrate is well mixed, and is warming up to 80 DEG C, is incubated 4h, is subsequently added into 1 part of acetum and is well mixed, turns in 2500r/min
Speed stirring 20min, then adds well mixed, standing 1.5h, is subsequently added into 2 parts of glutaraldehydes and is well mixed, be washed to neutrality, in
95 DEG C of dry 2h, are cooled to room temperature and obtain soil acid-base conditioning agent.
Embodiment 3
A kind of weeding composite for being used to adjust soil ph proposed by the present invention, its raw material includes by weight：
50 parts of Controlled-release filler, 15 parts of soil acid-base conditioning agent, 15 parts of silica gel, 2 parts of tourmaline powder, 5 parts of flyash, 3 parts of sepiolite powder, just
3 parts of hexadecyl trimethylamine, 2 parts of bromide sixteen alkyls pyridine, 6 parts of polymetaphosphate sodium, 3 parts of hexa, carboxymethyl
8 parts of cellulose, 2 parts of na-montmorillonite, 6 parts of atrazine, 1 part of metribuzin, 6 parts of Acetochlor, 3 parts of sodium bentonite, nicosulfuron 5
Part, 3 parts of neopelex, 4 parts of lauryl sodium sulfate, 1 part of glycerine, 5 parts of butyl acetate, 1 part of potassium dihydrogen phosphate,
8 parts of sodium tetraborate.
Controlled-release filler is prepared by following technique：25 parts of attapulgites are soaked in 4 parts of hydrochloric acid solutions by weight
20min, stirs 40min in 650r/min rotating speeds at room temperature, and suction filtration is washed, in 100 DEG C of dry 4h, ground 180 mesh sieve is cold
But material a is obtained to room temperature；6 parts of chitosan solutions and 2 parts of sodium alginates are well mixed, salt acid for adjusting pH are then added to 4,
It is subsequently added into 1 part of disodium hydrogen phosphate, 8 parts of calcium nitrate solutions and 3 parts of 3,5- dihydroxy-benzoic acids to be well mixed, turns in 850r/min
Speed stirring 20min, is then warming up to 35 DEG C, is incubated 2h, is subsequently added into material a and 8 parts of octylames are well mixed, turn in 450r/min
Speed stirring 35min, with acetone precipitation, then solid filtering, washing are dissolved with distilled water, and dialysed 2d, and freeze-drying is delayed
Release filler.
Soil acid-base conditioning agent is prepared by following technique：By weight by 9 parts of pyrolkigneous liquid, 2 parts of orange peels, 6 parts of mushroom brans,
1 part of humic acid, 6 parts of oyster shell powders, 1 part of kaolin powder, 6 parts of talcum powder, 2 parts of dolomite rock powders, 3 parts take stone flour, 6 parts of deionized waters
It is well mixed with 8 parts of cetyl trimethylammonium bromides, 40min is stirred in 650r/min rotating speeds, washing, suction filtration is dry in 80 DEG C
Dry 3h, is cooled to room temperature, and ground 110 mesh sieve obtains material A, and 5 parts of acrylic acid amides, 4 parts of poly- second are then added into material A
Enol, 5 parts of calcium sulfate, 1 part of magnesium sulfate, 6 parts of ammonium molybdates, 2 parts of Boratexes, 4 parts of diammonium hydrogen phosphates and 3 parts of ammonium dihydrogen phosphates and lemon
Lemon acid potassium is well mixed, and is warming up to 120 DEG C, is incubated 2h, is subsequently added into 4 parts of acetums and is well mixed, in 1500r/min rotating speeds
40min is stirred, well mixed, standing 0.5h is then added, is subsequently added into 6 parts of glutaraldehydes and is well mixed, neutrality is washed to, in 85
DEG C dry 4h, be cooled to room temperature and obtain soil acid-base conditioning agent.
Embodiment 4
A kind of weeding composite for being used to adjust soil ph proposed by the present invention, its raw material includes by weight：
25 parts of Controlled-release filler, 22 parts of soil acid-base conditioning agent, 8 parts of silica gel, 5 parts of tourmaline powder, 2 parts of flyash, 5 parts of sepiolite powder, just
1.5 parts of hexadecyl trimethylamine, 4 parts of bromide sixteen alkyls pyridine, 3 parts of polymetaphosphate sodium, 4.5 parts of hexa, carboxylic
5 parts of methylcellulose, 4 parts of na-montmorillonite, 4 parts of atrazine, 4 parts of metribuzin, 4.5 parts of Acetochlor, 5 parts of sodium bentonite, cigarette
3 parts of Sulfometuron Methyl, 5 parts of neopelex, 2.5 parts of lauryl sodium sulfate, 3 parts of glycerine, 3 parts of butyl acetate, phosphoric acid
5 parts of potassium dihydrogen, 5 parts of sodium tetraborate.
Controlled-release filler is prepared by following technique：18 parts of attapulgites are soaked in 7 parts of hydrochloric acid solutions by weight
12min, stirs 25min in 820r/min rotating speeds at room temperature, suction filtration, washing, in 108 DEG C of dry 2.5h, ground 215 mesh sieve,
It is cooled to room temperature and obtains material a；4 parts of chitosan solutions and 4 parts of sodium alginates are well mixed, then salt acid for adjusting pH are added extremely
3.2, it is subsequently added into 4 parts of disodium hydrogen phosphates, 5 parts of calcium nitrate solutions and 5 parts of 3,5- dihydroxy-benzoic acids and is well mixed, in 680r/
Min rotating speeds stir 35min, are then warming up to 28 DEG C, are incubated 2.8h, be subsequently added into material a and 3 parts of octylames are well mixed, in
520r/min rotating speeds stir 18min, with acetone precipitation, and then solid filtering, washing are dissolved with distilled water, and dialyse 3.5d, freezing
Dry, obtain Controlled-release filler.
Soil acid-base conditioning agent is prepared by following technique：By weight by 5 parts of pyrolkigneous liquid, 4 parts of orange peels, 4 parts of mushroom brans,
3 parts of humic acid, 3 parts of oyster shell powders, 4 parts of kaolin powder, 4 parts of talcum powder, 4 parts of dolomite rock powders, 1.5 parts of expense stone flours, 11 parts go from
Sub- water and 5 parts of cetyl trimethylammonium bromides are well mixed, and 25min, washing, suction filtration, in 88 are stirred in 820r/min rotating speeds
DEG C dry 1.5h, be cooled to room temperature, ground 125 mesh sieve obtains material A, then into material A add 3.5 parts of acrylic acid acyls
Amine, 7 parts of polyvinyl alcohol, 3 parts of calcium sulfate, 4 parts of magnesium sulfate, 4 parts of ammonium molybdates, 4 parts of Boratexes, 2.5 parts of diammonium hydrogen phosphates and 5 parts of phosphorus
Acid dihydride ammonium and potassium citrate are well mixed, are warming up to 85 DEG C, are incubated 3.5h, are subsequently added into 2 parts of acetums and are well mixed, in
2200r/min rotating speeds stir 25min, then add well mixed, standing 1.2h, are subsequently added into 3 parts of glutaraldehydes and are well mixed, water
Neutrality is washed till, in 92 DEG C of dry 2.5h, room temperature is cooled to and obtains soil acid-base conditioning agent.
Embodiment 5
A kind of weeding composite for being used to adjust soil ph proposed by the present invention, its raw material includes by weight：
45 parts of Controlled-release filler, 18 parts of soil acid-base conditioning agent, 12 parts of silica gel, 3 parts of tourmaline powder, 4 parts of flyash, 4 parts of sepiolite powder, just
2.5 parts of hexadecyl trimethylamine, 3 parts of bromide sixteen alkyls pyridine, 5 parts of polymetaphosphate sodium, 3.5 parts of hexa, carboxylic
7 parts of methylcellulose, 3 parts of na-montmorillonite, 5 parts of atrazine, 2 parts of metribuzin, 5.5 parts of Acetochlor, 4 parts of sodium bentonite, cigarette
4 parts of Sulfometuron Methyl, 4 parts of neopelex, 3.5 parts of lauryl sodium sulfate, 2 parts of glycerine, 4 parts of butyl acetate, phosphoric acid
2 parts of potassium dihydrogen, 7 parts of sodium tetraborate.
Controlled-release filler is prepared by following technique：22 parts of attapulgites are soaked in 5 parts of hydrochloric acid solutions by weight
18min, stirs 35min in 680r/min rotating speeds at room temperature, suction filtration, washing, in 102 DEG C of dry 3.5h, ground 185 mesh sieve,
It is cooled to room temperature and obtains material a；5 parts of chitosan solutions and 3 parts of sodium alginates are well mixed, then salt acid for adjusting pH are added extremely
3.8, it is subsequently added into 2 parts of disodium hydrogen phosphates, 7 parts of calcium nitrate solutions and 4 parts of 3,5- dihydroxy-benzoic acids and is well mixed, in 820r/
Min rotating speeds stir 25min, are then warming up to 32 DEG C, are incubated 2.2h, be subsequently added into material a and 7 parts of octylames are well mixed, in
480r/min rotating speeds stir 32min, with acetone precipitation, and then solid filtering, washing are dissolved with distilled water, and dialyse 2.5d, freezing
Dry, obtain Controlled-release filler.
Soil acid-base conditioning agent is prepared by following technique：By weight by 8 parts of pyrolkigneous liquid, 3 parts of orange peels, 5 parts of mushroom brans,
2 parts of humic acid, 5 parts of oyster shell powders, 2 parts of kaolin powder, 5 parts of talcum powder, 3 parts of dolomite rock powders, 2.5 parts take stone flour, 7 parts of deionizations
Water and 7 parts of cetyl trimethylammonium bromides are well mixed, and 35min, washing, suction filtration, in 82 DEG C are stirred in 680r/min rotating speeds
2.5h is dried, room temperature is cooled to, ground 115 mesh sieve obtains material A, 4.5 parts of acrylic acid amides, 5 are then added into material A
Part polyvinyl alcohol, 4 parts of calcium sulfate, 2 parts of magnesium sulfate, 5 parts of ammonium molybdates, 3 parts of Boratexes, 3.5 parts of diammonium hydrogen phosphates and 4 parts of di(2-ethylhexyl)phosphates
Hydrogen ammonium and potassium citrate are well mixed, are warming up to 115 DEG C, are incubated 2.5h, are subsequently added into 3 parts of acetums and are well mixed, in
1800r/min rotating speeds stir 35min, then add well mixed, standing 0.8h, are subsequently added into 5 parts of glutaraldehydes and are well mixed, water
Neutrality is washed till, in 88 DEG C of dry 3.5h, room temperature is cooled to and obtains soil acid-base conditioning agent.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (7)
1. a kind of weeding composite for being used to adjust soil ph, it is characterised in that its raw material includes by weight：Sustained release
20-50 parts of filler, 15-25 parts of soil acid-base conditioning agent, 5-15 parts of silica gel, 2-6 parts of tourmaline powder, 1-5 parts of flyash, sepiolite
3-6 parts of powder, 1-3 parts of n-hexadecyl trimethylamine, 2-5 parts of bromide sixteen alkyls pyridine, 2-6 parts of polymetaphosphate sodium, six methylenes
3-5 parts of urotropine, 4-8 parts of carboxymethyl cellulose, 2-5 parts of na-montmorillonite, 3-6 parts of atrazine, 1-5 parts of metribuzin, Acetochlor
4-6 parts, 3-6 parts of sodium bentonite, 2-5 parts of nicosulfuron, 3-6 parts of neopelex, lauryl sodium sulfate 2-4
Part, 1-4 parts of glycerine, 2-5 parts of butyl acetate, 1-6 parts of potassium dihydrogen phosphate, 4-8 parts of sodium tetraborate.
2. the weeding composite according to claim 1 for being used to adjust soil ph, it is characterised in that Controlled-release filler
Raw material include by weight：15-25 parts of attapulgite, 4-8 parts of hydrochloric acid solution, 3-6 parts of chitosan solution, sodium alginate 2-5
Part, 1-5 parts of disodium hydrogen phosphate, 4-8 parts of calcium nitrate solution, 3-6 parts of 3,5- dihydroxy-benzoic acids, 2-8 parts of octylame.
3. the weeding composite according to claim 1 or 2 for being used to adjust soil ph, it is characterised in that sustained release
Filler is prepared by following technique：Attapulgite is soaked in hydrochloric acid solution, stirred at room temperature, suction filtration, is washed, is dried,
Grinding sieving, is cooled to room temperature and obtains material a；Chitosan solution and sodium alginate are well mixed, hydrochloric acid regulation is then added
PH, is subsequently added into disodium hydrogen phosphate, calcium nitrate solution and 3,5- dihydroxy-benzoic acid and is well mixed, and stirring then heats up, and protects
Temperature, is subsequently added into material a and octylame is well mixed, stirring, and with acetone precipitation, solid filtering, washing are then water-soluble with distilling
Solution, dialyses, and freeze-drying obtains Controlled-release filler.
4. being used for according to claim any one of 1-3 adjusts the weeding composite of soil ph, it is characterised in that
Controlled-release filler is prepared by following technique：Attapulgite is soaked into 10-20min in hydrochloric acid solution, at room temperature in 650-
850r/min rotating speeds stir 20-40min, suction filtration, washing, in 100-110 DEG C of dry 2-4h, ground 180-220 mesh sieves, cooling
Material a is obtained to room temperature；Chitosan solution and sodium alginate are well mixed, salt acid for adjusting pH is then added to 3-4, then adds
Enter disodium hydrogen phosphate, calcium nitrate solution and 3,5- dihydroxy-benzoic acid well mixed, 20- is stirred in 650-850r/min rotating speeds
40min, is then warming up to 25-35 DEG C, is incubated 2-3h, is subsequently added into material a and octylame is well mixed, turn in 450-550r/min
Speed stirring 15-35min, with acetone precipitation, then solid filtering, washing are dissolved with distilled water, and dialysed 2-4d, and freeze-drying is obtained
To Controlled-release filler.
5. being used for according to claim any one of 1-4 adjusts the weeding composite of soil ph, it is characterised in that
The raw material of soil acid-base conditioning agent includes by weight：4-9 parts of pyrolkigneous liquid, 2-5 parts of orange peel, 3-6 parts of mushroom bran, 1-4 parts of humic acid,
2-6 parts of oyster shell powder, 1-5 parts of kaolin powder, 3-6 parts of talcum powder, 2-5 parts of dolomite rock powder, take 1-3 parts of stone flour, deionized water 6-
12 parts, 4-8 parts of cetyl trimethylammonium bromide, 3-5 parts of acrylic acid amides, 4-8 parts of polyvinyl alcohol, 2-5 parts of calcium sulfate, sulfuric acid
2-4 parts of 1-5 parts of magnesium, 3-6 parts of ammonium molybdate, 2-5 parts of Boratex, diammonium hydrogen phosphate and ammonium dihydrogen phosphate, 3-6 parts of potassium citrate, vinegar
1-4 parts of acid solution, 2-6 parts of glutaraldehyde.
6. being used for according to claim any one of 1-5 adjusts the weeding composite of soil ph, it is characterised in that
Soil acid-base conditioning agent is prepared by following technique：By pyrolkigneous liquid, orange peel, mushroom bran, humic acid, oyster shell powder, kaolin powder,
Talcum powder, dolomite rock powder, to take stone flour, deionized water and cetyl trimethylammonium bromide well mixed, stirs, washing, suction filtration,
Dry, be cooled to room temperature, grinding sieving obtains material A, acrylic acid amides, polyvinyl alcohol, sulfuric acid are then added into material A
Calcium, magnesium sulfate, ammonium molybdate, Boratex, diammonium hydrogen phosphate and ammonium dihydrogen phosphate and potassium citrate are well mixed, heat up, and insulation connects
Addition acetum to be well mixed, stirring, then add well mixed, standing, be subsequently added into glutaraldehyde and be well mixed, washing
To neutral, dry, be cooled to room temperature and obtain soil acid-base conditioning agent.
7. being used for according to claim any one of 1-6 adjusts the weeding composite of soil ph, it is characterised in that
Soil acid-base conditioning agent is prepared by following technique：By pyrolkigneous liquid, orange peel, mushroom bran, humic acid, oyster shell powder, kaolin powder,
Talcum powder, dolomite rock powder, to take stone flour, deionized water and cetyl trimethylammonium bromide well mixed, in 650-850r/min
Rotating speed stirs 20-40min, and washing, suction filtration in 80-90 DEG C of dry 1-3h, is cooled to room temperature, ground 110-130 mesh sieves are obtained
Material A, then adds acrylic acid amides, polyvinyl alcohol, calcium sulfate, magnesium sulfate, ammonium molybdate, Boratex, phosphoric acid hydrogen into material A
Two ammoniums and ammonium dihydrogen phosphate and potassium citrate are well mixed, are warming up to 80-120 DEG C, are incubated 2-4h, are subsequently added into acetum and mix
Close uniformly, 20-40min is stirred in 1500-2500r/min rotating speeds, then add and be well mixed, stand 0.5-1.5h, then add
Enter glutaraldehyde to be well mixed, be washed to neutrality, in 85-95 DEG C of dry 2-4h, be cooled to room temperature and obtain soil acid-base conditioning agent.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108208009A (en) * | 2017-12-29 | 2018-06-29 | 定远县润泰化工有限责任公司 | A kind of heat-resisting desinsection composite material of high slow release |
| CN112779019A (en) * | 2021-01-07 | 2021-05-11 | 何雨昕 | Soil conditioner for enhancing stress resistance of crops and preparation method thereof |
| CN114100829A (en) * | 2021-11-17 | 2022-03-01 | 武汉科技大学 | Semi-coke grinding aid and preparation and use methods thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106748032A (en) * | 2016-12-03 | 2017-05-31 | 安徽爱能洁生物科技有限公司 | A kind of Rice Cropping auxotype slow release compound fertilizer high and preparation method thereof |
| CN106883075A (en) * | 2017-04-11 | 2017-06-23 | 赵青娇 | A kind of compound fertilizer of adjustable soil ph |
-
2017
- 2017-07-26 CN CN201710618733.5A patent/CN107245339A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106748032A (en) * | 2016-12-03 | 2017-05-31 | 安徽爱能洁生物科技有限公司 | A kind of Rice Cropping auxotype slow release compound fertilizer high and preparation method thereof |
| CN106883075A (en) * | 2017-04-11 | 2017-06-23 | 赵青娇 | A kind of compound fertilizer of adjustable soil ph |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108208009A (en) * | 2017-12-29 | 2018-06-29 | 定远县润泰化工有限责任公司 | A kind of heat-resisting desinsection composite material of high slow release |
| CN112779019A (en) * | 2021-01-07 | 2021-05-11 | 何雨昕 | Soil conditioner for enhancing stress resistance of crops and preparation method thereof |
| CN114100829A (en) * | 2021-11-17 | 2022-03-01 | 武汉科技大学 | Semi-coke grinding aid and preparation and use methods thereof |
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Application publication date: 20171013 |