CN107216853A - A kind of environment-protecting and non-poisonous adhesive and its preparation technology - Google Patents

A kind of environment-protecting and non-poisonous adhesive and its preparation technology Download PDF

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Publication number
CN107216853A
CN107216853A CN201710640853.5A CN201710640853A CN107216853A CN 107216853 A CN107216853 A CN 107216853A CN 201710640853 A CN201710640853 A CN 201710640853A CN 107216853 A CN107216853 A CN 107216853A
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China
Prior art keywords
parts
chitosan
intermixture
environment
afterwards
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CN201710640853.5A
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Chinese (zh)
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伊婕
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Individual
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Individual
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Priority to CN201710640853.5A priority Critical patent/CN107216853A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J191/00Adhesives based on oils, fats or waxes; Adhesives based on derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a kind of environment-protecting and non-poisonous adhesive and its preparation technology, binder component includes 20 40 parts of emulsifying agent, 5 12 parts of silicic acid, 6 17 parts of high energy refined fish oil, 28 parts of poly- diethanol, 3 10 parts of AEO, 5 15 parts of rosin resin of thickening, 4 10 parts of Aloe Vera Gel, 2 10 parts of chitosan, 38 parts of carbon black, 15 parts of chitosan by weight, preparation technology of the present invention is simple, preparation process is environment friendly and pollution-free, obtained adhesive bonding effect is good, its volatile matter will not pollute surrounding environment, it is used for a long time, it is harmless.

Description

A kind of environment-protecting and non-poisonous adhesive and its preparation technology
Technical field
The present invention relates to adhesive preparing technical field, specially a kind of environment-protecting and non-poisonous adhesive and its preparation technology.
Background technology
In recent years, due to lightweight, the appearance and application of high-strength engineering plastic, and economize on resources, the energy, improve product An urgent demand of quality and processing efficiency, the assemblings of mechanical linkages, processing method are replaced by developed country with bonding technology People accept extensively, and become increasingly popular, and the consumption of adhesive increasingly increases, and the research of the adhesive of early stage is all confined to organic molten Oily molten type based on agent, such as toluene, isopropanol, methanol, butanol, these organic solvents have certain toxicity, tight when using Heavily contaminated environment, deteriorates condition of work, and infringement staff is healthy.
The content of the invention
It is an object of the invention to provide a kind of environment-protecting and non-poisonous adhesive and its preparation technology, to solve above-mentioned background technology The problem of middle proposition.
To achieve the above object, the present invention provides following technical scheme:A kind of environment-protecting and non-poisonous adhesive, binder component is pressed Parts by weight include 20-40 parts of emulsifying agent, 5-12 parts of silicic acid, 6-17 parts of high energy refined fish oil, poly- diethanol 2-8 parts, fatty alcohol 3-10 parts of APEO, 5-15 parts of rosin resin of thickening, 4-10 parts of Aloe Vera Gel, 2-10 parts of chitosan, 3-8 parts of carbon black, shell gather It is sugared 1-5 parts.
It is preferred that, the preferred composition proportion of binder component is:30 parts of emulsifying agent, 9 parts of silicic acid, high energy refined fish oil 12 Part, 5 parts of poly- diethanol, 7 parts of AEO, 10 parts of rosin resin of thickening, 7 parts of Aloe Vera Gel, 6 parts of chitosan, carbon black 5 Part, 3 parts of chitosan.
It is preferred that, preparation technology comprises the following steps:
A, emulsifying agent, silicic acid, high energy refined fish oil, poly- diethanol added in stirred tank after mixing and stirred, in whipping process not It is disconnected to add AEO, thickening rosin resin, intermixture A is obtained after mixing;
B, Aloe Vera Gel and carbon black are sequentially added in intermixture A, low-temperature heat is carried out afterwards, heating-up temperature is 35 DEG C -45 DEG C, plus The hot time is 5min-10min, and room temperature is cooled to afterwards, intermixture B is obtained;
C, addition chitosan and chitosan in intermixture B, are thoroughly mixed, 1h are stood afterwards, that is, is glued afterwards Mixture.
Compared with prior art, the beneficial effects of the invention are as follows:Preparation technology of the present invention is simple, and preparation process environmental protection is without dirt Dye, obtained adhesive bonding effect is good, and its volatile matter will not pollute surrounding environment, is used for a long time, harmless;The present invention In be also added with chitosan and chitosan, it is possible to increase the antibacterial ability of adhesive, long-term preserve is not in rotten, mouldy existing As;In addition, the preparation technology cost that uses of the present invention is low, the activity of adhesive can be effectively raised, and preparation process without Noxious material is produced, and obtained adhesive use occasion is wide, is adapted to widely use.
Embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment Only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, the common skill in this area The every other embodiment that art personnel are obtained under the premise of creative work is not made, belongs to the model that the present invention is protected Enclose.
The present invention provides following technical scheme:A kind of environment-protecting and non-poisonous adhesive, binder component includes breast by weight 20-40 parts of agent, 5-12 parts of silicic acid, 6-17 parts of high energy refined fish oil, poly- diethanol 2-8 parts, AEO 3-10 Part, 5-15 parts of rosin resin of thickening, 4-10 parts of Aloe Vera Gel, 2-10 parts of chitosan, 3-8 parts of carbon black, 1-5 parts of chitosan.
Embodiment one:
Binder component includes 20 parts of emulsifying agent, 5 parts of silicic acid, 6 parts of high energy refined fish oil, 2 parts of poly- diethanol, fat by weight 3 parts of fat alcohol APEO, 5 parts of rosin resin of thickening, 4 parts of Aloe Vera Gel, 2 parts of chitosan, 3 parts of carbon black, 1 part of chitosan.
The preparation technology of the present embodiment comprises the following steps:
A, emulsifying agent, silicic acid, high energy refined fish oil, poly- diethanol added in stirred tank after mixing and stirred, in whipping process not It is disconnected to add AEO, thickening rosin resin, intermixture A is obtained after mixing;
B, Aloe Vera Gel and carbon black are sequentially added in intermixture A, low-temperature heat is carried out afterwards, heating-up temperature is 35 DEG C, during heating Between be 5min, room temperature is cooled to afterwards, intermixture B is obtained;
C, addition chitosan and chitosan in intermixture B, are thoroughly mixed, 1h are stood afterwards, that is, is glued afterwards Mixture.
Embodiment two:
Binder component by weight include 40 parts of emulsifying agent, 12 parts of silicic acid, 17 parts of high energy refined fish oil, 8 parts of poly- diethanol, 10 parts of AEO, 15 parts of rosin resin of thickening, 10 parts of Aloe Vera Gel, 10 parts of chitosan, 8 parts of carbon black, chitosan 5 Part.
The preparation technology of the present embodiment comprises the following steps:
A, emulsifying agent, silicic acid, high energy refined fish oil, poly- diethanol added in stirred tank after mixing and stirred, in whipping process not It is disconnected to add AEO, thickening rosin resin, intermixture A is obtained after mixing;
B, Aloe Vera Gel and carbon black are sequentially added in intermixture A, low-temperature heat is carried out afterwards, heating-up temperature is 45 DEG C, during heating Between be 10min, room temperature is cooled to afterwards, intermixture B is obtained;
C, addition chitosan and chitosan in intermixture B, are thoroughly mixed, 1h are stood afterwards, that is, is glued afterwards Mixture.
Embodiment three:
Binder component includes 25 parts of emulsifying agent, 7 parts of silicic acid, 7 parts of high energy refined fish oil, 3 parts of poly- diethanol, fat by weight 4 parts of fat alcohol APEO, 6 parts of rosin resin of thickening, 5 parts of Aloe Vera Gel, 3 parts of chitosan, 3 parts of carbon black, 2 parts of chitosan.
The preparation technology of the present embodiment comprises the following steps:
A, emulsifying agent, silicic acid, high energy refined fish oil, poly- diethanol added in stirred tank after mixing and stirred, in whipping process not It is disconnected to add AEO, thickening rosin resin, intermixture A is obtained after mixing;
B, Aloe Vera Gel and carbon black are sequentially added in intermixture A, low-temperature heat is carried out afterwards, heating-up temperature is 37 DEG C, during heating Between be 6min, room temperature is cooled to afterwards, intermixture B is obtained;
C, addition chitosan and chitosan in intermixture B, are thoroughly mixed, 1h are stood afterwards, that is, is glued afterwards Mixture.
Example IV:
Binder component by weight include 35 parts of emulsifying agent, 11 parts of silicic acid, 15 parts of high energy refined fish oil, 7 parts of poly- diethanol, 9 parts of AEO, 13 parts of rosin resin of thickening, 9 parts of Aloe Vera Gel, 9 parts of chitosan, 7 parts of carbon black, 4 parts of chitosan.
The preparation technology of the present embodiment comprises the following steps:
A, emulsifying agent, silicic acid, high energy refined fish oil, poly- diethanol added in stirred tank after mixing and stirred, in whipping process not It is disconnected to add AEO, thickening rosin resin, intermixture A is obtained after mixing;
B, Aloe Vera Gel and carbon black are sequentially added in intermixture A, low-temperature heat is carried out afterwards, heating-up temperature is 42 DEG C, during heating Between be 9min, room temperature is cooled to afterwards, intermixture B is obtained;
C, addition chitosan and chitosan in intermixture B, are thoroughly mixed, 1h are stood afterwards, that is, is glued afterwards Mixture.
Embodiment five:
Binder component by weight include 26 parts of emulsifying agent, 8 parts of silicic acid, 15 parts of high energy refined fish oil, 7 parts of poly- diethanol, 8 parts of AEO, 12 parts of rosin resin of thickening, 5 parts of Aloe Vera Gel, 8 parts of chitosan, 7 parts of carbon black, 4 parts of chitosan.
The preparation technology of the present embodiment comprises the following steps:
A, emulsifying agent, silicic acid, high energy refined fish oil, poly- diethanol added in stirred tank after mixing and stirred, in whipping process not It is disconnected to add AEO, thickening rosin resin, intermixture A is obtained after mixing;
B, Aloe Vera Gel and carbon black are sequentially added in intermixture A, low-temperature heat is carried out afterwards, heating-up temperature is 42 DEG C, during heating Between be 8min, room temperature is cooled to afterwards, intermixture B is obtained;
C, addition chitosan and chitosan in intermixture B, are thoroughly mixed, 1h are stood afterwards, that is, is glued afterwards Mixture.
Embodiment six:
Binder component by weight include 30 parts of emulsifying agent, 9 parts of silicic acid, 12 parts of high energy refined fish oil, 5 parts of poly- diethanol, 7 parts of AEO, 10 parts of rosin resin of thickening, 7 parts of Aloe Vera Gel, 6 parts of chitosan, 5 parts of carbon black, 3 parts of chitosan.
The preparation technology of the present embodiment comprises the following steps:
A, emulsifying agent, silicic acid, high energy refined fish oil, poly- diethanol added in stirred tank after mixing and stirred, in whipping process not It is disconnected to add AEO, thickening rosin resin, intermixture A is obtained after mixing;
B, Aloe Vera Gel and carbon black are sequentially added in intermixture A, low-temperature heat is carried out afterwards, heating-up temperature is 40 DEG C, during heating Between be 8min, room temperature is cooled to afterwards, intermixture B is obtained;
C, addition chitosan and chitosan in intermixture B, are thoroughly mixed, 1h are stood afterwards, that is, is glued afterwards Mixture.
Preparation technology of the present invention is simple, and preparation process is environment friendly and pollution-free, and obtained adhesive bonding effect is good, its volatile matter Surrounding environment will not be polluted, is used for a long time, it is harmless;Chitosan and chitosan are also added with the present invention, it is possible to increase The antibacterial ability of adhesive, long-term preserve is not in rotten, Signs of Mould, is obtained by experiment, is glued for a long time using traditional Mixture, can produce influence, people is chronically in the environment to surrounding environment and human body, uncomfortable in chest, vomiting phenomenon easily occur, and adopt With the present invention adhesive, while possessing nontoxic effect, additionally it is possible to extend the holding time of product;In addition, of the invention The preparation technology cost of use is low, using the preparation order for first stirring, heating, being stirred for afterwards, can effectively raise bonding The activity of agent, and preparation process, without noxious material generation, obtained adhesive use occasion is wide, is adapted to widely use.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (3)

1. a kind of environment-protecting and non-poisonous adhesive, it is characterised in that:Binder component includes 20-40 parts of emulsifying agent, silicon by weight Sour 5-12 parts, 6-17 parts of high energy refined fish oil, poly- diethanol 2-8 parts, 3-10 parts of AEO, thickening rosin resin 5-15 parts, 4-10 parts of Aloe Vera Gel, 2-10 parts of chitosan, 3-8 parts of carbon black, 1-5 parts of chitosan.
2. a kind of environment-protecting and non-poisonous adhesive according to claim 1, it is characterised in that:The preferred composition of binder component is matched somebody with somebody Than for:30 parts of emulsifying agent, 9 parts of silicic acid, 12 parts of high energy refined fish oil, 5 parts of poly- diethanol, 7 parts of AEO, thickening 10 parts of rosin resin, 7 parts of Aloe Vera Gel, 6 parts of chitosan, 5 parts of carbon black, 3 parts of chitosan.
3. realize a kind of preparation technology of environment-protecting and non-poisonous adhesive described in claim 1, it is characterised in that:Preparation technology includes Following steps:
A, emulsifying agent, silicic acid, high energy refined fish oil, poly- diethanol added in stirred tank after mixing and stirred, in whipping process not It is disconnected to add AEO, thickening rosin resin, intermixture A is obtained after mixing;
B, Aloe Vera Gel and carbon black are sequentially added in intermixture A, low-temperature heat is carried out afterwards, heating-up temperature is 35 DEG C -45 DEG C, plus The hot time is 5min-10min, and room temperature is cooled to afterwards, intermixture B is obtained;
C, addition chitosan and chitosan in intermixture B, are thoroughly mixed, 1h are stood afterwards, that is, is glued afterwards Mixture.
CN201710640853.5A 2017-07-31 2017-07-31 A kind of environment-protecting and non-poisonous adhesive and its preparation technology Pending CN107216853A (en)

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CN201710640853.5A CN107216853A (en) 2017-07-31 2017-07-31 A kind of environment-protecting and non-poisonous adhesive and its preparation technology

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Application Number Priority Date Filing Date Title
CN201710640853.5A CN107216853A (en) 2017-07-31 2017-07-31 A kind of environment-protecting and non-poisonous adhesive and its preparation technology

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108582904A (en) * 2018-03-16 2018-09-28 中塑新材料科技(杭州)有限公司 A kind of uvioresistant Obstruct membrane and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105111978A (en) * 2015-09-24 2015-12-02 天津市利顺达粘合剂有限公司 Environment-friendly nontoxic water-soluble adhesive
CN105400452A (en) * 2016-01-07 2016-03-16 郭敏 Environment-friendly binder

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105111978A (en) * 2015-09-24 2015-12-02 天津市利顺达粘合剂有限公司 Environment-friendly nontoxic water-soluble adhesive
CN105400452A (en) * 2016-01-07 2016-03-16 郭敏 Environment-friendly binder

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108582904A (en) * 2018-03-16 2018-09-28 中塑新材料科技(杭州)有限公司 A kind of uvioresistant Obstruct membrane and preparation method thereof
CN108582904B (en) * 2018-03-16 2020-12-11 中塑新材料科技(杭州)有限公司 Anti-ultraviolet barrier film and preparation method thereof

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Application publication date: 20170929