CN116535895A - Preparation method of environment-friendly non-mineral printing green ink - Google Patents
Preparation method of environment-friendly non-mineral printing green ink Download PDFInfo
- Publication number
- CN116535895A CN116535895A CN202310642588.XA CN202310642588A CN116535895A CN 116535895 A CN116535895 A CN 116535895A CN 202310642588 A CN202310642588 A CN 202310642588A CN 116535895 A CN116535895 A CN 116535895A
- Authority
- CN
- China
- Prior art keywords
- environment
- friendly
- ink
- steps
- mineral
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000007639 printing Methods 0.000 title claims abstract description 37
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 26
- 239000011707 mineral Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- 241000209140 Triticum Species 0.000 claims abstract description 28
- 235000021307 Triticum Nutrition 0.000 claims abstract description 28
- 239000010902 straw Substances 0.000 claims abstract description 28
- 238000002156 mixing Methods 0.000 claims abstract description 26
- 239000000025 natural resin Substances 0.000 claims abstract description 24
- 239000000463 material Substances 0.000 claims abstract description 16
- 235000011293 Brassica napus Nutrition 0.000 claims abstract description 13
- 240000002791 Brassica napus Species 0.000 claims abstract description 13
- 238000002485 combustion reaction Methods 0.000 claims abstract description 12
- 239000002131 composite material Substances 0.000 claims abstract description 12
- 239000010685 fatty oil Substances 0.000 claims abstract description 12
- 239000004519 grease Substances 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 12
- 239000000843 powder Substances 0.000 claims abstract description 12
- 244000188595 Brassica sinapistrum Species 0.000 claims abstract description 11
- 235000004977 Brassica sinapistrum Nutrition 0.000 claims abstract description 11
- 239000000839 emulsion Substances 0.000 claims abstract description 11
- 229920000747 poly(lactic acid) Polymers 0.000 claims abstract description 11
- 239000004626 polylactic acid Substances 0.000 claims abstract description 11
- 238000003756 stirring Methods 0.000 claims abstract description 11
- 239000003086 colorant Substances 0.000 claims abstract description 8
- 239000000126 substance Substances 0.000 claims abstract description 7
- 238000001035 drying Methods 0.000 claims abstract description 6
- 238000000227 grinding Methods 0.000 claims abstract description 6
- 238000010438 heat treatment Methods 0.000 claims abstract description 6
- 239000000049 pigment Substances 0.000 claims description 35
- 239000003381 stabilizer Substances 0.000 claims description 23
- 239000000853 adhesive Substances 0.000 claims description 20
- 230000001070 adhesive effect Effects 0.000 claims description 20
- 239000002562 thickening agent Substances 0.000 claims description 20
- 239000002274 desiccant Substances 0.000 claims description 15
- 241000196324 Embryophyta Species 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000011347 resin Substances 0.000 claims description 10
- 229920005989 resin Polymers 0.000 claims description 10
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 5
- 241001071795 Gentiana Species 0.000 claims description 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 5
- 239000000679 carrageenan Substances 0.000 claims description 5
- 229940113118 carrageenan Drugs 0.000 claims description 5
- 235000010418 carrageenan Nutrition 0.000 claims description 5
- 229920001525 carrageenan Polymers 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000003995 emulsifying agent Substances 0.000 claims description 5
- 230000001804 emulsifying effect Effects 0.000 claims description 5
- 230000001376 precipitating effect Effects 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 235000012239 silicon dioxide Nutrition 0.000 claims description 5
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 5
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical group [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- 239000004410 anthocyanin Substances 0.000 claims description 3
- 229930002877 anthocyanin Natural products 0.000 claims description 3
- 235000010208 anthocyanin Nutrition 0.000 claims description 3
- 150000004636 anthocyanins Chemical group 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 229930002875 chlorophyll Natural products 0.000 claims description 3
- 235000019804 chlorophyll Nutrition 0.000 claims description 3
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 claims description 3
- 238000004064 recycling Methods 0.000 abstract description 6
- 239000002028 Biomass Substances 0.000 abstract description 3
- 238000004134 energy conservation Methods 0.000 abstract description 3
- 239000003337 fertilizer Substances 0.000 abstract description 3
- 230000009467 reduction Effects 0.000 abstract description 3
- 239000002699 waste material Substances 0.000 abstract description 3
- 239000006227 byproduct Substances 0.000 abstract 1
- 239000000446 fuel Substances 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 43
- 239000002551 biofuel Substances 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 239000003209 petroleum derivative Substances 0.000 description 2
- 238000000053 physical method Methods 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- AOJJSUZBOXZQNB-VTZDEGQISA-N 4'-epidoxorubicin Chemical group O([C@H]1C[C@@](O)(CC=2C(O)=C3C(=O)C=4C=CC=C(C=4C(=O)C3=C(O)C=21)OC)C(=O)CO)[C@H]1C[C@H](N)[C@@H](O)[C@H](C)O1 AOJJSUZBOXZQNB-VTZDEGQISA-N 0.000 description 1
- 208000012902 Nervous system disease Diseases 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 208000019423 liver disease Diseases 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/08—Printing inks based on natural resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a preparation method of green ink for environment-friendly non-mineral printing, which comprises the steps of preparing shells, rapeseeds, wheat straws, semitransparent polylactic acid, natural resin and aqueous emulsion with required colors, respectively crushing, grinding the shells, the rapeseeds and the wheat straws, carrying out nano treatment after the treatment, and then drying in the sun for later use; extracting fatty oil from the rapeseed powder by a physical or chemical method, delivering wheat straw to an electric power plant for combustion, collecting the ash after combustion, adding the ground shell powder and ash into the fatty oil, and uniformly mixing through a fluidized bed column to obtain composite grease; adding the composite grease into natural resin, heating and stirring; the printing ink material can be completely separated out and precipitated to obtain pure biomass and extract, and the byproducts can be used as new materials, biological fuels and agricultural fertilizers, so that the heavy-duty recycling of wastes can be realized, and the functions of renewable energy source utilization, energy conservation and emission reduction are realized.
Description
Technical Field
The invention belongs to the technical field of green ink, and particularly relates to a preparation method of green ink for environment-friendly non-mineral printing.
Background
The existing printing ink generally uses mineral oil as a main component, and the compounds are not easy to degrade and difficult to decompose and remove, so that the long-term deposition in the land or water can pollute the environment, and the cost of environmental protection treatment is increased.
Mineral-containing printing inks generally contain harmful substances such as volatile organic compounds and heavy metals, which may affect human health and induce diseases such as nervous system diseases, liver diseases, skin diseases, etc.
The existing mineral-containing ink needs to consume larger energy and funds in the manufacturing process, is unfavorable for the regeneration and recycling of resources, and is difficult to realize the sustainable development of an ecological system.
In view of the above, the existing mineral-containing printing ink has some defects and shortcomings in environmental protection, human health, safe production, quality of printed matter and the like, and needs to be improved and replaced as soon as possible.
Disclosure of Invention
The invention aims to provide a preparation method of green ink for environment-friendly non-mineral printing, which aims to solve the problems in the background technology.
In order to achieve the above purpose, the present invention provides the following technical solutions: the preparation method of the green ink for environment-friendly non-mineral printing comprises the following materials in parts by weight: 10-20 parts of shell, 10-20 parts of rapeseed, 10-20 parts of wheat straw, 10-20 parts of semitransparent polylactic acid, 5-10 parts of natural resin and 5-10 parts of aqueous emulsion;
the preparation method comprises the following specific preparation steps:
step one: material preparation: preparing shells, rapeseeds, wheat straws, semitransparent polylactic acid, natural resin and aqueous emulsion with required colors, respectively crushing, grinding the shells, the rapeseeds and the wheat straws, carrying out nano treatment after the treatment, and then drying in the sun for later use;
step two: pigment is prepared by the following steps: extracting fatty oil from the rapeseed powder by a physical or chemical method, delivering wheat straw to an electric power plant for combustion, collecting the ash after combustion, adding the ground shell powder and ash into the fatty oil, and uniformly mixing through a fluidized bed column to obtain composite grease;
step three: and (3) processing and modulating: adding the composite grease into natural resin, heating and stirring, adding an emulsifying agent for mixing, emulsifying and precipitating to obtain pigment;
step four: mixing the obtained pigment with a viscous agent and an adhesive, and then adding a drying agent and a color stabilizer to obtain printing ink;
step five: adding the ink into baking equipment, baking at 150-200deg.C, and homogenizing the consistency of the ink to obtain environment-friendly non-mineral green ink;
step six: pouring the prepared ink into an air-tight container, and placing the container in a dry and shady place at the temperature of 20-30 ℃ to avoid direct sunlight and high-temperature environment and ensure stable quality of the ink.
Further, the natural resin is rosin resin or gentian resin.
Further, the working temperature during the crushing of the shells, the rapes and the wheat straw in the step one is lower than 80 ℃.
Further, the operation temperature of the fluidized bed column in the second step is controlled within the range of 60-80 ℃.
Further, the stirring and mixing in the third and fourth steps are performed by an electrothermal mixer, and the temperature during the mixing is maintained within a range of 40-60 ℃.
Further, the thickener is an environment-friendly plant thickener, the plant thickener is carrageenan, and the usage amount of the thickener is 0.5% -3% of the total amount of the pigment.
Further, the adhesive is an environment-friendly adhesive, the environment-friendly adhesive is natural fatty acid or calcium carbonate, and the usage amount of the adhesive is 2% -5% of the total amount of the pigment.
Further, the drying agent is an environment-friendly dryer, the environment-friendly dryer is silicon dioxide, and the usage amount of the drying agent is 2% -5% of the total amount of the pigment.
Further, the color stabilizer is an environment-friendly color stabilizer, the environment-friendly color stabilizer is anthocyanin, chlorophyll or theafat, and the usage amount of the color stabilizer is 1% -3% of the total amount of the pigment.
Compared with the prior art, the invention has the beneficial effects that: the environment-friendly printing ink disclosed by the invention is strong in environment friendliness, does not contain harmful substances, replaces a traditional petroleum product, can reduce pollution and ecological damage to the environment, is a sustainable green choice, can show rich colors by utilizing natural resin, is not weaker than the traditional printing ink in perfect degree of record, can be widely applied to the fields of publishing, printing, packaging and the like, can play a role in enhancing the durability and stability of the printing ink, can fully separate out and precipitate pure biomass and extract after being used as a printing ink material, can be used as a new material, a biofuel and an agricultural fertilizer, can realize the heavy-duty recycling of wastes, and can realize the functions of recycling renewable energy sources and energy conservation and emission reduction.
Detailed Description
The technical solutions of the embodiments of the present invention will be clearly and completely described below in conjunction with the embodiments of the present invention, and it is apparent that the described embodiments are only some embodiments of the present invention, not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
Example 1
The preparation method of the green ink for environment-friendly non-mineral printing comprises the following materials in parts by weight: 10 parts of shell, 10 parts of rapeseed, 10 parts of wheat straw, 10 parts of semitransparent polylactic acid, 5 parts of natural resin and 5 parts of aqueous emulsion;
the preparation method comprises the following specific preparation steps:
step one: material preparation: preparing shells, rapeseeds, wheat straws, semitransparent polylactic acid, natural resin and aqueous emulsion with required colors, respectively crushing, grinding the shells, the rapeseeds and the wheat straws, carrying out nano treatment after the treatment, and then drying in the sun for later use;
step two: pigment is prepared by the following steps: extracting fatty oil from rapeseed powder by a physical method, delivering wheat straw to an electric power plant for combustion, collecting ash after combustion, adding the ground shell powder and ash into the fatty oil, and uniformly mixing through a fluidized bed column to obtain composite grease;
step three: and (3) processing and modulating: adding the composite grease into natural resin, heating and stirring, adding an emulsifying agent for mixing, emulsifying and precipitating to obtain pigment;
step four: mixing the obtained pigment with a viscous agent and an adhesive, and then adding a drying agent and a color stabilizer to obtain printing ink;
step five: adding the ink into baking equipment, baking at 150 ℃ to obtain environment-friendly non-mineral green ink, wherein the consistency of the ink is uniform;
step six: pouring the prepared ink into an air-tight container, and placing the container at a dry and cool place within the temperature range of 20 ℃ to avoid direct sunlight and high-temperature environment and ensure stable quality of the ink.
Wherein the natural resin is rosin resin or gentian resin.
Further, the working temperature during the crushing of the shells, the rapes and the wheat straw in the step one is lower than 80 ℃.
Wherein, the operation temperature of the fluidized bed column in the second step is controlled within the range of 60 ℃.
Wherein the stirring and mixing in the third and fourth steps are performed by an electrothermal mixer, and the temperature during mixing is maintained within a range of 40 ℃.
Wherein the thickening agent is an environment-friendly plant thickening agent, the plant thickening agent is carrageenan, and the use amount of the thickening agent is 0.5% of the total amount of the pigment.
The adhesive is environment-friendly, the environment-friendly adhesive is natural fatty acid, and the usage amount of the adhesive is 2% of the total amount of the pigment.
And the drying agent is an environment-friendly dryer, the environment-friendly dryer is silicon dioxide, and the usage amount of the drying agent is 2% of the total amount of the pigment.
The color stabilizer is an environment-friendly color stabilizer, the environment-friendly color stabilizer is anthocyanin, and the use amount of the color stabilizer is 1% of the total amount of pigment.
Example 2
The preparation method of the green ink for environment-friendly non-mineral printing comprises the following materials in parts by weight: 15 parts of shell, 15 parts of rapeseed, 15 parts of wheat straw, 15 parts of semitransparent polylactic acid, 8 parts of natural resin and 7 parts of aqueous emulsion;
the preparation method comprises the following specific preparation steps:
step one: material preparation: preparing shells, rapeseeds, wheat straws, semitransparent polylactic acid, natural resin and aqueous emulsion with required colors, respectively crushing, grinding the shells, the rapeseeds and the wheat straws, carrying out nano treatment after the treatment, and then drying in the sun for later use;
step two: pigment is prepared by the following steps: extracting fatty oil from rapeseed powder by a chemical method, delivering wheat straw to an electric power plant for combustion, collecting ash after combustion, adding the ground shell powder and ash into the fatty oil, and uniformly mixing through a fluidized bed column to obtain composite grease;
step three: and (3) processing and modulating: adding the composite grease into natural resin, heating and stirring, adding an emulsifying agent for mixing, emulsifying and precipitating to obtain pigment;
step four: mixing the obtained pigment with a viscous agent and an adhesive, and then adding a drying agent and a color stabilizer to obtain printing ink;
step five: adding the ink into baking equipment, baking at 170 ℃ to obtain environment-friendly non-mineral green ink, wherein the consistency of the ink is uniform;
step six: pouring the prepared ink into an air sealing container, and placing the container in a dry and cool place within the temperature range of 25 ℃ to avoid direct sunlight and high-temperature environment and ensure stable quality of the ink.
Wherein the natural resin is rosin resin or gentian resin.
Further, the working temperature during the crushing of the shells, the rapes and the wheat straw in the step one is lower than 80 ℃.
Wherein, the operation temperature of the fluidized bed column in the second step is controlled within the range of 70 ℃.
Wherein the stirring and mixing in the third and fourth steps are performed by an electrothermal mixer, and the temperature during mixing is maintained within 50 ℃.
Wherein the thickening agent is an environment-friendly plant thickening agent, the plant thickening agent is carrageenan, and the use amount of the thickening agent is 1% of the total amount of the pigment.
The adhesive is environment-friendly, the environment-friendly adhesive is natural fatty acid, and the usage amount of the adhesive is 3% of the total amount of the pigment.
And the drying agent is an environment-friendly dryer, the environment-friendly dryer is silicon dioxide, and the usage amount of the drying agent is 3% of the total amount of the pigment.
The color stabilizer is environment-friendly, chlorophyll and the usage amount of the color stabilizer is 2% of the total amount of the pigment.
Example 3
The preparation method of the green ink for environment-friendly non-mineral printing comprises the following materials in parts by weight: 20 parts of shell, 20 parts of rapeseed, 20 parts of wheat straw, 20 parts of semitransparent polylactic acid, 10 parts of natural resin and 10 parts of aqueous emulsion;
the preparation method comprises the following specific preparation steps:
step one: material preparation: preparing shells, rapeseeds, wheat straws, semitransparent polylactic acid, natural resin and aqueous emulsion with required colors, respectively crushing, grinding the shells, the rapeseeds and the wheat straws, carrying out nano treatment after the treatment, and then drying in the sun for later use;
step two: pigment is prepared by the following steps: extracting fatty oil from rapeseed powder by a physical method, delivering wheat straw to an electric power plant for combustion, collecting ash after combustion, adding the ground shell powder and ash into the fatty oil, and uniformly mixing through a fluidized bed column to obtain composite grease;
step three: and (3) processing and modulating: adding the composite grease into natural resin, heating and stirring, adding an emulsifying agent for mixing, emulsifying and precipitating to obtain pigment;
step four: mixing the obtained pigment with a viscous agent and an adhesive, and then adding a drying agent and a color stabilizer to obtain printing ink;
step five: adding the ink into baking equipment, baking at 200 ℃, and obtaining environment-friendly non-mineral green ink;
step six: pouring the prepared ink into an air sealing container, and placing the container at a dry and cool place within the temperature range of 30 ℃ to avoid direct sunlight and high-temperature environment and ensure stable quality of the ink.
Wherein the natural resin is rosin resin or gentian resin.
Further, the working temperature during the crushing of the shells, the rapes and the wheat straw in the step one is lower than 80 ℃.
Wherein, the operation temperature of the fluidized bed column in the second step is controlled within the range of 80 ℃.
Wherein the stirring and mixing in the third and fourth steps are performed by an electrothermal mixer, and the temperature during mixing is maintained within a range of 60 ℃.
Wherein the thickening agent is an environment-friendly plant thickening agent, the plant thickening agent is carrageenan, and the use amount of the thickening agent is 3% of the total amount of the pigment.
The adhesive is environment-friendly, the environment-friendly adhesive is calcium carbonate, and the usage amount of the adhesive is 5% of the total amount of the pigment.
And the drying agent is an environment-friendly dryer, the environment-friendly dryer is silicon dioxide, and the usage amount of the drying agent is 5% of the total amount of the pigment.
The color stabilizer is an environment-friendly color stabilizer, the environment-friendly color stabilizer is thealipoxin, and the usage amount of the color stabilizer is 3% of the total amount of the pigment.
The working principle and the using flow of the invention are as follows: the environment-friendly printing ink disclosed by the invention is strong in environment friendliness, does not contain harmful substances, replaces a traditional petroleum product, can reduce pollution and ecological damage to the environment, is a sustainable green choice, can show rich colors by utilizing natural resin, is not weaker than the traditional printing ink in perfect degree of record, can be widely applied to the fields of publishing, printing, packaging and the like, can play a role in enhancing the durability and stability of the printing ink, can fully separate out and precipitate pure biomass and extract after being used as a printing ink material, can be used as a new material, a biofuel and an agricultural fertilizer, can realize the heavy-duty recycling of wastes, and can realize the functions of recycling renewable energy sources and energy conservation and emission reduction.
Although embodiments of the present invention have been shown and described, it will be understood by those skilled in the art that various changes, modifications, substitutions and alterations can be made therein without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (9)
1. The preparation method of the green ink for environment-friendly non-mineral printing is characterized by comprising the following materials in parts by weight: 10-20 parts of shell, 10-20 parts of rapeseed, 10-20 parts of wheat straw, 10-20 parts of semitransparent polylactic acid, 5-10 parts of natural resin and 5-10 parts of aqueous emulsion;
the preparation method comprises the following specific preparation steps:
step one: material preparation: preparing shells, rapeseeds, wheat straws, semitransparent polylactic acid, natural resin and aqueous emulsion with required colors, respectively crushing, grinding the shells, the rapeseeds and the wheat straws, carrying out nano treatment after the treatment, and then drying in the sun for later use;
step two: pigment is prepared by the following steps: extracting fatty oil from the rapeseed powder by a physical or chemical method, delivering wheat straw to an electric power plant for combustion, collecting the ash after combustion, adding the ground shell powder and ash into the fatty oil, and uniformly mixing through a fluidized bed column to obtain composite grease;
step three: and (3) processing and modulating: adding the composite grease into natural resin, heating and stirring, adding an emulsifying agent for mixing, emulsifying and precipitating to obtain pigment;
step four: mixing the obtained pigment with a viscous agent and an adhesive, and then adding a drying agent and a color stabilizer to obtain printing ink;
step five: adding the ink into baking equipment, baking at 150-200deg.C, and homogenizing the consistency of the ink to obtain environment-friendly non-mineral green ink;
step six: pouring the prepared ink into an air-tight container, and placing the container in a dry and shady place at the temperature of 20-30 ℃ to avoid direct sunlight and high-temperature environment and ensure stable quality of the ink.
2. The method for preparing the green ink for environment-friendly non-mineral printing, which is characterized by comprising the following steps of: the natural resin is rosin resin or gentian resin.
3. The method for preparing the green ink for environment-friendly non-mineral printing, which is characterized by comprising the following steps of: the working temperature during the crushing of the shells, the rapeseeds and the wheat straw in the step one is lower than 80 ℃.
4. The method for preparing the green ink for environment-friendly non-mineral printing, which is characterized by comprising the following steps of: and in the second step, the operation temperature of the fluidized bed column is controlled within the range of 60-80 ℃.
5. The method for preparing the green ink for environment-friendly non-mineral printing, which is characterized by comprising the following steps of: the stirring and mixing in the third step and the fourth step are completed by an electrothermal mixer, and the temperature during mixing is kept in the range of 40-60 ℃.
6. The method for preparing the green ink for environment-friendly non-mineral printing, which is characterized by comprising the following steps of: the thickening agent is an environment-friendly plant thickening agent, the plant thickening agent is carrageenan, and the use amount of the thickening agent is 0.5% -3% of the total amount of the pigment.
7. The method for preparing the green ink for environment-friendly non-mineral printing, which is characterized by comprising the following steps of: the adhesive is environment-friendly, and is natural fatty acid or calcium carbonate, and the usage amount of the adhesive is 2% -5% of the total amount of the pigment.
8. The method for preparing the green ink for environment-friendly non-mineral printing, which is characterized by comprising the following steps of: the drying agent is an environment-friendly dryer, the environment-friendly dryer is silicon dioxide, and the usage amount of the drying agent is 2% -5% of the total amount of the pigment.
9. The method for preparing the green ink for environment-friendly non-mineral printing, which is characterized by comprising the following steps of: the color stabilizer is an environment-friendly color stabilizer, the environment-friendly color stabilizer is anthocyanin, chlorophyll or thealipoprotein, and the use amount of the color stabilizer is 1% -3% of the total amount of the pigment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310642588.XA CN116535895A (en) | 2023-06-01 | 2023-06-01 | Preparation method of environment-friendly non-mineral printing green ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310642588.XA CN116535895A (en) | 2023-06-01 | 2023-06-01 | Preparation method of environment-friendly non-mineral printing green ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN116535895A true CN116535895A (en) | 2023-08-04 |
Family
ID=87450724
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202310642588.XA Pending CN116535895A (en) | 2023-06-01 | 2023-06-01 | Preparation method of environment-friendly non-mineral printing green ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN116535895A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105038377A (en) * | 2015-07-30 | 2015-11-11 | 安徽省中彩印务有限公司 | Environment-friendly printing ink for printing, and preparation process thereof |
| CN107793832A (en) * | 2017-11-24 | 2018-03-13 | 天长市天翔包装有限公司 | A kind of degradable offset ink |
| CN110204956A (en) * | 2019-07-15 | 2019-09-06 | 深圳市裕同包装科技股份有限公司 | A kind of biodegradable green printing ink binder, ink and preparation method thereof |
| CN111334116A (en) * | 2020-03-31 | 2020-06-26 | 吴永淇 | Environment-friendly printing ink |
-
2023
- 2023-06-01 CN CN202310642588.XA patent/CN116535895A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105038377A (en) * | 2015-07-30 | 2015-11-11 | 安徽省中彩印务有限公司 | Environment-friendly printing ink for printing, and preparation process thereof |
| CN107793832A (en) * | 2017-11-24 | 2018-03-13 | 天长市天翔包装有限公司 | A kind of degradable offset ink |
| CN110204956A (en) * | 2019-07-15 | 2019-09-06 | 深圳市裕同包装科技股份有限公司 | A kind of biodegradable green printing ink binder, ink and preparation method thereof |
| CN111334116A (en) * | 2020-03-31 | 2020-06-26 | 吴永淇 | Environment-friendly printing ink |
Non-Patent Citations (1)
| Title |
|---|
| 纪立芳: "《江南建筑彩画研究》", 中国轻工业出版社, pages: 107 - 88 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101585723B (en) | Method for preparing seaweed biological long-acting fertilizer | |
| CN104072313A (en) | Organic fertilizer for forestry greening and preparation method thereof | |
| CN103396858B (en) | Production technology of novel biomass fuel | |
| CN104724694A (en) | Preparation method of rice straw biochar | |
| CN104593116B (en) | Method for preparing solid formed fuel from biomass liquefaction residues | |
| CN104694201A (en) | New biomass energy granules and preparation method thereof | |
| CN103626605A (en) | Special rapeseed fertilizer and preparation method thereof | |
| CN104151016B (en) | A kind of efficiently growth promoting green compound organic and inorganic fertilizer | |
| CN106244278B (en) | The method for preparing biomass fuel as primary raw material using fresh chicken manure | |
| CN104760945A (en) | Preparation method of wheat straw charcoal | |
| CN106047384A (en) | Method for preparing hydrothermal biological carbon with traditional Chinese medicine residues and application thereof | |
| CN103553790A (en) | Multi-nutrition seedling fermentation fertilizer and preparation method thereof | |
| CN104724695A (en) | Preparation method of bamboo biochar | |
| CN102910943B (en) | Method for preparing biological organic fertilizer by utilizing biodegradation of domestic wastes | |
| CN106244283A (en) | A kind of sawdust based biomass granule of NEW TYPE OF COMPOSITE cattle manure and preparation method thereof | |
| CN116535895A (en) | Preparation method of environment-friendly non-mineral printing green ink | |
| CN103332988B (en) | Non-mineral source humic acid water-soluble liquid fertilizer and preparation method thereof | |
| CN105710107B (en) | The method and system of Compositions of Bamboo Shoot Shell high value comprehensive utilization | |
| CN107217521B (en) | A kind of low ink paper sludge and preparation method thereof | |
| CN106244279A (en) | The method preparing biomass fuel for primary raw material with fresh cattle manure | |
| CN106590798A (en) | Preparation method of ash- free high calorific value biomass fuel | |
| CN104230594A (en) | Traditional Chinese medicine residue fermentation fertilizer and preparation method thereof | |
| CN103709125B (en) | The method of the biological plasticizer epoxy aliphatic acid methyl ester of kitchen castoff oil and fat preparation | |
| CN102115077A (en) | Preparation method of biomass sludge synthesized carbon | |
| CN101220310A (en) | Process technique for producing fuel by using stalk |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |