CN107190358A - A kind of environment-friendly antibacterial anti-radiation garment fabric - Google Patents

A kind of environment-friendly antibacterial anti-radiation garment fabric Download PDF

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Publication number
CN107190358A
CN107190358A CN201710522506.2A CN201710522506A CN107190358A CN 107190358 A CN107190358 A CN 107190358A CN 201710522506 A CN201710522506 A CN 201710522506A CN 107190358 A CN107190358 A CN 107190358A
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CN
China
Prior art keywords
parts
fiber
environment
radiation
antibacterial anti
Prior art date
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Pending
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CN201710522506.2A
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Chinese (zh)
Inventor
张红桥
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hongqiao Taicang Garments Co Ltd
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Hongqiao Taicang Garments Co Ltd
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Priority to CN201710522506.2A priority Critical patent/CN107190358A/en
Publication of CN107190358A publication Critical patent/CN107190358A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D13/00Complete machines for producing artificial threads
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/103Agents inhibiting growth of microorganisms
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/106Radiation shielding agents, e.g. absorbing, reflecting agents
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/02Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The present invention provides a kind of environment-friendly antibacterial anti-radiation garment fabric, the garment material is made into fabric body using antibiotic radiation proof fiber as yarn, gained fabric body is dyed and post-processes to obtain garment material finished product, and the antibiotic radiation proof fiber includes the composition of following parts by weight:Bamboo-carbon fibre:20 ~ 30 parts, graphene-based carbon nano-fiber:5 ~ 10 parts, nanometer silver antimicrobial master batch:20 ~ 30 parts, silk fiber:15 ~ 20 parts, methylcellulose:10 ~ 20 parts, chitosan:5 ~ 10 parts, stearmide:5 ~ 10 parts, water-soluble binder:5 ~ 10 parts.The garment material uses special antibiotic radiation proof fiber, assigns fabric excellent antibiotic radiation proof performance, and antibiotic radiation proof fibre composition is reasonable in design, and preparation cost is low, good in economic efficiency.

Description

A kind of environment-friendly antibacterial anti-radiation garment fabric
Technical field
The invention belongs to garment material technical field, in particular it relates to a kind of environment-friendly antibacterial anti-radiation garment fabric.
Background technology
Clothes are made with fabric, and fabric is exactly the material for making clothes.It is used as one of clothes three elements, fabric Can not only annotate the style and characteristic of clothes, and directly left and right the color of clothes, the expression effect of moulding.Presentation is come from The noble quality of body is perfect, soft.
Modern times are produced on the clothes of formal social life institute wear, many blended yarn weaved fabrics from high-quality.And it is pure cotton, pure The natural fabric such as hair, pure silk, pure fiber crops has become general cloth because there is the easily natural fabric such as wrinkle, yielding, compared with It is few to be used as high-grade clothing materials.Blended yarn weaved fabric has natural fabric sweat-absorbing breathable, it is soft comfortable the characteristics of, chemical fibre face is absorbed again Material is solid to wear well, overhangs the advantages of well-pressed, good luster color is vivid, has substantial amounts of high-grade high-quality blended yarn weaved fabric to be developed every year Come.
Intelligence is ground data research centre data and shown:Price of the cotton goes up to cause entirely to produce chain cost and increased, and produce chain one is Row product has to appreciate, and has exactly expedited the emergence of the new opportunity of apparel industry fabric, and the upgrading scapegoat zein fiber of cotton, bamboo are fine Dimension, novel plant flaxen fiber etc. come on stage with glittering appearance, and these bio-based fabrics more save water and agricultural chemicals, symbol in process of production than cotton Close the demand of consumer or even the whole society to low-carbon environment-friendly.
For garment surface flitch, the current country is primarily present following patent document:
China Patent Publication No.:CN106820369A, discloses radiation-proof fabric, it is characterised in that:It includes top layer (101), the first precoat(102)With the second precoat(103), second precoat(103)Outer surface covered with first Precoat(102), first precoat(102)Outer surface covers top layer(101), first precoat(102)With second Precoat(103)Between accompany wire netting.Radiation-proof fabric of the present invention is by increasing SEE lifes between outer shell fabric and lining fabric State cotton, using fabric there is biodegradable, energy-conservation to change row, it is environmental and ecological the features such as, be a kind of preferable environmental protection thermal surface Material.However, the radiation-proof fabric that the patent is provided, simple in construction, the only simple superposition of precoat, radiation-proof effect It is undesirable.
The content of the invention
To solve above-mentioned problem, it is an object of the invention to provide a kind of environment-friendly antibacterial anti-radiation garment fabric, The garment material uses special antibiotic radiation proof fiber, assigns fabric excellent antibiotic radiation proof performance, and the anti-spoke of antibacterial Penetrate fibre composition reasonable in design, preparation cost is low, good in economic efficiency.
To reach above-mentioned purpose, the technical scheme is that:
A kind of environment-friendly antibacterial anti-radiation garment fabric, the garment material is made into fabric sheet by yarn of antibiotic radiation proof fiber Body, gained fabric body is dyed and post-processes to obtain garment material finished product, and the antibiotic radiation proof fiber includes following weight The composition of part:Bamboo-carbon fibre:20 ~ 30 parts, graphene-based carbon nano-fiber:5 ~ 10 parts, nanometer silver antimicrobial master batch:20 ~ 30 parts, silkworm Silk fiber:15 ~ 20 parts, methylcellulose:10 ~ 20 parts, chitosan:5 ~ 10 parts, stearmide:5 ~ 10 parts, water-soluble binder: 5 ~ 10 parts.
Further, the antibiotic radiation proof fiber includes the composition of following parts by weight:Bamboo-carbon fibre:25 ~ 30 parts, graphene Base carbon nano-fiber:5 ~ 8 parts, nanometer silver antimicrobial master batch:20 ~ 25 parts, silk fiber:15 ~ 17 parts, methylcellulose:15~20 Part, chitosan:8 ~ 10 parts, stearmide:5 ~ 7 parts, water-soluble binder:7 ~ 10 parts.
Preferably, the antibiotic radiation proof fiber includes the composition of following parts by weight:Bamboo-carbon fibre:It is 25 parts, graphene-based Carbon nano-fiber:7 parts, nanometer silver antimicrobial master batch:25 parts, silk fiber:16 parts, methylcellulose:15 parts, chitosan:8 parts, Stearmide:7 parts, water-soluble binder:7 parts.
Preferably, the nanometer silver antimicrobial master batch includes the composition of following parts by weight:Nano-Ag particles:20 ~ 30 parts, carry Body:10 ~ 15 parts, polyester slice:30 ~ 40 parts, coupling agent:5 ~ 10 parts, dispersant:5 ~ 10 parts.
Preferably, the nanometer silver antimicrobial agglomerate preparation method comprises the following steps:Nano-Ag particles and carrier are reacted, Make nano-Ag particles uniform adsorption into carrier, then with coupling agent and dispersant and being added in high-speed mixer, 180 At ~ 220 DEG C, mixer inner screw rotating speed is 200 ~ 300 revs/min, is kneaded 30 ~ 50 minutes, obtains powder, then by powder and with gathering The extrusion of the mixed merga pass double screw extruder of ester section, shaping, pelletizing, obtain the nanometer silver antimicrobial master batch.
Preferably, the polyester slice is cut into slices for PBT.
Preferably, the carrier is particular type zeolite or SiO2
Preferably, the dispersant is AEO, APES, aliphatic acid polyethenoxy ether Or tristerin.
Preferably, the coupling agent is monoalkoxytitanates, monoalkoxy vinethene or many alkoxy vinyl ethers.
Preferably, the antibiotic radiation proof fiber producing processes comprise the following steps:Bamboo-carbon fibre, graphene-based carbon are received Rice fiber, silk fiber are uniformly mixed, and add nanometer silver antimicrobial master batch, methylcellulose, chitosan, stearmide, water solubility Adhesive, stirring, blending, is added in screw extruder and carries out melt extruded, the melt fully melted is passed through into melt pipe It is transported in spinning manifold, 270 ~ 300 DEG C of manifold spinning temperature, 2500 ~ 3500m/min of spinning speed, afterwards from spinning head Spray orifice in extrude, tow carries out cooled and solidified into silk, Ran Houfang in the crosswind that temperature is 18-20 DEG C, humidity is 58 ~ 60% Enter and 20 ~ 25min is boiled in boiling water, take out drying, you can obtain the antibiotic radiation proof fiber.
The beneficial effects of the present invention are:
The garment material uses special antibiotic radiation proof fiber, assigns fabric excellent antibiotic radiation proof performance, and antibacterial Rationally, preparation cost is low, good in economic efficiency for radiation resistant fiber composition design.
Embodiment
Below by specific embodiment, the present invention is described further, but embodiment is not intended to limit the protection of the present invention Scope.
A kind of environment-friendly antibacterial anti-radiation garment fabric of the present invention, the garment material using antibiotic radiation proof fiber as Yarn is made into fabric body, and gained fabric body is dyed and post-processes to obtain garment material finished product, and the antibiotic radiation proof is fine Dimension includes the composition of following parts by weight:Bamboo-carbon fibre:20 ~ 30 parts, graphene-based carbon nano-fiber:5 ~ 10 parts, nanometer silver antimicrobial Master batch:20 ~ 30 parts, silk fiber:15 ~ 20 parts, methylcellulose:10 ~ 20 parts, chitosan:5 ~ 10 parts, stearmide:5~10 Part, water-soluble binder:5 ~ 10 parts.
Further, the antibiotic radiation proof fiber includes the composition of following parts by weight:Bamboo-carbon fibre:25 ~ 30 parts, graphene Base carbon nano-fiber:5 ~ 8 parts, nanometer silver antimicrobial master batch:20 ~ 25 parts, silk fiber:15 ~ 17 parts, methylcellulose:15~20 Part, chitosan:8 ~ 10 parts, stearmide:5 ~ 7 parts, water-soluble binder:7 ~ 10 parts.
Preferably, the antibiotic radiation proof fiber includes the composition of following parts by weight:Bamboo-carbon fibre:It is 25 parts, graphene-based Carbon nano-fiber:7 parts, nanometer silver antimicrobial master batch:25 parts, silk fiber:16 parts, methylcellulose:15 parts, chitosan:8 parts, Stearmide:7 parts, water-soluble binder:7 parts.
Preferably, the nanometer silver antimicrobial master batch includes the composition of following parts by weight:Nano-Ag particles:20 ~ 30 parts, carry Body:10 ~ 15 parts, polyester slice:30 ~ 40 parts, coupling agent:5 ~ 10 parts, dispersant:5 ~ 10 parts.
Preferably, the nanometer silver antimicrobial agglomerate preparation method comprises the following steps:Nano-Ag particles and carrier are reacted, Make nano-Ag particles uniform adsorption into carrier, then with coupling agent and dispersant and being added in high-speed mixer, 180 At ~ 220 DEG C, mixer inner screw rotating speed is 200 ~ 300 revs/min, is kneaded 30 ~ 50 minutes, obtains powder, then by powder and with gathering The extrusion of the mixed merga pass double screw extruder of ester section, shaping, pelletizing, obtain the nanometer silver antimicrobial master batch.
Preferably, the polyester slice is cut into slices for PBT.
Preferably, the carrier is particular type zeolite or SiO2
Preferably, the dispersant is AEO, APES, aliphatic acid polyethenoxy ether Or tristerin.
Preferably, the coupling agent is monoalkoxytitanates, monoalkoxy vinethene or many alkoxy vinyl ethers.
Preferably, the antibiotic radiation proof fiber producing processes comprise the following steps:Bamboo-carbon fibre, graphene-based carbon are received Rice fiber, silk fiber are uniformly mixed, and add nanometer silver antimicrobial master batch, methylcellulose, chitosan, stearmide, water solubility Adhesive, stirring, blending, is added in screw extruder and carries out melt extruded, the melt fully melted is passed through into melt pipe It is transported in spinning manifold, 270 ~ 300 DEG C of manifold spinning temperature, 2500 ~ 3500m/min of spinning speed, afterwards from spinning head Spray orifice in extrude, tow carries out cooled and solidified into silk, Ran Houfang in the crosswind that temperature is 18-20 DEG C, humidity is 58 ~ 60% Enter and 20 ~ 25min is boiled in boiling water, take out drying, you can obtain the antibiotic radiation proof fiber.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the technology of invention Scheme is modified or equivalent substitution, and without departing from the scope of technical solution of the present invention, it all should cover the power in the present invention In sharp claimed range.

Claims (10)

1. a kind of environment-friendly antibacterial anti-radiation garment fabric, it is characterised in that the garment material is using antibiotic radiation proof fiber as yarn Line is made into fabric body, and gained fabric body is dyed and post-processes to obtain garment material finished product, the antibiotic radiation proof fiber Include the composition of following parts by weight:Bamboo-carbon fibre:20 ~ 30 parts, graphene-based carbon nano-fiber:5 ~ 10 parts, nanometer silver antimicrobial is female Grain:20 ~ 30 parts, silk fiber:15 ~ 20 parts, methylcellulose:10 ~ 20 parts, chitosan:5 ~ 10 parts, stearmide:5 ~ 10 parts, Water-soluble binder:5 ~ 10 parts.
2. a kind of environment-friendly antibacterial anti-radiation garment fabric according to claim 1, it is characterised in that the antibiotic radiation proof Fiber includes the composition of following parts by weight:Bamboo-carbon fibre:25 ~ 30 parts, graphene-based carbon nano-fiber:5 ~ 8 parts, nanometer silver antimicrobial Master batch:20 ~ 25 parts, silk fiber:15 ~ 17 parts, methylcellulose:15 ~ 20 parts, chitosan:8 ~ 10 parts, stearmide:5~7 Part, water-soluble binder:7 ~ 10 parts.
3. a kind of environment-friendly antibacterial anti-radiation garment fabric according to claim 1, it is characterised in that the antibiotic radiation proof Fiber includes the composition of following parts by weight:Bamboo-carbon fibre:25 parts, graphene-based carbon nano-fiber:7 parts, nanometer silver antimicrobial master batch: 25 parts, silk fiber:16 parts, methylcellulose:15 parts, chitosan:8 parts, stearmide:7 parts, water-soluble binder:7 parts.
4. a kind of environment-friendly antibacterial anti-radiation garment fabric according to any one of claim 1 ~ 3, it is characterised in that described Nanometer silver antimicrobial master batch includes the composition of following parts by weight:Nano-Ag particles:20 ~ 30 parts, carrier:10 ~ 15 parts, polyester slice: 30 ~ 40 parts, coupling agent:5 ~ 10 parts, dispersant:5 ~ 10 parts.
5. a kind of environment-friendly antibacterial anti-radiation garment fabric according to claim 4, it is characterised in that the nanometer silver antimicrobial Agglomerate preparation method comprises the following steps:Nano-Ag particles and carrier are reacted, make nano-Ag particles uniform adsorption into carrier, Again with coupling agent and dispersant and being added in high-speed mixer, at 180 ~ 220 DEG C, mixer inner screw rotating speed is 200 ~ 300 revs/min, knead 30 ~ 50 minutes, obtain powder, then merga pass twin-screw extrusion is mixed by powder and with polyester slice The extrusion of machine, shaping, pelletizing, obtain the nanometer silver antimicrobial master batch.
6. a kind of environment-friendly antibacterial anti-radiation garment fabric according to claim 4, it is characterised in that the polyester slice is PBT cuts into slices.
7. a kind of environment-friendly antibacterial anti-radiation garment fabric according to claim 4, it is characterised in that the carrier is special type Zeolite or SiO2
8. a kind of environment-friendly antibacterial anti-radiation garment fabric according to claim 4, it is characterised in that the dispersant is fat Fat alcohol APEO, APES, aliphatic acid polyethenoxy ether or tristerin.
9. a kind of environment-friendly antibacterial anti-radiation garment fabric according to claim 4, it is characterised in that the coupling agent is single Alkoxy titanates, monoalkoxy vinethene or many alkoxy vinyl ethers.
10. a kind of environment-friendly antibacterial anti-radiation garment fabric according to claim 1, it is characterised in that the anti-spoke of antibacterial Fiber producing processes are penetrated to comprise the following steps:Bamboo-carbon fibre, graphene-based carbon nano-fiber, silk fiber are uniformly mixed, plus Enter nanometer silver antimicrobial master batch, methylcellulose, chitosan, stearmide, water-soluble binder, stirring, blending are added to screw rod Melt extruded is carried out in extruder, the melt fully melted is transported in spinning manifold by melt pipe, manifold spinning 270 ~ 300 DEG C of temperature, 2500 ~ 3500m/min of spinning speed is extruded from the spray orifice of spinning head afterwards, and tow is 18- in temperature 20 DEG C, humidity for 58 ~ 60% crosswind in carry out cooled and solidified into silk, be then placed in boiling water and boil 20 ~ 25min, take out drying, It can obtain the antibiotic radiation proof fiber.
CN201710522506.2A 2017-06-30 2017-06-30 A kind of environment-friendly antibacterial anti-radiation garment fabric Pending CN107190358A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108085832A (en) * 2017-12-21 2018-05-29 河南新野纺织股份有限公司 A kind of graphene radiation resistant fiber yarn fabric
CN108560072A (en) * 2018-03-30 2018-09-21 湖州益科纺织科技有限公司 Antiseptic health care fiber silk and preparation method thereof
CN108998846A (en) * 2018-08-10 2018-12-14 苏州郎旭志远科技有限公司 A kind of environment-friendly antibacterial composite high-molecular fiber and preparation method
CN109097865A (en) * 2018-07-18 2018-12-28 苏州洛特兰新材料科技有限公司 A kind of preparation method of radiation protection new material
CN109183377A (en) * 2018-11-28 2019-01-11 江西辉鹏实业有限公司 A kind of joining method of radiation protection leggings
CN110592772A (en) * 2019-10-11 2019-12-20 湖南科力嘉纺织股份有限公司 Antibacterial spinning fabric and spinning method thereof
CN111235887A (en) * 2020-03-31 2020-06-05 江西服装学院 Antibacterial finishing agent, antibacterial fabric and preparation method of antibacterial fabric
CN112593321A (en) * 2020-11-26 2021-04-02 福建省长乐市泰源纺织实业有限公司 Anti-radiation antibacterial yarn and spinning process thereof
CN113882144A (en) * 2021-11-02 2022-01-04 广东鹏运实业有限公司 Anti-electromagnetic radiation fabric with surface coated with nano wave absorber and preparation method thereof
CN117568968A (en) * 2024-01-15 2024-02-20 苏州扬越高新材料有限公司 Production process of polyester fine denier yarn

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108085832A (en) * 2017-12-21 2018-05-29 河南新野纺织股份有限公司 A kind of graphene radiation resistant fiber yarn fabric
CN108560072A (en) * 2018-03-30 2018-09-21 湖州益科纺织科技有限公司 Antiseptic health care fiber silk and preparation method thereof
CN109097865A (en) * 2018-07-18 2018-12-28 苏州洛特兰新材料科技有限公司 A kind of preparation method of radiation protection new material
CN108998846A (en) * 2018-08-10 2018-12-14 苏州郎旭志远科技有限公司 A kind of environment-friendly antibacterial composite high-molecular fiber and preparation method
CN109183377A (en) * 2018-11-28 2019-01-11 江西辉鹏实业有限公司 A kind of joining method of radiation protection leggings
CN110592772A (en) * 2019-10-11 2019-12-20 湖南科力嘉纺织股份有限公司 Antibacterial spinning fabric and spinning method thereof
CN111235887A (en) * 2020-03-31 2020-06-05 江西服装学院 Antibacterial finishing agent, antibacterial fabric and preparation method of antibacterial fabric
CN112593321A (en) * 2020-11-26 2021-04-02 福建省长乐市泰源纺织实业有限公司 Anti-radiation antibacterial yarn and spinning process thereof
CN113882144A (en) * 2021-11-02 2022-01-04 广东鹏运实业有限公司 Anti-electromagnetic radiation fabric with surface coated with nano wave absorber and preparation method thereof
CN117568968A (en) * 2024-01-15 2024-02-20 苏州扬越高新材料有限公司 Production process of polyester fine denier yarn
CN117568968B (en) * 2024-01-15 2024-03-22 苏州扬越高新材料有限公司 Production process of polyester fine denier yarn

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