CN110093055A - One kind can quick-setting Teflon finishing coat and preparation method thereof - Google Patents
One kind can quick-setting Teflon finishing coat and preparation method thereof Download PDFInfo
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- CN110093055A CN110093055A CN201810080943.8A CN201810080943A CN110093055A CN 110093055 A CN110093055 A CN 110093055A CN 201810080943 A CN201810080943 A CN 201810080943A CN 110093055 A CN110093055 A CN 110093055A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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Abstract
The invention discloses one kind can quick-setting Teflon finishing coat, including following component (by mass percentage): ptfe emulsion 20-25%, epoxy resin solution 15-20%, boiled wood oil 8-12%, dicyandiamide solution 6-9%, adipic dihydrazide 2.4-2.8%, polyether polyamine 2.2-2.5%, polymercaptan 1.8-2.4%, maleic anhydride 1.6-2.1%, extender pigment 4-8%, coloring pigment 5-9%, auxiliary agent are surplus;The invention also discloses it is a kind of can quick-setting Teflon finishing coat preparation method, comprising the following steps: ball milling screening, centrifugal filtration, carefully filtering, high agitation, ventilatory response, heating and cooling;Formula of the invention is more reasonable, the Teflon finishing coat, regular time can effectively be shortened, reduce it is cured need temperature so that the finishing coat processing in use, reducing difficulty of processing, save process time, and preparation method of the invention is more simple, and equipment requirement is low, has good promotion effect.
Description
Technical field
The present invention relates to Teflon finishing coat correlative technology field, in particular to one kind can quick-setting Teflon finishing coat and
Preparation method.
Background technique
Polytetrafluoroethylene (PTFE) (Polytetrafluoroethylene), english abbreviation PTFE (are commonly called as " King, Kazakhstan
Draw "), trade (brand) nameIn China, due to the reason of pronunciation, " Teflon " this trade mark is referred to as " Teflon again
Dragon ", " Teflon ", " Tie Fulong ", " Teflon ", " teflon " etc., it is all the transliteration of " Teflon ", the product of this material
Generally it is referred to as " non-sticking lining ";It is a kind of artificial synthesized macromolecule material for having used fluorine to replace all hydrogen atoms in polyethylene
Material.This material has the characteristics that antiacid alkali resistant, resists various organic solvents, is practically insoluble in all solvents.Meanwhile polytetrafluoro
Ethylene has the characteristics that resistant to high temperature, its coefficient of friction is extremely low, so can make lubricating action way, also becomes non-stick cooker and water
The ideal coating of inner tube layer.
Currently, although Teflon finishing coat available on the market has a lot of advantages, it is traditional using Teflon as former
Expect that the finishing coat of preparation, the fixative being added during the preparation process are difficult quick-setting effect, and generally existing solidification temperature
Excessively high and curing time longer disadvantage so that it in processing in use, increase difficulty of processing and waste process time, from
And improve processing cost.
Therefore, invent one kind can quick-setting Teflon finishing coat and preparation method thereof to solve the above problems have very much must
It wants.
Summary of the invention
The purpose of the present invention is to provide one kind can quick-setting Teflon finishing coat and preparation method thereof, it is above-mentioned to solve
The problem of being proposed in background technique.
To achieve the above object, the invention provides the following technical scheme: one kind can quick-setting Teflon finishing coat, including
Following component (by mass percentage): ptfe emulsion 20-25%, epoxy resin solution 15-20%, boiled wood oil 8-
12%, dicyandiamide solution 6-9%, adipic dihydrazide 2.4-2.8%, polyether polyamine 2.2-2.5%, polymercaptan 1.8-
2.4%, maleic anhydride 1.6-2.1%, extender pigment 4-8%, coloring pigment 5-9%, auxiliary agent are surplus.
Preferably, including following component (by mass percentage): ptfe emulsion 2%, epoxy resin solution 15%,
Boiled wood oil 8%, dicyandiamide solution 6%, adipic dihydrazide 2.4%, polyether polyamine 2.2%, polymercaptan 1.8%, maleic
Dicarboxylic anhydride 1.6%, extender pigment 4%, coloring pigment 5%, auxiliary agent are surplus.
Preferably, including following component (by mass percentage): ptfe emulsion 22%, epoxy resin solution
18%, boiled wood oil 10%, dicyandiamide solution 7%, adipic dihydrazide 2.6%, polyether polyamine 2.4%, polymercaptan 2.2%,
Maleic anhydride 1.9%, extender pigment 6%, coloring pigment 7%, auxiliary agent are surplus.
Preferably, including following component (by mass percentage): ptfe emulsion 25%, epoxy resin solution
20%, boiled wood oil 12%, dicyandiamide solution 9%, adipic dihydrazide 2.8%, polyether polyamine 2.5%, polymercaptan 2.4%,
Maleic anhydride 2.1%, extender pigment 8%, coloring pigment 9%, auxiliary agent are surplus.
Preferably, the auxiliary agent includes tackifier 35%, dispersing agent 35% and defoaming agent 30%, and the tackifier are
DINP, the dispersing agent are BYK-190, and the defoaming agent is 104E.
Preferably, the extender pigment is made of 45% silica flour and 55% barium sulfate, and the coloring pigment is by silver powder
50% and pearl powder 50% form.
It is a kind of can quick-setting Teflon finishing coat preparation method, comprising the following steps:
Step 1: weighing a certain amount of adipic dihydrazide and maleic anhydride, is placed individually into ball milling in ball mill
40-60 minutes, revolving speed 50-60r/min, -1000 mesh sieve of 600 mesh was crossed after ball milling and is screened, mixes the two after screening
It closes, obtains mixture A;
Step 2: dicyandiamide solution, polyether polyamine and polymercaptan is taken to mix 20-30 points of merga pass high-speed mixer stirring
Clock is filtered after stirring using filter centrifugal, is heated to 45-60 DEG C in filtered fluid investment heating equipment, is taken out
To mixture B;
Step 3: mixture B is poured into mixture A obtained in step 1, uses 35-45 points of high-speed mixer stirring
Then clock reuses filter plant and is carefully filtered, mixed type fixative is obtained after filtering;
Step 4: taking ptfe emulsion, epoxy resin solution and boiled wood oil to pour into high-speed stirred cylinder, first with 300-
The mixing speed of 400rpm is sufficiently stirred 5-10 minutes, and tackifier, dispersing agent are then sequentially added into high-speed stirred cylinder and is disappeared
Infusion is then sufficiently stirred 15-20 minutes using the mixing speed of 1650-1750rpm, after high degree of dispersion, uses high fineness
It is 5.5-6 μm that horizontal sand mill, which is ground to fineness, obtains mixture C;
Step 5: pouring into sealing bucket to mixture C obtained in step 4, then sequentially adds constitution into sealing bucket
Pigment and coloring pigment are simultaneously sufficiently stirred, and will then be sealed with vacuum air pump and are extracted into vacuum state in bucket, and into sealing bucket
It is passed through 5-8% carbon dioxide gas precursor reactant 30-50 minutes, obtains mixture D;
Step 6: mixed type fixative obtained in step 3 is added in mixture D, is used using high-speed mixer
The mixing speed of 1650-1750rpm is sufficiently stirred 25-35 minutes, then puts into steam oven and is heated, and heating temperature is
155-170 degrees Celsius, heating time is 15-25 minutes, is taken out after heating, is placed on 18-25 DEG C of 60- cooling at room temperature
80 minutes, Teflon finishing coat can be obtained.
Technical effect and advantage of the invention: formula of the invention is more reasonable, the Teflon finishing coat, by with poly- four
Vinyl fluoride lotion and epoxy resin solution are primary raw material, and dicyandiamide solution, adipic dihydrazide, polyether polyols is added in cooperation
Amine, polymercaptan and maleic anhydride can effectively shorten regular time, reduce it is cured need temperature so that
The finishing coat in use, reduce difficulty of processing, saves process time, and preparation method of the invention is more simple in processing
Single, equipment requirement is low, has good promotion effect.
Present invention process is simple, and equipment requirement is low, strong operability, has good society generalization application.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
Embodiment one:
One kind can quick-setting Teflon finishing coat, including following component (by mass percentage): ptfe emulsion
2%, epoxy resin solution 15%, boiled wood oil 8%, dicyandiamide solution 6%, adipic dihydrazide 2.4%, polyether polyamine
2.2%, polymercaptan 1.8%, maleic anhydride 1.6%, extender pigment 4%, coloring pigment 5%, auxiliary agent are surplus.
Further, auxiliary agent includes tackifier 35%, dispersing agent 35% and defoaming agent 30%, tackifier DINP, dispersion
Agent is BYK-190, defoaming agent 104E.
Further, extender pigment is made of 45% silica flour and 55% barium sulfate, and coloring pigment is by silver powder 50% and pearl
Light powder 50% forms.
It is a kind of can quick-setting Teflon finishing coat preparation method, comprising the following steps:
Step 1: weighing a certain amount of adipic dihydrazide and maleic anhydride, is placed individually into ball milling in ball mill
40 minutes, revolving speed 50r/min, 600 mesh sieve were crossed after ball milling and are screened, the two is mixed after screening, obtains mixture
A;
Step 2: taking dicyandiamide solution, polyether polyamine and polymercaptan to mix merga pass high-speed mixer and stir 20 minutes,
It is filtered after stirring using filter centrifugal, is heated to 45 DEG C in filtered fluid investment heating equipment, taking-up is mixed
Expect B;
Step 3: mixture B is poured into mixture A obtained in step 1, is stirred 35 minutes using high-speed mixer,
Then it reuses filter plant carefully to be filtered, mixed type fixative is obtained after filtering;
Step 4: taking ptfe emulsion, epoxy resin solution and boiled wood oil to pour into high-speed stirred cylinder, first with
The mixing speed of 300rpm is sufficiently stirred 5 minutes, and tackifier, dispersing agent and defoaming are then sequentially added into high-speed stirred cylinder
Agent is then sufficiently stirred 15 minutes using the mixing speed of 1650rpm, after high degree of dispersion, uses high fineness horizontal sand mill
Being ground to fineness is 5.5 μm, obtains mixture C;
Step 5: pouring into sealing bucket to mixture C obtained in step 4, then sequentially adds constitution into sealing bucket
Pigment and coloring pigment are simultaneously sufficiently stirred, and will then be sealed with vacuum air pump and are extracted into vacuum state in bucket, and into sealing bucket
It is passed through 5% carbon dioxide gas precursor reactant 30 minutes, obtains mixture D;
Step 6: mixed type fixative obtained in step 3 is added in mixture D, is used using high-speed mixer
The mixing speed of 1650rpm is sufficiently stirred 25 minutes, then puts into steam oven and is heated, and heating temperature is 155 Celsius
Degree, heating time be 15 minutes, taken out after heating, be placed on 18 DEG C at room temperature cool down 60 minutes, Teflon can be obtained
Imperial finishing coat.
Embodiment two:
One kind can quick-setting Teflon finishing coat, including following component (by mass percentage): ptfe emulsion
22%, epoxy resin solution 18%, boiled wood oil 10%, dicyandiamide solution 7%, adipic dihydrazide 2.6%, polyether polyamine
2.4%, polymercaptan 2.2%, maleic anhydride 1.9%, extender pigment 6%, coloring pigment 7%, auxiliary agent are surplus.
Further, auxiliary agent includes tackifier 35%, dispersing agent 35% and defoaming agent 30%, tackifier DINP, dispersion
Agent is BYK-190, defoaming agent 104E.
Further, extender pigment is made of 45% silica flour and 55% barium sulfate, and coloring pigment is by silver powder 50% and pearl
Light powder 50% forms.
It is a kind of can quick-setting Teflon finishing coat preparation method, comprising the following steps:
Step 1: weighing a certain amount of adipic dihydrazide and maleic anhydride, is placed individually into ball milling in ball mill
50 minutes, revolving speed 55r/min, 800 mesh sieve were crossed after ball milling and are screened, the two is mixed after screening, obtains mixture
A;
Step 2: taking dicyandiamide solution, polyether polyamine and polymercaptan to mix merga pass high-speed mixer and stir 25 minutes,
It is filtered after stirring using filter centrifugal, is heated to 55 DEG C in filtered fluid investment heating equipment, taking-up is mixed
Expect B;
Step 3: mixture B is poured into mixture A obtained in step 1, is stirred 40 minutes using high-speed mixer,
Then it reuses filter plant carefully to be filtered, mixed type fixative is obtained after filtering;
Step 4: taking ptfe emulsion, epoxy resin solution and boiled wood oil to pour into high-speed stirred cylinder, first with
The mixing speed of 350rpm is sufficiently stirred 7 minutes, and tackifier, dispersing agent and defoaming are then sequentially added into high-speed stirred cylinder
Agent is then sufficiently stirred 18 minutes using the mixing speed of 1700rpm, after high degree of dispersion, uses high fineness horizontal sand mill
Being ground to fineness is 5.8 μm, obtains mixture C;
Step 5: pouring into sealing bucket to mixture C obtained in step 4, then sequentially adds constitution into sealing bucket
Pigment and coloring pigment are simultaneously sufficiently stirred, and will then be sealed with vacuum air pump and are extracted into vacuum state in bucket, and into sealing bucket
It is passed through 6% carbon dioxide gas precursor reactant 40 minutes, obtains mixture D;
Step 6: mixed type fixative obtained in step 3 is added in mixture D, is used using high-speed mixer
The mixing speed of 1700rpm is sufficiently stirred 30 minutes, then puts into steam oven and is heated, and heating temperature is 165 Celsius
Degree, heating time be 20 minutes, taken out after heating, be placed on 22 DEG C at room temperature cool down 70 minutes, Teflon can be obtained
Imperial finishing coat.
Embodiment three:
One kind can quick-setting Teflon finishing coat, including following component (by mass percentage): ptfe emulsion
25%, epoxy resin solution 20%, boiled wood oil 12%, dicyandiamide solution 9%, adipic dihydrazide 2.8%, polyether polyamine
2.5%, polymercaptan 2.4%, maleic anhydride 2.1%, extender pigment 8%, coloring pigment 9%, auxiliary agent are surplus.
Further, auxiliary agent includes tackifier 35%, dispersing agent 35% and defoaming agent 30%, tackifier DINP, dispersion
Agent is BYK-190, defoaming agent 104E.
Further, extender pigment is made of 45% silica flour and 55% barium sulfate, and coloring pigment is by silver powder 50% and pearl
Light powder 50% forms.
It is a kind of can quick-setting Teflon finishing coat preparation method, comprising the following steps:
Step 1: weighing a certain amount of adipic dihydrazide and maleic anhydride, is placed individually into ball milling in ball mill
60 minutes, revolving speed 60r/min, 1000 mesh sieve were crossed after ball milling and are screened, the two is mixed after screening, obtains mixture
A;
Step 2: taking dicyandiamide solution, polyether polyamine and polymercaptan to mix merga pass high-speed mixer and stir 30 minutes,
It is filtered after stirring using filter centrifugal, is heated to 60 DEG C in filtered fluid investment heating equipment, taking-up is mixed
Expect B;
Step 3: mixture B is poured into mixture A obtained in step 1, is stirred 45 minutes using high-speed mixer,
Then it reuses filter plant carefully to be filtered, mixed type fixative is obtained after filtering;
Step 4: taking ptfe emulsion, epoxy resin solution and boiled wood oil to pour into high-speed stirred cylinder, first with
The mixing speed of 400rpm is sufficiently stirred 10 minutes, and tackifier, dispersing agent and defoaming are then sequentially added into high-speed stirred cylinder
Agent is then sufficiently stirred 20 minutes using the mixing speed of 1750rpm, after high degree of dispersion, uses high fineness horizontal sand mill
Being ground to fineness is 6 μm, obtains mixture C;
Step 5: pouring into sealing bucket to mixture C obtained in step 4, then sequentially adds constitution into sealing bucket
Pigment and coloring pigment are simultaneously sufficiently stirred, and will then be sealed with vacuum air pump and are extracted into vacuum state in bucket, and into sealing bucket
It is passed through 8% carbon dioxide gas precursor reactant 50 minutes, obtains mixture D;
Step 6: mixed type fixative obtained in step 3 is added in mixture D, is used using high-speed mixer
The mixing speed of 1750rpm is sufficiently stirred 35 minutes, then puts into steam oven and is heated, and heating temperature is 170 Celsius
Degree, heating time be 25 minutes, taken out after heating, be placed on 25 DEG C at room temperature cool down 80 minutes, Teflon can be obtained
Imperial finishing coat.
By above three groups of embodiments can be made can quick-setting Teflon finishing coat, and formula of the invention is more
What is added is reasonable, the Teflon finishing coat, by the way that using ptfe emulsion and epoxy resin solution as primary raw material, cooperation is added double
Cyanamide solution, adipic dihydrazide, polyether polyamine, polymercaptan and maleic anhydride can be shortened effectively fixed
Time, reduce it is cured need temperature so that the finishing coat processing in use, difficulty of processing is reduced, when saving processing
Between, and preparation method of the invention is more simple, and equipment requirement is low, has good promotion effect.
Finally, it should be noted that the foregoing is only a preferred embodiment of the present invention, it is not intended to restrict the invention,
Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used
To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features,
All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention
Within protection scope.
Claims (7)
1. one kind can quick-setting Teflon finishing coat, which is characterized in that including following component (by mass percentage): polytetrafluoro
Vac emulsion 20-25%, epoxy resin solution 15-20%, boiled wood oil 8-12%, dicyandiamide solution 6-9%, adipic dihydrazide
2.4-2.8%, polyether polyamine 2.2-2.5%, polymercaptan 1.8-2.4%, maleic anhydride 1.6-2.1%, extender pigment
4-8%, coloring pigment 5-9%, auxiliary agent are surplus.
2. one kind according to claim 1 can quick-setting Teflon finishing coat, which is characterized in that including following component
(by mass percentage): ptfe emulsion 2%, epoxy resin solution 15%, boiled wood oil 8%, dicyandiamide solution 6%, oneself
Dihydrazi 2.4%, polyether polyamine 2.2%, polymercaptan 1.8%, maleic anhydride 1.6%, extender pigment 4%,
Color pigment 5%, auxiliary agent are surplus.
3. one kind according to claim 1 can quick-setting Teflon finishing coat, which is characterized in that including following component
(by mass percentage): ptfe emulsion 22%, epoxy resin solution 18%, boiled wood oil 10%, dicyandiamide solution 7%,
Adipic dihydrazide 2.6%, polyether polyamine 2.4%, polymercaptan 2.2%, maleic anhydride 1.9%, extender pigment 6%,
Coloring pigment 7%, auxiliary agent are surplus.
4. one kind according to claim 1 can quick-setting Teflon finishing coat, which is characterized in that including following component
(by mass percentage): ptfe emulsion 25%, epoxy resin solution 20%, boiled wood oil 12%, dicyandiamide solution 9%,
Adipic dihydrazide 2.8%, polyether polyamine 2.5%, polymercaptan 2.4%, maleic anhydride 2.1%, extender pigment 8%,
Coloring pigment 9%, auxiliary agent are surplus.
5. one kind according to claim 1 can quick-setting Teflon finishing coat, it is characterised in that: the auxiliary agent includes increasing
Stick 35%, dispersing agent 35% and defoaming agent 30%, the tackifier are DINP, and the dispersing agent is BYK-190, the defoaming
Agent is 104E.
6. one kind according to claim 1 can quick-setting Teflon finishing coat, it is characterised in that: the extender pigment by
45% silica flour and 55% barium sulfate composition, the coloring pigment are made of silver powder 50% and pearl powder 50%.
7. it is a kind of as described in claim 1-6 can quick-setting Teflon finishing coat preparation method, which is characterized in that including
Following steps:
Step 1: weighing a certain amount of adipic dihydrazide and maleic anhydride, is placed individually into ball milling 40-60 in ball mill
Minute, revolving speed 50-60r/min crosses -1000 mesh sieve of 600 mesh after ball milling and is screened, mixes the two after screening, obtain
To mixture A;
Step 2: taking dicyandiamide solution, polyether polyamine and polymercaptan to mix merga pass high-speed mixer and stir 20-30 minutes,
It is filtered after stirring using filter centrifugal, is heated to 45-60 DEG C in filtered fluid investment heating equipment, taking-up is mixed
Close material B;
Step 3: mixture B is poured into mixture A obtained in step 1, is stirred 35-45 minutes using high-speed mixer,
Then it reuses filter plant carefully to be filtered, mixed type fixative is obtained after filtering;
Step 4: taking ptfe emulsion, epoxy resin solution and boiled wood oil to pour into high-speed stirred cylinder, first with 300-
The mixing speed of 400rpm is sufficiently stirred 5-10 minutes, and tackifier, dispersing agent are then sequentially added into high-speed stirred cylinder and is disappeared
Infusion is then sufficiently stirred 15-20 minutes using the mixing speed of 1650-1750rpm, after high degree of dispersion, uses high fineness
It is 5.5-6 μm that horizontal sand mill, which is ground to fineness, obtains mixture C;
Step 5: pouring into sealing bucket to mixture C obtained in step 4, then sequentially adds extender pigment into sealing bucket
With coloring pigment and be sufficiently stirred, will then be sealed with vacuum air pump and be extracted into vacuum state in bucket, and be passed through into sealing bucket
5-8% carbon dioxide gas precursor reactant 30-50 minutes, obtains mixture D;
Step 6: mixed type fixative obtained in step 3 is added in mixture D, is used using high-speed mixer
The mixing speed of 1650-1750rpm is sufficiently stirred 25-35 minutes, then puts into steam oven and is heated, and heating temperature is
155-170 degrees Celsius, heating time is 15-25 minutes, is taken out after heating, is placed on 18-25 DEG C of 60- cooling at room temperature
80 minutes, Teflon finishing coat can be obtained.
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CN201810080943.8A CN110093055A (en) | 2018-01-28 | 2018-01-28 | One kind can quick-setting Teflon finishing coat and preparation method thereof |
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CN106634454A (en) * | 2016-09-30 | 2017-05-10 | 合肥华运机械制造有限公司 | Oil paint for chemical industry pump shell surface |
US20170253760A1 (en) * | 2014-07-01 | 2017-09-07 | Arkema Inc. | Stable aqueous fluoropolymer coating composition |
CN107629572A (en) * | 2017-09-21 | 2018-01-26 | 金华大荣涂料有限公司 | A kind of oiliness teflon non-stick coating and its manufacture method |
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2018
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CN103911050A (en) * | 2014-03-19 | 2014-07-09 | 浙江歌瑞新材料有限公司 | Teflon coating, its preparation method and application thereof |
US20170253760A1 (en) * | 2014-07-01 | 2017-09-07 | Arkema Inc. | Stable aqueous fluoropolymer coating composition |
CN104073086A (en) * | 2014-07-27 | 2014-10-01 | 广西梧州龙鱼漆业有限公司 | Teflon finishing coat |
CN105238227A (en) * | 2015-11-25 | 2016-01-13 | 湖南沃特邦恩新材料有限公司 | Waterborne epoxy impregnating insulating varnish and preparation method thereof |
CN105504122A (en) * | 2015-12-10 | 2016-04-20 | 海南大学 | Preparation method of novel epoxy resin curing agent |
CN105694563A (en) * | 2016-03-30 | 2016-06-22 | 浙江宠悦工贸有限公司 | Water-resistant paint |
CN106634454A (en) * | 2016-09-30 | 2017-05-10 | 合肥华运机械制造有限公司 | Oil paint for chemical industry pump shell surface |
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