CN110438794A - A kind of wear-resisting veil and preparation method thereof - Google Patents

A kind of wear-resisting veil and preparation method thereof Download PDF

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Publication number
CN110438794A
CN110438794A CN201910618848.3A CN201910618848A CN110438794A CN 110438794 A CN110438794 A CN 110438794A CN 201910618848 A CN201910618848 A CN 201910618848A CN 110438794 A CN110438794 A CN 110438794A
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China
Prior art keywords
parts
wear
resisting
veil
follows
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CN201910618848.3A
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Chinese (zh)
Inventor
吴晓虹
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Zhuzhou Tianlun Textile Co Ltd
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Zhuzhou Tianlun Textile Co Ltd
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Priority to CN201910618848.3A priority Critical patent/CN110438794A/en
Publication of CN110438794A publication Critical patent/CN110438794A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/08Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyacrylonitrile as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/10Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/16Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/18Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from other substances
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35Abrasion, pilling or fibrillation resistance

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Materials For Medical Uses (AREA)

Abstract

The present invention relates to textile technology fields, and in particular to a kind of wear-resisting veil and preparation method thereof;The composition of the wear-resisting veil are as follows: mass fraction is 10-20 parts of polytetrafluoroethylene (PTFE), 60-80 parts of polyurethane, 12-18 parts of carbon fiber, 5-10 parts of polyacrylonitrile, 20-30 parts of activated carbon SiClx, 2-4 parts of lubricant, 2-5 parts of age resister.Wear-resisting veil prepared by the present invention is compound using the progress of many kinds of substance such as polytetrafluoroethylene (PTFE), polyurethane, carbon fiber, polyacrylonitrile, activated carbon SiClx, lubricant, age resister, reel off raw silk from cocoons what technique was prepared using heat fusing, its high intensity and toughness for having polyurethane, carbon fiber, polyacrylonitrile well, it has been also equipped with the hydrophobicity of polytetrafluoroethylene (PTFE) simultaneously, it is effectively guaranteed and is not easy dirty and easy to wash characteristic, it has been also equipped with the wear-resisting property of activated carbon SiClx simultaneously, in addition, it is also equipped with certain anti-aging property.

Description

A kind of wear-resisting veil and preparation method thereof
Technical field
The invention belongs to textile technology fields, and in particular to a kind of wear-resisting veil and preparation method thereof.
Background technique
Veil, be it is a kind of commonly using textile, more frivolous, good air permeability, the relatively low one kind of moisture pick-up properties Fabric.Because use is very easy dirty and fuzz balls, seriously in fields such as performance, wedding celebration, costume and props mostly for it Affect its using effect and service life, therefore develop it is a can bear dirty, easy to wash, the good product of wearability just seems It is very necessary, and a kind of wear-resisting veil proposed by the present invention can be good at meeting these requirements.
Summary of the invention
In order to achieve the purpose that in background technique, a kind of wear-resisting veil proposed by the present invention and preparation method thereof;
What the present invention realized by the following technical solutions:
A kind of wear-resisting veil and preparation method thereof, which is characterized in that the composition of the wear-resisting veil are as follows: mass fraction is 10-20 parts of polytetrafluoroethylene (PTFE), 60-80 parts of polyurethane, 12-18 parts of carbon fiber, 5-10 parts of polyacrylonitrile, 20-30 parts Activated carbon SiClx, 2-4 parts of lubricant, 2-5 parts of age resister;
A kind of wear-resisting veil the preparation method comprises the following steps: by mass fraction be 10-20 parts polytetrafluoroethylene (PTFE), 60-80 parts Polyurethane, 12-18 parts of carbon fiber, 5-10 parts of polyacrylonitrile, 20-30 parts of activated carbon SiClx, 2-4 parts of lubricant add Enter in batch mixer and mixed, after mixing, material is added in twin-screw granulating extruder and carries out granulation extrusion, is mixed Material grain is closed, is then reeled off raw silk from cocoons obtained particle to obtain silk thread up to specification, then will be received using vacuum high-pressure spray coating method Rice aluminium dioxide uniformly sprays on silk thread, after then being post-processed obtained silk, is woven into veil, the veil It is exactly wear-resisting veil.
Further, the activated carbon SiClx are as follows: the silicon carbide powder (diameier for being 100-120 parts by mass fraction Be 500-800 nanometers), 10-20 parts of polylactic acid, 3-5 parts MDI, 0.2-0.5 part organic Raney nickel, 2-5 parts of beeswax It is added in batch mixer and carries out hybrid reaction 2-3 hours, reaction temperature is 70-80 DEG C, and after fully reacting, what is obtained is exactly activated carbon SiClx.
Further, the carbon fiber are as follows: be the carbon fiber being prepared with PAN base.
Further, the lubricant are as follows: by the beeswax, 1-2 parts of olive of EBS, 3-4 part that mass fraction is 3-5 parts Oil, 2-4 parts of G60 are added in reaction kettle, and reaction 2-3 hours is carried out under the conditions of 60-65 DEG C, after fully reacting, is cooled to room Temperature, obtained substance are exactly lubricant.
Further, the age resister are as follows: one or more of UV531, UV321, UV-P, UV-O, UV-9 combination.
Further, the silk size are as follows: fiber number 1-3dtex.
Further, the nanometer titanium dioxide aluminium of the spraying with a thickness of are as follows: 500-700nm.
Beneficial to benefit
Wear-resisting veil prepared by the present invention is using polytetrafluoroethylene (PTFE), polyurethane, carbon fiber, polyacrylonitrile, active carbide The progress of many kinds of substance such as silicon, lubricant, age resister is compound, reels off raw silk from cocoons what technique was prepared using heat fusing, has well For the high intensity and toughness of polyurethane, carbon fiber, polyacrylonitrile, while it being also equipped with the hydrophobicity of polytetrafluoroethylene (PTFE), effectively Ensure that it is not easy dirty and easy to wash characteristic, while the wear-resisting property of activated carbon SiClx has been also equipped with, in addition, it is also equipped with Certain anti-aging property.
Specific embodiment
In order to keep the purpose of the present invention, technical scheme and beneficial effects clearer, below in conjunction with experimental data, to this The preferred embodiment of invention is described in detail, to facilitate the technical staff to understand.
Embodiment 1
A kind of wear-resisting veil the preparation method comprises the following steps:
It is 15 parts of polytetrafluoroethylene (PTFE), 80 parts of polyurethane, 15 parts of carbon fiber, 10 parts of polypropylene by mass fraction Nitrile, 20 parts of activated carbon SiClx, 4 parts of lubricant are added in batch mixer and are mixed, and after mixing, double spiral shells are added in material Granulation extrusion is carried out in bar granulating extruder, obtains mixture grain, then is reeled off raw silk from cocoons to obtain by obtained particle up to specification Silk thread, then nanometer titanium dioxide aluminium is uniformly sprayed on silk thread using vacuum high-pressure spray coating method, the silk that then will be obtained After being post-processed, it is woven into veil, which is exactly wear-resisting veil.
Further, the activated carbon SiClx are as follows: (diameier is the silicon carbide powder for being 110 parts by mass fraction 500-800 nanometers), 20 parts of polylactic acid, 4 parts of MDI, 0.5 part of organic Raney nickel, 2 parts beeswax be added batch mixer in It carries out hybrid reaction 2-3 hours, reaction temperature is 70-80 DEG C, and after fully reacting, what is obtained is exactly activated carbon SiClx.
Further, the carbon fiber are as follows: be the carbon fiber being prepared with PAN base.
Further, the lubricant are as follows: by mass fraction be 4 parts of EBS, 4 parts of beeswax, 1 part of olive oil, 2 parts G60 be added reaction kettle in, carried out under the conditions of 60-65 DEG C reaction 2-3 hours, after fully reacting, be cooled to room temperature, obtain Substance is exactly lubricant.
Further, the age resister are as follows: UV-9.
Further, the silk size are as follows: fiber number 1-3dtex.
Further, the nanometer titanium dioxide aluminium of the spraying with a thickness of are as follows: 500-700nm.
Embodiment 2
A kind of wear-resisting veil the preparation method comprises the following steps:
By mass fraction be 20 parts of polytetrafluoroethylene (PTFE), 70 parts of polyurethane, 18 parts of carbon fiber, 8 parts of polyacrylonitrile, 25 parts of activated carbon SiClx, 4 parts of lubricant are added in batch mixer and are mixed, and after mixing, twin-screw are added in material Granulation extrusion is carried out in granulating extruder, obtains mixture grain, then is reeled off raw silk from cocoons to obtain by obtained particle up to specification Then silk thread is uniformly sprayed nanometer titanium dioxide aluminium on silk thread using vacuum high-pressure spray coating method, then by obtained silk into After row post-processing, it is woven into veil, which is exactly wear-resisting veil.
Further, the activated carbon SiClx are as follows: (diameier is the silicon carbide powder for being 120 parts by mass fraction 500-800 nanometers), 15 parts of polylactic acid, 5 parts of MDI, 0.3 part of organic Raney nickel, 2 parts beeswax be added batch mixer in It carries out hybrid reaction 2-3 hours, reaction temperature is 70-80 DEG C, and after fully reacting, what is obtained is exactly activated carbon SiClx.
Further, the carbon fiber are as follows: be the carbon fiber being prepared with PAN base.
Further, the lubricant are as follows: by mass fraction be 5 parts of EBS, 3 parts of beeswax, 2 parts of olive oil, 3 parts G60 be added reaction kettle in, carried out under the conditions of 60-65 DEG C reaction 2-3 hours, after fully reacting, be cooled to room temperature, obtain Substance is exactly lubricant.
Further, the age resister are as follows: UV-O.
Further, the silk size are as follows: fiber number 1-3dtex.
Further, the nanometer titanium dioxide aluminium of the spraying with a thickness of are as follows: 500-700nm.
Embodiment 3
A kind of wear-resisting veil the preparation method comprises the following steps:
By mass fraction be 10 parts of polytetrafluoroethylene (PTFE), 60 parts of polyurethane, 12 parts of carbon fiber, 5 parts of polyacrylonitrile, 20 parts of activated carbon SiClx, 2 parts of lubricant are added in batch mixer and are mixed, and after mixing, twin-screw are added in material Granulation extrusion is carried out in granulating extruder, obtains mixture grain, then is reeled off raw silk from cocoons to obtain by obtained particle up to specification Then silk thread is uniformly sprayed nanometer titanium dioxide aluminium on silk thread using vacuum high-pressure spray coating method, then by obtained silk into After row post-processing, it is woven into veil, which is exactly wear-resisting veil.
Further, the activated carbon SiClx are as follows: (diameier is the silicon carbide powder for being 100 parts by mass fraction 500-800 nanometers), 10 parts of polylactic acid, 3 parts of MDI, 0.2 part of organic Raney nickel, 2 parts beeswax be added batch mixer in It carries out hybrid reaction 2-3 hours, reaction temperature is 70-80 DEG C, and after fully reacting, what is obtained is exactly activated carbon SiClx.
Further, the carbon fiber are as follows: be the carbon fiber being prepared with PAN base.
Further, the lubricant are as follows: by mass fraction be 3 parts of EBS, 3 parts of beeswax, 1 part of olive oil, 2 parts G60 be added reaction kettle in, carried out under the conditions of 60-65 DEG C reaction 2-3 hours, after fully reacting, be cooled to room temperature, obtain Substance is exactly lubricant.
Further, the age resister are as follows: UV-P.
Further, the silk size are as follows: fiber number 1-3dtex.
Further, the nanometer titanium dioxide aluminium of the spraying with a thickness of are as follows: 500-700nm.
Embodiment 4
A kind of wear-resisting veil the preparation method comprises the following steps:
It is 20 parts of polytetrafluoroethylene (PTFE), 80 parts of polyurethane, 18 parts of carbon fiber, 10 parts of polypropylene by mass fraction Nitrile, 30 parts of activated carbon SiClx, 4 parts of lubricant are added in batch mixer and are mixed, and after mixing, double spiral shells are added in material Granulation extrusion is carried out in bar granulating extruder, obtains mixture grain, then is reeled off raw silk from cocoons to obtain by obtained particle up to specification Silk thread, then nanometer titanium dioxide aluminium is uniformly sprayed on silk thread using vacuum high-pressure spray coating method, the silk that then will be obtained After being post-processed, it is woven into veil, which is exactly wear-resisting veil.
Further, the activated carbon SiClx are as follows: (diameier is the silicon carbide powder for being 120 parts by mass fraction 500-800 nanometers), 20 parts of polylactic acid, 5 parts of MDI, 0.5 part of organic Raney nickel, 5 parts beeswax be added batch mixer in It carries out hybrid reaction 2-3 hours, reaction temperature is 70-80 DEG C, and after fully reacting, what is obtained is exactly activated carbon SiClx.
Further, the carbon fiber are as follows: be the carbon fiber being prepared with PAN base.
Further, the lubricant are as follows: by mass fraction be 5 parts of EBS, 4 parts of beeswax, 2 parts of olive oil, 4 parts G60 be added reaction kettle in, carried out under the conditions of 60-65 DEG C reaction 2-3 hours, after fully reacting, be cooled to room temperature, obtain Substance is exactly lubricant.
Further, the age resister are as follows: UV531.
Further, the silk size are as follows: fiber number 1-3dtex.
Further, the nanometer titanium dioxide aluminium of the spraying with a thickness of are as follows: 500-700nm.
Experimental analysis:
1, properties of product are tested
The wear-resisting veil of the preparation of embodiment 1-4 is subjected to properties test, is tested, as a result as shown in the table:
Above-mentioned test result it is found that wear-resisting veil prepared by the present invention its receive elongation at break it is relatively high, illustrate its tool There is good elastic property, meanwhile, wear-resisting property is preferable, and the wear-resisting property of material is effectively guaranteed.
Finally, it is stated that preferred embodiment above is only used to illustrate the technical scheme of the present invention rather than limits, although logical It crosses above preferred embodiment the present invention is described in detail, however, those skilled in the art should understand that, can be Various changes are made to it in form and in details, without departing from defined by claims of the present invention.

Claims (7)

1. a kind of wear-resisting veil and preparation method thereof, which is characterized in that the composition of the wear-resisting veil are as follows: mass fraction 10- 20 parts of polytetrafluoroethylene (PTFE), 60-80 parts of polyurethane, 12-18 parts of carbon fiber, 5-10 parts of polyacrylonitrile, 20-30 parts of work Property silicon carbide, 2-4 parts of lubricant, 2-5 parts of age resister;
A kind of wear-resisting veil the preparation method comprises the following steps: by mass fraction be 10-20 part polytetrafluoroethylene (PTFE), 60-80 parts gather Urethane, 12-18 parts of carbon fiber, 5-10 parts of polyacrylonitrile, 20-30 parts of activated carbon SiClx, 2-4 parts of lubricant are added mixed It is mixed in material machine, after mixing, material is added in twin-screw granulating extruder and carries out granulation extrusion, obtains mixture Grain, is then reeled off raw silk from cocoons obtained particle to obtain silk thread up to specification, then uses vacuum high-pressure spray coating method by nanometer two Aluminium oxide uniformly sprays on silk thread, after then being post-processed obtained silk, is woven into veil, which is exactly Wear-resisting veil.
2. a kind of wear-resisting veil according to claim 1 and preparation method thereof, which is characterized in that the activated carbon SiClx Are as follows: by mass fraction be 100-120 parts silicon carbide powder (diameier is 500-800 nanometers), 10-20 parts of polylactic acid, It is small that progress hybrid reaction 2-3 in batch mixer is added in organic Raney nickel of 3-5 parts MDI, 0.2-0.5 part, 2-5 parts of beeswax When, reaction temperature is 70-80 DEG C, and after fully reacting, what is obtained is exactly activated carbon SiClx.
3. a kind of wear-resisting veil according to claim 1 and preparation method thereof, which is characterized in that the carbon fiber are as follows: be The carbon fiber being prepared with PAN base.
4. a kind of wear-resisting veil according to claim 1 and preparation method thereof, which is characterized in that the lubricant are as follows: will The beeswax, 1-2 parts of olive oil, 2-4 parts of G60 of EBS, 3-4 part that mass fraction is 3-5 parts are added in reaction kettle, in 60-65 Reaction 2-3 hours is carried out under the conditions of DEG C, after fully reacting, is cooled to room temperature, obtained substance is exactly lubricant.
5. a kind of wear-resisting veil according to claim 1 and preparation method thereof, which is characterized in that the age resister are as follows: One or more of UV531, UV321, UV-P, UV-O, UV-9 combination.
6. a kind of wear-resisting veil and preparation method thereof according to claim 1, which is characterized in that the silk size are as follows: fiber number For 1-3dtex.
7. a kind of wear-resisting veil according to claim 1 and preparation method thereof, which is characterized in that the nanometer two of the spraying Aluminium oxide with a thickness of are as follows: 500-700nm.
CN201910618848.3A 2019-07-10 2019-07-10 A kind of wear-resisting veil and preparation method thereof Pending CN110438794A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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