CN106244283A - A kind of sawdust based biomass granule of NEW TYPE OF COMPOSITE cattle manure and preparation method thereof - Google Patents
A kind of sawdust based biomass granule of NEW TYPE OF COMPOSITE cattle manure and preparation method thereof Download PDFInfo
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- CN106244283A CN106244283A CN201610677380.1A CN201610677380A CN106244283A CN 106244283 A CN106244283 A CN 106244283A CN 201610677380 A CN201610677380 A CN 201610677380A CN 106244283 A CN106244283 A CN 106244283A
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- cattle manure
- sawdust
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
- C10L5/442—Wood or forestry waste
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/42—Solid fuels essentially based on materials of non-mineral origin on animal substances or products obtained therefrom, e.g. manure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
- C10L5/445—Agricultural waste, e.g. corn crops, grass clippings, nut shells or oil pressing residues
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/46—Solid fuels essentially based on materials of non-mineral origin on sewage, house, or town refuse
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Biodiversity & Conservation Biology (AREA)
- Ecology (AREA)
- Forests & Forestry (AREA)
- Wood Science & Technology (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Treatment Of Sludge (AREA)
Abstract
nullThe invention discloses the sawdust based biomass granule of a kind of NEW TYPE OF COMPOSITE cattle manure,On the one hand sawdust carbonization is processed the most modified,Improve toughness and the density of DIC granule,The combustion heat value that improve sawdust carbon residue the volatile matter reducing in combustion process,The waste gas sulfur content of discharge is low free from environmental pollution,On the other hand,By cotton stalk、After seedling of Semen arachidis hypogaeae carries out fermentation process,The structure sheaf changing raw material forms the organizational structure of densification,And form the organic material of high-load,Improve organic constituent,Again by modified manganese Iron-ore Slag、Cattle manure adds continues fermentation process,And then the combustible in raising organic matter material,Last other effective auxiliary agents of compatibility again are extruded,The present invention solves the problem of environmental pollution that plant's cattle manure is caused,Cattle manure is just made biomass fuel,Its clean environmental protection,Can substantially realize environmental protection zero-emission standard,Effectively substitute high pollution、The big energy of the three of maximum discharge.
Description
Technical field
The present invention relates to biomass fuel technical field, particularly relate to the sawdust based biomass of a kind of NEW TYPE OF COMPOSITE cattle manure
Grain and preparation method thereof.
Background technology
Along with mankind's increase day by day to energy demand, now widely used oil, coal, natural gas etc. are non-renewable
The energy be faced with day by day exhausted problem.The energy crisis that will face to solve the mankind be necessary to develop reproducible newly
The energy replaces non-renewable Fossil fuel.Biomass energy, as a kind of cheap, regenerative resource of cleaning, is the most more come
More being paid close attention to by people widely, China is as large agricultural country, in the raw material supply of biomass energy, energy demand, government's political affairs
The aspects such as the support of plan all have greater advantage.Sawdust, straw source is abundant, and with low cost, sawdust sulfur content is the lowest simultaneously, with it
The biomass granule fuel substitute fossil fuels prepared for raw material, to preserving the ecological environment, Development of Social Economy, implementing the energy can
Sustainable development strategy has major and immediate significance.But traditional biomass granule fuel utilizing sawdust straw to prepare exists
Calorific value slagging scorification boiler low, easy uses dangerous, sulfur content to exceed standard many defects such as pollution environment, ash are big.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that the sawdust base of a kind of NEW TYPE OF COMPOSITE cattle manure is biological
Matter granule and preparation method thereof.
The present invention is achieved by the following technical solutions:
The sawdust based biomass granule of a kind of NEW TYPE OF COMPOSITE cattle manure, is prepared by the raw materials in: sawdust 119-128, cotton
Chopped straw stalk 40-42, seedling of Semen arachidis hypogaeae 30-34, cattle manure 25-30, Exocarpium Citrulli 14-16, ferromanganese ore slag 17-20, sodium hydroxide 2-4, peroxide
Change calcium 3-5, pig fat 7-9, isothiazolone 1-3, suitable quantity of water.
The manufacture method of the sawdust based biomass granule of described a kind of NEW TYPE OF COMPOSITE cattle manure, comprises the following steps:
(1) sawdust is put in retort at a temperature of 450-500 DEG C, isolation air carbonization 20-30 minute, it is cooled to room temperature
Add calper calcium peroxide to grind 40-50 minute;
(2) being soaked 1-2 hour by ferromanganese ore slag 5-10wt% hydrochloric acid solution, washing, to neutral, adds water ultrasonic at 80-100 DEG C
Ripple processes 8-10 minute, then soaks 1-2 hour with 8-12wt% sodium hydroxide solution, and washing, to neutral, adds water at 80-100 DEG C
Ultrasonic Treatment 8-10 minute, is subsequently adding pig fat, isothiazolone grinding 20-30 minute, dries and prepare modified manganese iron mine
Slag;
(3) by cotton stalk, seedling of Semen arachidis hypogaeae with hot-water soak 10-12 hour of 60-70 DEG C, filter and put in fermentation vat, control to send out
Ferment pond temperature is at 30-50 DEG C, and humidity is 50-60%, after fermentation process 20-30 hour, adds modified manganese Iron-ore Slag, cattle manure stirring
Uniformly continue fermentation 10-20 days, be cooled to room temperature and put into pulverizer is crushed to 60-80 mesh;
(4) Exocarpium Citrulli drying is pulverized, add step (1), the mixing of (3) material stirring, add suitable quantity of water and other residue
Composition stirring and evenly mixing, sends into single lead screw ex truding briquetting machine, is squeezed into a diameter of 5-8mm with the briquetting pressure of 45MPa, a length of 3-8cm's
Cylindrical particle, is dried, discharging.
The invention have the advantage that present invention process simple operations is easy, on the one hand sawdust carbonization processed the most modified,
Improve toughness and the density of DIC granule, the combustion heat value that improve sawdust carbon residue the volatilization reducing in combustion process
Point, the waste gas sulfur content of discharge is low free from environmental pollution, on the other hand, after cotton stalk, seedling of Semen arachidis hypogaeae are carried out fermentation process, changes
The structure sheaf of raw material forms the organizational structure of densification, and forms the organic material of high-load, improves organic matter and forms into
Point, then modified manganese Iron-ore Slag, cattle manure are added continuation fermentation process, and then improve the combustible in organic matter material, the most again
Other effective auxiliary agents of compatibility are extruded, and the present invention solves the problem of environmental pollution that plant's cattle manure is caused, and cattle manure is just made
Become biomass fuel, its clean environmental protection, can substantially realize environmental protection zero-emission standard, effectively substitute high pollution, maximum discharge three big
The energy.
Detailed description of the invention
The sawdust based biomass granule of a kind of NEW TYPE OF COMPOSITE cattle manure, is prepared by the raw materials in: sawdust 119, cotton
Chopped straw stalk 40, seedling of Semen arachidis hypogaeae 30, cattle manure 25, Exocarpium Citrulli 14, ferromanganese ore slag 17, sodium hydroxide 2, calper calcium peroxide 3, pig fat 7, different thiophene
Oxazoline ketone 1, suitable quantity of water.
The manufacture method of the sawdust based biomass granule of described a kind of NEW TYPE OF COMPOSITE cattle manure, comprises the following steps:
(1) sawdust is put in retort at a temperature of 450 DEG C, isolation air carbonization 20 minutes, be cooled to room temperature and added
Calcium oxide grinds 40 minutes;
(2) being soaked 1 hour by ferromanganese ore slag 5-10wt% hydrochloric acid solution, washing is to neutral, and add water ultrasonic Treatment at 80 DEG C
8 minutes, then soak 1 hour with 8-12wt% sodium hydroxide solution, washing is to neutral, and add water ultrasonic Treatment 8 points at 80 DEG C
Clock, is subsequently adding pig fat, isothiazolone grinding 20-30 minute, dries and prepare modified manganese Iron-ore Slag;
(3) by cotton stalk, seedling of Semen arachidis hypogaeae with the hot-water soak 10 hours of 60 DEG C, filter and put in fermentation vat, control fermentation vat temperature
Degree is at 30 DEG C, and humidity is 50%, and fermentation process is after 20 hours, and addition modified manganese Iron-ore Slag, cattle manure stir and continue fermentation 10
My god, it is cooled to room temperature and puts into pulverizer is crushed to 60 mesh;
(4) Exocarpium Citrulli drying is pulverized, add step (1), the mixing of (3) material stirring, add suitable quantity of water and other residue
Composition stirring and evenly mixing, sends into single lead screw ex truding briquetting machine, is squeezed into a diameter of 5mm, the cylinder of a length of 3cm with the briquetting pressure of 45MPa
Shape granule, is dried, discharging.
The technical parameter index using the sawdust based biomass granule of present invention production is as follows:
(1) density: 0.92g/cm3;
(2) sulfur content: 0.284%, less than the standard of special low-sulfur coal 0.50%;
(3) ash: 8.66%, in the range of low ash coal (ash is 5.01%-10.00%);
(4) calorific value: 25.23MJ/kg, in the range of high combustion value coal (calorific value is 24.01-27.00MJ/kg).
Claims (2)
1. the sawdust based biomass granule of a NEW TYPE OF COMPOSITE cattle manure, it is characterised in that be prepared by the raw materials in: saw
End 119-128, cotton stalk 40-42, seedling of Semen arachidis hypogaeae 30-34, cattle manure 25-30, Exocarpium Citrulli 14-16, ferromanganese ore slag 17-20, hydrogen-oxygen
Change sodium 2-4, calper calcium peroxide 3-5, pig fat 7-9, isothiazolone 1-3, suitable quantity of water.
The manufacture method of the sawdust based biomass granule of a kind of NEW TYPE OF COMPOSITE cattle manure the most according to claim 1, its feature
It is to comprise the following steps:
(1) sawdust is put in retort at a temperature of 450-500 DEG C, isolation air carbonization 20-30 minute, it is cooled to room temperature
Add calper calcium peroxide to grind 40-50 minute;
(2) being soaked 1-2 hour by ferromanganese ore slag 5-10wt% hydrochloric acid solution, washing, to neutral, adds water ultrasonic at 80-100 DEG C
Ripple processes 8-10 minute, then soaks 1-2 hour with 8-12wt% sodium hydroxide solution, and washing, to neutral, adds water at 80-100 DEG C
Ultrasonic Treatment 8-10 minute, is subsequently adding pig fat, isothiazolone grinding 20-30 minute, dries and prepare modified manganese iron mine
Slag;
(3) by cotton stalk, seedling of Semen arachidis hypogaeae with hot-water soak 10-12 hour of 60-70 DEG C, filter and put in fermentation vat, control to send out
Ferment pond temperature is at 30-50 DEG C, and humidity is 50-60%, after fermentation process 20-30 hour, adds modified manganese Iron-ore Slag, cattle manure stirring
Uniformly continue fermentation 10-20 days, be cooled to room temperature and put into pulverizer is crushed to 60-80 mesh;
(4) Exocarpium Citrulli drying is pulverized, add step (1), the mixing of (3) material stirring, add suitable quantity of water and other residue
Composition stirring and evenly mixing, sends into single lead screw ex truding briquetting machine, is squeezed into a diameter of 5-8mm with the briquetting pressure of 45MPa, a length of 3-8cm's
Cylindrical particle, is dried, discharging.
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CN201610677380.1A CN106244283A (en) | 2016-08-17 | 2016-08-17 | A kind of sawdust based biomass granule of NEW TYPE OF COMPOSITE cattle manure and preparation method thereof |
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CN201610677380.1A CN106244283A (en) | 2016-08-17 | 2016-08-17 | A kind of sawdust based biomass granule of NEW TYPE OF COMPOSITE cattle manure and preparation method thereof |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107177393A (en) * | 2017-06-12 | 2017-09-19 | 思南县唯山棕制品厂 | It is a kind of to extract the method that monofilament remaining material draft machine presses charcoal |
CN108048150A (en) * | 2017-12-07 | 2018-05-18 | 广德盛源电器有限公司 | A kind of sawdust biological particles |
CN108854957A (en) * | 2018-06-28 | 2018-11-23 | 普定县石阶农业开发有限公司 | A method of administering pig farm exhaust gas |
CN111057601A (en) * | 2020-01-07 | 2020-04-24 | 扬州工业职业技术学院 | Preparation method of sawdust biomass energy material |
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JP2009161747A (en) * | 2007-12-12 | 2009-07-23 | Japan Livestock Trading Corp | Fuel and method for producing the same |
CN104479784A (en) * | 2014-12-01 | 2015-04-01 | 葫芦岛市南票区腾兴生物质燃料厂 | Environment-friendly type carbon-adding biomass fuel and processing method thereof |
CN104877728A (en) * | 2015-06-10 | 2015-09-02 | 山西天润丰农业科技开发有限公司 | Method for preparing biomass lump coal |
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2016
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2009161747A (en) * | 2007-12-12 | 2009-07-23 | Japan Livestock Trading Corp | Fuel and method for producing the same |
CN101255367A (en) * | 2008-04-22 | 2008-09-03 | 刘明全 | Herbivore dejecta fuel and method for manufacturing same |
CN104479784A (en) * | 2014-12-01 | 2015-04-01 | 葫芦岛市南票区腾兴生物质燃料厂 | Environment-friendly type carbon-adding biomass fuel and processing method thereof |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107177393A (en) * | 2017-06-12 | 2017-09-19 | 思南县唯山棕制品厂 | It is a kind of to extract the method that monofilament remaining material draft machine presses charcoal |
CN108048150A (en) * | 2017-12-07 | 2018-05-18 | 广德盛源电器有限公司 | A kind of sawdust biological particles |
CN108854957A (en) * | 2018-06-28 | 2018-11-23 | 普定县石阶农业开发有限公司 | A method of administering pig farm exhaust gas |
CN111057601A (en) * | 2020-01-07 | 2020-04-24 | 扬州工业职业技术学院 | Preparation method of sawdust biomass energy material |
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