CN107141008A - A kind of seamless stem grafting technique of double-deck hair porcelain - Google Patents

A kind of seamless stem grafting technique of double-deck hair porcelain Download PDF

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Publication number
CN107141008A
CN107141008A CN201610139294.5A CN201610139294A CN107141008A CN 107141008 A CN107141008 A CN 107141008A CN 201610139294 A CN201610139294 A CN 201610139294A CN 107141008 A CN107141008 A CN 107141008A
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China
Prior art keywords
cup
porcelain
seamless
double
glaze
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Pending
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CN201610139294.5A
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Chinese (zh)
Inventor
黄文澜
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Zhuzhou Secret Ceramic Technology Development Co Ltd
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Zhuzhou Secret Ceramic Technology Development Co Ltd
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Priority to CN201610139294.5A priority Critical patent/CN107141008A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B37/00Joining burned ceramic articles with other burned ceramic articles or other articles by heating
    • C04B37/003Joining burned ceramic articles with other burned ceramic articles or other articles by heating by means of an interlayer consisting of a combination of materials selected from glass, or ceramic material with metals, metal oxides or metal salts
    • C04B37/005Joining burned ceramic articles with other burned ceramic articles or other articles by heating by means of an interlayer consisting of a combination of materials selected from glass, or ceramic material with metals, metal oxides or metal salts consisting of glass or ceramic material
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/24Manufacture of porcelain or white ware
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/14Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/16Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Structural Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Inorganic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

The present invention relates to a kind of double-deck seamless stem grafting technique of hair porcelain, the present invention comprises the following steps:1) two layers of 2mm ultra-thin cup is first done, then enters kiln biscuiting one time;2) and then outside the tank draw a design, then spliced cup on side and cup face with pug;3) kiln-firing again, i.e., high temperature is burnt till twice.Bilayer hair porcelain stem grafting technique of the invention, you can allow cup thinness to reach the standard of mao porcelain, and can accomplish seamless spliced, do not stay fabrication hole, makes that cup exquisiteness is attractive in appearance, and heat insulation effect is splendid.

Description

A kind of seamless stem grafting technique of double-deck hair porcelain
Technical field
The present invention relates to field of ceramic processing, a kind of seamless stem grafting technique of double-deck hair porcelain is referred in particular to.
Background technology
Ceramic cup is almost our most common products, and either articles for daily use or ornament are all frequently using ceramics.Ceramic cup Pernicious gas and material that plastic cup is brought are lacked compared with plastic cup, have confirmed that plastic cup, which is used for a long time, carcinogenic disease according to expert May.Ceramic cup is completely harmless, and the possibility for having intake poisonous metal will not be used for a long time as metal cup in it.Its In increasingly liked with double-layer ceramic cup by people because double-layer ceramic cup heat insulation and preservation effect is good.
Double-layer ceramic cup original splicing process is as follows:Two layers of cup is done, it is stitched together when cup is in wet moulded pottery not yet put in a kiln to bake state, stay one Aperture, kiln-firing, the water vapour that wet moulded pottery not yet put in a kiln to bake is produced in high temperature can be discharged by aperture, so that hollow drying is kept, Then by 1380 degree of high temperature once-firings.The splicing process by technology and method due to being limited, it is impossible to is made thin tire splicing, is led Cause cup thicker, and leave fabrication hole, not only influence attractive in appearance, can also cause air to enter, influence heat insulation effect.
The content of the invention
The purpose of the present invention is to be improved and innovated that there is provided a kind of technique is simple for shortcoming present in background technology and problem The seamless stem grafting technique of double-deck hair porcelain.
The present invention comprises the following steps:1) two layers of 2mm ultra-thin cup is first done, then enters kiln biscuiting one time;2) and then inside Draw a design, then spliced cup on the outside of courage and on cup face with pug;3) kiln-firing again, i.e., high temperature is burnt till twice.
Present invention cup when pug splices cup is dried, and does not stay steam to discharge aperture.
Advantages of the present invention and beneficial effect:
Bilayer hair porcelain stem grafting technique of the invention, you can allow cup thinness to reach the standard of mao porcelain, and can accomplish seamless spliced, do not stay Fabrication hole, makes that cup exquisiteness is attractive in appearance, and heat insulation effect is splendid.
Embodiment
For ease of understanding the present invention, embodiments of the invention are shown below is.But, the present invention can be in many different forms To realize, however it is not limited to embodiment described herein.On the contrary, the purpose for providing these embodiments is to make the public affairs to the present invention Open content more thorough comprehensive.
Unless otherwise defined, all technologies used herein and scientific terminology and the those skilled in the art of the present invention The implication being generally understood that is identical.Term used in the description is intended merely to describe specifically to implement purpose, it is not intended that in limit The system present invention.
Embodiment:
Two layers of 2mm ultra-thin cup is done, enters kiln biscuiting one time, is then drawn a design outside the tank on side and cup face, will with pug Cup splices, and now cup is dried, and is not required to stay aperture, again kiln-firing, i.e., high temperature is burnt till twice.
The ceramic production technology flow that the present invention is used:
--- --- prepared by base, glaze --- --- glazing --- burns till --- decoration --- inspection --- packaging to raw material for shaping for inspection --- dispatch from the factory.
1st, base, glaze raw material.
A, base raw material
Preparing blank primary raw material has quartzy (main component is silica-SiO2), the feldspar (silicon of alkali metal or alkaline-earth metal Hydrochlorate, commonly uses potassium feldspar-K2OAl2O36SiO2), clay (aqueous aluminium silicon salt mineral, predominantly Al2O36SiO2 and knot Brilliant water) etc..
B, glaze raw material
Glaze is to be covered in the very thin glass state material of ceramic body surface last layer, and its thickness is usually 0.2---0.8mm, is prepared Ceramic glaze primary raw material has feldspar (silicate of alkali metal or alkaline-earth metal commonly uses potassium feldspar-K2OAl2O36SiO2), slided Stone (aqueous silicon salt mineral-Mg3 [Si4O10] (OH) 2), quartzy (main component is silica-SiO2), clay (contain The aluminium silicon salt mineral of water, predominantly Al2O36SiO2 and the crystallization water) and calcite (main component is calcium carbonate-CaCO3) Deng.
Clay (aqueous aluminium silicon salt mineral, predominantly Al2O36SiO2 and the crystallization water) belongs to plastic material in ceramic raw material, With certain plasticity, main in production to play plasticizing and combination, it assigns blank plasticity and injection forming performance, protects Various performances such as mechanical strength, heat endurance, chemical stability etc. after demonstrate,proving dry body strength and burning, they are that shaping can The basis of progress, is also the basic into porcelain of clay potting porcelain.
Quartzy (main component is silica-SiO2) category non-plastic raw material, is non-plastic material, and visbreaking work is played in production With, it is possible to decrease the viscosity of blank, burn till rear part quartz and be dissolved in feldspar glass, improve liquid phase viscosity, prevent high temperature deformation, After cooling skeleton function is played in porcelain base.
The alkali metal such as feldspar, calcite, the oxide of alkaline-earth metal and oxysalt belong to solvent borne raw material, and they rise help in production A part of quartz and kaolin catabolite can be dissolved after molten effect, high-temperature fusion, the height glass after melting can play height Warm cementation.Also visbreaking is played during normal temperature.
2nd, prepared by base, glaze.
A, blank preparation technology flow:
Ceramic batch can be divided into stiff-mud process blank and slip casting method blank by the forming method of its product.
(1) stiff-mud process blank preparation technology flow:
Weighing and feed intake by formula, --- --- slurry detection fineness --- blowing (multistage is sieved, except iron) --- is taken out in ball milling timing to ball milling --- taking out slurry press filt, --- --- old (15 days) --- concise (2 times) --- are standby for thick white silk (2 times) for slurry sediment pool.
(2) slip casting method blank preparation technology flow:
Weighing and feed intake by formula, --- --- slurry detection fineness --- blowing (multistage is sieved, except iron) --- is taken out in ball milling timing to ball milling Slurry sediment pool --- take out slurry press filt --- broken cake slurrying --- plus electrolyte is --- old --- standby.
B, glaze preparation technique flow:
Weighing and feed intake by formula, --- --- slurry detection fineness is taken out in ball milling timing, and --- blowing --- sieving (2 times) --- is removed ball milling Iron (3 times) --- deposit stock tank old standby.
3rd, it is molded.
Shaping is exactly, with dry plaster mold, the blank prepared to be made to required blank of a variety of methods, at present The conventional method of forming has plastic molding, injection forming, dry-pressing formed and isostatic pressing, Hunan producing region domestic ceramics and art pottery Porcelain mainly uses (spinning the is He Roll is pressed) shaping of machine pressure and injection forming in plastic forming.
A, machine pressure (spinning is He Roll is pressed) forming technology flow:
Pug --- cutting slice, --- --- --- --- examine leather-hard drying pressed compact for the demoulding by body drying --- repaired biscuit ---.
B, slip-casting shaping process flow:
Mud --- --- pouring out remaining slurry, --- --- being stripped base, --- examine leather-hard drying for slip casting by repaired biscuit --- body drying --- Test.
4th, glazing.
To molding inspection qualified products glazing, " glazing " is commonly called as, has two kinds of green compact glazing method and biscuit glazing method, according to difference Product and blank size, thickness and glaze performance, can use leaching glaze, pour the methods such as glaze, brushing glazing, glaze spraying.
5th, burn till.
It is very crucial process together in technology in producing porcelain to burn till, and always has speaking for " raw on mud, extremely on kiln ", it is seen that burn Into the importance in ceramic making.Through the semi-finished product after overmolding, glazing, in the presence of high temperature, occurs a series of physical Chemical reaction, last apparent porosity can be only achieved the porcelain phenomenon of complete compactness extent close to zero.
Product burns till quality control mainly by calcining system control, and calcining system includes temperature schedule, atmosphere system and pressure system Degree.
A, preheating (normal temperature~300 DEG C):
This stage is mainly the exclusion of base glaze residual moisture.In this stage, appropriate programming rate should be kept to ensure base substrate And in glaze layer moisture discharge, there is no particular/special requirement to atmosphere, usually oxidizing atmosphere.
B, oxidation Decomposition stage (300~950 DEG C):
The chemical change that ceramic blank glaze occurs in this stage mainly has:The crystallization water is excluded, organic matter, sulfide-oxidation, carbonate Decompose, quartz crystal transformation etc..
This stage programming rate and atmosphere are mainly relevant with the factor such as blank chemical composition, base substrate size, shape and setting density, Carrying out appropriate insulation in the oxidation Decomposition later stage contributes to decomposition reaction to carry out completely.This stage is typically burnt till using oxidizing flame, with Make some organic matters, sulfide-oxidation.
C, hot stage (950 DEG C~maximum sintering temperature):
The stage base substrate starts liquid phase occur, and glaze layer starts melting.
Determine whether to use firing with reductive flame according to ferrotitanium content in base glaze and to the color requirement of products appearance.Using reduction When flame is burnt till, this stage is divided into strong reduction period, weak reduction period stage again.
Reduction phase should terminate after weak reduction period is switched to by strong reduction period.At this moment glaze layer has been mature on the whole, and various reduction reactions are Substantially terminate.But, if at this moment switching to oxidizing atmosphere quickly, the easy secondary oxidation of divalence iron rule after reduction makes product turn to be yellow, Therefore, a section of reduction atmosphere should be maintained until glaze layer full maturity.
In hot stage, due to amount of liquid phase increase, the porosity reduces, and base substrate produces larger contraction, at this moment it should be noted that by kiln The temperature difference minimizes, and prevents from causing product deformation or cracking greatly very much due to shrinking difference.
D, high fiery holding stage:
The main function of high fire insulation is to reduce the temperature difference in kiln, so that base substrate each several part physical-chemical reaction carries out complete, tissue Structure tends to be homogeneous, glaze melt is sprawled well on base substrate.
E, cooling stage:
More than 850 DEG C due to there is more liquid phase, therefore base substrate is also in mecystasis, can carry out rapid cooling.Rapid cooling can prevent liquid phase Crystallization, crystal are grown up and low price iron is reoxidized, so as to improve the intensity of base substrate, whiteness and glaze glossiness.
Because liquid phase starts solidification below 850 DEG C, slow cooling is answered.Particularly to containing the more product of alkali and Free quartz, not Same cooling stage should control appropriate cooling velocity, to ensure glaze quality.
6th, decorate.
Ceramic decoration can be divided into according to the difference of ornament materials:Base substrate decoration, color glaze decoration and painted decoration.
Base substrate decoration is on half-dried or absolutely dry base substrate, to be decorated using the clay of same nature, can carve, carve, heap, picking Deng.
Color glaze decoration is that assorted coloured glaze is hung on absolutely dry base substrate or the ceramic body of biscuiting, and after being burnt till through high temperature, the five colors are presented Bright-colored decorative effect.
Ceramic illuminated is a kind of decoration side painted with various proprietary pigment after ceramic body or glazing are burnt till on semi-finished product Method.It can be divided on glaze and underglaze colour is painted, over-glaze decoration is to be painted on the glaze for burnt till porcelain with pigment, reenters kiln and exists The kind of after baking between 600--900 DEG C.It is that decorative pattern adds coloured silk on green compact or biscuiting base substrate or glaze tire that underglaze colour, which is painted, on Glaze, through 1340 DEG C of high temperature above once-firings, color is fully penetrated into base glaze, bright in luster, light grace.
Embodiment of the present invention is only the description carried out to the preferred embodiment of the present invention, not to present inventive concept and Scope is defined, on the premise of design philosophy of the present invention is not departed from, technology of the engineers and technicians to the present invention in this area The all variations and modifications that scheme is made, all should fall into protection scope of the present invention, claimed technology contents of the invention, Through all recording in detail in the claims.

Claims (2)

1. a kind of seamless stem grafting technique of double-deck hair porcelain, it is characterised in that comprise the following steps:
1) two layers of 2mm ultra-thin cup is first done, then enters kiln biscuiting one time;
2) and then outside the tank draw a design, then spliced cup on side and cup face with pug;
3) kiln-firing again, i.e., high temperature is burnt till twice.
2. the seamless stem grafting technique of double-deck hair porcelain according to claim 1, it is characterised in that cup when described pug splices cup Soma is dry, does not stay steam to discharge aperture.
CN201610139294.5A 2016-03-01 2016-03-01 A kind of seamless stem grafting technique of double-deck hair porcelain Pending CN107141008A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610139294.5A CN107141008A (en) 2016-03-01 2016-03-01 A kind of seamless stem grafting technique of double-deck hair porcelain

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Application Number Priority Date Filing Date Title
CN201610139294.5A CN107141008A (en) 2016-03-01 2016-03-01 A kind of seamless stem grafting technique of double-deck hair porcelain

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CN107141008A true CN107141008A (en) 2017-09-08

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108383508A (en) * 2018-03-01 2018-08-10 台宜陶瓷(宜兴)有限公司 Double layer cup technological process
CN116135816A (en) * 2021-11-16 2023-05-19 深圳市智善陶瓷科技有限公司 Ceramic preparation method
CN116655350A (en) * 2022-02-21 2023-08-29 深圳市智善陶瓷科技有限公司 Adhesive for green compact, adhesive preparation method and ceramic preparation method

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CN101967060A (en) * 2009-12-30 2011-02-09 福建省德化县云姿陶瓷有限公司 Method for firing domestic porcelain
CN102503442A (en) * 2011-11-24 2012-06-20 危用之 High-temperature fine porcelain splice connecting method
CN103508723A (en) * 2012-06-29 2014-01-15 醴陵四德五彩国瓷有限公司 Method for manufacturing high-temperature underglazed five-color mao-ceramic double-layer vacuum cup

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6077179A (en) * 1983-10-03 1985-05-01 工業技術院長 Method of adhering silicon nitride ceramic sintered body
CN101967060A (en) * 2009-12-30 2011-02-09 福建省德化县云姿陶瓷有限公司 Method for firing domestic porcelain
CN102503442A (en) * 2011-11-24 2012-06-20 危用之 High-temperature fine porcelain splice connecting method
CN103508723A (en) * 2012-06-29 2014-01-15 醴陵四德五彩国瓷有限公司 Method for manufacturing high-temperature underglazed five-color mao-ceramic double-layer vacuum cup

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Title
周旭: "提出"毛瓷"醴陵烧制的第一人——萧根如", 《陶瓷科学与艺术》 *
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108383508A (en) * 2018-03-01 2018-08-10 台宜陶瓷(宜兴)有限公司 Double layer cup technological process
CN116135816A (en) * 2021-11-16 2023-05-19 深圳市智善陶瓷科技有限公司 Ceramic preparation method
CN116655350A (en) * 2022-02-21 2023-08-29 深圳市智善陶瓷科技有限公司 Adhesive for green compact, adhesive preparation method and ceramic preparation method

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Application publication date: 20170908