CN105694563A - Water-resistant paint - Google Patents
Water-resistant paint Download PDFInfo
- Publication number
- CN105694563A CN105694563A CN201610194120.9A CN201610194120A CN105694563A CN 105694563 A CN105694563 A CN 105694563A CN 201610194120 A CN201610194120 A CN 201610194120A CN 105694563 A CN105694563 A CN 105694563A
- Authority
- CN
- China
- Prior art keywords
- parts
- paint
- resistance
- water
- antioxidant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003973 paint Substances 0.000 title claims abstract description 70
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 55
- 239000002270 dispersing agent Substances 0.000 claims abstract description 27
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 20
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 19
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 19
- 239000000049 pigment Substances 0.000 claims abstract description 19
- 239000012178 vegetable wax Substances 0.000 claims abstract description 19
- 239000002994 raw material Substances 0.000 claims abstract description 16
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 11
- 239000000057 synthetic resin Substances 0.000 claims abstract description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 24
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 16
- 239000003822 epoxy resin Substances 0.000 claims description 8
- 229920000647 polyepoxide Polymers 0.000 claims description 8
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 claims description 7
- 239000004925 Acrylic resin Substances 0.000 claims description 7
- 229920000178 Acrylic resin Polymers 0.000 claims description 7
- 241000692870 Inachis io Species 0.000 claims description 7
- STZCRXQWRGQSJD-GEEYTBSJSA-M methyl orange Chemical compound [Na+].C1=CC(N(C)C)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 STZCRXQWRGQSJD-GEEYTBSJSA-M 0.000 claims description 7
- 229940012189 methyl orange Drugs 0.000 claims description 7
- 229960000907 methylthioninium chloride Drugs 0.000 claims description 7
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 claims description 7
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical group C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 claims description 6
- 239000004203 carnauba wax Substances 0.000 claims description 6
- 229920001169 thermoplastic Polymers 0.000 claims description 6
- 239000004416 thermosoftening plastic Substances 0.000 claims description 6
- 239000013078 crystal Substances 0.000 claims description 5
- -1 acrylic compounds sodium salt Chemical class 0.000 claims description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 3
- 229940043267 rhodamine b Drugs 0.000 claims description 2
- 239000002023 wood Substances 0.000 abstract description 23
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 20
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract description 14
- 239000012948 isocyanate Substances 0.000 abstract description 14
- 150000002513 isocyanates Chemical class 0.000 abstract description 14
- 239000003921 oil Substances 0.000 abstract description 14
- 241000779819 Syncarpia glomulifera Species 0.000 abstract 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000001739 pinus spp. Substances 0.000 abstract 1
- 229940036248 turpentine Drugs 0.000 abstract 1
- 235000019198 oils Nutrition 0.000 description 13
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 10
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 10
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 10
- 238000002474 experimental method Methods 0.000 description 6
- 238000004078 waterproofing Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 3
- 238000004088 simulation Methods 0.000 description 3
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical class [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241000521257 Hydrops Species 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 206010030113 Oedema Diseases 0.000 description 1
- LQNYBXQRMCHSHV-UHFFFAOYSA-M P.[Cl-].C(C1=CC=CC=C1)[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1 Chemical compound P.[Cl-].C(C1=CC=CC=C1)[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1 LQNYBXQRMCHSHV-UHFFFAOYSA-M 0.000 description 1
- 244000137852 Petrea volubilis Species 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- NPAIMXWXWPJRES-UHFFFAOYSA-N butyltin(3+) Chemical compound CCCC[Sn+3] NPAIMXWXWPJRES-UHFFFAOYSA-N 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000001087 glyceryl triacetate Substances 0.000 description 1
- 235000013773 glyceryl triacetate Nutrition 0.000 description 1
- ZCTXEAQXZGPWFG-UHFFFAOYSA-N imidurea Chemical compound O=C1NC(=O)N(CO)C1NC(=O)NCNC(=O)NC1C(=O)NC(=O)N1CO ZCTXEAQXZGPWFG-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
- 235000019796 monopotassium phosphate Nutrition 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- MUMZUERVLWJKNR-UHFFFAOYSA-N oxoplatinum Chemical compound [Pt]=O MUMZUERVLWJKNR-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000032696 parturition Effects 0.000 description 1
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229910003446 platinum oxide Inorganic materials 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 208000009146 rhinoscleroma Diseases 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- WYXIGTJNYDDFFH-UHFFFAOYSA-Q triazanium;borate Chemical compound [NH4+].[NH4+].[NH4+].[O-]B([O-])[O-] WYXIGTJNYDDFFH-UHFFFAOYSA-Q 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a water-resistant paint which is composed of the following raw materials in parts by weight: 10-16 parts of synthetic resin 5-7 parts of isocyanate, 8-12 parts of methyl methacrylate, 16-24 parts of boiled wood oil, 4-6 parts of vegetable wax, 2-6 parts of color matching pigment, 0.2-0.5 part of dispersing agent, 6-9 parts of ethanol, 2-4 parts of emulsifier, 6-10 parts of turpentine, 3-6 parts of nano titanium dioxide and 0.6-1.6 parts of antioxidant. The water-resistant paint has the advantages of high water resistance and low shedding tendency, and is uniform and glossy.
Description
Technical field
The present invention relates to paint technology field, especially wood paints technical field, be specifically related to a kind of resistance to water paint。
Background technology
Wood paints is the requirement of wood preservation, waterproof, is widely used in furniture and outdoor furniture。The material of timber is hygroscopic, when outdoor application, it is easy to because hydrops too much rots, is also easily corroded by insect, the use of wood paints, just seems very necessary。Traditional paint often contains the carcinogen such as toluene, formaldehyde, and volatilization lasting after using, it is detrimental to health。Along with the raising of health of people consciousness, to the requirement painted also improving, not only it is satisfied with defencive function。To paint safety, water proofing property, aesthetic property requirement improve further。
Such as, the Chinese invention patent application document that publication number is CN104356903A discloses a kind of timber floor water-and fire-proof alkyd paint, is made up of the raw material of following weight portion: long oil alkyd 30-35, amino resins 13-16, potassium dihydrogen phosphate 2-3, copper sulfate 1-2, tartaric acid 3-5, dimethylaminoethyl methacrylate 10-12, glycerol 5-6, trimethylolethane 6-8, xylitol 3-4, linoleic acid 2-3, triallylcyanurate 3-4, methyl methacrylate 3-5, vermiculite power 4-8, auxiliary agent 5-6, dimethylbenzene 10-12, butyl acetate 10-12。
Publication number is that the Chinese invention patent application document of CN104774555A discloses a kind of wooden tables and chairs waterproof antiwear and paints, it is made up of the raw material of following weight portion: Ludox 12-15, cobalt nitrate 3-5, imidazolidinyl urea 2-3, three platinum oxide 1-2, ethylene glycol 1-2, ferrocene 3-5, aromatic urethane acrylate 30-35, epoxy acrylate 14-18, methyl methacrylate 12-14, benzyl triphenyl phosphonium chloride phosphine 1-2, montmorillonite powder 4-6, four acicular type zinc oxide crystal whisker 10-12, diisocyanate 1-2, cross-linking agent TAC2-3, triacetin 10-12, auxiliary agent 5-6, dimethylbenzene 10-12, butyl acetate 10-12。
The Chinese invention patent application document that publication number is CN104927447A discloses a kind of timber floor moisture-resisting lacquer, it is characterized in that: it is made up of the raw material of following parts by weight: Pulvis Talci 4-6 part, Isooctyl acrylate monomer 7-9 part, coumarone 5-8 part, zinc naphthenate 1-4 part, rosin modified phenolic resin 12-21 part, isocyanates 3-5 part, schmigel 3-4 part, melamine resin 7-9 part, butyl acetate 12-18 part, phthalic anhydride 6-8 part, pigment 2-4 part, wetting agent 0.5-1.2 part, Firebrake ZB 4-6 part, aluminium hydroxide 3-7 part, Hydroxylated acrylic resin 7-9 part, Mono-n-butyltin 3-4 part, fatty acid polyethylene glycol ester 4-5 part, ammonium borate 2.5-3.5 part。The timber floor moisture-resisting lacquer of this invention, has good waterproof, anticorrosion, moistureproof effect
In water proofing property, some paint is because of the relation of composition own, and waterproofing wood is not high；Antiseptical requirement taken into account by some paint, and water proofing property is not high；Being combined with timber of having is not tight, it is easy to come off, thus easily moist。Thus, research and development resistance to water paint, the use for wood-based product is very necessary, has very big demand。
Summary of the invention
The present invention seeks to overcome deficiency of the prior art, it is provided that a kind of water-fast, reasonable raw material proportioning, not easily fade, the resistance to water paint of difficult drop-off, be particularly suited for wood-based product。
A kind of resistance to water paint, is made up of the raw material of following components by weight percent: synthetic resin 10-16 part, isocyanates 5-7 part, methyl methacrylate 8-12 part, boiled wood oil 16-24 part, vegetable wax 4-6 part, toner pigment 2-6 part, dispersant 0.2-0.5 part, ethanol 6-9 part, emulsifying agent 2-4 part, rosin 6-10 part, nano titanium oxide 3-6 part, antioxidant 0.6-1.6 part。
It is further preferred that resistance to water paint, it is made up of the raw material of following components by weight percent: synthetic resin 12 parts, isocyanates 5-7 part, methyl methacrylate 8-12 part, boiled wood oil 16-24 part, vegetable wax 4-6 part, toner pigment 2-6 part, dispersant 0.2-0.5 part, ethanol 6-9 part, emulsifying agent 2-4 part, rosin 6-10 part, nano titanium oxide 3-6 part, antioxidant 0.6-1.6 part。
Described synthetic resin is by thermoplastic acrylic resin, one or both compositions in epoxy resin。Adopt two kinds when combining, any proportion can be adopted to mix, it is preferable that to adopt equal proportion mixing。
There is not further crosslinking in thermoplastic acrylic resin, have good physical and mechanical properties, weatherability, chemical-resistant and excellent water resistance, protect light colour retention high in film forming procedure；Epoxy resin not only have as anticorrosive closely knit, water resistant, anti-leakage are good, intensity high, have the good manufacturabilities such as adhesive force strong, normal-temperature operation, easy construction simultaneously, and moderate；Isocyanates is the important intermediate of organic synthesis, can be used for improving the water proofing property of plastics, fabric, leather etc.。Synthetic resin, isocyanates, the comprehensive of methyl methacrylate use, and increase resistance to water and the film forming structural stability of paint。
Oleum Verniciae fordii is a kind of natural vegetable oil, and it has the rapidly feature such as dry, high temperature resistant, corrosion-resistant。Oleum Verniciae fordii also has good water proofing property, is widely used in the aspects such as building, paint, farm machinery。Boiled wood oil is processed by giving birth to Oleum Verniciae fordii, can replace the coating such as varnish and paint, can be directly used for the protection of Wood products。Vegetable wax can be combined closely with lumber fibre, strengthens case hardness, water proof anti-soil, wear-resisting anti-scratch；Oleum Verniciae fordii can penetrate into wood internal, gives timber deep layer and moistens maintenance；Wax can be combined closely with lumber fibre, strengthens case hardness, and water proof anti-soil, wear-resisting anti-scratch, such combination provides outstanding maintenance and decoration function to timber。Described boiled wood oil is the skillful Oleum Verniciae fordii after filtering。Any chemical composition of interpolation that skillful Oleum Verniciae fordii is inartificial, is suitable for environment friendly and pollution-free finishing, is especially suitable for the use of timber。
Described vegetable wax includes one or both in palm wax, sugarcane wax。
Described toner pigment select nano zine oxide (white), rhodamine B (redness), methyl orange, methylene blue, in peacock green one or more。
The use of nano titanium oxide, can make paint colors bright-coloured, strong coloring force, improve the stability to medium, and mechanical strength and the adhesive force of paint film can be strengthened, it is prevented that crackle, preventing ultraviolet and moisture from passing through, extend the paint film life-span, rutile crystal form nano titanium oxide effect is more excellent。
Therefore, described nano titanium oxide is preferably rutile crystal form nano titanium oxide。Particle diameter is 5～25nm, it is preferable that 5～10nm。
Described antioxidant is antioxidant MB or antioxidant 1010, and antioxidant can slow down the oxidation of paint Related Component, especially resinae composition。
Described dispersant is anti-loose colour dispersant, poly-(methyl) acrylic compounds sodium salt or poly-(methyl) acrylic compounds ammonium salt；It is preferably anti-loose colour dispersant 204S。Described emulsifying agent is BYK-110 or epoxy resin emulsifying agent DisponilLS500；It is preferably BYK-110。
Described dispersant is anti-loose colour dispersant 204S, it is prevented that titanium dioxide and ferrum oxide and other color adapted are made produced color separation spy and had effect, and can avoid producing deposition scleroma, good fluidity。Described emulsifying agent is BYK-110, reduces process of lapping required time and makes solvent based coating moistening and the dispersing aid of pigment dispersion stabilisation, can make titanium dioxide stabilisation, and reduce the viscosity of abrasive。
The present invention paint preparation method for said components is sufficiently mixed, all raw materials of the present invention all can by city available from。
It is an object of the invention to provide a kind of resistance to water paint, synthetic resin, isocyanates, the comprehensive of methyl methacrylate use, increase resistance to water and film forming structural stability, the addition boiled wood oil of characteristic, the vegetable wax of paint so that paint has timber to combine tightr and do not fall off。And add rutile crystal form nano titanium oxide and antioxidant, further antioxidation, prevent moisture from passing through。
The present invention works in coordination with between each component mutually, the common water resistance improving paint, and not fugitive color, difficult drop-off:
(1) the dry plank scribbling present invention paint soaks 6 hours in water, weighs after drying, and before and after it, weight change is within 0.02g, is optimized further by formula and can reach 0.00g；
(2) scribbling the dry plank of present invention paint, to soak 12 hours surfaces in water non-foaming；
(3) the dry plank scribbling present invention paint washes away 4 hours under the current of simulation heavy rain, and board surface paint is still smooth。
It is further preferred that resistance to water paint is made up of the raw material of following components by weight percent:
Synthetic resin 14 parts, isocyanates 6 parts, methyl methacrylate 10 parts, boiled wood oil 20 parts, vegetable wax 5 parts, toner pigment 5 parts, dispersant 0.4 part, ethanol 6 parts, emulsifying agent 3 parts, 8 parts of rosin, nano titanium oxide 5 parts, 1.2 parts of antioxidant。
Or:
Synthetic resin 12 parts, isocyanates 6 parts, methyl methacrylate 10 parts, boiled wood oil 24 parts, vegetable wax 6 parts, toner pigment 4 parts, dispersant 0.4 part, ethanol 9 parts, emulsifying agent 4 parts, 6 parts of rosin, nano titanium oxide 4 parts, 1.4 parts of antioxidant。
Under above-mentioned optimization formula, the resistance to water paint obtained, as follows through waterproof test result:
(1) being placed in water by the dry plank scribbling this optimization formula resistance to water paint to soak 6 hours, weigh after drying, weightening finish is 0；(2) the dry plank scribbling resistance to water of the present invention paint is soaked 12 hours its surfaces in water non-foaming；The plank scribbling resistance to water of the present invention paint is washed away under simulation heavy rain, washes away 4 hours rear surfaces still smooth。
Compared with existing waterproof paint, there is advantages that (1) resistance to water is high: (2) difficult drop-off: (3) uniformly have luminosity。
Detailed description of the invention
The present invention, in conjunction with specific examples below, further describes。
Embodiment 1
A kind of resistance to water paint, is made up of the raw material of following components by weight percent:
Thermoplastic acrylic resin 10 parts, isocyanates 6 parts, methyl methacrylate 8 parts, boiled wood oil 18 parts, vegetable wax 4 parts, toner pigment 2 parts, dispersant 0.2 part, ethanol 6 parts, emulsifying agent 2 parts, 6 parts of rosin, nano titanium oxide 4 parts, 1 part of antioxidant。
Wherein vegetable wax to be palm wax, dispersant be anti-loose colour dispersant 204S, emulsifying agent to be BYK-110, antioxidant be antioxidant MB, toner pigment select nano zine oxide, rhodamine, methyl orange, methylene blue or peacock green。
Embodiment 2
A kind of resistance to water paint, is made up of the raw material of following components by weight percent:
Epoxy resin 12 parts, isocyanates 5 parts, methyl methacrylate 10 parts, boiled wood oil 16 parts, vegetable wax 5 parts, toner pigment 4 parts, dispersant 0.3 part, ethanol 8 parts, emulsifying agent 2 parts, 8 parts of rosin, nano titanium oxide 3 parts, 0.8 part of antioxidant。
Wherein vegetable wax to be palm wax, dispersant be anti-loose colour dispersant 204S, emulsifying agent to be BYK-110, antioxidant be antioxidant MB, toner pigment select nano zine oxide, rhodamine, methyl orange, methylene blue or peacock green。
Embodiment 3
A kind of resistance to water paint, is made up of the raw material of following components by weight percent:
Thermoplastic acrylic resin 14 parts, isocyanates 6 parts, methyl methacrylate 10 parts, boiled wood oil 20 parts, vegetable wax 5 parts, toner pigment 5 parts, dispersant 0.4 part, ethanol 6 parts, emulsifying agent 3 parts, 8 parts of rosin, nano titanium oxide 5 parts, 1.2 parts of antioxidant。
Wherein vegetable wax to be palm wax, dispersant be anti-loose colour dispersant 204S, emulsifying agent to be BYK-110, antioxidant be antioxidant 1010, toner pigment select nano zine oxide, rhodamine, methyl orange, methylene blue or peacock green。
Embodiment 4
A kind of resistance to water paint, is made up of the raw material of following components by weight percent:
Epoxy resin 15 parts, isocyanates 7 parts, methyl methacrylate 8 parts, boiled wood oil 24 parts, vegetable wax 4 parts, toner pigment 3 parts, dispersant 0.5 part, ethanol 8 parts, emulsifying agent 2 parts, 6 parts of rosin, nano titanium oxide 6 parts, 1 part of antioxidant。
Wherein vegetable wax to be Caulis Sacchari sinensis, dispersant be anti-loose colour dispersant 204S, emulsifying agent to be BYK-110, antioxidant be antioxidant MB, toner pigment select nano zine oxide, rhodamine, methyl orange, methylene blue or peacock green。
Embodiment 5
A kind of resistance to water paint, is made up of the raw material of following components by weight percent:
Synthetic resin 12 parts, isocyanates 6 parts, methyl methacrylate 10 parts, boiled wood oil 24 parts, vegetable wax 6 parts, toner pigment 4 parts, dispersant 0.4 part, ethanol 9 parts, emulsifying agent 4 parts, 6 parts of rosin, nano titanium oxide 4 parts, 1.4 parts of antioxidant。
Wherein: synthetic resin is that thermoplastic acrylic resin mixes with epoxy resin equal proportion。
Wherein vegetable wax to be palm wax, dispersant be anti-loose colour dispersant 204S, emulsifying agent to be BYK-110, antioxidant be antioxidant MB, toner pigment select nano zine oxide, rhodamine, methyl orange, methylene blue or peacock green。
Embodiment 6
Take the plank being of a size of 10cm*10cm*1cm (long * width * is high), carry out resistance to water experiment, operate as follows:
(1) with polishing with 400 orders, 1000 order sand paper successively, deburring etc.；
(2) tiny wood flour is wiped with clean rag, paint stirring is uniform；
(3) use paintbrush brush thin layer paint on plank equably, dry；
(4) spray paint is repeated, homogeneous, there is certain thickness, dry and do not reduce to weight, weigh。
(5) resistance to water 1: the dry plank of resistance to water paint will be scribbled, be placed in water and soak 6 hours, weigh after drying, weight change before and after record。
Resistance to water 2: board surface bubbling degree after immersion 12h。
Resistance to water 3: be placed under current by plank after paint and wash away 4h, flow velocity 6m/s (simulation heavy rain), observes surface paint integrated degree。
By in embodiment of the present invention 1-5 prepare resistance to water paint carry out above-mentioned resistance to water experiment, result asTable 1 below。
Table 1Different paints resistance to water experiment effect
ByTable 1Result it can be seen that the paint of the present invention has good water resistance。
Embodiment 7
Take the plank being of a size of 10cm*10cm*1cm (long * width * high), the paint prepared by the paint on market and embodiment 3, carry out resistance to water experiment, according to the operation experiments of embodiment 6, result asTable 2 below。
Table 2Market paint and preparation paint resistance to water experiment effect
ByTable 2Result it can be seen that compare existing waterproof paint, each index of the paint water resistance of the present invention has good improvement。
The foregoing is only the case that is embodied as of patent of the present invention, but the technical characteristic of patent of the present invention is not limited thereto, any those skilled in the relevant art are in the field of the invention, and change or the modification made all are encompassed among the scope of the claims of the present invention。
Claims (9)
1. a resistance to water paint, it is characterised in that be made up of following raw material with parts by weight:
2. a resistance to water paint, it is characterised in that be made up of following raw material with parts by weight:
3. resistance to water according to claim 1 or claim 2 paint, it is characterised in that described synthetic resin is at least one in thermoplastic acrylic resin and epoxy resin。
4. resistance to water according to claim 1 or claim 2 paint, it is characterised in that vegetable wax is one or both in palm wax and Caulis Sacchari sinensis。
5. resistance to water according to claim 1 or claim 2 paint, it is characterised in that toner pigment is at least one in nano zine oxide, rhodamine B, methyl orange, methylene blue and peacock green。
6. resistance to water according to claim 1 or claim 2 paint, it is characterised in that nano titanium oxide is rutile crystal form nano titanium oxide。
7. resistance to water according to claim 1 or claim 2 paint, it is characterised in that antioxidant is antioxidant MB or antioxidant 1010。
8. resistance to water according to claim 1 or claim 2 paint, it is characterised in that described dispersant is anti-loose colour dispersant, poly-(methyl) acrylic compounds sodium salt or poly-(methyl) acrylic compounds ammonium salt。
9. resistance to water according to claim 1 or claim 2 paint, it is characterised in that described emulsifying agent is BYK-110 or epoxy resin emulsifying agent DisponilLS500。
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| CN108995457A (en) * | 2018-08-22 | 2018-12-14 | 安徽远锦文化环境艺术工程有限公司 | A kind of sculpture carving root art pedestal |
| CN110093085A (en) * | 2018-01-28 | 2019-08-06 | 吴军 | A kind of corrosion-resistant chemical pump surface lacquer and its application method |
| CN110093055A (en) * | 2018-01-28 | 2019-08-06 | 姚建珍 | One kind can quick-setting Teflon finishing coat and preparation method thereof |
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| CN105694563B (en) | 2018-05-11 |
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