CN106147613A - A kind of Environment-friendlynon-toxic non-toxic paint - Google Patents

A kind of Environment-friendlynon-toxic non-toxic paint Download PDF

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Publication number
CN106147613A
CN106147613A CN201610805679.0A CN201610805679A CN106147613A CN 106147613 A CN106147613 A CN 106147613A CN 201610805679 A CN201610805679 A CN 201610805679A CN 106147613 A CN106147613 A CN 106147613A
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China
Prior art keywords
parts
resin
toxic
paint
environment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610805679.0A
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Chinese (zh)
Inventor
张树霞
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Maanshan Numen Intellectual Property Management Services Co Ltd
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Maanshan Numen Intellectual Property Management Services Co Ltd
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Priority to CN201610805679.0A priority Critical patent/CN106147613A/en
Publication of CN106147613A publication Critical patent/CN106147613A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00—Coating compositions based on unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of Environment-friendlynon-toxic non-toxic paint, its component includes the sexual resin of plant 15 25 parts by weight, thermoplastic acrylic resin 10 15 parts, ferrous oxide nanoscale micro mist 25 parts, sodium carboxymethylcellulose 6 12 parts, zinc naphthenate 36 parts, dibutyl tin laurate 14 parts, nano phase ag_2 o 14 parts, nano titanium oxide 5 15 parts, fluorine silicon resin 8 12 parts, 3 10 parts of 5A type molecular sieve, 10 20 parts of radioresistance slurry, epoxy resin 5 15 parts, manufacture craft of the present invention is simple, manufacturing process is environment friendly and pollution-free, the paint environment-protecting asepsis preparing, harmless, can be widely used for various timber, iron material, plastic, paper wood, high-grade coloured furniture, hotel, the finishing of hospital etc.；In addition, its holding time is long, oxidation resistance is strong.

Description

A kind of Environment-friendlynon-toxic non-toxic paint
Technical field
The present invention relates to paint preparing technical field, be specially a kind of Environment-friendlynon-toxic non-toxic paint.
Background technology
Paint is that one can firmly cover at body surface, and the chemistry playing protection, decoration, mark and other specific uses mixes Compound coating.More authoritative " coating process " book of China's coating circle is defined such that " coating is a kind of material, this Material can be coated in object surface by different construction technologies, formed adhere to firmly, to have some strength, continuous print solid-state thin Film.The film common name film so being formed, also known as paint film or coating." after current paint is all chemicals especially application, can be constantly Ground volatile organic compound and episome.Not only produce ozone pollution to the Nature, but also human body can be made to cause headache, whole body The various diseases such as paralysis, anaemia, cancer, bring serious threat to health, but are that the one being not fee from must material Material.
Content of the invention
It is an object of the invention to provide a kind of Environment-friendlynon-toxic non-toxic paint, with the problem solving to propose in above-mentioned background technology.
For achieving the above object, the present invention provides following technical scheme: a kind of Environment-friendlynon-toxic non-toxic paint, its component is by weight Number includes plant sexual resin 15-25 part, thermoplastic acrylic resin 10-15 part, ferrous oxide nanoscale micro mist 2-5 part, carboxylic Sodium carboxymethylcellulose pyce 6-12 part, zinc naphthenate 3-6 part, dibutyl tin laurate 1-4 part, nano phase ag_2 o 1-4 part, nanometer two Titanium oxide 5-15 part, fluorine silicon resin 8-12 part, 5A type molecular sieve 3-10 part, radioresistance slurry 10-20 part, epoxy resin 5-15 Part.
Preferably, preferred composition proportion is: the sexual resin of plant 20 parts, thermoplastic acrylic resin 12 parts, titanium dioxide Iron nanoscale micro mist 3 parts, sodium carboxymethylcellulose 9 parts, zinc naphthenate 5 parts, dibutyl tin laurate 3 parts, nano phase ag_2 o 2 Part, nano titanium oxide 10 parts, fluorine silicon resin 10 parts, 6 parts of 5A type molecular sieve, 15 parts of radioresistance slurry, epoxy resin 10 parts.
Preferably, its preparation technology comprises the following steps:
A, by sexual for plant resin, thermoplastic acrylic resin, fluorine silicon resin, radioresistance slurry, epoxy resin mixing after add Stirring in mixer, mixer rotating speed is 3000-5000 rev/min, and mixing time is 20min-30min, stands and obtains mixture A；
B, in mixture A add ferrous oxide nanoscale micro mist, sodium carboxymethylcellulose, zinc naphthenate, tin dilaurate two fourth Ji Xi, nano phase ag_2 o, nano titanium oxide, add heating in reactor after mixing, temperature of reaction kettle is 70 DEG C-90 DEG C, adds The heat time is 30min, is cooled to normal temperature afterwards, obtains mixture B；
C, in mixture B add 5A type molecular sieve, at normal temperatures stir 30min, afterwards stand 2h, i.e. obtain nontoxic paint.
Compared with prior art, the invention has the beneficial effects as follows: manufacture craft of the present invention is simple, and manufacturing process environmental protection is without dirt Dye, the paint environment-protecting asepsis preparing, harmless, can be widely used for various timber, iron material, plastic, paper wood, high-grade coloured family The finishing of tool, hotel, hospital etc.；In addition, the present invention is added with multiple nanometer materials, it is possible to increase the anti-oxidant energy of paint Power, extends the holding time of paint.
Detailed description of the invention
Below the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment It is only a part of embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, the common skill in this area The every other embodiment that art personnel are obtained under the premise of not making creative work, broadly falls into the model of present invention protection Enclose.
The present invention provides a kind of technical scheme: a kind of Environment-friendlynon-toxic non-toxic paint, its component includes that plant is sexual by weight Resin 15-25 part, thermoplastic acrylic resin 10-15 part, ferrous oxide nanoscale micro mist 2-5 part, sodium carboxymethylcellulose 6- 12 parts, zinc naphthenate 3-6 part, dibutyl tin laurate 1-4 part, nano phase ag_2 o 1-4 part, nano titanium oxide 5-15 part, Fluorine silicon resin 8-12 part, 5A type molecular sieve 3-10 part, radioresistance slurry 10-20 part, epoxy resin 5-15 part.
Embodiment one:
The composition proportion using is: the sexual resin of plant 15 parts, thermoplastic acrylic resin 10 parts, ferrous oxide nanoscale micro mist 2 parts, sodium carboxymethylcellulose 6 parts, zinc naphthenate 3 parts, dibutyl tin laurate 1 part, nano phase ag_2 o 1 part, nano-silica Change titanium 5 parts, fluorine silicon resin 8 parts, 3 parts of 5A type molecular sieve, 10 parts of radioresistance slurry, epoxy resin 5 parts.
The preparation technology of the present embodiment comprises the following steps:
A, by sexual for plant resin, thermoplastic acrylic resin, fluorine silicon resin, radioresistance slurry, epoxy resin mixing after add Stirring in mixer, mixer rotating speed is 3000 revs/min, and mixing time is 20min, stands and obtains mixture A；
B, in mixture A add ferrous oxide nanoscale micro mist, sodium carboxymethylcellulose, zinc naphthenate, tin dilaurate two fourth Ji Xi, nano phase ag_2 o, nano titanium oxide, add heating in reactor after mixing, temperature of reaction kettle is 70 DEG C, the heat time It for 30min, is cooled to normal temperature afterwards, obtain mixture B；
C, in mixture B add 5A type molecular sieve, at normal temperatures stir 30min, afterwards stand 2h, i.e. obtain nontoxic paint.
Embodiment two:
The composition proportion using is: the sexual resin of plant 25 parts, thermoplastic acrylic resin 15 parts, ferrous oxide nanoscale micro mist 5 parts, sodium carboxymethylcellulose 12 parts, zinc naphthenate 6 parts, dibutyl tin laurate 4 parts, nano phase ag_2 o 4 parts, nano-silica Change titanium 15 parts, fluorine silicon resin 12 parts, 10 parts of 5A type molecular sieve, 20 parts of radioresistance slurry, epoxy resin 15 parts.
The preparation technology of the present embodiment comprises the following steps:
A, by sexual for plant resin, thermoplastic acrylic resin, fluorine silicon resin, radioresistance slurry, epoxy resin mixing after add Stirring in mixer, mixer rotating speed is 5000 revs/min, and mixing time is 30min, stands and obtains mixture A；
B, in mixture A add ferrous oxide nanoscale micro mist, sodium carboxymethylcellulose, zinc naphthenate, tin dilaurate two fourth Ji Xi, nano phase ag_2 o, nano titanium oxide, add heating in reactor after mixing, temperature of reaction kettle is 90 DEG C, the heat time It for 30min, is cooled to normal temperature afterwards, obtain mixture B；
C, in mixture B add 5A type molecular sieve, at normal temperatures stir 30min, afterwards stand 2h, i.e. obtain nontoxic paint.
Embodiment three:
The composition proportion using is: the sexual resin of plant 17 parts, thermoplastic acrylic resin 11 parts, ferrous oxide nanoscale micro mist 3 parts, sodium carboxymethylcellulose 7 parts, zinc naphthenate 4 parts, dibutyl tin laurate 2 parts, nano phase ag_2 o 2 parts, nano-silica Change titanium 7 parts, fluorine silicon resin 9 parts, 4 parts of 5A type molecular sieve, 12 parts of radioresistance slurry, epoxy resin 6 parts.
The preparation technology of the present embodiment comprises the following steps:
A, by sexual for plant resin, thermoplastic acrylic resin, fluorine silicon resin, radioresistance slurry, epoxy resin mixing after add Stirring in mixer, mixer rotating speed is 3500 revs/min, and mixing time is 22min, stands and obtains mixture A；
B, in mixture A add ferrous oxide nanoscale micro mist, sodium carboxymethylcellulose, zinc naphthenate, tin dilaurate two fourth Ji Xi, nano phase ag_2 o, nano titanium oxide, add heating in reactor after mixing, temperature of reaction kettle is 75 DEG C, the heat time It for 30min, is cooled to normal temperature afterwards, obtain mixture B；
C, in mixture B add 5A type molecular sieve, at normal temperatures stir 30min, afterwards stand 2h, i.e. obtain nontoxic paint.
Embodiment four:
The composition proportion using is: the sexual resin of plant 22 parts, thermoplastic acrylic resin 14 parts, ferrous oxide nanoscale micro mist 4 parts, sodium carboxymethylcellulose 11 parts, zinc naphthenate 5 parts, dibutyl tin laurate 3 parts, nano phase ag_2 o 3 parts, nano-silica Change titanium 14 parts, fluorine silicon resin 11 parts, 9 parts of 5A type molecular sieve, 18 parts of radioresistance slurry, epoxy resin 14 parts.
The preparation technology of the present embodiment comprises the following steps:
A, by sexual for plant resin, thermoplastic acrylic resin, fluorine silicon resin, radioresistance slurry, epoxy resin mixing after add Stirring in mixer, mixer rotating speed is 4500 revs/min, and mixing time is 28min, stands and obtains mixture A；
B, in mixture A add ferrous oxide nanoscale micro mist, sodium carboxymethylcellulose, zinc naphthenate, tin dilaurate two fourth Ji Xi, nano phase ag_2 o, nano titanium oxide, add heating in reactor after mixing, temperature of reaction kettle is 85 DEG C, the heat time It for 30min, is cooled to normal temperature afterwards, obtain mixture B；
C, in mixture B add 5A type molecular sieve, at normal temperatures stir 30min, afterwards stand 2h, i.e. obtain nontoxic paint.
Embodiment five:
The composition proportion using is: the sexual resin of plant 20 parts, thermoplastic acrylic resin 12 parts, ferrous oxide nanoscale micro mist 3 parts, sodium carboxymethylcellulose 9 parts, zinc naphthenate 5 parts, dibutyl tin laurate 3 parts, nano phase ag_2 o 2 parts, nano-silica Change titanium 10 parts, fluorine silicon resin 10 parts, 6 parts of 5A type molecular sieve, 15 parts of radioresistance slurry, epoxy resin 10 parts.
The preparation technology of the present embodiment comprises the following steps:
A, by sexual for plant resin, thermoplastic acrylic resin, fluorine silicon resin, radioresistance slurry, epoxy resin mixing after add Stirring in mixer, mixer rotating speed is 4000 revs/min, and mixing time is 25min, stands and obtains mixture A；
B, in mixture A add ferrous oxide nanoscale micro mist, sodium carboxymethylcellulose, zinc naphthenate, tin dilaurate two fourth Ji Xi, nano phase ag_2 o, nano titanium oxide, add heating in reactor after mixing, temperature of reaction kettle is 80 DEG C, the heat time It for 30min, is cooled to normal temperature afterwards, obtain mixture B；
C, in mixture B add 5A type molecular sieve, at normal temperatures stir 30min, afterwards stand 2h, i.e. obtain nontoxic paint.
Manufacture craft of the present invention is simple, and manufacturing process is environment friendly and pollution-free, the paint environment-protecting asepsis preparing, harmless, Can be widely used for the finishing of various timber, iron material, plastic, paper wood, high-grade coloured furniture, hotel, hospital etc.；In addition, the present invention In be added with multiple nanometer materials, it is possible to increase the oxidation resistance of paint, extend the holding time of paint.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, permissible Understand and multiple change, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention And modification, the scope of the present invention be defined by the appended.

Claims (3)

1. an Environment-friendlynon-toxic non-toxic paint, it is characterised in that: its component includes plant sexual resin 15-25 part, heat by weight Plastic propene's acid resin 10-15 part, ferrous oxide nanoscale micro mist 2-5 part, sodium carboxymethylcellulose 6-12 part, zinc naphthenate 3- 6 parts, dibutyl tin laurate 1-4 part, nano phase ag_2 o 1-4 part, nano titanium oxide 5-15 part, fluorine silicon resin 8-12 part, 5A type molecular sieve 3-10 part, radioresistance slurry 10-20 part, epoxy resin 5-15 part.
2. a kind of Environment-friendlynon-toxic non-toxic paint according to claim 1, it is characterised in that: preferred composition proportion is: plant has Property resin 20 parts, thermoplastic acrylic resin 12 parts, ferrous oxide nanoscale micro mist 3 parts, sodium carboxymethylcellulose 9 parts, cycloalkanes 5 parts of zinc of acid, dibutyl tin laurate 3 parts, nano phase ag_2 o 2 parts, nano titanium oxide 10 parts, fluorine silicon resin 10 parts, 5A type 6 parts of molecular sieve, 15 parts of radioresistance slurry, epoxy resin 10 parts.
3. a kind of Environment-friendlynon-toxic non-toxic paint according to claim 1, it is characterised in that: its preparation technology comprises the following steps:
A, by sexual for plant resin, thermoplastic acrylic resin, fluorine silicon resin, radioresistance slurry, epoxy resin mixing after add Stirring in mixer, mixer rotating speed is 3000-5000 rev/min, and mixing time is 20min-30min, stands and obtains mixture A；
B, in mixture A add ferrous oxide nanoscale micro mist, sodium carboxymethylcellulose, zinc naphthenate, tin dilaurate two fourth Ji Xi, nano phase ag_2 o, nano titanium oxide, add heating in reactor after mixing, temperature of reaction kettle is 70 DEG C-90 DEG C, adds The heat time is 30min, is cooled to normal temperature afterwards, obtains mixture B；
C, in mixture B add 5A type molecular sieve, at normal temperatures stir 30min, afterwards stand 2h, i.e. obtain nontoxic paint.
CN201610805679.0A 2016-09-07 2016-09-07 A kind of Environment-friendlynon-toxic non-toxic paint Pending CN106147613A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610805679.0A CN106147613A (en) 2016-09-07 2016-09-07 A kind of Environment-friendlynon-toxic non-toxic paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610805679.0A CN106147613A (en) 2016-09-07 2016-09-07 A kind of Environment-friendlynon-toxic non-toxic paint

Publications (1)

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CN106147613A true CN106147613A (en) 2016-11-23

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107312434A (en) * 2017-06-30 2017-11-03 安徽新创智能科技有限公司 One kind finishing environment-friendly type waterproof paint and preparation method thereof
CN107418339A (en) * 2017-09-22 2017-12-01 安徽慕曼德家具有限公司 A kind of composite environmental-friendly paint
CN107474738A (en) * 2017-06-28 2017-12-15 安徽慕曼德家具有限公司 A kind of furniture insect prevention environment protection oil paint

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CN105504929A (en) * 2015-12-31 2016-04-20 文登蓝岛建筑工程有限公司 Moisture-proof paint and preparation method thereof
CN105585958A (en) * 2014-10-24 2016-05-18 邵杰 Environmental friendly anti-fouling paint
CN105694563A (en) * 2016-03-30 2016-06-22 浙江宠悦工贸有限公司 Water-resistant paint

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CN104371472A (en) * 2014-12-03 2015-02-25 张亦彬 Weather-resistant paint and preparation method thereof
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CN105694563A (en) * 2016-03-30 2016-06-22 浙江宠悦工贸有限公司 Water-resistant paint

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107474738A (en) * 2017-06-28 2017-12-15 安徽慕曼德家具有限公司 A kind of furniture insect prevention environment protection oil paint
CN107312434A (en) * 2017-06-30 2017-11-03 安徽新创智能科技有限公司 One kind finishing environment-friendly type waterproof paint and preparation method thereof
CN107418339A (en) * 2017-09-22 2017-12-01 安徽慕曼德家具有限公司 A kind of composite environmental-friendly paint

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Application publication date: 20161123