CN109137138A - A kind of novel waterproof air previous antibacterial fabric and preparation method thereof - Google Patents

A kind of novel waterproof air previous antibacterial fabric and preparation method thereof Download PDF

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Publication number
CN109137138A
CN109137138A CN201811068599.7A CN201811068599A CN109137138A CN 109137138 A CN109137138 A CN 109137138A CN 201811068599 A CN201811068599 A CN 201811068599A CN 109137138 A CN109137138 A CN 109137138A
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Prior art keywords
parts
added
substance
antibacterial fabric
reaction
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Chinese (zh)
Inventor
郑福尔
蔡涛
吴秋兰
邓梦颖
吴中献
李建妮
陈美英
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Shishi Sino Textile Institute Of Clothing And Accessories Industry
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Shishi Sino Textile Institute Of Clothing And Accessories Industry
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Priority to CN201811068599.7A priority Critical patent/CN109137138A/en
Publication of CN109137138A publication Critical patent/CN109137138A/en
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/103Agents inhibiting growth of microorganisms
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/12Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/18Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from other substances
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • D04B1/16Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D06M15/572Reaction products of isocyanates with polyesters or polyesteramides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention belongs to textile technology fields, and in particular to a kind of novel waterproof air previous antibacterial fabric;A kind of composition of novel waterproof air previous antibacterial fabric proposed by the present invention includes following substance: the nylon, 10-12 parts of modified bamboo fiber, 20-30 parts of terylene, 4-8 parts of toughener, 1-2 parts of lubricant, 1-3 parts of coloring agent, 2-3 parts of age resister, 1-2 parts of dispersing agent of 15-20 part according to the mass fraction;The present invention carries out preparing a kind of novel fabric by weaving complex technique, the fabric is due to having used nylon, modified bamboo fiber, terylene, toughener etc. as raw material, it is prepared to be modified, therefore its with waterproof, intensity is high, wear-resisting, antibacterial and other effects, simultaneously as the bamboo fibre used is modified, so buckling phenomena will not occur after being cleaned with fabric prepared by the present invention.

Description

A kind of novel waterproof air previous antibacterial fabric and preparation method thereof
Technical field
The invention belongs to textile technology fields, and in particular to a kind of novel waterproof air previous antibacterial fabric.
Background technique
Clothes referred to all kinds of clothes and accessories worn originally, was initially the substance of warming;But with society Economic and science and technology development clothes has gradually been evolved into the decorative article of human body, has signified a people's when more Standard of living and social status, requirement of the people to it is also higher and higher, therefore develops a flexible, breathable, antibacterial waterproof work Fabric is just very necessary.
Chinese patent CN107351467A discloses a kind of lightweight comfort air-permeable anti-bacterial fabric, by base, antibiotic layer and thoroughly Gas-bearing formation composition, the base upper layer be equipped with antibiotic layer, subbase be equipped with air-permeable layer, the base according to parts by weight, including Following components: 12-20 parts of tencel fiber, 3-9 parts of pearl fiber, 10-16 parts of silk fiber, 6-10 parts of flaxen fiber, bamboo fibre 2-6 Part and soybean fiber 5-8 parts.Lightweight comfort air-permeable anti-bacterial fabric structure described in the invention is simple, reasonable, quality exquisiteness, feel Softness, warmth retention property are good, and environmentally protective, comfort is good, but it is bad with respect to waterproof effect, and buckling phenomena can occur after being washed with water, Its wear-resisting property is poor simultaneously;
Chinese patent CN103625078A discloses a kind of waterproof and breathable antibacterial fabric, it is added with nanometer or nanoscale Silver ion powder PTFE film, make PTFE film other than having effects that waterproof and breathable also with lasting wide spectrum antibacterial imitate Fruit, but comparatively it does not have absorbing sweat effect, physically feel under the weather after wearing if perspiring to paste, while its is resistance to It is poor to grind performance.
Therefore, mentioned above in order to solve the problems, such as, we have invented a kind of novel waterproof air previous antibacterial fabric, this materials It can be good at solving issue noted above, meet the needs of present market.
Summary of the invention
In order to achieve the purpose that in background technique, novel waterproof air previous antibacterial fabric proposed by the present invention and its preparation side Method;
What the present invention realized by the following technical solutions,
A kind of novel waterproof air previous antibacterial fabric:
(1) a kind of composition of novel waterproof air previous antibacterial fabric includes following substance: 15-20 part according to the mass fraction Nylon, 10-12 parts of modified bamboo fiber, 20-30 parts of terylene, 4-8 parts of toughener, 1-2 parts of lubricant, 1-3 parts of dye Toner, 2-3 parts of age resister, 1-2 parts of dispersing agent.
(2) a kind of novel waterproof air previous antibacterial fabric the preparation method is as follows: 15-20 parts of nylon, 10-12 parts are changed Property bamboo fibre, 20-30 parts of terylene, 4-8 parts of toughener, 1-2 parts of lubricant, 1-3 parts of coloring agent, 2-3 parts anti-ageing Agent, 1-2 parts of dispersing agent is added to the mixer, and is mixed, time 10-20min, uniformly rear taking-up to be mixed, by object Material is placed in charge chute, is added into and is carried out being granulated modified extrusion in double screw extruder, obtains the identical particle of particle size, The material grain being modified is added in heat fusing spinning machine and carries out technique of reeling off raw silk from cocoons, the silk thread of various diameters is prepared, then Obtained silk thread is woven using knitting machine, by machine parameter, knitting needle arrangement, triangle arrangement, yarn preparation, coil The technological parameters such as length, needle depth, yarn tension are adjusted, and prepare waterproof and breathable antibacterial fabric.
The preparation process for wherein preparing the substance that the fabric uses is as follows:
(1) preparation of modified bamboo fiber
Temperature of reaction kettle is controlled at 70 DEG C, revolving speed 200rpm, by 10-15 parts of bamboo fibre and 2-5 parts of polyester polyols Alcohol is added in reaction kettle, and after mixing to it, 1-2 parts of dispersing agent and 1-2 parts of propylene dicyanate substance are added In reaction kettle, after carrying out reaction 3-4 hours, stops heating, be cooled to room temperature, obtained substance be sealed preservation, the object Matter is exactly modified bamboo fiber.
(2) preparation of toughener
By 30-40 parts of polyurethane, 10-20 parts of epoxy resin, 4-8 parts of polymethacrylates, 1-2 parts of lubrication Agent, 1-2 parts of dispersing agent are added to the mixer and are mixed, and after mixing, double screw extruder are added in obtained substance Middle progress melt modification extrusion and granulation squeeze out, and are granulated after squeezing out and obtain particle of uniform size, which is toughener.
(3) preparation of lubricant
4-6 parts of zinc stearate, 4-6 parts of tristerin, 3-4 parts of stearyl alcohol, 2-3 parts of phosphate are added In reaction kettle, after reaction being carried out under the conditions of 60 DEG C 1-2 hours, the substance obtained after being cooled to room temperature, the substance is exactly to lubricate Agent.
(4) preparation of dispersing agent
The PE wax of AC-316,2-5 part of 4-5 parts of addition, 1-3 parts of polypropylene wax are added in reaction kettle in a kettle, After carrying out reaction under the conditions of 60 DEG C 1-2 hours, the substance obtained after being cooled to room temperature, the substance is exactly dispersing agent.
(5) preparation of age resister
It is 2-4 parts of sodium pyrosulfite, 1-3 parts of sodium thiosulfate, 3-5 parts of cysteine, 3-4 parts by mass fraction Methyl hydroxybenzoate, 1-2 parts of 2,4-DihydroxyBenzophenone, 4-8 parts PE wax be added reaction kettle in, in 56 DEG C of conditions It is reacted, after reaction 1-2 hours, is cooled to room temperature, obtained substance is crushed, the powder obtained after crushing is exactly anti- Aging agent.
(6) preparation of coloring agent
4-5 parts of regular activated dyestuff, 2-5 parts of silane coupling agent, 10-12 parts of polyvinyl alcohol are added in a kettle It is added in reaction kettle, is carried out under the conditions of 65 DEG C after reacting 1-2 hours, the substance obtained after being cooled to room temperature, which is exactly Coloring agent.
Beneficial to benefit
The present invention prepare by weaving complex technique a kind of novel fabric, the fabric due to used nylon, Modified bamboo fiber, terylene, toughener etc., which are modified as raw material, to be prepared, therefore it is with waterproof, intensity is high, Wear-resisting, antibacterial and other effects, simultaneously as the bamboo fibre used is modified, so will not after being cleaned with fabric prepared by the present invention Occur buckling phenomena, on the other hand, fabric prepared by the present invention be woven by using knitting machine, therefore its using when be As snug as a bug in a rug, simultaneously as joined age resister in fabric prepared by the present invention, therefore there is long-time will not fade for it Effect.
Specific embodiment
In order to keep the purpose of the present invention, technical scheme and beneficial effects clearer, below in conjunction with experimental data, to this The preferred embodiment of invention is described in detail, to facilitate the technical staff to understand.
Embodiment 1
A kind of novel waterproof air previous antibacterial fabric:
(1) a kind of composition of novel waterproof air previous antibacterial fabric includes following substance: 15 parts of Buddhist nun according to the mass fraction Dragon, 12 parts of modified bamboo fiber, 30 parts of terylene, 8 parts of toughener, 2 parts of lubricant, 3 parts of coloring agent, 3 parts anti-ageing Agent, 2 parts of dispersing agent.
(2) a kind of novel waterproof air previous antibacterial fabric the preparation method is as follows: 15 parts of nylon, 12 parts of modified bamboo is fine Dimension, 30 parts of terylene, 8 parts of toughener, 2 parts of lubricant, 3 parts of coloring agent, 3 parts of age resister, 2 parts of dispersing agent add Enter in mixing machine, mixed, time 10-20min, it is to be mixed uniformly after take out, material is placed in charge chute, by itself plus Enter and carry out being granulated modified extrusion in double screw extruder, obtain the identical particle of particle size, heat is added in the material grain being modified Technique of reeling off raw silk from cocoons is carried out in melting spinning machine, the silk thread of various diameters is prepared, then by obtained silk thread using knitting Machine is woven, by machine parameter, knitting needle arrangement, triangle arrangement, yarn preparation, coil length, needle depth, yarn tension Equal technological parameters are adjusted, and prepare waterproof and breathable antibacterial fabric.
The preparation process for wherein preparing the substance that the fabric uses is as follows:
(1) preparation of modified bamboo fiber
Temperature of reaction kettle is controlled at 70 DEG C, revolving speed 200rpm, 15 parts of bamboo fibre and 5 parts of polyester polyol are added In reaction kettle, after mixing to it, 1 part of dispersing agent and 2 parts of propylene dicyanate substance are added in reaction kettle, into After row reaction 3 hours, stop heating, be cooled to room temperature, obtained substance is sealed preservation, which is exactly modified bamboo fibre Dimension.
(2) preparation of toughener
By 40 parts of polyurethane, 10 parts of epoxy resin, 4 parts of polymethacrylates, 2 parts of lubricant, 1 part of point Powder, which is added to the mixer, to be mixed, after mixing, obtained substance is added twin-screw extrude carry out melting change Property squeeze out and be granulated squeeze out, be granulated squeeze out after obtain particle of uniform size, which is toughener.
(3) preparation of lubricant
Reaction kettle is added in 4 parts of zinc stearate, 6 parts of tristerin, 4 parts of stearyl alcohol, 2 parts of phosphate In, after reaction being carried out under the conditions of 60 DEG C 1 hour, the substance obtained after being cooled to room temperature, the substance is exactly lubricant.
(4) preparation of dispersing agent
5 parts of AC-316,2 parts of PE wax, 1 part of polypropylene wax are added in a kettle to be added in reaction kettle, at 60 DEG C Under the conditions of carry out reaction 1 hour after, the substance obtained after being cooled to room temperature, the substance is exactly dispersing agent.
(5) preparation of age resister
It is 2 parts of sodium pyrosulfite, 1 part of sodium thiosulfate, 5 parts of cysteine, 4 parts of hydroxy benzenes by mass fraction Methyl formate, 1 part of 2,4-DihydroxyBenzophenone, 8 parts of PE wax are added in reaction kettle, are reacted in 56 DEG C of conditions, instead It after answering 1 hour, is cooled to room temperature, obtained substance is crushed, the powder obtained after crushing is exactly age resister.
(6) preparation of coloring agent
5 parts of regular activated dyestuff, 5 parts of silane coupling agent, 12 parts of polyvinyl alcohol are added in a kettle to be added instead It answers in kettle, after reaction being carried out under the conditions of 65 DEG C 1 hour, the substance obtained after being cooled to room temperature, the substance is exactly coloring agent.
Embodiment 2
A kind of novel waterproof air previous antibacterial fabric:
(1) a kind of composition of novel waterproof air previous antibacterial fabric includes following substance: 20 parts of Buddhist nun according to the mass fraction Dragon, 10 parts of modified bamboo fiber, 20 parts of terylene, 4 parts of toughener, 1 part of lubricant, 1 part of coloring agent, 2 parts anti-ageing Agent, 1 part of dispersing agent.
(2) a kind of novel waterproof air previous antibacterial fabric the preparation method is as follows: 20 parts of nylon, 10 parts of modified bamboo is fine Dimension, 20 parts of terylene, 4 parts of toughener, 1 part of lubricant, 1 part of coloring agent, 2 parts of age resister, 1 part of dispersing agent add Enter in mixing machine, mixed, material is placed in charge chute, is added by time 20min, uniformly rear taking-up to be mixed It carries out being granulated modified extrusion in double screw extruder, obtains the identical particle of particle size, the material grain being modified is added and is heated Melt and carry out technique of reeling off raw silk from cocoons in spinning machine, the silk thread of various diameters is prepared, obtained silk thread is then used into knitting machine It is woven, by machine parameter, knitting needle arrangement, triangle arrangement, yarn preparation, coil length, needle depth, yarn tension etc. Technological parameter is adjusted, and prepares waterproof and breathable antibacterial fabric.
The preparation process for wherein preparing the substance that the fabric uses is as follows:
(1) preparation of modified bamboo fiber
Temperature of reaction kettle is controlled at 70 DEG C, revolving speed 200rpm, 10 parts of bamboo fibre and 2 parts of polyester polyol are added In reaction kettle, after mixing to it, 2 parts of dispersing agent and 1 part of propylene dicyanate substance are added in reaction kettle, into After row reaction 4 hours, stop heating, be cooled to room temperature, obtained substance is sealed preservation, which is exactly modified bamboo fibre Dimension.
(2) preparation of toughener
By 30 parts of polyurethane, 20 parts of epoxy resin, 8 parts of polymethacrylates, 1 part of lubricant, 2 parts of point Powder, which is added to the mixer, to be mixed, after mixing, obtained substance is added twin-screw extrude carry out melting change Property squeeze out and be granulated squeeze out, be granulated squeeze out after obtain particle of uniform size, which is toughener.
(3) preparation of lubricant
Reaction kettle is added in 6 parts of zinc stearate, 4 parts of tristerin, 3 parts of stearyl alcohol, 3 parts of phosphate In, after reaction being carried out under the conditions of 60 DEG C 2 hours, the substance obtained after being cooled to room temperature, the substance is exactly lubricant.
(4) preparation of dispersing agent
4 parts of AC-316,5 parts of PE wax, 3 parts of polypropylene wax are added in a kettle to be added in reaction kettle, at 60 DEG C Under the conditions of carry out reaction 2 hours after, the substance obtained after being cooled to room temperature, the substance is exactly dispersing agent.
(5) preparation of age resister
It is 4 parts of sodium pyrosulfite, 3 parts of sodium thiosulfate, 3 parts of cysteine, 3 parts of hydroxy benzenes by mass fraction Methyl formate, 2 parts of 2,4-DihydroxyBenzophenone, 4 parts of PE wax are added in reaction kettle, are reacted in 56 DEG C of conditions, instead It after answering 2 hours, is cooled to room temperature, obtained substance is crushed, the powder obtained after crushing is exactly age resister.
(6) preparation of coloring agent
4 parts of regular activated dyestuff, 2 parts of silane coupling agent, 10 parts of polyvinyl alcohol are added in a kettle to be added instead It answers in kettle, after reaction being carried out under the conditions of 65 DEG C 2 hours, the substance obtained after being cooled to room temperature, the substance is exactly coloring agent.
Embodiment 3
A kind of novel waterproof air previous antibacterial fabric:
(1) a kind of composition of novel waterproof air previous antibacterial fabric includes following substance: 20 parts of Buddhist nun according to the mass fraction Dragon, 12 parts of modified bamboo fiber, 20 parts of terylene, 4 parts of toughener, 1 part of lubricant, 3 parts of coloring agent, 3 parts anti-ageing Agent, 2 parts of dispersing agent.
(2) a kind of novel waterproof air previous antibacterial fabric the preparation method is as follows: 20 parts of nylon, 12 parts of modified bamboo is fine Dimension, 20 parts of terylene, 4 parts of toughener, 1 part of lubricant, 3 parts of coloring agent, 3 parts of age resister, 2 parts of dispersing agent add Enter in mixing machine, mixed, time 10-20min, it is to be mixed uniformly after take out, material is placed in charge chute, by itself plus Enter and carry out being granulated modified extrusion in double screw extruder, obtain the identical particle of particle size, heat is added in the material grain being modified Technique of reeling off raw silk from cocoons is carried out in melting spinning machine, the silk thread of various diameters is prepared, then by obtained silk thread using knitting Machine is woven, by machine parameter, knitting needle arrangement, triangle arrangement, yarn preparation, coil length, needle depth, yarn tension Equal technological parameters are adjusted, and prepare waterproof and breathable antibacterial fabric.
The preparation process for wherein preparing the substance that the fabric uses is as follows:
(1) preparation of modified bamboo fiber
Temperature of reaction kettle is controlled at 70 DEG C, revolving speed 200rpm, 15 parts of bamboo fibre and 5 parts of polyester polyol are added In reaction kettle, after mixing to it, 1 part of dispersing agent and 2 parts of propylene dicyanate substance are added in reaction kettle, into After row reaction 3 hours, stop heating, be cooled to room temperature, obtained substance is sealed preservation, which is exactly modified bamboo fibre Dimension.
(2) preparation of toughener
By 40 parts of polyurethane, 10 parts of epoxy resin, 4 parts of polymethacrylates, 2 parts of lubricant, 1 part of point Powder, which is added to the mixer, to be mixed, after mixing, obtained substance is added twin-screw extrude carry out melting change Property squeeze out and be granulated squeeze out, be granulated squeeze out after obtain particle of uniform size, which is toughener.
(3) preparation of lubricant
Reaction kettle is added in 4 parts of zinc stearate, 6 parts of tristerin, 4 parts of stearyl alcohol, 2 parts of phosphate In, after reaction being carried out under the conditions of 60 DEG C 1 hour, the substance obtained after being cooled to room temperature, the substance is exactly lubricant.
(4) preparation of dispersing agent
5 parts of AC-316,2 parts of PE wax, 1 part of polypropylene wax are added in a kettle to be added in reaction kettle, at 60 DEG C Under the conditions of carry out reaction 1, hour after, the substance obtained after being cooled to room temperature, the substance is exactly dispersing agent.
(5) preparation of age resister
It is 2 parts of sodium pyrosulfite, 1 part of sodium thiosulfate, 5 parts of cysteine, 4 parts of hydroxy benzenes by mass fraction Methyl formate, 1 part of 2,4-DihydroxyBenzophenone, 8 parts of PE wax are added in reaction kettle, are reacted in 56 DEG C of conditions, instead It after answering 1 hour, is cooled to room temperature, obtained substance is crushed, the powder obtained after crushing is exactly age resister.
(6) preparation of coloring agent
5 parts of regular activated dyestuff, 5 parts of silane coupling agent, 12 parts of polyvinyl alcohol are added in a kettle to be added instead It answers in kettle, after reaction being carried out under the conditions of 65 DEG C 1 hour, the substance obtained after being cooled to room temperature, the substance is exactly coloring agent.
Embodiment 4
A kind of novel waterproof air previous antibacterial fabric:
(1) a kind of composition of novel waterproof air previous antibacterial fabric includes following substance: 18 parts of Buddhist nun according to the mass fraction Dragon, 11 parts of modified bamboo fiber, 15 parts of terylene, 6 parts of toughener, 2 parts of lubricant, 2 parts of coloring agent, 2 parts anti-ageing Agent, 1 part of dispersing agent.
(2) a kind of novel waterproof air previous antibacterial fabric the preparation method is as follows: 18 parts of nylon, 11 parts of modified bamboo is fine Dimension, 15 parts of terylene, 6 parts of toughener, 2 parts of lubricant, 2 parts of coloring agent, 2 parts of age resister, 1 part of dispersing agent add Enter in mixing machine, mixed, material is placed in charge chute, is added by time 15min, uniformly rear taking-up to be mixed It carries out being granulated modified extrusion in double screw extruder, obtains the identical particle of particle size, the material grain being modified is added and is heated Melt and carry out technique of reeling off raw silk from cocoons in spinning machine, the silk thread of various diameters is prepared, obtained silk thread is then used into knitting machine It is woven, by machine parameter, knitting needle arrangement, triangle arrangement, yarn preparation, coil length, needle depth, yarn tension etc. Technological parameter is adjusted, and prepares waterproof and breathable antibacterial fabric.
The preparation process for wherein preparing the substance that the fabric uses is as follows:
(1) preparation of modified bamboo fiber
Temperature of reaction kettle is controlled at 70 DEG C, revolving speed 200rpm, 18 parts of bamboo fibre and 3 parts of polyester polyol are added In reaction kettle, after mixing to it, 2 parts of dispersing agent and 1 part of propylene dicyanate substance are added in reaction kettle, into After row reaction 4 hours, stop heating, be cooled to room temperature, obtained substance is sealed preservation, which is exactly modified bamboo fibre Dimension.
(2) preparation of toughener
By 35 parts of polyurethane, 15 parts of epoxy resin, 6 parts of polymethacrylates, 1 part of lubricant, 2 parts of point Powder, which is added to the mixer, to be mixed, after mixing, obtained substance is added twin-screw extrude carry out melting change Property squeeze out and be granulated squeeze out, be granulated squeeze out after obtain particle of uniform size, which is toughener.
(3) preparation of lubricant
Reaction kettle is added in 5 parts of zinc stearate, 5 parts of tristerin, 4 parts of stearyl alcohol, 2 parts of phosphate In, after reaction being carried out under the conditions of 60 DEG C 2 hours, the substance obtained after being cooled to room temperature, the substance is exactly lubricant.
(4) preparation of dispersing agent
4 parts of AC-316,3 parts of PE wax, 2 parts of polypropylene wax are added in a kettle to be added in reaction kettle, at 60 DEG C Under the conditions of carry out reaction 2 hours after, the substance obtained after being cooled to room temperature, the substance is exactly dispersing agent.
(5) preparation of age resister
It is 3 parts of sodium pyrosulfite, 2 parts of sodium thiosulfate, 4 parts of cysteine, 4 parts of hydroxy benzenes by mass fraction Methyl formate, 1 part of 2,4-DihydroxyBenzophenone, 6 parts of PE wax are added in reaction kettle, are reacted in 56 DEG C of conditions, instead It after answering 1-2 hours, is cooled to room temperature, obtained substance is crushed, the powder obtained after crushing is exactly age resister.
(6) preparation of coloring agent
4 parts of regular activated dyestuff, 3 parts of silane coupling agent, 11 parts of polyvinyl alcohol are added in a kettle to be added instead It answers in kettle, after reaction being carried out under the conditions of 65 DEG C 2 hours, the substance obtained after being cooled to room temperature, the substance is exactly coloring agent.
Experimental analysis:
1, mechanics properties testing
The common fabric that the embodiment 1-4 fabric prepared and market are bought is subjected to Mechanics Performance Testing, testing result It is as follows:
Mechanical properties of fabric prepared by the present invention is better than the fabric that market is sold as can be seen from the above table, comparatively Intensity is very high simultaneously, and toughness is also very outstanding, while its abrasive resistance is very good, and the fabric that relative market is sold comes Say it is a very outstanding fabric.
Finally, it is stated that preferred embodiment above is only used to illustrate the technical scheme of the present invention rather than limits, although logical It crosses above preferred embodiment the present invention is described in detail, however, those skilled in the art should understand that, can be Various changes are made to it in form and in details, without departing from defined by claims of the present invention.

Claims (7)

1. a kind of novel waterproof air previous antibacterial fabric, it is characterised in that: a kind of composition of novel waterproof air previous antibacterial fabric includes Following substance: nylon, 10-12 parts of modified bamboo fiber, 20-30 parts of the terylene, 4-8 parts of 15-20 part according to the mass fraction Toughener, 1-2 parts of lubricant, 1-3 parts of coloring agent, 2-3 parts of age resister, 1-2 parts of dispersing agent;
The novel waterproof air previous antibacterial fabric the preparation method is as follows: 15-20 parts of nylon, 10-12 parts of modified bamboo is fine Dimension, 20-30 parts of terylene, 4-8 parts of toughener, 1-2 parts of lubricant, 1-3 parts of coloring agent, 2-3 parts of age resister, 1- 2 parts of dispersing agent is added to the mixer, and is mixed, time 10-20min, and material is placed in dress by uniformly rear taking-up to be mixed It in hopper, is added into and carries out being granulated modified extrusion in double screw extruder, obtain the identical particle of particle size, will be modified Material grain be added in heat fusing spinning machine and carry out technique of reeling off raw silk from cocoons, be prepared the silk thread of various diameters, then will obtain Silk thread is woven using knitting machine, by machine parameter, knitting needle arrangement, triangle arrangement, yarn preparation, coil length, needle The technological parameters such as depth, yarn tension be adjusted, prepare waterproof and breathable antibacterial fabric.
2. a kind of novel waterproof air previous antibacterial fabric according to claim 1, which is characterized in that the modified bamboo fiber For temperature of reaction kettle is controlled at 70 DEG C, revolving speed 200rpm, 10-15 parts of bamboo fibre and 2-5 parts of polyester polyol are added In reaction kettle, after mixing to it, reaction kettle is added in 1-2 parts of dispersing agent and 1-2 parts of propylene dicyanate substance In, after carrying out reaction 3-4 hours, stops heating, be cooled to room temperature, obtained substance is sealed preservation, which is exactly Modified bamboo fiber.
3. a kind of novel waterproof air previous antibacterial fabric according to claim 1, which is characterized in that the toughener is, By 30-40 parts of polyurethane, 10-20 parts of epoxy resin, 4-8 parts of polymethacrylates, 1-2 parts of lubricant, 1-2 parts Dispersing agent be added to the mixer and mixed, after mixing, obtained substance is added twin-screw extrude and is melted Melt modified extrusion and be granulated and squeeze out, is granulated after squeezing out and obtains particle of uniform size, which is toughener.
4. a kind of novel waterproof air previous antibacterial fabric according to claim 1, which is characterized in that the lubricant is, Reaction kettle is added in 4-6 parts of zinc stearate, 4-6 parts of tristerin, 3-4 parts of stearyl alcohol, 2-3 parts of phosphate In, after reaction being carried out under the conditions of 60 DEG C 1-2 hours, the substance obtained after being cooled to room temperature, the substance is exactly lubricant.
5. a kind of novel waterproof air previous antibacterial fabric according to claim 1, which is characterized in that the dispersing agent is, The PE wax of AC-316,2-5 part of 4-5 parts of addition, 1-3 parts of polypropylene wax are added in reaction kettle in a kettle, in 60 DEG C of items After carrying out reaction under part 1-2 hours, the substance obtained after being cooled to room temperature, the substance is exactly dispersing agent.
6. a kind of novel waterproof air previous antibacterial fabric according to claim 1, which is characterized in that the age resister For, by mass fraction be 2-4 parts of sodium pyrosulfite, 1-3 parts of sodium thiosulfate, 3-5 parts of cysteine, 3-4 parts of hydroxyl Yl benzoic acid methyl esters, 1-2 parts of 2,4-DihydroxyBenzophenone, 4-8 parts of PE wax are added in reaction kettle, carry out in 56 DEG C of conditions Reaction is cooled to room temperature after reaction 1-2 hours, obtained substance is crushed, the powder obtained after crushing is exactly anti-aging Agent.
7. a kind of novel waterproof air previous antibacterial fabric according to claim 1, which is characterized in that the coloring agent is, 4-5 parts of regular activated dyestuff, 2-5 parts of silane coupling agent, 10-12 parts of polyvinyl alcohol are added in a kettle, reaction is added In kettle, after reaction being carried out under the conditions of 65 DEG C 1-2 hours, the substance obtained after being cooled to room temperature, the substance is exactly coloring agent.
CN201811068599.7A 2018-09-13 2018-09-13 A kind of novel waterproof air previous antibacterial fabric and preparation method thereof Pending CN109137138A (en)

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CN110129913A (en) * 2019-05-09 2019-08-16 江苏恒宇纺织集团有限公司 It is a kind of without dye 6 color high tenacity silk of polyamide fibre and preparation method thereof
CN110438794A (en) * 2019-07-10 2019-11-12 株洲天伦纺织有限责任公司 A kind of wear-resisting veil and preparation method thereof
CN110983484A (en) * 2019-12-06 2020-04-10 浙江升丽纺织有限公司 High-wear-resistance flame-retardant fabric and preparation method thereof
CN112813560A (en) * 2021-02-20 2021-05-18 康文广 Flame-retardant antibacterial high-performance garment fabric and preparation method thereof
CN113930999A (en) * 2021-10-25 2022-01-14 上海棉芙生物科技有限公司 Antibacterial non-woven fabric and preparation method thereof
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Publication number Priority date Publication date Assignee Title
CN110129913A (en) * 2019-05-09 2019-08-16 江苏恒宇纺织集团有限公司 It is a kind of without dye 6 color high tenacity silk of polyamide fibre and preparation method thereof
CN110438794A (en) * 2019-07-10 2019-11-12 株洲天伦纺织有限责任公司 A kind of wear-resisting veil and preparation method thereof
CN110983484A (en) * 2019-12-06 2020-04-10 浙江升丽纺织有限公司 High-wear-resistance flame-retardant fabric and preparation method thereof
CN112813560A (en) * 2021-02-20 2021-05-18 康文广 Flame-retardant antibacterial high-performance garment fabric and preparation method thereof
CN113930999A (en) * 2021-10-25 2022-01-14 上海棉芙生物科技有限公司 Antibacterial non-woven fabric and preparation method thereof
CN114703660A (en) * 2022-03-16 2022-07-05 安徽恒益纺织科技有限公司 Antibacterial waterproof textile and production process thereof
CN114703660B (en) * 2022-03-16 2024-01-12 安徽贺赢新材料科技有限公司 Antibacterial waterproof textile and production process thereof

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