CN105696325A - Antifungal anti-mite textile material and preparation method thereof - Google Patents

Antifungal anti-mite textile material and preparation method thereof Download PDF

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Publication number
CN105696325A
CN105696325A CN201610246559.1A CN201610246559A CN105696325A CN 105696325 A CN105696325 A CN 105696325A CN 201610246559 A CN201610246559 A CN 201610246559A CN 105696325 A CN105696325 A CN 105696325A
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parts
fiber
textile material
ester
antifungal
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吴林水
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Linwang Weaving Mill
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Linwang Weaving Mill
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • D06M13/21—Halogenated carboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2246—Esters of unsaturated carboxylic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/335—Amines having an amino group bound to a carbon atom of a six-membered aromatic ring
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D06M2101/08—Esters or ethers of cellulose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses an antifungal anti-mite textile material. The antifungal anti-mite textile material comprises, by weight, 20-40 parts of polyester fiber, 20-40 parts of polyester fiber, 15-35 parts of nylon fiber, 15-35 parts of natural bamboo fiber, 15-35 parts of polylactic acid fiber, 15-30 parts of cellulose acetate, 25-45 parts of kapok, 15-25 parts of cotton, 15-25 parts of sisal hemp, 15-25 parts of flax, 10-25 parts of chitin, 5-15 parts of azadirachtin, 5-10 parts of chloroacetic acid, 2-5 parts of p-phenylenediamine, 2-5 parts of bis-hydroxypropyl polydimethylsiloxane ester, 2-5 parts of phosphoric acid monoisotridecyl ester, 5-10 parts of dispersing agent, 5-10 parts of sizing agent and 5-10 parts of adhesive. The antifungal anti-mite textile material can have excellent antifungal and anti-mite effects. The invention further discloses a preparation method of the antifungal anti-mite textile material.

Description

A kind of textile material of antifungal and dust mite and preparation method thereof
Technical field
The present invention relates to textile material technical field, be specifically related to textile material of a kind of antifungal and dust mite and preparation method thereof。
Background technology
Textile material refers to fiber and fibre, is embodied in fiber, yarn, fabric and complex thereof。Traditional textile material can apply to the every aspect of society。Traditional textile industry is exactly that natural fiber is processed or utilizes ready-made textile material carry out in processing, to obtain the raw material making related supplies。Functional strong on antifungal and dust mite of these traditional textile raw materials, causes that the use of medicated clothing or the related supplies using these raw materials to make has limited, and service life is shorter。
Textile material directly as product, can also turn to industry textile product from traditional natural material quickly as raw material, and the demand simultaneously for fresh composite textile materials strengthens day by day。Textile industry also increases to some extent for raw-material functional dependence at present simultaneously。The at present technological innovation for traditional textile industry is faced with technical bottleneck, is particularly important for the requirement of textile material antifungal and dust mite so working out a kind of novel textile material to tackle industry。
Summary of the invention
For solving above-mentioned technical problem, the present invention provides textile material of a kind of antifungal and dust mite and preparation method thereof, by adopting specified raw material to be combined, coordinate corresponding production technology, obtain the textile material of a kind of antifungal and dust mite, having the performance of excellent antifungal and dust mite, its durability significantly strengthens, to human body and environmentally friendly。
Detailed description of the invention
The purpose of the present invention can be achieved through the following technical solutions:
A kind of textile material of antifungal and dust mite, it is made up of the raw material of following weight portion: polyster fibre 20-40 part, polyester fiber 20-40 part, nylon fiber 15-35 part, bamboo fiber 15-35 part, acid fiber by polylactic 15-35 part, acetate fiber 15-30 part, kapok 25-45 part, cotton 15-25 part, Folium Agaves Sisalanae 15-25 part, Caulis et Folium Lini 15-25 part, chitin 10-25 part, nimbin 5-15 part, monoxone 5-10 part, p-phenylenediamine 2-5 part, Oleum Ricini pair-hydroxypropyl polydimethylsiloxane ester 2-5 part, mono phosphoric acid ester different tridecane ester 2-5 part, dispersant 5-10 part, wetting agent 5-10 part and binding agent 5-10 part。
Preferably, one or more in taurate, aminoguanidine sulfonate, lignosulfonates and vinylsulfonate of described dispersant。
Preferably, one or more in pyroglutamic acid methyl ester, silicone grease ethyl ester, sucrose stearate and stearate of described wetting agent。
Preferably, one or more in 5-chlorosamide, a few lactams, sulfenamide and nicotinamide of described binding agent。
The preparation method of the textile material of a kind of antifungal and dust mite, comprises the following steps:
(1) each raw material is weighed according to weight portion；
(2) mixing of polyster fibre, polyester fiber, nylon fiber, bamboo fiber, acid fiber by polylactic and acetate fiber is added in the alcoholic solution of 10%, insulation activation 1.5-3 hour；
(3) mixing of kapok, cotton, Folium Agaves Sisalanae, Caulis et Folium Lini and chitin is added in the boric acid solution of 5%, adopt ultrasonic grinder, Ultrasonic Pulverization 30-60 minute；
(4) solution of step (2) and step (3) is mixed, add reactor, then in mixed liquor, it is sequentially added into nimbin, monoxone, p-phenylenediamine, Oleum Ricini pair-hydroxypropyl polydimethylsiloxane ester, the different tridecane ester of mono phosphoric acid ester, stirring 30-60 minute, mixing speed is 1000 revs/min；
(5) in reactor, add dispersant and wetting agent, then reacting by heating still successively, make reaction temperature be promoted to 100 DEG C, be subsequently adding binding agent, keep the mixing speed 1500 revs/min of reactor, continuously stirred 60 minutes；
(6) it is filtered treated mixed solution processing；
(7) filter the liquid flowed out and enter double screw extruder, product is extruded, plastotype and drying。
Preferably, in described step (2), the temperature of insulation is 50-70 DEG C。
Preferably, in described step (3), the power of ultrasonic grinder is 150-250W。
Preferably, in described step (6), the pore size filter of filtration treatment is 20-70 micron。
Compared with prior art, it has the beneficial effect that the present invention
(1) antifungal of the present invention and the textile material of dust mite are with polyster fibre, polyester fiber, nylon fiber, bamboo fiber, acid fiber by polylactic, acetate fiber, kapok, cotton, Folium Agaves Sisalanae, Caulis et Folium Lini, chitin, nimbin, monoxone, p-phenylenediamine, Oleum Ricini pair-hydroxypropyl polydimethylsiloxane ester, the different tridecane ester of mono phosphoric acid ester is main component, by adding dispersant, wetting agent and binding agent, it is aided with activation, pulverize, stirring, filter, extrusion, plastotype, the techniques such as drying, the textile material being prepared from is made to have the performance of good antifungal and dust mite。
(2) the novel textile material cheaper starting materials of the present invention, technique are simple, are suitable to heavy industrialization and use, practical。
Detailed description of the invention
Below in conjunction with specific embodiment, the technical scheme of invention is described in detail。
Embodiment 1
(1) polyster fibre 20 parts, 20 parts of polyester fiber, nylon fiber 15 parts, bamboo fiber 15 parts, acid fiber by polylactic 15 parts, acetate fiber 15 parts, kapok 25 parts, 15 parts of cotton, 15 parts of Folium Agaves Sisalanae, 15 parts of Caulis et Folium Lini, chitin 10 parts, nimbin 5 parts, monoxone 5 parts, p-phenylenediamine 2 parts, Oleum Ricini pair-hydroxypropyl polydimethylsiloxane ester 2 parts, the different tridecane ester of mono phosphoric acid ester 2 parts, taurate 5 parts, pyroglutamic acid methyl ester 5 parts and 5-chlorosamide 5 parts are weighed according to weight portion；
(2) mixing of polyster fibre, polyester fiber, nylon fiber, bamboo fiber, acid fiber by polylactic and acetate fiber being added in the alcoholic solution of 10%, insulation activation 1.5 hours, holding temperature is 50 DEG C；
(3) mixing of kapok, cotton, Folium Agaves Sisalanae, Caulis et Folium Lini and chitin being added in the boric acid solution of 5%, adopt ultrasonic grinder, Ultrasonic Pulverization 30 minutes, the power of ultrasonic grinder is 150W；
(4) solution of step (2) and step (3) is mixed, add reactor, then being sequentially added into nimbin, monoxone, p-phenylenediamine, Oleum Ricini pair-hydroxypropyl polydimethylsiloxane ester, the different tridecane ester of mono phosphoric acid ester in mixed liquor, stir 30 minutes, mixing speed is 1000 revs/min；
(5) in reactor, add taurate and pyroglutamic acid methyl ester, then reacting by heating still successively, make reaction temperature be promoted to 100 DEG C, be subsequently adding 5-chlorosamide, keep the mixing speed 1500 revs/min of reactor, continuously stirred 60 minutes；
(6) being filtered treated mixed solution processing, pore size filter is 20 microns；
(7) filter the liquid flowed out and enter double screw extruder, product is extruded, plastotype and drying。
The performance test results of the textile material prepared is as shown in table 1。
Embodiment 2
(1) polyster fibre 30 parts, 30 parts of polyester fiber, nylon fiber 20 parts, bamboo fiber 20 parts, acid fiber by polylactic 20 parts, acetate fiber 20 parts, kapok 20 parts, 20 parts of cotton, 20 parts of Folium Agaves Sisalanae, 20 parts of Caulis et Folium Lini, chitin 15 parts, nimbin 6 parts, monoxone 6 parts, p-phenylenediamine 3 parts, Oleum Ricini pair-hydroxypropyl polydimethylsiloxane ester 3 parts, mono phosphoric acid ester different tridecane ester 3 parts, 3 parts of aminoguanidine sulfonate, silicone grease ethyl ester 6 parts and 6 parts of a few lactams are weighed according to weight portion；
(2) mixing of polyster fibre, polyester fiber, nylon fiber, bamboo fiber, acid fiber by polylactic and acetate fiber being added in the alcoholic solution of 10%, insulation activation 2 hours, holding temperature is 60 DEG C；
(3) mixing of kapok, cotton, Folium Agaves Sisalanae, Caulis et Folium Lini and chitin being added in the boric acid solution of 5%, adopt ultrasonic grinder, Ultrasonic Pulverization 40 minutes, the power of ultrasonic grinder is 180W；
(4) solution of step (2) and step (3) is mixed, add reactor, then being sequentially added into nimbin, monoxone, p-phenylenediamine, Oleum Ricini pair-hydroxypropyl polydimethylsiloxane ester, the different tridecane ester of mono phosphoric acid ester in mixed liquor, stir 40 minutes, mixing speed is 1000 revs/min；
(5) in reactor, add aminoguanidine sulfonate and silicone grease ethyl ester, then reacting by heating still successively, make reaction temperature be promoted to 100 DEG C, be subsequently adding a few lactams, keep the mixing speed 1500 revs/min of reactor, continuously stirred 60 minutes；
(6) being filtered treated mixed solution processing, pore size filter is 30 microns；
(7) filter the liquid flowed out and enter double screw extruder, product is extruded, plastotype and drying。
The performance test results of the textile material prepared is as shown in table 1。
Embodiment 3
(1) polyster fibre 35 parts, 35 parts of polyester fiber, nylon fiber 30 parts, bamboo fiber 30 parts, acid fiber by polylactic 30 parts, acetate fiber 25 parts, kapok 35 parts, 20 parts of cotton, 20 parts of Folium Agaves Sisalanae, 18 parts of Caulis et Folium Lini, chitin 22 parts, nimbin 10 parts, monoxone 8 parts, p-phenylenediamine 4 parts, Oleum Ricini pair-hydroxypropyl polydimethylsiloxane ester 4 parts, the different tridecane ester of mono phosphoric acid ester 4 parts, lignosulfonates 7 parts, sucrose stearate 7 parts and sulfenamide 7 parts are weighed according to weight portion；
(2) mixing of polyster fibre, polyester fiber, nylon fiber, bamboo fiber, acid fiber by polylactic and acetate fiber being added in the alcoholic solution of 10%, insulation activation 2.5 hours, holding temperature is 65 DEG C；
(3) mixing of kapok, cotton, Folium Agaves Sisalanae, Caulis et Folium Lini and chitin being added in the boric acid solution of 5%, adopt ultrasonic grinder, Ultrasonic Pulverization 50 minutes, the power of ultrasonic grinder is 200W；
(4) solution of step (2) and step (3) is mixed, add reactor, then being sequentially added into nimbin, monoxone, p-phenylenediamine, Oleum Ricini pair-hydroxypropyl polydimethylsiloxane ester, the different tridecane ester of mono phosphoric acid ester in mixed liquor, stir 50 minutes, mixing speed is 1000 revs/min；
(5) in reactor, add lignosulfonates and sucrose stearate, then reacting by heating still successively, make reaction temperature be promoted to 100 DEG C, be subsequently adding sulfenamide, keep the mixing speed 1500 revs/min of reactor, continuously stirred 60 minutes；
(6) being filtered treated mixed solution processing, pore size filter is 65 microns；
(7) filter the liquid flowed out and enter double screw extruder, product is extruded, plastotype and drying。
The performance test results of the textile material prepared is as shown in table 1。
Embodiment 4
(1) polyster fibre 40 parts, 40 parts of polyester fiber, nylon fiber 35 parts, bamboo fiber 35 parts, acid fiber by polylactic 35 parts, acetate fiber 30 parts, kapok 45 parts, 25 parts of cotton, 25 parts of Folium Agaves Sisalanae, 25 parts of Caulis et Folium Lini, chitin 25 parts, nimbin 15 parts, monoxone 10 parts, p-phenylenediamine 5 parts, Oleum Ricini pair-hydroxypropyl polydimethylsiloxane ester 5 parts, the different tridecane ester of mono phosphoric acid ester 5 parts, vinylsulfonate 10 parts, stearate 10 parts and nicotinamide 10 parts are weighed according to weight portion；
(2) mixing of polyster fibre, polyester fiber, nylon fiber, bamboo fiber, acid fiber by polylactic and acetate fiber being added in the alcoholic solution of 10%, insulation activation 1.5-3 hour, holding temperature is 70 DEG C；
(3) mixing of kapok, cotton, Folium Agaves Sisalanae, Caulis et Folium Lini and chitin being added in the boric acid solution of 5%, adopt ultrasonic grinder, Ultrasonic Pulverization 60 minutes, the power of ultrasonic grinder is 250W；
(4) solution of step (2) and step (3) is mixed, add reactor, then being sequentially added into nimbin, monoxone, p-phenylenediamine, Oleum Ricini pair-hydroxypropyl polydimethylsiloxane ester, the different tridecane ester of mono phosphoric acid ester in mixed liquor, stir 60 minutes, mixing speed is 1000 revs/min；
(5) in reactor, add vinylsulfonate and stearate, then reacting by heating still successively, make reaction temperature be promoted to 100 DEG C, be subsequently adding nicotinamide, keep the mixing speed 1500 revs/min of reactor, continuously stirred 60 minutes；
(6) being filtered treated mixed solution processing, pore size filter is 70 microns；
(7) filter the liquid flowed out and enter double screw extruder, product is extruded, plastotype and drying。
The performance test results of the textile material prepared is as shown in table 1。
Comparative example 1
(1) 20 parts of polyester fiber, nylon fiber 15 parts, bamboo fiber 15 parts, acetate fiber 15 parts, kapok 25 parts, 15 parts of cotton, 15 parts of Folium Agaves Sisalanae, nimbin 5 parts, monoxone 5 parts, p-phenylenediamine 2 parts, Oleum Ricini pair-hydroxypropyl polydimethylsiloxane ester 2 parts, the different tridecane ester of mono phosphoric acid ester 2 parts, taurate 5 parts and 5-chlorosamide 5 parts are weighed according to weight portion；
(2) mixing of polyester fiber, nylon fiber, bamboo fiber and acetate fiber being added in the alcoholic solution of 10%, insulation activation 2 hours, holding temperature is 50 DEG C；
(3) mixing of kapok, cotton and Folium Agaves Sisalanae being added in the boric acid solution of 5%, adopt ultrasonic grinder, Ultrasonic Pulverization 40 minutes, the power of ultrasonic grinder is 150W；
(4) solution of step (2) and step (3) is mixed, add reactor, then being sequentially added into nimbin, monoxone, p-phenylenediamine, Oleum Ricini pair-hydroxypropyl polydimethylsiloxane ester, the different tridecane ester of mono phosphoric acid ester in mixed liquor, stir 40 minutes, mixing speed is 1000 revs/min；
(5) in reactor, add taurate, then reacting by heating still successively, make reaction temperature be promoted to 100 DEG C, be subsequently adding 5-chlorosamide, keep the mixing speed 1500 revs/min of reactor, continuously stirred 60 minutes；
(6) being filtered treated mixed solution processing, pore size filter is 50 microns；
(7) filter the liquid flowed out and enter double screw extruder, product is extruded, plastotype and drying。
The performance test results of the textile material prepared is as shown in table 1。
Comparative example 2
(1) polyster fibre 40 parts, nylon fiber 35 parts, bamboo fiber 35 parts, acid fiber by polylactic 35 parts, 25 parts of cotton, 25 parts of Folium Agaves Sisalanae, 25 parts of Caulis et Folium Lini, chitin 25 parts, monoxone 10 parts, p-phenylenediamine 5 parts, Oleum Ricini pair-hydroxypropyl polydimethylsiloxane ester 5 parts, the different tridecane ester of mono phosphoric acid ester 5 parts, sucrose stearate 10 parts and sulfenamide 10 parts are weighed according to weight portion；
(2) mixing of polyster fibre nylon fiber, bamboo fiber and acid fiber by polylactic being added in the alcoholic solution of 10%, insulation activation 2.5 hours, holding temperature is 60 DEG C；
(3) mixing of cotton, Folium Agaves Sisalanae, Caulis et Folium Lini and chitin being added in the boric acid solution of 5%, adopt ultrasonic grinder, Ultrasonic Pulverization 50 minutes, the power of ultrasonic grinder is 200W；
(4) solution of step (2) and step (3) is mixed, add reactor, then being sequentially added into monoxone, p-phenylenediamine, Oleum Ricini pair-hydroxypropyl polydimethylsiloxane ester, the different tridecane ester of mono phosphoric acid ester in mixed liquor, stir 50 minutes, mixing speed is 1000 revs/min；
(5) in reactor, add sucrose stearate, then reacting by heating still successively, make reaction temperature be promoted to 100 DEG C, be subsequently adding sulfenamide, keep the mixing speed 1500 revs/min of reactor, continuously stirred 60 minutes；
(6) being filtered treated mixed solution processing, pore size filter is 50 microns；
(7) filter the liquid flowed out and enter double screw extruder, product is extruded, plastotype and drying。
The performance test results of the textile material prepared is as shown in table 1。
The textile material of embodiment 1-4 and comparative example 1-2 is carried out respectively the performance test of antifungal and dust mite。
Table 1
The antifungal of the present invention and the textile material of dust mite are with polyster fibre, polyester fiber, nylon fiber, bamboo fiber, acid fiber by polylactic, acetate fiber, kapok, cotton, Folium Agaves Sisalanae, Caulis et Folium Lini, chitin, nimbin, monoxone, p-phenylenediamine, Oleum Ricini pair-hydroxypropyl polydimethylsiloxane ester, the different tridecane ester of mono phosphoric acid ester for main component, by adding dispersant, wetting agent and binding agent, it is aided with the techniques such as activation, pulverizing, stirring, filtration, extrusion, plastotype, drying so that the textile material being prepared from has the performance of good antifungal and dust mite。The novel textile material cheaper starting materials of the present invention, technique are simple, are suitable to heavy industrialization and use, practical。
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every equivalent structure utilizing description of the present invention to make or equivalence flow process conversion; or directly or indirectly it is used in other relevant technical fields, all in like manner include in the scope of patent protection of the present invention。

Claims (8)

1. the textile material of an antifungal and dust mite, it is characterized in that: be made up of the raw material of following weight portion: polyster fibre 20-40 part, polyester fiber 20-40 part, nylon fiber 15-35 part, bamboo fiber 15-35 part, acid fiber by polylactic 15-35 part, acetate fiber 15-30 part, kapok 25-45 part, cotton 15-25 part, Folium Agaves Sisalanae 15-25 part, Caulis et Folium Lini 15-25 part, chitin 10-25 part, nimbin 5-15 part, monoxone 5-10 part, p-phenylenediamine 2-5 part, Oleum Ricini pair-hydroxypropyl polydimethylsiloxane ester 2-5 part, mono phosphoric acid ester different tridecane ester 2-5 part, dispersant 5-10 part, wetting agent 5-10 part and binding agent 5-10 part。
2. the textile material of antifungal according to claim 1 and dust mite, it is characterised in that: one or more in taurate, aminoguanidine sulfonate, lignosulfonates and vinylsulfonate of described dispersant。
3. the textile material of antifungal according to claim 1 and dust mite, it is characterised in that: one or more in pyroglutamic acid methyl ester, silicone grease ethyl ester, sucrose stearate and stearate of described wetting agent。
4. the textile material of antifungal according to claim 1 and dust mite, it is characterised in that: one or more in 5-chlorosamide, a few lactams, sulfenamide and nicotinamide of described binding agent。
5. the preparation method according to the arbitrary described antifungal of Claims 1 to 4 and the textile material of dust mite, it is characterised in that comprise the following steps:
(1) each raw material is weighed according to weight portion；
(2) mixing of polyster fibre, polyester fiber, nylon fiber, bamboo fiber, acid fiber by polylactic and acetate fiber is added in the alcoholic solution of 10%, insulation activation 1.5-3 hour；
(3) mixing of kapok, cotton, Folium Agaves Sisalanae, Caulis et Folium Lini and chitin is added in the boric acid solution of 5%, adopt ultrasonic grinder, Ultrasonic Pulverization 30-60 minute；
(4) solution of step (2) and step (3) is mixed, add reactor, then in mixed liquor, it is sequentially added into nimbin, monoxone, p-phenylenediamine, Oleum Ricini pair-hydroxypropyl polydimethylsiloxane ester, the different tridecane ester of mono phosphoric acid ester, stirring 30-60 minute, mixing speed is 1000 revs/min；
(5) in reactor, add dispersant and wetting agent, then reacting by heating still successively, make reaction temperature be promoted to 100 DEG C, be subsequently adding binding agent, keep the mixing speed 1500 revs/min of reactor, continuously stirred 60 minutes；
(6) it is filtered treated mixed solution processing；
(7) filter the liquid flowed out and enter double screw extruder, product is extruded, plastotype and drying。
6. the preparation method of the textile material of antifungal according to claim 5 and dust mite, it is characterised in that in described step (2), the temperature of insulation is 50-70 DEG C。
7. the preparation method of the textile material of antifungal according to claim 5 and dust mite, it is characterised in that in described step (3), the power of ultrasonic grinder is 150-250W。
8. the preparation method of the textile material of antifungal according to claim 5 and dust mite, it is characterised in that in described step (6), the pore size filter of filtration treatment is 20-70 micron。
CN201610246559.1A 2016-04-20 2016-04-20 Antifungal anti-mite textile material and preparation method thereof Pending CN105696325A (en)

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CN107142552A (en) * 2017-07-03 2017-09-08 苏州市丹纺纺织研发有限公司 A kind of waterproof composite textile materials and preparation method thereof
CN107190356A (en) * 2017-05-17 2017-09-22 安徽新生纺织有限公司 A kind of medical fabric antibiotic radiation proof spinning and preparation method thereof
CN107254778A (en) * 2017-07-25 2017-10-17 安徽亚源印染有限公司 A kind of flax artificial cotton elastic fabric of antibacterial resistant
CN107268115A (en) * 2017-07-03 2017-10-20 苏州舒而适纺织新材料科技有限公司 A kind of composite textile materials added with Kaempferol and preparation method thereof
CN107326473A (en) * 2017-07-03 2017-11-07 苏州舒而适纺织新材料科技有限公司 A kind of antifouling wear-resisting textile material and preparation method thereof
CN108193312A (en) * 2017-12-29 2018-06-22 付主枝 A kind of preparation method and applications of composite fibre textile material
CN108893994A (en) * 2018-06-06 2018-11-27 吴江康欣医用敷料有限公司 A kind of preparation method of hydrophobic toughening type non-woven fabrics
CN109137138A (en) * 2018-09-13 2019-01-04 石狮市中纺学服装及配饰产业研究院 A kind of novel waterproof air previous antibacterial fabric and preparation method thereof
CN109938054A (en) * 2019-04-16 2019-06-28 宁波芮颂生物科技有限公司 A kind of preparation method of house dust mite antiallergy spray
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Publication number Priority date Publication date Assignee Title
CN106917162A (en) * 2017-04-19 2017-07-04 马志明 Weaving face fabric for medical care industry and preparation method thereof
CN107190356A (en) * 2017-05-17 2017-09-22 安徽新生纺织有限公司 A kind of medical fabric antibiotic radiation proof spinning and preparation method thereof
CN107142552A (en) * 2017-07-03 2017-09-08 苏州市丹纺纺织研发有限公司 A kind of waterproof composite textile materials and preparation method thereof
CN107268115A (en) * 2017-07-03 2017-10-20 苏州舒而适纺织新材料科技有限公司 A kind of composite textile materials added with Kaempferol and preparation method thereof
CN107326473A (en) * 2017-07-03 2017-11-07 苏州舒而适纺织新材料科技有限公司 A kind of antifouling wear-resisting textile material and preparation method thereof
CN107254778A (en) * 2017-07-25 2017-10-17 安徽亚源印染有限公司 A kind of flax artificial cotton elastic fabric of antibacterial resistant
CN108193312A (en) * 2017-12-29 2018-06-22 付主枝 A kind of preparation method and applications of composite fibre textile material
CN108893994A (en) * 2018-06-06 2018-11-27 吴江康欣医用敷料有限公司 A kind of preparation method of hydrophobic toughening type non-woven fabrics
CN109137138A (en) * 2018-09-13 2019-01-04 石狮市中纺学服装及配饰产业研究院 A kind of novel waterproof air previous antibacterial fabric and preparation method thereof
CN109938054A (en) * 2019-04-16 2019-06-28 宁波芮颂生物科技有限公司 A kind of preparation method of house dust mite antiallergy spray
CN114045673A (en) * 2021-11-12 2022-02-15 杭州港华纺织有限公司 Antibacterial polyester mixed fiber elastic yarn and preparation method thereof
CN114045673B (en) * 2021-11-12 2023-10-03 杭州港华纺织有限公司 Antibacterial polyester mixed fiber elastic yarn and preparation method thereof

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Application publication date: 20160622