CN107083087A - A kind of environment-friendly diatom ooze ornament materials and preparation method thereof - Google Patents
A kind of environment-friendly diatom ooze ornament materials and preparation method thereof Download PDFInfo
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- CN107083087A CN107083087A CN201710412928.4A CN201710412928A CN107083087A CN 107083087 A CN107083087 A CN 107083087A CN 201710412928 A CN201710412928 A CN 201710412928A CN 107083087 A CN107083087 A CN 107083087A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
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Abstract
The invention discloses a kind of environment-friendly diatom ooze ornament materials and preparation method thereof, the ornament materials includes the raw material of following parts by weight：60 80 parts of diatomite, 70 90 parts of quartz sand, 15 30 parts of sepiolite, 20 30 parts of talcum powder, 8 20 parts of calcium hydroxide powder, 5 10 parts of bamboo-carbon fibre, 15 parts of polyester fiber, 0.6 2 parts of sodium perborate, 13 parts of nano zine oxide, 0.2 0.6 parts of Kathon CG, 0.1 0.5 parts of dispersant, 0.2 0.8 parts of wetting agent, 0.1 0.3 parts of defoamer.The preparation method of the ornament materials includes diatomaceous purifying, mixing and ball milling technique.The environment-friendly diatom ooze ornament materials of the present invention, safety and environmental protection, antibacterial bacteriostatic, waterproof, mould proof, fire protecting performance are more excellent, and preparation method is simple, is suitable as the coating of interior wall.
Description
Technical field
The present invention relates to building material technical field, and in particular to a kind of environment-friendly diatom ooze ornament materials and its preparation side
Method.
Background technology
Now, low-carbon environment-friendly, energy-saving and emission-reduction are the basic norms of world's every country sustainable economic development.With society
Development and growth in the living standard, the awareness of environment protection and health of people is remarkably reinforced, to the comfort level and safety of living environment
Property require more and more higher.Indoor temperature, relative air humidity, air quality are the important environmental parameters of residence comfort.Work as room
When interior temperature is 20-23 DEG C, relative humidity is 50-60%, VOC content is low, anion concentration is high, human body sensory is comfortable, has
Beneficial health.Diatom ooze is a kind of house decorative material based on diatomite, and diatomite is the one kind lived in before millions of years
Unicellular aquatic class of swimming is biological, diatom after death can connate water bottom, turn into diatomite by the accumulation of 1 years and geology transition.
Diatomaceous main component is protein, and quality is light and soft, porous, and porosity is up to more than 90%, and specific surface area is up to 65 m2/g.It is this
Structures shape its there is extremely strong physical absorption performance and ion-exchange performance.
In existing diatom ooze product, often there is function phase in most advantages just with diatom ooze in itself
To relatively simple and narrower purposes situation.Therefore, study it is a kind of have improve air quality, it is adjusting air humidity, mould proof, anti-
The functions such as fire, are not limited the Multifunctional diatom ooze ornament materials limited with technical requirements significant by water source.
The content of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of environment-friendly diatom ooze ornament materials and its system
Preparation Method, the ornament materials safety and environmental protection, antibacterial bacteriostatic, waterproof, mould proof, fire protecting performance are more excellent, and preparation method is simple, is suitable as
For the coating of interior wall.
The present invention solves technical problem and adopted the following technical scheme that：
A kind of environment-friendly diatom ooze ornament materials, includes the raw material of following parts by weight：60-80 parts of diatomite, quartz sand 70-90
Part, 15-30 parts of sepiolite, 20-30 parts of talcum powder, 8-20 parts of calcium hydroxide powder, 5-10 parts of bamboo-carbon fibre, 1-5 parts of polyester fiber,
0.6-2 parts of sodium perborate, 1-3 parts of nano zine oxide, 0.2-0.6 parts of Kathon CG, 0.1-0.5 parts of dispersant, wetting agent 0.2-0.8
Part, 0.1-0.3 parts of defoamer.
Preferably, the ornament materials includes the raw material of following parts by weight：70 parts of diatomite, 80 parts of quartz sand, sepiolite
25 parts, it is 26 parts of talcum powder, 14 parts of calcium hydroxide powder, 7 parts of bamboo-carbon fibre, 3 parts of polyester fiber, 1.3 parts of sodium perborate, nano oxidized
2 parts of zinc, 0.3 part of Kathon CG, 0.2 part of dispersant, 0.5 part of wetting agent, 0.1 part of defoamer.
Preferably, the dispersant is one or more in sodium polyphosphate, calgon, PEG400,5040
Combination.
Preferably, the wetting agent is one or both of Dynol 960 or Dynol 980.
Preferably, the defoamer is silicone emulsion, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether or poly- two
One or more combinations in methylsiloxane.
The preparation method of above-mentioned environment-friendly diatom ooze ornament materials, comprises the following steps：
（1）By diatomite through natural drying, weathering, crushing, soaked 30-40 minutes using deionized water, centrifuge 5-10 points
Zhong Hou, using 20-40 mesh filter-cloth filterings, filtrate is in the 50-60 DEG C of dry diatomite obtained after purification for 6-8 hours；
（2）Diatomite after purification, talcum powder, calcium hydroxide powder, bamboo-carbon fibre, polyester fiber are mixed, stirred using taper
After machine is stirred 20-30 minutes, 100-200 mesh sieves are crossed, mixed-powder a is obtained；
（3）Mixed-powder a, quartz sand, sepiolite, sodium perborate, nano zine oxide, Kathon CG, dispersant, wetting agent, defoamer
After mixing, feeding ball mill ball mill grinding 1-1.6 hours, after 200-300 mesh sieves, packaging produces the diatom ooze ornament materials.
Preferably, the step（1）Diatomite moisture after purification is maintained at less than 5%.
Preferably, the step（3）Ball mill barrel rotating speed is 38r/min, power of motor 22Kw.
Wherein, diatomite has loose structure, when indoor humidity is high, diatomite can by Vapor adsorption, when indoor humidity is low,
Steam can be desorbed by diatomite to be discharged, and the relative humidity of the interior space is automatically adjusted in 40%-70%, and this exactly body-sensing is relaxed
Suitable humidity is interval, will not also produce the bait mould of acarid, can anti-mite.Diatomaceous loose structure so that in space
Dry air has preferable heat-proof quality.
Quartz sand is the broken quartz particles processed of quartz warp, is a kind of hard, wear-resisting, stable chemical performance
Silicate mineral, its main mineral constituent is SiO2, safety non-toxic, be widely used in glass, casting, ceramics and fire proofing material, smelting
Refine ferrosilicon, flux for metallurgy, metallurgy, building, chemical industry, plastics, rubber, abrasive material, the industry such as filtrate.
Sepiolite is a kind of clay mineral of magnesium silicate containing Shuifu County for having layer chain structure, and shrinkage factor is low, and plasticity is good, matter
Gently, bigger than surface, adsorptivity is strong, with decolourizing, heat-insulated, insulation, anticorrosive, radioresistance and the performance such as thermally-stabilised.
Talcum powder is white or off-white color, powder fine, without grittiness, has lubrication, helps stream, fire resisting, antiacid, insulation, screening
The good characteristic such as lid power is good, soft, absorption affinity is strong.
Bamboo-carbon fibre takes mao bamboon to be raw material, employs the calcining new technology and new skill of pure oxygen high temperature and nitrogen barrier delay
Art so that the micropore that bamboo charcoal innately has more refine with honeycomb, with moisture absorption is ventilative, bacteriostasis antibiosis, cool in summer and warm in winter, green ring
The features such as guarantor.
Polyester fiber is the synthetic fibers as obtained by organic dibasic acid and the polyester of dihydric alcohol polycondensation through spinning, crease-resistant
Property and conformality very well, with higher intensity and elastic recovery capability.
Sodium perborate is a kind of white monoclinic system crystal particle or powder, can be used as oxidant, bleaching agent, bactericide,
Additive in deodorant, detergent etc., and fiber will not be damaged.
Nano zine oxide can be used for ultraviolet light masking material, antiseptic, fluorescent material, catalysis material etc., and it is by inhaling
The heat that human-body emitting goes out is received, and again to the far infrared of the wavelength range of human body radiation one, can be made in subcutis
Blood flow increase, stimulates circulation outer, can also cover infrared ray, reduce thermal loss, the effect with heat storing and heat preserving.
Compared with prior art, the present invention has following beneficial effect：
（1）The environment-friendly diatom ooze ornament materials of the present invention, safety and environmental protection, antibacterial bacteriostatic, waterproof, mould proof, fire protecting performance are more excellent,
Preparation method is simple, is suitable as the coating of interior wall.
（2）The environment-friendly diatom ooze ornament materials of the present invention, diatomite, quartz sand, sepiolite light weight, adsorptivity are strong and compare
Surface area is big, improves heat-insulating flame-retardant performance, the chemical resistance of the ornament materials；Diatomaceous loose structure and bamboo-carbon fibre
Honeycomb micropore so that the ornament materials moisture absorption breathe freely, antibacterial bacteriostatic；Nano zine oxide reduces the loss of heat, improves
Heat storing and heat preserving ability.Electric energy and heating cost are greatlyd save, very superior condition is provided for energy conservation standard.
Embodiment
Invention is described in further detail below in conjunction with specific embodiment.
Embodiment 1.
A kind of environment-friendly diatom ooze ornament materials, includes the raw material of following weight：Diatomite 140g, quartz sand 160g, sepiolite
50g, talcum powder 52g, calcium hydroxide powder 28g, bamboo-carbon fibre 14g, polyester fiber 6g, sodium perborate 2.6g, nano zine oxide 4g,
Kathon CG 0.6g, sodium hexametaphosphate dispersant 0.4g, the 1g of wetting agent Dynol 960, defoamer dimethyl silicone polymer 0.2g.
The preparation method of above-mentioned environment-friendly diatom ooze ornament materials, comprises the following steps：
（1）By diatomite through natural drying, weathering, crushing, soaked 30-40 minutes using deionized water, centrifuge 5-10 points
Zhong Hou, using 20-40 mesh filter-cloth filterings, filtrate is in the 50-60 DEG C of dry diatomite obtained after purification for 6-8 hours, moisture
It is maintained at less than 5%；
（2）Diatomite after purification, talcum powder, calcium hydroxide powder, bamboo-carbon fibre, polyester fiber are mixed, stirred using taper
After machine is stirred 20-30 minutes, 100-200 mesh sieves are crossed, mixed-powder a is obtained；
（3）Mixed-powder a, quartz sand, sepiolite, sodium perborate, nano zine oxide, Kathon CG, dispersant, wetting agent, defoamer
After mixing, feeding ball mill ball mill grinding 1-1.6 hours, after 200-300 mesh sieves, packaging produces the diatom ooze ornament materials.
Wherein, ball mill barrel rotating speed is 38r/min, power of motor 22Kw.
Embodiment 2.
A kind of environment-friendly diatom ooze ornament materials, includes the raw material of following weight：Diatomite 130g, quartz sand 152g, sepiolite
36g, talcum powder 44g, calcium hydroxide powder 30g, bamboo-carbon fibre 12g, polyester fiber 10g, sodium perborate 3.2g, nano zine oxide
4g, Kathon CG 1g, dispersant PEG400 0.8g, the 1.4g of wetting agent Dynol 980, defoamer polyoxyethylene polyoxy propyl alcohol amidogen ether
0.4g。
The preparation method of above-mentioned environment-friendly diatom ooze ornament materials, comprises the following steps：
（1）By diatomite through natural drying, weathering, crushing, soaked 30-40 minutes using deionized water, centrifuge 5-10 points
Zhong Hou, using 20-40 mesh filter-cloth filterings, filtrate is in the 50-60 DEG C of dry diatomite obtained after purification for 6-8 hours, moisture
It is maintained at less than 5%；
（2）Diatomite after purification, talcum powder, calcium hydroxide powder, bamboo-carbon fibre, polyester fiber are mixed, stirred using taper
After machine is stirred 20-30 minutes, 100-200 mesh sieves are crossed, mixed-powder a is obtained；
（3）Mixed-powder a, quartz sand, sepiolite, sodium perborate, nano zine oxide, Kathon CG, dispersant, wetting agent, defoamer
After mixing, feeding ball mill ball mill grinding 1-1.6 hours, after 200-300 mesh sieves, packaging produces the diatom ooze ornament materials.
Wherein, ball mill barrel rotating speed is 38r/min, power of motor 22Kw.
Embodiment 3.
A kind of environment-friendly diatom ooze ornament materials, includes the raw material of following weight：Diatomite 144g, quartz sand 156g, sepiolite
50g, talcum powder 52g, calcium hydroxide powder 28g, bamboo-carbon fibre 16g, polyester fiber 10g, sodium perborate 3g, nano zine oxide 6g,
Kathon CG 0.4g, the 0.6g of dispersant 5040, the 1.2g of wetting agent Dynol 960, defoamer polypropylene glycerol aether 0.6g.
The preparation method of above-mentioned environment-friendly diatom ooze ornament materials, comprises the following steps：
（1）By diatomite through natural drying, weathering, crushing, soaked 30-40 minutes using deionized water, centrifuge 5-10 points
Zhong Hou, using 20-40 mesh filter-cloth filterings, filtrate is in the 50-60 DEG C of dry diatomite obtained after purification for 6-8 hours, moisture
It is maintained at less than 5%；
（2）Diatomite after purification, talcum powder, calcium hydroxide powder, bamboo-carbon fibre, polyester fiber are mixed, stirred using taper
After machine is stirred 20-30 minutes, 100-200 mesh sieves are crossed, mixed-powder a is obtained；
（3）Mixed-powder a, quartz sand, sepiolite, sodium perborate, nano zine oxide, Kathon CG, dispersant, wetting agent, defoamer
After mixing, feeding ball mill ball mill grinding 1-1.6 hours, after 200-300 mesh sieves, packaging produces the diatom ooze ornament materials.
Wherein, ball mill barrel rotating speed is 38r/min, power of motor 22Kw.
Embodiment 4.
A kind of environment-friendly diatom ooze ornament materials, includes the raw material of following weight：Diatomite 150g, quartz sand 172g, sepiolite
48g, talcum powder 52g, calcium hydroxide powder 36g, bamboo-carbon fibre 16g, polyester fiber 6g, sodium perborate 3.6g, nano zine oxide 4g,
Kathon CG 1.2g, sodium hexametaphosphate dispersant 1g, the 1g of wetting agent Dynol 980, defoamer silicone emulsion 0.4g.
The preparation method of above-mentioned environment-friendly diatom ooze ornament materials, comprises the following steps：
（1）By diatomite through natural drying, weathering, crushing, soaked 30-40 minutes using deionized water, centrifuge 5-10 points
Zhong Hou, using 20-40 mesh filter-cloth filterings, filtrate is in the 50-60 DEG C of dry diatomite obtained after purification for 6-8 hours, moisture
It is maintained at less than 5%；
（2）Diatomite after purification, talcum powder, calcium hydroxide powder, bamboo-carbon fibre, polyester fiber are mixed, stirred using taper
After machine is stirred 20-30 minutes, 100-200 mesh sieves are crossed, mixed-powder a is obtained；
（3）Mixed-powder a, quartz sand, sepiolite, sodium perborate, nano zine oxide, Kathon CG, dispersant, wetting agent, defoamer
After mixing, feeding ball mill ball mill grinding 1-1.6 hours, after 200-300 mesh sieves, packaging produces the diatom ooze ornament materials.
Wherein, ball mill barrel rotating speed is 38r/min, power of motor 22Kw.
Embodiment 5.
A kind of environment-friendly diatom ooze ornament materials, includes the raw material of following weight：Diatomite 160g, quartz sand 176g, sepiolite
52g, talcum powder 60g, calcium hydroxide powder 36g, bamboo-carbon fibre 18g, polyester fiber 6g, sodium perborate 3g, nano zine oxide 4g, card
Loose 1.2g, the 1g of dispersant 5040, the 1.6g of wetting agent Dynol 980, defoamer polyoxyethylene polyoxy propyl alcohol amidogen ether 0.4g.
The preparation method of above-mentioned environment-friendly diatom ooze ornament materials, comprises the following steps：
（1）By diatomite through natural drying, weathering, crushing, soaked 30-40 minutes using deionized water, centrifuge 5-10 points
Zhong Hou, using 20-40 mesh filter-cloth filterings, filtrate is in the 50-60 DEG C of dry diatomite obtained after purification for 6-8 hours, moisture
It is maintained at less than 5%；
（2）Diatomite after purification, talcum powder, calcium hydroxide powder, bamboo-carbon fibre, polyester fiber are mixed, stirred using taper
After machine is stirred 20-30 minutes, 100-200 mesh sieves are crossed, mixed-powder a is obtained；
（3）Mixed-powder a, quartz sand, sepiolite, sodium perborate, nano zine oxide, Kathon CG, dispersant, wetting agent, defoamer
After mixing, feeding ball mill ball mill grinding 1-1.6 hours, after 200-300 mesh sieves, packaging produces the diatom ooze ornament materials.
Wherein, ball mill barrel rotating speed is 38r/min, power of motor 22Kw.
The present invention environment-friendly diatom ooze ornament materials, safety and environmental protection, antibacterial bacteriostatic, waterproof, mould proof, fire protecting performance compared with
Excellent, preparation method is simple, is suitable as the coating of interior wall.
Described above is only the preferred embodiment of the present invention, and protection scope of the present invention is not limited merely to above-mentioned implementation
Example, all technical schemes belonged under thinking of the present invention belong to protection scope of the present invention.It should be pointed out that for the art
Those of ordinary skill for, some improvements and modifications without departing from the principles of the present invention, also should be regarded as the present invention
Protection domain.
Claims (8)
1. a kind of environment-friendly diatom ooze ornament materials, it is characterised in that include the raw material of following parts by weight：60-80 parts of diatomite,
It is 70-90 parts of quartz sand, 15-30 parts of sepiolite, 20-30 parts of talcum powder, 8-20 parts of calcium hydroxide powder, 5-10 parts of bamboo-carbon fibre, poly-
1-5 parts of ester fiber, 0.6-2 parts of sodium perborate, 1-3 parts of nano zine oxide, 0.2-0.6 parts of Kathon CG, 0.1-0.5 parts of dispersant, profit
0.2-0.8 parts of humectant, 0.1-0.3 parts of defoamer.
2. environment-friendly diatom ooze ornament materials according to claim 1, it is characterised in that the ornament materials includes as follows
The raw material of parts by weight：70 parts of diatomite, 80 parts of quartz sand, 25 parts of sepiolite, 26 parts of talcum powder, 14 parts of calcium hydroxide powder, bamboo charcoal
7 parts of fiber, 3 parts of polyester fiber, 1.3 parts of sodium perborate, 2 parts of nano zine oxide, 0.3 part of Kathon CG, 0.2 part of dispersant, wetting agent
0.5 part, 0.1 part of defoamer.
3. environment-friendly diatom ooze ornament materials according to claim 1, it is characterised in that the dispersant is polyphosphoric acids
One or more combinations in sodium, calgon, PEG400,5040.
4. environment-friendly diatom ooze ornament materials according to claim 1, it is characterised in that the wetting agent is Dynol
One or both of 960 or Dynol 980.
5. environment-friendly diatom ooze ornament materials according to claim 1, it is characterised in that the defoamer is emulsification silicon
One or more combinations in oil, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether or dimethyl silicone polymer.
6. the preparation method of the environment-friendly diatom ooze ornament materials according to claim 1-5 any one, it is characterised in that
Comprise the following steps：
（1）By diatomite through natural drying, weathering, crushing, soaked 30-40 minutes using deionized water, centrifuge 5-10 points
Zhong Hou, using 20-40 mesh filter-cloth filterings, filtrate is in the 50-60 DEG C of dry diatomite obtained after purification for 6-8 hours；
（2）Diatomite after purification, talcum powder, calcium hydroxide powder, bamboo-carbon fibre, polyester fiber are mixed, stirred using taper
After machine is stirred 20-30 minutes, 100-200 mesh sieves are crossed, mixed-powder a is obtained；
（3）Mixed-powder a, quartz sand, sepiolite, sodium perborate, nano zine oxide, Kathon CG, dispersant, wetting agent, defoamer
After mixing, feeding ball mill ball mill grinding 1-1.6 hours, after 200-300 mesh sieves, packaging produces the diatom ooze ornament materials.
7. the preparation method of environment-friendly diatom ooze ornament materials according to claim 6, it is characterised in that the step
（1）Diatomite moisture after purification is maintained at less than 5%.
8. the preparation method of environment-friendly diatom ooze ornament materials according to claim 6, it is characterised in that the step
（3）Ball mill barrel rotating speed is 38r/min, power of motor 22Kw.
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| CN108084805A (en) * | 2017-12-06 | 2018-05-29 | 田秋珍 | A kind of preparation method of water proof type diatom ooze coating |
| CN109913026A (en) * | 2019-02-28 | 2019-06-21 | 江苏佑宝家居科技有限公司 | A kind of anion propellant, white overlay coating and preparation method |
| CN111269591A (en) * | 2018-12-04 | 2020-06-12 | 翟林 | Preparation method and preparation equipment of shell powder composite diatomite coating |
| CN115058177A (en) * | 2022-06-20 | 2022-09-16 | 中国船舶重工集团公司第七二五研究所 | Stainless steel anticorrosive paint and preparation method thereof |
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| CN105271954A (en) * | 2015-11-06 | 2016-01-27 | 刘明珠 | Decorative material containing diatom ooze |
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