CN107117816A - 窑变白釉及其制作方法、用窑变白釉制作窑变白釉陶瓷制品的方法 - Google Patents

窑变白釉及其制作方法、用窑变白釉制作窑变白釉陶瓷制品的方法 Download PDF

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CN107117816A
CN107117816A CN201710481944.9A CN201710481944A CN107117816A CN 107117816 A CN107117816 A CN 107117816A CN 201710481944 A CN201710481944 A CN 201710481944A CN 107117816 A CN107117816 A CN 107117816A
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曾金钟
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Fujian Province Dehua Qili New Technology Co Ltd
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Abstract

本发明涉及一种窑变白釉及其制作方法、用窑变白釉制作窑变白釉陶瓷制品的方法,属于陶瓷技术领域。该发明的窑变白釉包括按照质量份数计的如下组份:长石45~55份,石英8~11份,高岭土8.0~8.4份,氧化钙8.0~8.4份,氧化钡8.0~8.4份,五氧化二钒6.3~6.7份,氧化锆6.2~6.8份,氧化钛3.1~3.8份,氧化钠4.1~4.5份,氧化铈5~7份,氧化镧6~8份,天青石2~4份,菱锶矿2~4份,所述的窑变白釉的制作方法包括如下步骤:备料并球磨、除铁及过筛、釉浆制作、模具制作、坯体制作、施釉和釉烧。本发明的窑变白釉陶瓷制品环保节能,釉面白里透黄,微观有拉丝结晶。

Description

窑变白釉及其制作方法、用窑变白釉制作窑变白釉陶瓷制品 的方法
技术领域
本发明属于陶瓷技术领域,具体涉及一种窑变白釉及其制作方法、用窑变白釉制作窑变白釉陶瓷制品的方法。
背景技术
白釉是瓷器传统釉色之一,真正的白釉应该是乳白色的乳浊釉,这种釉是近代才发明的。我国古代仅有元代枢府釉是失透的,其他白釉并不是白色的釉,而是将不含金属氧化物呈色元素的釉料施于胎骨洁白的器物上,入窑高温烧制而成的透明釉,釉色因白润瓷胎的映衬而显出白色,现在习惯上将这种透明釉也称为白釉。
瓷器釉料中的含铁量降低到0.75%以下,施于洁白的瓷胎上,入窑经高温烧制,就会出现白釉。严格地说,白釉是一种无色透明釉,而不是白色的釉。白釉是瓷器传统釉色之一,真正的白釉应该是乳白色的乳浊釉,这种釉是近代才发明的。我国古代仅有元代枢府釉是失透的,其他白釉并不是白色的釉,而是将不含金属氧化物呈色元素的釉料施于胎骨洁白的器物上,入窑高温烧制而成的透明釉,釉色因白润瓷胎的映衬而显出白色,现在习惯上将这种透明釉也称为白釉。由于白釉陶瓷制品的对色泽要求高,选料特殊,传统的用料和烧制过程对环境的负面影响较大,因此申请人提供一种用料环保,烧制温度低,釉面光滑白质,环保节能的窑变白釉及其制作方法、用窑变白釉制作窑变白釉陶瓷制品的方法。
发明内容
本发明的目的是克服现有技术的不足而提供一种环保节能,釉面白里透黄,微观有拉丝结晶的窑变白釉及其制作方法、用窑变白釉制作窑变白釉陶瓷制品的方法。
本发明采用如下技术方案:
窑变白釉包括按照质量份数计的如下组份:长石45~55份,石英8~11份,高岭土8.0~8.4份,氧化钙8.0~8.4份,氧化钡8.0~8.4份,五氧化二钒6.3~6.7份,氧化锆6.2~6.8份,氧化钛3.1~3.8份,氧化钠4.1~4.5份,氧化铈5~7份,氧化镧6~8份,天青石2~4份,菱锶矿2~4份。
进一步的,所述的窑变白釉包括按照质量份数计的如下组份:长石49份,石英10份,高岭土8.2份,氧化钙8.2份,氧化钡8.2份,五氧化二钒6.5份,氧化锆6.5份,氧化钛3.4份,氧化钠4.1~4.5份,氧化铈5~7份,氧化镧6~8份,天青石3份,菱锶矿3份。
所述的窑变白釉的制作方法,包括如下步骤:
S1、备料并球磨:
将所述的长石、石英、高岭土、氧化钙、氧化钡、五氧化二钒、氧化锆、氧化钛、氧化钠、氧化铈、氧化镧、天青石和菱锶矿混合均匀,得混合料,然后进行球磨,得球磨料;
S2、除铁及过筛:
先将S1中所得球磨料进行除铁,得除铁料,然后将除铁料进行过筛,得过筛料,其中,筛网为200~280目网筛;
S3、釉浆制作:
调节S2中所得过筛料波美度为45~50,得窑变白釉。
进一步的,所述S2中筛网为250目网筛,所述S3中釉浆料的波美度为48。
用所述的窑变白釉制作窑变白釉陶瓷制品的方法,包括如下步骤:
S4、模具制作:
根据所需陶瓷制品的形状制作石膏模具;
S5、坯体制作:
将陶瓷浆料注入到S4中所得石膏模具内,并进行素烧,得坯体,其中,所述陶瓷浆料包括按照质量份数计的如下组份:长石28~32份,石英11~15份,白云石11~15份,膨润土1~3份,天青石2~4份,菱锶矿2~4份,废弃白瓷粉3~5份,玻璃胶0.055~0.060份,其中,所述陶瓷浆料的制作包括如下步骤:
步骤一、备料:将上述组份按照所述质量份数进行配比,混合均匀后得混合料,然后将混合料进行研磨并过筛,得研磨料;
步骤二、除铁及陈腐:将步骤一中所得研磨料进行除铁及陈腐,得陈腐料;
步骤三、浆料制作:调节步骤二中所得陈腐料波美度至45~49,得陶瓷浆料;
所述素烧温度为730~780℃,所述素烧时间为10~15h;
S6、施釉:
通过浸釉法,将S3所得釉浆料施釉至S5中所得坯体上,得施釉陶瓷制品,其中,所述施釉的厚度为0.02~0.04cm;
S7、釉烧:
将S6中所得施釉陶瓷制品进行釉烧,得窑变白釉陶瓷制品,其中,所述釉烧的温度为1250~1280℃,釉烧时间为10~15h。
进一步的,所述S5中步骤一研磨时加入水进行研磨,水和所得混合料的比例为4~6:10,过筛时采用180~230网筛;
步骤二中陈腐时的温度为40~50℃,陈腐5~6天;
步骤三中调节陈腐料波美度至47。
进一步的,S5中所述陶瓷浆料包括按照质量份数计的如下组份:长石30份,石英13份,白云石13份,膨润土2份,天青石3份,菱锶矿3份,废弃白瓷粉4份,玻璃胶0.058份,其中,所述素烧温度为750℃,所述素烧时间为12h。
进一步的,S6中所述施釉的厚度为0.03cm,S7中所述釉烧的温度为1270℃,所述釉烧的时间为12h。
本发明与现有技术相比,具有以下有益效果:
将本发明的窑变白釉施釉于坯体上,经过釉烧冷却后,得到窑变白釉陶瓷制品,陶瓷釉面白里透黄,微观有拉丝结晶,同时,在浆料的组份中添加了废弃白瓷粉粉,添加废白瓷粉代替部分石英形成瓷胎骨架,不但克服了高温烧成时瓷胎内石英晶型转化,还可提高产品的抗热震性;而且,废弃白瓷粉的使用有助于提高废弃物回收利用率,环保节能。
具体实施方式
下面通过具体实施方式对本发明作进一步详细说明,但本领域技术人员将会理解,下列实施例仅用于说明本发明,而不应视为限定本发明的范围。
实施例1
窑变白釉包括按照质量份数计的如下组份:长石45份,石英8份,高岭土8.0份,氧化钙8.0份,氧化钡8.0份,五氧化二钒6.3份,氧化锆6.2份,氧化钛3.1份,氧化钠4.1份,氧化铈5份,氧化镧6份,天青石2份,菱锶矿2份。
所述的窑变白釉的制作方法包括如下步骤:
S1、备料并球磨:
将所述的长石、石英、高岭土、氧化钙、氧化钡、五氧化二钒、氧化锆、氧化钛、氧化钠、氧化铈、氧化镧、天青石和菱锶矿混合均匀,得混合料,然后进行球磨,得球磨料;
S2、除铁及过筛:
先将S1中所得球磨料进行除铁,得除铁料,然后将除铁料进行过筛,得过筛料,其中,筛网为200目网筛;
S3、釉浆制作:
调节S2中所得过筛料波美度为45,得釉浆料。
用所述的窑变白釉制作窑变白釉陶瓷制品的方法,包括如下步骤:
S4、模具制作:
根据所需陶瓷制品的形状制作石膏模具;
S5、坯体制作:
将陶瓷浆料注入到S4中所得石膏模具内,并进行素烧,得坯体,其中,所述陶瓷浆料包括按照质量份数计的如下组份:长石28份,石英11份,白云石11份,膨润土1份,天青石2份,菱锶矿2份,废弃白瓷粉3份,玻璃胶0.055份,其中,
所述浆料的制作包括如下步骤:
步骤一、备料:将上述组份按照所述质量份数进行配比,混合均匀后得混合料,然后将混合料进行研磨并过筛,得研磨料,研磨时的加入水进行研磨,水和所得混合料的比例为4:10,过筛时采用180网筛;
步骤二、除铁及陈腐:将步骤一中所得研磨料进行除铁及陈腐,得陈腐料,陈腐时的温度为40℃,陈腐5天;
步骤三、浆料制作:调节步骤二中所得陈腐料波美度至,得陶瓷浆料;
所述素烧温度为730℃,所述素烧时间为10h;
S6、施釉:
通过浸釉法,将S3所得釉浆料施釉至S5中所得坯体上,得施釉陶瓷制品,其中,所述施釉的厚度为0.02cm;
S7、釉烧:
将S6中所得施釉陶瓷制品进行釉烧,得窑变白釉陶瓷制品,其中,所述釉烧的温度为1250℃,釉烧时间为10h。
实施例2
窑变白釉,包括按照质量份数计的如下组份:长石49份,石英10份,高岭土8.2份,氧化钙8.2份,氧化钡8.2份,五氧化二钒6.5份,氧化锆6.5份,氧化钛3.4份,氧化钠4.1~4.5份,氧化铈5~7份,氧化镧6~8份,天青石3份,菱锶矿3份。
所述的窑变白釉的制作方法,包括如下步骤:
S1、备料并球磨:
将所述的长石、石英、高岭土、氧化钙、氧化钡、五氧化二钒、氧化锆、氧化钛、氧化钠、氧化铈、氧化镧、天青石和菱锶矿混合均匀,得混合料,然后进行球磨,得球磨料;
S2、除铁及过筛:
先将S1中所得球磨料进行除铁,得除铁料,然后将除铁料进行过筛,得过筛料,其中,筛网为250目网筛;
S3、釉浆制作:
调节S2中所得过筛料波美度为48,得釉浆料;
用所述的窑变白釉制作窑变白釉陶瓷制品的方法,包括如下步骤:
S4、模具制作:
根据所需陶瓷制品的形状制作石膏模具;
S5、坯体制作:
将陶瓷浆料注入到S4中所得石膏模具内,并进行素烧,得坯体,其中,所述陶瓷浆料包括按照质量份数计的如下组份:长石30份,石英13份,白云石13份,膨润土2份,天青石3份,菱锶矿3份,废弃白瓷粉4份,玻璃胶0.058份,其中,
所述浆料的制作包括如下步骤:
步骤一、备料:将上述组份按照所述质量份数进行配比,混合均匀后得混合料,然后将混合料进行研磨并过筛,得研磨料,所述研磨时加入水进行研磨,水和所得混合料的比例为5:10,过筛时采用200网筛;;
步骤二、除铁及陈腐:将步骤一中所得研磨料进行除铁及陈腐,得陈腐料,陈腐时的温度为48℃,陈腐6天;
步骤三、浆料制作:调节步骤二中所得陈腐料波美度至47,得陶瓷浆料;
所述素烧温度为750℃,所述素烧时间为12h;
S6、施釉:
通过浸釉法,将S3所得釉浆料施釉至S5中所得坯体上,得施釉陶瓷制品,其中,所述施釉的厚度为0.03cm;
S7、釉烧:
将S6中所得施釉陶瓷制品进行釉烧,得窑变白釉陶瓷制品,其中,所述釉烧的温度为1270℃,釉烧时间为12h。
实施例3
窑变白釉,包括按照质量份数计的如下组份:长石55份,石英11份,高岭土8.4份,氧化钙8.4份,氧化钡8.4份,五氧化二钒6.7份,氧化锆6.8份,氧化钛3.8份,氧化钠4.5份,氧化铈7份,氧化镧8份,天青石4份,菱锶矿4份。
所述的窑变白釉的制作方法,,包括如下步骤:
S1、备料并球磨:
将所述的长石、石英、高岭土、氧化钙、氧化钡、五氧化二钒、氧化锆、氧化钛、氧化钠、氧化铈、氧化镧、天青石和菱锶矿混合均匀,得混合料,然后进行球磨,得球磨料;
S2、除铁及过筛:
先将S1中所得球磨料进行除铁,得除铁料,然后将除铁料进行过筛,得过筛料,其中,筛网为280目网筛;
S3、釉浆制作:
调节S2中所得过筛料波美度为50,得釉浆料;
4、用权利要求3所述的窑变白釉制作窑变白釉陶瓷制品的方法,其特征在于,包括如下步骤:
S4、模具制作:
根据所需陶瓷制品的形状制作石膏模具;
S5、坯体制作:
将陶瓷浆料注入到S4中所得石膏模具内,并进行素烧,得坯体,其中,所述陶瓷浆料包括按照质量份数计的如下组份:长石32份,石英15份,白云石15份,膨润土3份,天青石4份,菱锶矿4份,废弃白瓷粉5份,玻璃胶0.060份,其中,
所述陶瓷浆料的制作包括如下步骤:
步骤一、备料:将上述组份按照所述质量份数进行配比,混合均匀后得混合料,然后将混合料进行研磨并过筛,得研磨料,所述S5中步骤一研磨时加入水进行研磨,水和所得混合料的比例为6:10,过筛时采用230网筛;;
步骤二、除铁及陈腐:将步骤一中所得研磨料进行除铁及陈腐,得陈腐料,陈腐时的温度为50℃,陈腐6天;
步骤三、浆料制作:调节步骤二中所得陈腐料波美度至49,得陶瓷浆料;
所述素烧温度为780℃,所述素烧时间为15h;
S6、施釉:
通过浸釉法,将S3所得釉浆料施釉至S5中所得坯体上,得施釉陶瓷制品,其中,所述施釉的厚度为0.04cm;
S7、釉烧:
将S6中所得施釉陶瓷制品进行釉烧,得窑变白釉陶瓷制品,其中,所述釉烧的温度为1280℃,釉烧时间为15h。
将实施例1~3所得的窑变白釉陶瓷进行性能检测,体膨胀系数检测在25~850℃进行试验检测结果如下表1:
表1:实施例1~3所得的窑变白釉陶瓷检测结果
由表1可知,窑变白釉陶瓷制品光测度高,白度高,铅、镉含量低,抗摩擦性能强,色差小,耐酸碱性能强,体膨胀系数小,抗热震性能强。

Claims (8)

1.窑变白釉,其特征在于,包括按照质量份数计的如下组份:长石45~55份,石英8~11份,高岭土8.0~8.4份,氧化钙8.0~8.4份,氧化钡8.0~8.4份,五氧化二钒6.3~6.7份,氧化锆6.2~6.8份,氧化钛3.1~3.8份,氧化钠4.1~4.5份,氧化铈5~7份,氧化镧6~8份,天青石2~4份,菱锶矿2~4份。
2.根据权利要求1所述的窑变白釉,其特征在于,包括按照质量份数计的如下组份:长石49份,石英10份,高岭土8.2份,氧化钙8.2份,氧化钡8.2份,五氧化二钒6.5份,氧化锆6.5份,氧化钛3.4份,氧化钠4.1~4.5份,氧化铈5~7份,氧化镧6~8份,天青石3份,菱锶矿3份。
3.权利要求1所述的窑变白釉的制作方法,其特征在于,包括如下步骤:
S1、备料并球磨:
将所述的长石、石英、高岭土、氧化钙、氧化钡、五氧化二钒、氧化锆、氧化钛、氧化钠、氧化铈、氧化镧、天青石和菱锶矿混合均匀,得混合料,然后进行球磨,得球磨料;
S2、除铁及过筛:
先将S1中所得球磨料进行除铁,得除铁料,然后将除铁料进行过筛,得过筛料,其中,筛网为200~280目网筛;
S3、釉浆制作:
调节S2中所得过筛料波美度为45~50,得窑变白釉。
4.根据权利要求3所述的窑变白釉的制作方法,其特征在于,所述S2中筛网为250目网筛,所述S3中釉浆料的波美度为48。
5.用权利要求3所述的窑变白釉制作窑变白釉陶瓷制品的方法,其特征在于,包括如下步骤:
S4、模具制作:
根据所需陶瓷制品的形状制作石膏模具;
S5、坯体制作:
将陶瓷浆料注入到S4中所得石膏模具内,并进行素烧,得坯体,其中,所述陶瓷浆料包括按照质量份数计的如下组份:长石28~32份,石英11~15份,白云石11~15份,膨润土1~3份,天青石2~4份,菱锶矿2~4份,废弃白瓷粉3~5份,玻璃胶0.055~0.060份,其中,所述陶瓷浆料的制作包括如下步骤:
步骤一、备料:将上述组份按照所述质量份数进行配比,混合均匀后得混合料,然后将混合料进行研磨并过筛,得研磨料;
步骤二、除铁及陈腐:将步骤一中所得研磨料进行除铁及陈腐,得陈腐料;
步骤三、浆料制作:调节步骤二中所得陈腐料波美度至45~49,得陶瓷浆料;
所述素烧温度为730~780℃,所述素烧时间为10~15h;
S6、施釉:
通过浸釉法,将S3所得釉浆料施釉至S5中所得坯体上,得施釉陶瓷制品,其中,所述施釉的厚度为0.02~0.04cm;
S7、釉烧:
将S6中所得施釉陶瓷制品进行釉烧,得窑变白釉陶瓷制品,其中,所述釉烧的温度为1250~1280℃,釉烧时间为10~15h。
6.根据权利要求4所述的用窑变白釉制作窑变白釉陶瓷制品的方法,其特征在于,
所述S5中步骤一研磨时加入水进行研磨,水和所得混合料的比例为4~6:10,过筛时采用180~230网筛;
步骤二中陈腐时的温度为40~50℃,陈腐5~6天;
步骤三中调节陈腐料波美度至47。
7.根据权利要求4所述的窑变白釉的制作方法,其特征在于,S5中所述陶瓷浆料包括按照质量份数计的如下组份:长石30份,石英13份,白云石13份,膨润土2份,天青石3份,菱锶矿3份,废弃白瓷粉4份,玻璃胶0.058份,其中,所述素烧温度为750℃,所述素烧时间为12h。
8.根据权利要求4所述的窑变白釉的制作方法,其特征在于,S6中所述施釉的厚度为0.03cm,S7中所述釉烧的温度为1270℃,所述釉烧的时间为12h。
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CN109879596A (zh) * 2019-04-23 2019-06-14 福建省德化云水窑陶瓷有限公司 釉下窑变釉色料及用其制备釉下窑变釉陶瓷制品的方法
CN109879596B (zh) * 2019-04-23 2021-07-20 福建省德化云水窑陶瓷有限公司 釉下窑变釉色料及用其制备釉下窑变釉陶瓷制品的方法
CN113307497A (zh) * 2019-04-23 2021-08-27 福建省德化云水窑陶瓷有限公司 釉下窑变釉色料的制备方法及用釉下窑变釉色料制得的陶瓷制品
CN113307497B (zh) * 2019-04-23 2022-07-01 福建省德化云水窑陶瓷有限公司 釉下窑变釉色料的制备方法及用釉下窑变釉色料制得的陶瓷制品
CN111439989A (zh) * 2020-04-13 2020-07-24 福建省德化县邦威陶瓷有限公司 一种环保型抗热震日用陶瓷制品及其制备方法
CN111559865A (zh) * 2020-07-07 2020-08-21 广东民洁卫浴有限公司 一种色釉及其制备方法
CN112456801A (zh) * 2020-11-30 2021-03-09 湖南景翌湘台环保高新技术开发有限公司 一种搪瓷面釉及其制备方法
CN112759262A (zh) * 2021-03-05 2021-05-07 德化县嘉翔工艺品有限公司 一种耐磨钻石透明釉、耐磨钻石透明釉陶瓷制品及其制备方法

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Application publication date: 20170901