CN107418339A - A kind of composite environmental-friendly paint - Google Patents
A kind of composite environmental-friendly paint Download PDFInfo
- Publication number
- CN107418339A CN107418339A CN201710862890.0A CN201710862890A CN107418339A CN 107418339 A CN107418339 A CN 107418339A CN 201710862890 A CN201710862890 A CN 201710862890A CN 107418339 A CN107418339 A CN 107418339A
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- Prior art keywords
- parts
- composite environmental
- friendly paint
- curing agent
- weight
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to technical field of fine, and in particular to a kind of composite environmental-friendly paint.This kind of composite environmental-friendly paint, is made up of the raw material below according to parts by weight：25 ~ 50 parts of thermoplastic acrylic resin, 15 ~ 30 parts of epoxy resin, 12 ~ 25 parts of oronain bentonite, 5 ~ 12 parts of tributyl 2-acetylcitrate draw in 10 ~ 18 parts of hydroxyethyl cellulose, department, 2 ~ 10 parts of silica gel, 0.3 ~ 1.8 part of quartz sand, 0.7 ~ 1.5 part of alumina powder, 2 ~ 8 parts of bamboo charcoal, 1 ~ 5 part of 120 ~ 260 parts of water, 4 ~ 8 parts of curing agent and Phenoxyethanol.This kind of composite environmental-friendly paint is safe, and without benzene, toluene, formaldehyde, free TDI toxic heavy metal, nontoxic non-stimulated smell is harmless, free from environmental pollution, and hardness is high, and oil resistance is good.
Description
Technical field
The present invention relates to technical field of fine, and in particular to a kind of composite environmental-friendly paint.
Background technology
Paint is that one kind can firmly be covered in body surface, and the chemistry for playing protection, decoration, mark and other specific uses mixes
Compound coating, has a wide range of applications in daily life.Paint as viscous oily pigment, it is inflammable in the case of not dry,
It is not soluble in water, fat is slightly soluble in, dissolves in alcohol, aldehyde, ether, benzene, alkane, is soluble in gasoline, kerosene, diesel oil.Contain benzene, first in paint
Benzene, dimethylbenzene, formaldehyde, free TDI toxic heavy metal, irritant smell, harm is produced to health.
With the development of society, the environmental consciousness of people constantly strengthens, original paint has been substituted using environment protection oil paint
As the common recognition of people.However, existing environment protection oil paint still has in terms of hardness and resistance to elevated temperatures with existing paint
Larger gap, and its influence application of the environment protection oil paint in terms of dining table, desk.A kind of accordingly, it is desirable to provide composite environmental-friendly
Paint to meet use demand.
The content of the invention
In order to solve the problems, such as to be mentioned in above-mentioned background, present invention aims at provide a kind of composite environmental-friendly paint.
To achieve the above object, the present invention provides following technical scheme：
A kind of composite environmental-friendly paint, is made up of the raw material below according to parts by weight：25 ~ 50 parts of thermoplastic acrylic resin, ring
12 ~ 25 parts of oronain bentonite, tributyl 2-acetylcitrate 5 ~ 12 draw in 15 ~ 30 parts of oxygen tree fat, 10 ~ 18 parts of hydroxyethyl cellulose, department
Part, 2 ~ 10 parts of silica gel, 0.3 ~ 1.8 part of quartz sand, 0.7 ~ 1.5 part of alumina powder, 2 ~ 8 parts of bamboo charcoal, 120 ~ 260 parts of water, curing agent 4
~ 8 parts and 1 ~ 5 part of Phenoxyethanol.
As the further scheme of the present invention：The composite environmental-friendly paint, is made up of the raw material below according to parts by weight：
32 ~ 40 parts of thermoplastic acrylic resin, 18 ~ 25 parts of epoxy resin, 13 ~ 16 parts of hydroxyethyl cellulose, department's drawing oronain bentonite 15 ~
21 parts, 8 ~ 10 parts of tributyl 2-acetylcitrate, 4 ~ 7 parts of silica gel, 0.8 ~ 1.3 part of quartz sand, 0.9 ~ 1.3 part of alumina powder, bamboo charcoal 4
~ 6 parts, 170 ~ 220 parts of water, 2 ~ 4 parts of 5 ~ 7 parts of curing agent and Phenoxyethanol.
As the further scheme of the present invention：The composite environmental-friendly paint, is made up of the raw material below according to parts by weight：
18 parts of oronain bentonite, acetyl lemon draw in 35 parts of thermoplastic acrylic resin, 20 parts of epoxy resin, 15 parts of hydroxyethyl cellulose, department
9 parts of lemon acid tributyl, 5 parts of silica gel, 1.1 parts of quartz sand, 1.2 parts of alumina powder, 5 parts of bamboo charcoal, 200 parts of water, 6 parts of curing agent and benzene
3 parts of oxyethanol.
As the further scheme of the present invention：The curing agent of composite environmental-friendly paint by phenolsulfonic acid, aqueous polyurethane,
Tetraethyl orthosilicate is 2 according to ratio of weight and number:5:1 is formulated.
The composite environmental-friendly paint of the present invention is without benzene, toluene, formaldehyde, free TDI, toxic heavy metal, nontoxic non-stimulated gas
Taste, it is harmless, it is free from environmental pollution.Hydroxyethyl cellulose be with the addition of as surfactant, serve emulsification and suspending
Effect so that the stability of composite environmental-friendly paint is more preferably；Tributyl 2-acetylcitrate be with the addition of as plasticizer, improved compound
The pliability of environment protection oil paint；Quartz sand and alumina powder are with the addition of, it is resistance to that lifting composite environmental-friendly improves its while painting hardness
High-temperature behavior.This kind of composite environmental-friendly paint is also equipped with good weatherability, oil preventing performance, safe.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of composite environmental-friendly paint, it is made up of the raw material below according to parts by weight：Thermoplastic acrylic
18 parts of oronain bentonite, tributyl 2-acetylcitrate 9 draw in 35 parts of resin, 20 parts of epoxy resin, 15 parts of hydroxyethyl cellulose, department
3 parts of part, 5 parts of silica gel, 1.1 parts of quartz sand, 1.2 parts of alumina powder, 5 parts of bamboo charcoal, 200 parts of water, 6 parts of curing agent and Phenoxyethanol.
Composite environmental-friendly paint curing agent be according to ratio of weight and number by phenolsulfonic acid, aqueous polyurethane, tetraethyl orthosilicate
2:5:1 is formulated.
Embodiment 2
In the embodiment of the present invention, a kind of composite environmental-friendly paint, it is made up of the raw material below according to parts by weight：Thermoplastic acrylic
12 parts of oronain bentonite, tributyl 2-acetylcitrate 5 draw in 25 parts of resin, 15 parts of epoxy resin, 10 parts of hydroxyethyl cellulose, department
1 part of part, 2 parts of silica gel, 0.3 part of quartz sand, 0.7 part of alumina powder, 2 parts of bamboo charcoal, 120 parts of water, 4 parts of curing agent and Phenoxyethanol.
Composite environmental-friendly paint curing agent be according to ratio of weight and number by phenolsulfonic acid, aqueous polyurethane, tetraethyl orthosilicate
2:5:1 is formulated.
Embodiment 3
In the embodiment of the present invention, a kind of composite environmental-friendly paint, it is made up of the raw material below according to parts by weight：Thermoplastic acrylic
25 parts of oronain bentonite, tributyl 2-acetylcitrate 12 draw in 50 parts of resin, 30 parts of epoxy resin, 18 parts of hydroxyethyl cellulose, department
5 parts of part, 10 parts of silica gel, 1.8 parts of quartz sand, 1.5 parts of alumina powder, 8 parts of bamboo charcoal, 260 parts of water, 8 parts of curing agent and Phenoxyethanol.
Composite environmental-friendly paint curing agent be according to ratio of weight and number by phenolsulfonic acid, aqueous polyurethane, tetraethyl orthosilicate
2:5:1 is formulated.
Embodiment 4
In the embodiment of the present invention, a kind of composite environmental-friendly paint, it is made up of the raw material below according to parts by weight：Thermoplastic acrylic
15 parts of oronain bentonite, tributyl 2-acetylcitrate 8 draw in 32 parts of resin, 18 parts of epoxy resin, 13 parts of hydroxyethyl cellulose, department
2 parts of part, 4 parts of silica gel, 0.8 part of quartz sand, 0.9 part of alumina powder, 4 parts of bamboo charcoal, 170 parts of water, 5 parts of curing agent and Phenoxyethanol.
Composite environmental-friendly paint curing agent be according to ratio of weight and number by phenolsulfonic acid, aqueous polyurethane, tetraethyl orthosilicate
2:5:1 is formulated.
Embodiment 5
In the embodiment of the present invention, a kind of composite environmental-friendly paint, it is made up of the raw material below according to parts by weight：Thermoplastic acrylic
21 parts of oronain bentonite, tributyl 2-acetylcitrate 10 draw in 40 parts of resin, 25 parts of epoxy resin, 16 parts of hydroxyethyl cellulose, department
4 parts of part, 7 parts of silica gel, 1.3 parts of quartz sand, 1.3 parts of alumina powder, 6 parts of bamboo charcoal, 220 parts of water, 7 parts of curing agent and Phenoxyethanol.
Composite environmental-friendly paint curing agent be according to ratio of weight and number by phenolsulfonic acid, aqueous polyurethane, tetraethyl orthosilicate
2:5:1 is formulated.
Performance detection is carried out to composite environmental-friendly paint made from the formula of embodiment 1 ~ 5, testing result is as shown in table 1.
The composite environmental-friendly of table 1 paints performance
| Examination criteria | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| Appearance of coat | Range estimation | Coating is smooth | Coating is smooth | Coating is smooth | Coating is smooth | Coating is smooth |
| Coating layer thickness | Measurement | 2-4mm | 2-5mm | 3-5mm | 2-5mm | 2-5mm |
| Pencil hardness（7d） | GB/T6739 | >2H | >2H | >2H | >2H | >2H |
| High temperature resistant（600 DEG C, 4h） | ASTMD3359 | Nothing has been stung | Nothing has been stung | Nothing has been stung | Nothing has been stung | Nothing has been stung |
| Oil resistivity 15dh | GB/T1734-93 | 161 | 170 | 155 | 160 | 164 |
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and do not carrying on the back
In the case of spirit or essential attributes from the present invention, the present invention can be realized in other specific forms.Therefore, no matter from which
From the point of view of a bit, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention will by appended right
Ask rather than described above limits, it is intended that all changes in the implication and scope of the equivalency of claim will be fallen
Include in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that those skilled in the art should for clarity
Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
It is appreciated that other embodiment.
Claims (4)
1. a kind of composite environmental-friendly paint, it is characterised in that be made up of the raw material below according to parts by weight：Thermoplastic acrylic tree
12 ~ 25 parts of oronain bentonite, acetyl lemon are drawn by 25 ~ 50 parts of fat, 15 ~ 30 parts of epoxy resin, 10 ~ 18 parts of hydroxyethyl cellulose, department
Sour 5 ~ 12 parts of tributyl, 2 ~ 10 parts of silica gel, 0.3 ~ 1.8 part of quartz sand, 0.7 ~ 1.5 part of alumina powder, 2 ~ 8 parts of bamboo charcoal, water 120 ~
260 parts, 1 ~ 5 part of 4 ~ 8 parts of curing agent and Phenoxyethanol.
2. composite environmental-friendly paint according to claim 1, it is characterised in that by below according to the raw material group of parts by weight
Into：Oronain bentonite draws in 32 ~ 40 parts of thermoplastic acrylic resin, 18 ~ 25 parts of epoxy resin, 13 ~ 16 parts of hydroxyethyl cellulose, department
15 ~ 21 parts, 8 ~ 10 parts of tributyl 2-acetylcitrate, 4 ~ 7 parts of silica gel, 0.8 ~ 1.3 part of quartz sand, 0.9 ~ 1.3 part of alumina powder, bamboo
2 ~ 4 parts of 4 ~ 6 parts of charcoal, 170 ~ 220 parts of water, 5 ~ 7 parts of curing agent and Phenoxyethanol.
3. composite environmental-friendly paint according to claim 1, it is characterised in that by below according to the raw material group of parts by weight
Into：18 parts of oronain bentonite, acetyl draw in 35 parts of thermoplastic acrylic resin, 20 parts of epoxy resin, 15 parts of hydroxyethyl cellulose, department
9 parts of ATBC, 5 parts of silica gel, 1.1 parts of quartz sand, 1.2 parts of alumina powder, 5 parts of bamboo charcoal, 200 parts of water, 6 parts of curing agent and
3 parts of Phenoxyethanol.
4. painted according to any described composite environmental-friendlies of claim 1-3, it is characterised in that：Curing agent is by phenolsulfonic acid, water-based
Polyurethane, tetraethyl orthosilicate are 2 according to ratio of weight and number:5:1 is formulated.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710862890.0A CN107418339A (en) | 2017-09-22 | 2017-09-22 | A kind of composite environmental-friendly paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710862890.0A CN107418339A (en) | 2017-09-22 | 2017-09-22 | A kind of composite environmental-friendly paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107418339A true CN107418339A (en) | 2017-12-01 |
Family
ID=60433428
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710862890.0A Withdrawn CN107418339A (en) | 2017-09-22 | 2017-09-22 | A kind of composite environmental-friendly paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107418339A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108641529A (en) * | 2018-05-28 | 2018-10-12 | 广东韩丽家居集团股份有限公司 | It is a kind of environmental protection furniture paint and preparation method thereof |
Citations (6)
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|---|---|---|---|---|
| CN103881525A (en) * | 2012-12-24 | 2014-06-25 | 青岛宣威涂层材料有限公司 | Coating material adopting acrylic acid resin as raw material |
| CN103897448A (en) * | 2013-10-23 | 2014-07-02 | 东南大学 | Waterproof paint |
| CN106147613A (en) * | 2016-09-07 | 2016-11-23 | 马鞍山纽盟知识产权管理服务有限公司 | A kind of Environment-friendlynon-toxic non-toxic paint |
| CN106543791A (en) * | 2016-11-02 | 2017-03-29 | 张振宾 | A kind of odorless environment protection oil paint |
| CN106833066A (en) * | 2017-02-27 | 2017-06-13 | 霍碧滢 | A kind of antifreeze paint |
| CN107115226A (en) * | 2017-05-16 | 2017-09-01 | 佛山市汇汾化妆品科技有限公司 | A kind of Environmental-friendnail nail enamel |
-
2017
- 2017-09-22 CN CN201710862890.0A patent/CN107418339A/en not_active Withdrawn
Patent Citations (6)
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|---|---|---|---|---|
| CN103881525A (en) * | 2012-12-24 | 2014-06-25 | 青岛宣威涂层材料有限公司 | Coating material adopting acrylic acid resin as raw material |
| CN103897448A (en) * | 2013-10-23 | 2014-07-02 | 东南大学 | Waterproof paint |
| CN106147613A (en) * | 2016-09-07 | 2016-11-23 | 马鞍山纽盟知识产权管理服务有限公司 | A kind of Environment-friendlynon-toxic non-toxic paint |
| CN106543791A (en) * | 2016-11-02 | 2017-03-29 | 张振宾 | A kind of odorless environment protection oil paint |
| CN106833066A (en) * | 2017-02-27 | 2017-06-13 | 霍碧滢 | A kind of antifreeze paint |
| CN107115226A (en) * | 2017-05-16 | 2017-09-01 | 佛山市汇汾化妆品科技有限公司 | A kind of Environmental-friendnail nail enamel |
Non-Patent Citations (1)
| Title |
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| 董秀琦 等: "《消失模铸造实用技术》", 31 August 2005, 机械工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108641529A (en) * | 2018-05-28 | 2018-10-12 | 广东韩丽家居集团股份有限公司 | It is a kind of environmental protection furniture paint and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20171201 |