CN107108783B - 用于捕集甲醛的聚合物材料 - Google Patents

用于捕集甲醛的聚合物材料 Download PDF

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CN107108783B
CN107108783B CN201580062169.2A CN201580062169A CN107108783B CN 107108783 B CN107108783 B CN 107108783B CN 201580062169 A CN201580062169 A CN 201580062169A CN 107108783 B CN107108783 B CN 107108783B
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hydrogen
polymer material
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CN107108783A (zh
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M·S·文德兰德
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3M Innovative Properties Co
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81—Solid phase processes
    • B01D53/82—Solid phase processes with stationary reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/261—Synthetic macromolecular compounds obtained by reactions only involving carbon to carbon unsaturated bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/264—Synthetic macromolecular compounds derived from different types of monomers, e.g. linear or branched copolymers, block copolymers, graft copolymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/265—Synthetic macromolecular compounds modified or post-treated polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B01J20/28061—Surface area, e.g. B.E.T specific surface area being in the range 100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/32—Monomers containing only one unsaturated aliphatic radical containing two or more rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/34—Monomers containing two or more unsaturated aliphatic radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/34—Monomers containing two or more unsaturated aliphatic radicals
    • C08F212/36—Divinylbenzene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/34—Introducing sulfur atoms or sulfur-containing groups
    • C08F8/36—Sulfonation; Sulfation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/202—Polymeric adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/306—Surface area, e.g. BET-specific surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708—Volatile organic compounds V.O.C.'s
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/06—Polluted air
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
CN201580062169.2A 2014-11-17 2015-11-10 用于捕集甲醛的聚合物材料 Active CN107108783B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462080817P 2014-11-17 2014-11-17
US62/080,817 2014-11-17
PCT/US2015/059909 WO2016081226A1 (en) 2014-11-17 2015-11-10 Polymeric materials for capturing formaldehyde

Publications (2)

Publication Number Publication Date
CN107108783A CN107108783A (zh) 2017-08-29
CN107108783B true CN107108783B (zh) 2019-08-30

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US (1) US10391471B2 (https=)
EP (1) EP3221367A1 (https=)
JP (1) JP6567052B2 (https=)
KR (1) KR20170085550A (https=)
CN (1) CN107108783B (https=)
TW (1) TWI647009B (https=)
WO (1) WO2016081226A1 (https=)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016205083A1 (en) 2015-06-19 2016-12-22 3M Innovative Properties Company Hydrolyzed divinylbenzene/maleic anhydride polymeric sorbents for carbon dioxide
CN107810054B (zh) 2015-06-19 2020-05-19 3M创新有限公司 用于二氧化碳的二乙烯基苯/马来酸酐聚合物吸附剂
CN108367270B (zh) 2015-12-18 2021-07-09 3M创新有限公司 用于二氧化碳的聚合物吸附剂
JP6925339B2 (ja) 2015-12-18 2021-08-25 スリーエム イノベイティブ プロパティズ カンパニー アルデヒド用ポリマー吸着剤
JP6925338B2 (ja) 2015-12-18 2021-08-25 スリーエム イノベイティブ プロパティズ カンパニー 反応性ガス用ポリマー吸着剤
JP7010452B2 (ja) 2016-03-14 2022-02-10 スリーエム イノベイティブ プロパティズ カンパニー 反応性ガス用のポリマー収着剤を含むエアフィルタ
US10960341B2 (en) 2016-03-14 2021-03-30 3M Innovative Properties Company Air filters comprising polymeric sorbents for aldehydes
CN108778487B (zh) 2016-03-14 2022-02-18 3M创新有限公司 包含用于醛的聚合物吸附剂的复合颗粒
EP3638414B1 (en) 2017-06-16 2024-03-27 3M Innovative Properties Company Polymeric sorbents for aldehydes
WO2018229604A2 (en) 2017-06-16 2018-12-20 3M Innovative Properties Company Air filters comprising polymeric sorbents for aldehydes
DE102018114351B4 (de) * 2017-06-30 2026-02-19 Mann+Hummel Gmbh Filtermedium, Filtermedienkörper, Filterelement sowie Luftfilter
US11612877B2 (en) * 2017-12-04 2023-03-28 Stichting Voor De Technische Wetenschappen Macromolecular compositions comprising indene-derivatives, preparation thereof, and use thereof
CN110156930A (zh) * 2019-04-30 2019-08-23 昆明理工大学 一种化学吸附降解甲醛的水性丙烯酸树脂及其制备方法
US20220258128A1 (en) * 2019-08-30 2022-08-18 3M Innovative Properties Company Polymeric sorbents for aldehydes and methods of making
CN114307986B (zh) * 2021-12-28 2023-05-12 南昌航空大学 一种钯离子吸附剂的制备方法

Citations (5)

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Publication number Priority date Publication date Assignee Title
CN1062541A (zh) * 1992-01-24 1992-07-08 中国林业科学院林产化学工业研究所 Au甲醛捕捉剂生产工艺
CN1548164A (zh) * 2003-05-22 2004-11-24 王永利 甲醛吸收剂及其制备方法
CN1569313A (zh) * 2004-04-30 2005-01-26 罗文圣 一种有害气体捕捉材料及其制备方法
CN103173004A (zh) * 2011-12-23 2013-06-26 烟台万华聚氨酯股份有限公司 具有甲醛反应性的水性聚氨酯分散体组合物及其制备和应用
WO2014052021A1 (en) * 2012-09-25 2014-04-03 3M Innovative Properties Company Polymerizable spirobisindane monomers and polymers prepared therefrom

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GB800639A (en) 1955-07-08 1958-08-27 Wolfgang Muhlberg Manufacture of cation exchangers of the polystyrene-type
JP3953638B2 (ja) * 1997-09-11 2007-08-08 日本合成化学工業株式会社 アルデヒド吸着剤
JP6185999B2 (ja) 2012-09-25 2017-08-23 スリーエム イノベイティブ プロパティズ カンパニー 剛性回旋状ジビニル架橋剤
TWI490232B (zh) 2012-12-28 2015-07-01 Ind Tech Res Inst 甲醛捕捉劑及其製備方法
US9463454B2 (en) 2013-05-14 2016-10-11 3M Innovative Properties Company Amino-containing polymeric material with rigid and contorted divinyl crosslinker
CN105229055B (zh) 2013-05-14 2017-04-26 3M创新有限公司 基于可自由基聚合的螺双茚单体的含磺酰基聚合物
CN106660039B (zh) 2014-06-13 2020-10-27 3M创新有限公司 含磺酸聚合物材料作为胺吸附剂

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1062541A (zh) * 1992-01-24 1992-07-08 中国林业科学院林产化学工业研究所 Au甲醛捕捉剂生产工艺
CN1548164A (zh) * 2003-05-22 2004-11-24 王永利 甲醛吸收剂及其制备方法
CN1569313A (zh) * 2004-04-30 2005-01-26 罗文圣 一种有害气体捕捉材料及其制备方法
CN103173004A (zh) * 2011-12-23 2013-06-26 烟台万华聚氨酯股份有限公司 具有甲醛反应性的水性聚氨酯分散体组合物及其制备和应用
WO2014052021A1 (en) * 2012-09-25 2014-04-03 3M Innovative Properties Company Polymerizable spirobisindane monomers and polymers prepared therefrom

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Publication number Publication date
EP3221367A1 (en) 2017-09-27
JP2018501086A (ja) 2018-01-18
TW201627066A (zh) 2016-08-01
US20170333870A1 (en) 2017-11-23
CN107108783A (zh) 2017-08-29
US10391471B2 (en) 2019-08-27
KR20170085550A (ko) 2017-07-24
JP6567052B2 (ja) 2019-08-28
WO2016081226A1 (en) 2016-05-26
TWI647009B (zh) 2019-01-11

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