CN107129288B - 替代天然玉石石材的环保型瓷砖及其制备方法 - Google Patents

替代天然玉石石材的环保型瓷砖及其制备方法 Download PDF

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CN107129288B
CN107129288B CN201710332007.7A CN201710332007A CN107129288B CN 107129288 B CN107129288 B CN 107129288B CN 201710332007 A CN201710332007 A CN 201710332007A CN 107129288 B CN107129288 B CN 107129288B
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宋文通
周桂林
张京洞
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Shandong Yadi Ceramics Co Ltd
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Abstract

本发明属于建筑陶瓷技术领域,具体涉及一种替代天然玉石石材的环保型瓷砖及其制备方法。所述的瓷砖,包括坯体料层、装饰釉料层和功能釉料层,其中,坯体料层由如下原料制成:烟台长石、海南泥、高铝石、沙河瓷石、广西土和河北土;装饰釉料层由如下原料制成:钾长石、钠长石、烧滑石、氧化锌、高岭土、煅烧土、石英和氧化铝;功能釉料层由如下原料制成:钾长石、烧滑石、氧化锌、碳酸钡、氧化铝、熔块、高岭土、煅烧土和刚玉。本发明瓷砖具有陶瓷地砖的优异性能及天然玉石石材的装饰效果,耐用、耐磨、透感强、无辐射,经检测莫氏硬度5级以上,耐磨度4级以上,达到促进人体健康,保护生活和工作环境的作用。

Description

替代天然玉石石材的环保型瓷砖及其制备方法
技术领域
本发明属于建筑陶瓷技术领域,具体涉及一种替代天然玉石石材的环保型瓷砖及其制备方法。
背景技术
建筑装饰用瓷砖因能赋予装饰空间美观、整洁和优雅的氛围,近年来备受消费者的青睐。天然玉石石材是近年来广受人们喜爱的一种产品,但因为天然玉石石材成本高,开采时破坏自然环境。另外,天然大理石、花岗岩、玉石石材存在硬度差、不耐磨、吸污、有辐射、易损坏、有瑕疵等问题。相比于其它地面装饰材料,瓷砖在装饰效果的实现和家居卫生的保洁及价格方面具有明显的优势。
如何制备出能够替代天然玉石石材使用的环保型瓷砖,成为亟待解决的技术问题。
发明内容
针对现有技术的不足,本发明的目的是提供一种替代天然玉石石材的环保型瓷砖,仿天然玉石石材纹理和花色逼真,硬度高、耐磨性好、透感强、无辐射,具有“源于玉石,高于玉石”的良好装饰效果;本发明同时提供其制备方法,科学合理、简单易行。
本发明所述的替代天然玉石石材的环保型瓷砖,包括坯体料层、装饰釉料层和功能釉料层,其中,
坯体料层由如下重量百分比的原料制成:
坯体料层原料总质量按100%计;
装饰釉料层由如下重量百分比的原料制成:
装饰釉料层原料总质量按100%计;
功能釉料层由如下重量百分比的原料制成:
功能釉料层原料总质量按100%计。
本发明坯体料层中采用的海南泥为蒙脱石类粘土,具有高强度、高白度、耐高温、好氧化的特性。
所述的装饰釉料层选用的原料之间协同作用,制备得到的装饰釉料层具有遮盖力强、白度高、发色强、成本低的优点。
本发明在功能釉料中加入刚玉、熔块,经烧成后的瓷砖表面釉料层透明度高,对底部装饰釉料层的遮盖力非常小,以及釉料层内均匀分布的化学组分、表面致密无细孔的结构使得瓷砖的防污性能、莫氏硬度、耐磨度都有很好的保障及极佳的装饰效果。
其中:
所述的坯体料层的厚度为10-12mm,装饰釉料层的厚度为0.5-0.8mm,功能釉料层的厚度为0.2-0.5mm。
所述的熔块的组成如下:以重量百分比计:
SiO2 50.5%,Al2O3 14.8%,BaO 7.5%,CaO 10.3%,MgO 3.2%,ZnO 5.8%,R2O2.9%,B2O3 3.2%,Fe2O3 0.2%,TiO2 0.08%,余量为常规矿物杂质,烧失4.3,其中,R2O为Na2O和K2O之和。
本发明所述的替代天然玉石石材的环保型瓷砖的制备方法,包括如下步骤:
(1)坯体制备:首先,将坯体原料装入球磨机湿法研磨成泥浆,然后通过喷雾造粒成空心圆形颗粒,再陈腐后经过压机压制成型,烘干后制成坯体;
(2)釉料制备及施釉:将装饰釉料层和功能釉料层原料分别研磨制成釉浆,在坯体上首先施装饰釉料,然后通过喷墨打印机打印玉石石材纹理,再施功能釉料后烘干;
(3)产品烧成:步骤(2)所得的施釉后的坯体经辊道窑烧成,得产品。
其中:
步骤(1)中,湿法研磨的时间为13-15小时。
步骤(1)中,泥浆细度为250目筛余0.8-1.2%,水分为37.5-38.5wt.%。
步骤(1)中,陈腐时间为24-48h。
步骤(1)中,颗粒的粒径为2.5-3.0mm。
步骤(1)中,经干燥窑烘干后制成坯体,烘干温度为200-230℃,时间为45-55分钟。烘干过程利用一部分余热。
步骤(2)中,釉浆细度为325目筛余0.8-1.0%,水分为28-31wt.%。
步骤(2)中,通过喷墨打印机打印玉石石材纹理为:将天然玉石石材通过高清分辨率扫描仪把纹理做成喷墨文件,再修改整理通过喷墨打印机8通道8色打印玉石石材纹理。所述的修改整理为对天然玉石石材上的瑕疵进行修改和整理。
步骤(2)中,施功能釉料后经干燥窑烘干,烘干温度为70-100℃,时间为10-20分钟。烘干过程利用一部分余热。
步骤(3)中,烧成温度为1170-1190℃,烧成周期为50-70min。
本发明生产工艺流程如下:原料选购→原料进仓→原料检验分析→原料陈腐均化→制定配方→原料球磨→浆料过筛除铁→料粉陈腐→压制成型→砖坯干燥→釉线施装饰釉→喷墨→施功能釉→窑炉烧成→抛光→成品分级→打蜡上光→打包→入库。
本发明采用以下六大环保节能措施:
1、低碳化供应链:原材料与燃料就地取材,缩短物资长途运输,降低废气污染排放。
2、低排放燃料替代:用燃烧值更高的天然气取代传统的煤和水煤气作为燃料减排环保。
3、绿色环保配方:废料回收利用,配方中不含辐射材料,倡导绿色生态砖,保护大众身体健康。
4、降低单位能耗:引进最先进的超长宽体窑炉,大吨位球磨机、压机与超洁亮抛光线,提高产量、降低单位能耗,走低碳发展道路。
5、热能循环利用:将窑炉热能同步导入干燥窑,充分利用窑炉余热达到低碳、节能的目的。
6、水资源再生利用:引进专业污水处理设施,对污水排放进行再生处理,循环利用。
本发明替代天然玉石石材的环保型瓷砖来源于天然玉石材的灵感,将天然玉石材通过高清分辨率扫描仪把纹理做成喷墨文件,通过合理的生产工艺流程把瓷砖的装饰图案,纹理和花色显得非常逼真,结合独有的配方生产出具有实用价值,装饰效果好,无辐射的绿色生态砖,应用前景十分广阔。
综上所述,本发明的有益效果如下:
(1)本发明所述的替代天然玉石石材的环保型瓷砖具有陶瓷地砖的优异性能及装饰效果,耐用、耐磨、透感强、无辐射,经检测莫氏硬度5级以上,耐磨度4级以上,达到促进人体健康,保护生活和工作环境的作用。
(2)本发明所述的制备方法,科学合理、简单易行。
具体实施方式
下面结合实施例对本发明做进一步说明。
实施例中采用的所有原料,除特殊说明外均为市购。
实施例中采用的原料的化学重量百分组成见表1。
表1 实施例中采用的原料的化学重量百分组成
SiO2 Al2O3 Fe2O3 TiO2 CaO MgO K2O Na2O 烧失
烟台长石 74.81 14.20 0.16 0.05 0.61 0.21 4.28 3.61 0.50
钾长石 65.33 19.60 0.02 - 0.05 0.03 11.20 2.85 0.65
钠长石 72.35 15.20 0.05 - 0.58 0.15 2.10 8.8 0.40
烧滑石 63.8 - - - - 33.85 - - 3.20
煅烧土 55.8 45.30 - - - - - - 0.70
高岭土 52.7 38.50 - - - - - - 7.80
海南泥 60.01 30.85 1.00 0.35 0.70 0.45 0.18 0.19 6.38
沙河瓷石 58.81 26.02 0.59 0.88 0.70 0.51 4.98 4.38 2.98
广西土 73.02 20.00 0.51 0.35 0.81 0.57 0.92 0.51 3.39
高铝石 37.41 59.03 0.72 0.99 0.51 0.30 0.18 0.25 0.73
河北土 74.20 13.71 0.45 0.09 2.01 1.35 2.01 2.13 3.58
石英 99.30 - 0.08 - - - - - 0.68
表中原料的组成不足100%者,余量为常规矿物杂质。
其它原料为工业纯化工原料。
所述的熔块的组成如下:以重量百分比计:
SiO2 50.5%,Al2O3 14.8%,BaO 7.5%,CaO 10.3%,MgO 3.2%,ZnO 5.8%,R2O2.9%,B2O3 3.2%,Fe2O3 0.2%,TiO2 0.08%,余量为常规矿物杂质,烧失4.3,其中,R2O为Na2O和K2O之和。
实施例1-6原料重量百分组成和和工艺参数见表2。
表2 实施例1-6原料重量百分组成和工艺参数
分别对实施例1-6制备的替代天然玉石石材的环保型瓷砖进行检测,检测结果见表3。
表3 检测结果
实施例1 实施例2 实施例3 实施例4 实施例5 实施例6
莫氏硬度 4.5 4.5 4.5 5 5 4.5
耐磨度 3.5 3.5 4 4 4 4
亮度 95 97 98 103 105 100
将实施例1-6制备的替代天然玉石石材的环保型瓷砖委托国家陶瓷与耐火材料产品质量监督检验中心进行检测,主要对以下性能进行检测:釉面耐磨性;耐污染性;抗化学腐蚀性;放射性等。检测结果见表4。
表4 检测结果

Claims (10)

1.一种替代天然玉石石材的环保型瓷砖,其特征在于:包括坯体料层、装饰釉料层和功能釉料层,其中,
坯体料层由如下重量百分比的原料制成:
烟台长石 36-45%;
海南泥 10-18%;
高铝石 8-15%;
沙河瓷石 3-10%;
广西土 5-15%;
河北土 5-15%;
坯体料层原料总质量按100%计;
装饰釉料层由如下重量百分比的原料制成:
钾长石 13-18%;
钠长石 30-40%;
烧滑石 2-6%;
氧化锌 1-2%;
高岭土 10-15%;
煅烧土 8-15%;
石英 13-26%;
氧化铝 3-10%;
装饰釉料层原料总质量按100%计;
功能釉料层由如下重量百分比的原料制成:
钾长石 15-35%;
烧滑石 8-15%;
氧化锌 10-16%;
碳酸钡 8-10%;
氧化铝 2-5%;
熔块 10-30%;
高岭土 8-13%;
煅烧土 2-5%;
刚玉 2-8%;
功能釉料层原料总质量按100%计。
2.根据权利要求1所述的替代天然玉石石材的环保型瓷砖,其特征在于:所述的坯体料层的厚度为10-12mm,装饰釉料层的厚度为0.5-0.8mm,功能釉料层的厚度为0.2-0.5mm。
3.根据权利要求1所述的替代天然玉石石材的环保型瓷砖,其特征在于:所述的熔块的组成如下:以重量百分比计:
SiO250.5%,Al2O314.8%,BaO7.5%,CaO10.3%,MgO3.2%,ZnO5.8%,R2O2.9%,B2O33.2%,Fe2O30.2%,TiO20.08%,余量为常规矿物杂质,烧失4.3%,其中,R2O为Na2O和K2O之和。
4.一种权利要求1-3任一所述的替代天然玉石石材的环保型瓷砖的制备方法,其特征在于:包括如下步骤:
(1)坯体制备:首先,将坯体原料装入球磨机湿法研磨成泥浆,然后通过喷雾造粒成空心圆形颗粒,再陈腐后经过压机压制成型,烘干后制成坯体;
(2)釉料制备及施釉:将装饰釉料层和功能釉料层原料分别研磨制成釉浆,在坯体上首先施装饰釉料,然后通过喷墨打印机打印玉石石材纹理,再施功能釉料后烘干;
(3)产品烧成:步骤(2)所得的施釉后的坯体经辊道窑烧成后得产品。
5.根据权利要求4所述的替代天然玉石石材的环保型瓷砖的制备方法,其特征在于:步骤(1)中,泥浆细度为250目筛余0.8-1.2%,水分为37.5-38.5wt.%。
6.根据权利要求4所述的替代天然玉石石材的环保型瓷砖的制备方法,其特征在于:步骤(1)中,颗粒的粒径为2.5-3.0mm。
7.根据权利要求4所述的替代天然玉石石材的环保型瓷砖的制备方法,其特征在于:步骤(1)中,经干燥窑烘干后制成坯体,烘干温度为200-230℃,时间为45-55分钟。
8.根据权利要求4所述的替代天然玉石石材的环保型瓷砖的制备方法,其特征在于:步骤(2)中,釉浆细度为325目筛余0.8-1.0%,水分为28-31wt.%。
9.根据权利要求4所述的替代天然玉石石材的环保型瓷砖的制备方法,其特征在于:步骤(2)中,施功能釉料后经干燥窑烘干,烘干温度为70-100℃,时间为10-20分钟。
10.根据权利要求4所述的替代天然玉石石材的环保型瓷砖的制备方法,其特征在于:步骤(3)中,烧成温度为1170-1190℃,烧成周期为50-70min。
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