CN109351165A - It is a kind of indoor except formaldehyde spray - Google Patents
It is a kind of indoor except formaldehyde spray Download PDFInfo
- Publication number
- CN109351165A CN109351165A CN201811512581.1A CN201811512581A CN109351165A CN 109351165 A CN109351165 A CN 109351165A CN 201811512581 A CN201811512581 A CN 201811512581A CN 109351165 A CN109351165 A CN 109351165A
- Authority
- CN
- China
- Prior art keywords
- formaldehyde
- nano
- spray
- imidazolidinone
- indoor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/58—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/06—Polluted air
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/45—Gas separation or purification devices adapted for specific applications
- B01D2259/4508—Gas separation or purification devices adapted for specific applications for cleaning air in buildings
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to environment protection fields, and in particular to a kind of indoor except formaldehyde spray.Ingredient including following mass percent: 2- imidazolidinone 5~10%；Nano-titanium dioxide 0.5~2%；Nano silica 1~3%；Plant extracts 0.2~3%；Dispersing agent 0.01~0.1%；Surplus is water.The present invention passes through the matter interactions such as biological enzyme contained in plant extracts etc. and nano-titanium dioxide, plant extracts, nano-titanium dioxide, it combines obtained except formaldehyde spray is except formaldehyde efficiency improves by a certain percentage, not only removal formaldehyde is high-efficient under ultraviolet light irradiation, but also also has under no radiation of visible light higher except formaldehyde efficiency；And the advantages that it is permanently effective to remove formaldehyde, and except formaldehyde process is environmentally protective, and secondary pollution will not be generated during removal, can also remove a variety of house ornamentation Common detrimental substances, such as benzene class, Ammonia.
Description
Technical field
The present invention relates to environment protection fields, and in particular to a kind of indoor except formaldehyde spray.
Background technique
Formaldehyde is colourless liquid soluble easily in water, and volatility is very strong, irritant smell.Indoor formaldehyde, which is mainly derived from, to be built
Build material, furniture, artificial board, various binder coating and synthesis textile etc..The formaldehyde amount of fossil-fuel-fired discharge
Very little, but smoking is an important emission source of formaldehyde.Every cigarette can discharge about 2.4mg formaldehyde according to surveying and determination, and direct from cigarette
The concentration for sucking formaldehyde in intracorporal flue gas can exceed that more than 400 times of concentration of warning.All kinds of artificial boards and its furniture are making
In generally use Lauxite as adhesive, it may be possible to the maximum emission source of formaldehyde.
The formaldehyde caused harm to the human body in life, it may be said that ubiquitous.The article being related to includes furniture, timber floor；
Children's garment, wash-and-wear of shirt；Instant noodles, rice flour；Bubble squid, sea cucumber, Omasum, peeled shrimp；Even car.It is not difficult to find out that clothing,
Food, shelter, row --- we live most important four things, and formaldehyde is all had a finger in every pie unexpectedly, and ubiquitous formaldehyde allows people's worry
It is laden with anxiety.
Formaldehyde may be from cosmetics, detergent, insecticide, disinfectant, preservative, printing ink, paper etc..Foam lath
When making house solar heat protection, resisting cold and insulating materials, under the action of light and heat, foam aging, going bad generates synthetic and discharges first
Aldehyde.(3) hydro carbons can generate formaldehyde gas through light chemical combination, and organic matter can also generate formaldehyde through biochemical reaction, in burning waste gas
Also contain a large amount of formaldehyde, the producible 7kg formaldehyde gas of such as every burning 1000L gasoline, or even light cigarette also to have
0.17mg formaldehyde gas generates.Formaldehyde is also from upholsteries finishing materials such as vehicle seat set, cushion and inside roof linings, with new
Vehicle burst size of methanal is most prominent.Formaldehyde is also from the pollution of outdoor air, such as industrial waste gas, vehicle exhaust, photochemical fog
It can discharge or generate to a certain extent a certain amount of formaldehyde.
Formaldehyde in indoor air has become the major pollutants for influencing human health, especially in the air in winter
Formaldehyde is maximum to the harm of human body.Formaldehyde source in family of China air mainly has the following aspects:
(1) artificial boards such as the glued board, core-board, medium density fibre board (MDF) and the particieboard that are used for indoor ornamentation.Production
For the adhesive that wood-based plate uses using formaldehyde as main component, formaldehyde that is remaining in plate and having neither part nor lot in reaction can be gradually to surrounding
Environment release is the main body to form formaldehyde in indoor air.
(2) furniture manufactured with wood-based plate.Some producers are for profit-push, using underproof plate, or viscous
Using glue inferior when connecing surface lining, plate is severely exceeded with the formaldehyde in glue.
(3) containing formaldehyde components and be possible to the other kinds ornament materials that outwardly distributes, as wall covering fabric, wallpaper,
Chemical fibre carpet, paint and coating etc..
The size of Formaldehyde Concentration of Indoor Air is related with following four factor: room temperature, indoor relative humidity, interior
The loading degree (the formaldehyde emission material surface area of the i.e. every cubic metre interior space) of material, room air circulation.In high temperature, height
It can aggravate the dynamics of formaldehyde emission under wet, negative pressure and high load condition.Under normal conditions the acquisition time of formaldehyde up to 3-10 it
Long.
Formaldehyde has a strong impulse effect to the mucous membrane of eye, nose, larynx, and most common symptom is exactly that eyes are stimulated and head
Bitterly, serious to cause allergic dermatitis and asthma.Make since formaldehyde can generate nitrogen methylidyne compound with albumen qualitative response
Protein coagulating denaturation in cell, thus function capable of inhibiting cell.In addition, formaldehyde can also be with the ionic chloride in air
Reaction generates dichlormetbylether, and the latter is a kind of carcinogen.Formaldehyde can be adsorbed by indoor high-ratio surface material and is enriched with, when
Room temperature releases again when increasing, and aggravates polluting effect.China's " Indoor Air Quality standards " provides that two classes are civilian
The limit value of architectural engineering formaldehyde in indoor air is 0.10mg/m3, the limit value of a kind of civil building engineering formaldehyde in indoor air
For 0.08mg/m3.One type civil building engineering includes: house, hospital, classroom, old building, kindergarten.How
The problem of quickly and effectively removing the formaldehyde in room air, becoming people's growing interest.
Publication No. CN106881093A, the Chinese invention patent that publication date is 20170623 disclose one kind and efficiently remove
Formaldehyde spray and its preparation method and application, 1) this method is specific steps are as follows: weigh zinc nitrate, titanium tetrachloride, chlorination
Iron and ethyl alcohol, first by titanium tetrachloride, zinc nitrate and iron chloride be added ethyl alcohol in, by be added dropwise acetic acid adjust PH=2~
3, and stirring dissolves it sufficiently；2) mixed solution is added in supercritical reaction kettle, controls certain temperature and pressure, and protect
Press certain time.Up to zinc oxide, titanium oxide and iron oxide ternary nano composite granule after pressure release；3) by above-mentioned powder with point
Powder and deionized water mixing, and be added in grinder, suitable grinding condition is controlled, the dispersion liquid finally prepared is
It is of the present invention efficiently to remove formaldehyde spray.
But in actual use, effect of formaldehyde is removed still not to the utmost such as people except formaldehyde spray in above-mentioned technical proposal
Meaning.
Summary of the invention
Mesh of the present invention provides a kind of indoor except formaldehyde spray, solves and cannot be removed effectively indoor formaldehyde in the prior art
The problem of.
The technical scheme adopted by the invention is as follows:
It is a kind of indoor except formaldehyde spray, the ingredient including following mass percent:
2- imidazolidinone 5~10%；
Nano-titanium dioxide 0.5~2%；
Nano silica 1~3%；
Plant extracts 0.2~3%；
Dispersing agent 0.01~0.1%；
Surplus is water.
As a preferred embodiment of the above technical solution, indoor except formaldehyde spray includes the ingredient of following mass percent:
2- imidazolidinone 8%；
Nano-titanium dioxide 1.2%；
Nano silica 2%；
Plant extracts 1.6%；
Dispersing agent 0.05%；
Water 87.15%.
Further, the plant extracts includes the ingredient of following mass percent:
Camphortree leaf 20~40%；
Japan cypress 15~35%；
Honeysuckle 5~15%；
Aloe 20~30%.
As a preferred embodiment of the above technical solution, the plant extracts includes the ingredient of following mass percent:
Camphortree leaf 35%；
Japan cypress 30%；
Honeysuckle 10%；
Aloe 25%.
Further, the dispersing agent includes the ingredient of following mass percent:
Alpha-methyl-naphthalene sulfonic formaldehyde condensation compound 40~70%；
Ethylene oxide and propylene oxide block copolymer 30~60%.
As a preferred embodiment of the above technical solution, the dispersing agent includes the ingredient of following mass percent:
Alpha-methyl-naphthalene sulfonic formaldehyde condensation compound 55%；
Ethylene oxide and propylene oxide block copolymer 45%.
A kind of indoor preparation method for removing formaldehyde spray, comprising the following steps:
S1: 2- imidazolidinone is added to the water, and is stirred 10~20min, is dissolved 2- imidazolidinone sufficiently；
S2: nano-titanium dioxide, nano silica and dispersing agent are added in the solution into S1, is stirred at 60~80 DEG C
Mix 30~50min；
S3: being added plant extracts in solution obtained into S2, and 10~20min is stirred at 30~40 DEG C, stands 10
~20min is obtained except formaldehyde spray.
As a preferred embodiment of the above technical solution, the indoor preparation method except formaldehyde spray the following steps are included:
S1: 2- imidazolidinone is added to the water, and is stirred 15min, is dissolved 2- imidazolidinone sufficiently；
S2: nano-titanium dioxide, nano silica and dispersing agent are added in the solution into S1, is stirred at 70 DEG C
40min；
S3: being added plant extracts in solution obtained into S2, and 150min is stirred at 35 DEG C, stands 15min, that is, makes
It obtains and removes formaldehyde spray.
The invention has the benefit that
The present invention passes through biological enzyme contained in plant extracts etc. and nano-titanium dioxide, plant extracts, nanometer two
The matter interactions such as titanium oxide combine obtained except formaldehyde spray is except formaldehyde efficiency mentions by a certain percentage
Height, not only removal formaldehyde is high-efficient under ultraviolet light irradiation, but also also has under no radiation of visible light higher except formaldehyde efficiency；
And the advantages that it is permanently effective to remove formaldehyde, and except formaldehyde process is environmentally protective, and secondary pollution will not be generated during removal,
A variety of house ornamentation Common detrimental substances, such as benzene class, Ammonia can also be removed.
Specific embodiment
The present invention is described in detail below.
It in order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below will be in the embodiment of the present invention
Technical solution be clearly and completely described, it is clear that described embodiments are some of the embodiments of the present invention, rather than
Whole embodiments.The component for the embodiment of the present invention for being usually described herein as and showing can carry out cloth with a variety of different configurations
It sets and designs.
Therefore, with the detailed description of the embodiment of the present invention be not intended to limit the range of claimed invention,
But it is merely representative of selected embodiment of the invention.Based on the embodiments of the present invention, those of ordinary skill in the art are not having
Every other embodiment obtained under the premise of creative work is made, shall fall within the protection scope of the present invention.
In the description of the present invention, it should be noted that the orientation of the instructions such as term " on ", "vertical", "inner", "outside" or
Positional relationship be the orientation or positional relationship based on shown in or the invention product using when the orientation or position usually put
The orientation or positional relationship that relationship or those skilled in the art usually understand is merely for convenience of the description present invention and letter
Change description, rather than the device or element of indication or suggestion meaning must have a particular orientation, with specific orientation construct and
Operation, therefore be not considered as limiting the invention.In addition, term " first ", " second " etc. are only used for distinguishing description, without
It can be interpreted as indication or suggestion relative importance.
In the description of the present invention, it is also necessary to which explanation is unless specifically defined or limited otherwise, term " setting ",
" installation ", " connection " shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or integrally connect
It connects；It can be mechanical connection, be also possible to be electrically connected；It can be directly connected, can also indirectly connected through an intermediary, it can
To be the connection inside two elements.For the ordinary skill in the art, above-mentioned term can be understood with concrete condition
Concrete meaning in the present invention.
Embodiment 1:
It present embodiments provides a kind of indoor except formaldehyde spray.
Every 1000g's removes in formaldehyde spray, including 2- imidazolidinone 80g；Nano-titanium dioxide 12g；Nano silica
20g；Plant extracts 16g；Dispersing agent 0.5g；Water 871.5g.
2- imidazolidinone is a kind of organic compound, and molecular formula is C3H6N2O, be colorless needle crystals, it is soluble easily in water and
Hot ethanol is insoluble in ether.The product be mainly used for it is all kinds of except aldehyde field, such as: high-performance formaldehyde scavenger, home air formaldehyde
Potent vigor enzyme, formaldehyde is long-acting to be melted matchmaker, glue aldehyde remover, photocatalyst, floor taste removal nursing wax, furniture eliminating smell agent, automobile-used removes
Taste agent, textile auxiliary are except aldehyde intermediate, resin are except aldehyde etc.；In addition, can also be used in fabric crease-shedding finishing agent in textile industry, resist
Tear finishing agent.
Nano-titanium dioxide is fluffy white powder, and shielding ultraviolet rays effect is strong, there is good dispersibility and weatherability.It can
The infringement of ultraviolet light is prevented as ultraviolet light screener for fields such as cosmetics, functional fibre, plastics, coating, paint.?
It can be used for superior automobile finishing coat, there is effect.It is sterilized for a long time under the action of light middle-ultraviolet lamp.It is demonstrated experimentally that
Pernicious HeLa cell can be thoroughly killed with the dichloride in anatase type TiO2 of 0.1mg/cm3 concentration, and with superoxide dismutase
Enzyme (SOD) additive amount increases, and the efficiency that cancer cell is killed in TiO2 photocatalysis also improves.To bacillus subtilis black variety gemma,
Pseudomonas aeruginosa, Escherichia coli, gold-coloured staphylococci, salmonella, tooth branch bacterium and aspergillus killing rate reach 98% or more；With
TiO2 photochemical catalytic oxidation advanced treating tap water, can greatly reduce the bacterial population in water；Adding nano TiO 2 in coating can be with
Sterilization, antifouling, deodorization, self-cleaning antibacterial antifouling paint are produced, it is thin to be applied to hospital ward, operating room and family bathroom space etc.
Nectar collection, the place easily bred prevent infection, deodorization taste removal.Harmful bacteria can effectively be killed etc..In daylight or light
It activates Ti02 under the action of ultraviolet light and generates the free radical with high catalytic activity, very strong photooxidation and reduction can be generated
Ability can be catalyzed, photodissociation is attached to the organic matters such as the various formaldehyde of body surface and part inorganic matter.
Nano silica is a kind of inorganic chemical industry material, is commonly called as white carbon black.Due to being ultrafine nanometer, size range exists
1~100nm, therefore there are many unique properties, such as have to anti-ultraviolet optical property, it is anti-ageing other materials to be improved
Change, intensity and chemical-resistance.Purposes is very extensive.Nanometer grade silica is amorphous white powder, nontoxic, tasteless, nothing
Pollution, micro-structure is spherical shape, and in cotton-shaped and netted quasi- grain structure, molecular formula and structural formula are SiO2, not soluble in water.It utilizes
The huge specific surface area of nano Si 02, the more meso-hole structures in surface and superpower adsorption capacity and unusual physicochemical property, will be silver-colored
The functional ionics such as ion be equably designed into the surface nano Si 0X it is mesoporous in, it is anti-to develop efficient, lasting, high temperature resistant, wide spectrum
The nano-antibacterial powder of bacterium can be widely used for bill, health care, chemical building material, family's electrical article, functional fibre, plastic products etc.
In industry.
Plant extracts refers to using solvent appropriate or method, mentions from plant (plant is all or certain is a part of) for raw material
The substance for taking or being process can be used for pharmaceuticals industry, food service industry, healthy industry, beauty industry and other industries.
Dispersing agent is one kind in the molecule while having lipophilic and two kinds of opposite natures of hydrophily interfacial agent.It can
Those are poorly soluble in the inorganic of liquid, the solid and liquid particles of organic pigment for uniform dispersion, while can also prevent particle
Sedimentation and cohesion, amphipathic reagent needed for forming stable suspension.
Embodiment 2:
It present embodiments provides a kind of indoor except formaldehyde spray.
Every 1000g's removes in formaldehyde spray, including 2- imidazolidinone 50g；Nano-titanium dioxide 10g；Nano silica
15g；Plant extracts 30g；Dispersing agent 1g；Water 894g.
Embodiment 3:
It present embodiments provides a kind of indoor except formaldehyde spray.
Every 1000g's removes in formaldehyde spray, including 2- imidazolidinone 100g；Nano-titanium dioxide 5g；Nano silica
10g；Plant extracts 2g；Dispersing agent 0.8g；Water 882.2g.
Embodiment 4:
It present embodiments provides a kind of indoor except formaldehyde spray.
Every 1000g's removes in formaldehyde spray, including 2- imidazolidinone 75g；Nano-titanium dioxide 20g；Nano silica
30g；Plant extracts 10g；Dispersing agent 0.1g；Water 864.9g.
Embodiment 5:
It present embodiments provides a kind of indoor except formaldehyde spray.
Every 1000g's removes in formaldehyde spray, including 2- imidazolidinone 80g；Nano-titanium dioxide 12g；Nano silica
20g；Camphortree leaf 5.6g；Japan cypress 4.8g；Honeysuckle 1.6g；Aloe 4g；Alpha-methyl-naphthalene sulfonic formaldehyde condensation compound 0.275g；Epoxy second
Alkane and propylene oxide block copolymer 0.225g；Water 871.5g.
Embodiment 6:
It present embodiments provides a kind of indoor except formaldehyde spray.
Every 1000g's removes in formaldehyde spray, including 2- imidazolidinone 50g；Nano-titanium dioxide 10g；Nano silica
15g；Camphortree leaf 6g；Japan cypress 10.5g；Honeysuckle 4.5g；Aloe 9g；Alpha-methyl-naphthalene sulfonic formaldehyde condensation compound 0.4g；Ethylene oxide
With propylene oxide block copolymer 0.6g；Water 894g.
Embodiment 7:
It present embodiments provides a kind of indoor except formaldehyde spray.
Every 1000g's removes in formaldehyde spray, including 2- imidazolidinone 100g；Nano-titanium dioxide 5g；Nano silica
10g；Camphortree leaf 0.8g；Japan cypress 0.3g；Honeysuckle 0.3g；Aloe 0.6g；Alpha-methyl-naphthalene sulfonic formaldehyde condensation compound 0.56g；Epoxy
Ethane and propylene oxide block copolymer 0.24g；Water 882.2g.
Embodiment 8:
It present embodiments provides a kind of indoor except formaldehyde spray.
Every 1000g's removes in formaldehyde spray, including 2- imidazolidinone 75g；Nano-titanium dioxide 20g；Nano silica
30g；Camphortree leaf 4g；Japan cypress 3.5g；Honeysuckle 0.5g；Aloe 2g；Alpha-methyl-naphthalene sulfonic formaldehyde condensation compound 0.07g；Ethylene oxide
With propylene oxide block copolymer 0.03g；Water 864.9g.
Embodiment 9:
Present embodiments provide a kind of indoor preparation method for removing formaldehyde spray.
S1: the 2- imidazolidinone of 80g is added in 871.5g water, is stirred 15min, is dissolved 2- imidazolidinone sufficiently；
S2: nano-titanium dioxide 12g, nano silica 20g and dispersing agent 0.5g are added in the solution into S1,70
40min is stirred at DEG C；
S3: plant extracts 16g being added into S2 in solution obtained, 15min is stirred at 35 DEG C, stands 15min, i.e.,
It is made and removes formaldehyde spray.
Embodiment 10:
Present embodiments provide a kind of indoor preparation method for removing formaldehyde spray.
S1: the 2- imidazolidinone of 50g is added in 894g water, is stirred 10min, is dissolved 2- imidazolidinone sufficiently；
S2: nano-titanium dioxide 10g, nano silica 15g and dispersing agent 1g are added in the solution into S1, at 60 DEG C
Lower stirring 30min；
S3: plant extracts 30g being added into S2 in solution obtained, 10min is stirred at 30 DEG C, stands 10min, i.e.,
It is made and removes formaldehyde spray.
Embodiment 11:
Present embodiments provide a kind of indoor preparation method for removing formaldehyde spray.
S1: the 2- imidazolidinone of 100g is added in 882.2g water, is stirred 20min, is dissolved 2- imidazolidinone sufficiently；
S2: nano-titanium dioxide 5g, nano silica 10g and dispersing agent 0.8g are added in the solution into S1,80
50min is stirred at DEG C；
S3: plant extracts 2g being added into S2 in solution obtained, 20min is stirred at 40 DEG C, stands 20min, i.e.,
It is made and removes formaldehyde spray.
Embodiment 12:
Present embodiments provide a kind of indoor preparation method for removing formaldehyde spray.
S1: the 2- imidazolidinone of 75g is added in 864.9g water, is stirred 180min, is dissolved 2- imidazolidinone sufficiently；
S2: nano-titanium dioxide 20g, nano silica 30g and dispersing agent 0.1g are added in the solution into S1,73
42min is stirred at DEG C；
S3: plant extracts 10g being added into S2 in solution obtained, 180min is stirred at 33 DEG C, stands 16min,
It obtains except formaldehyde spray.
Embodiment 13:
Present embodiments provide a kind of indoor preparation method for removing formaldehyde spray.
S1: the 2- imidazolidinone of 80g is added in 871.5g water, is stirred 15min, is dissolved 2- imidazolidinone sufficiently；
S2: nano-titanium dioxide 12g, nano silica 20g, alpha-methyl-naphthalene sulfonic acid and formaldehyde are added in the solution into S1
Condensation product 0.275g and ethylene oxide and propylene oxide block copolymer 0.225g, stir 40min at 70 DEG C；
S3: camphortree leaf 5.6g, Japan cypress 4.8g, honeysuckle 1.6g and aloe 4g is added in solution obtained into S2,35
15min is stirred at DEG C, is stood 15min, is obtained except formaldehyde spray.
Embodiment 14:
Present embodiments provide a kind of indoor preparation method for removing formaldehyde spray.
S1: the 2- imidazolidinone of 50g is added in 894g water, is stirred 10min, is dissolved 2- imidazolidinone sufficiently；
S2: nano-titanium dioxide 10g, nano silica 15g, alpha-methyl-naphthalene sulfonic acid and formaldehyde are added in the solution into S1
Condensation product 0.4g and ethylene oxide and propylene oxide block copolymer 0.6g, stir 30min at 60 DEG C；
S3: camphortree leaf 6g, Japan cypress 10.5g, honeysuckle 4.5g and aloe 9g is added in solution obtained into S2, at 30 DEG C
Lower stirring 10min stands 10min, obtains except formaldehyde spray.
Embodiment 15:
Present embodiments provide a kind of indoor preparation method for removing formaldehyde spray.
S1: the 2- imidazolidinone of 100g is added in 882.2g water, is stirred 20min, is dissolved 2- imidazolidinone sufficiently；
S2: nano-titanium dioxide 5g, nano silica 10g, alpha-methyl-naphthalene sulfonic acid and formaldehyde are added in the solution into S1
Condensation product 0.56g and ethylene oxide and propylene oxide block copolymer 0.24g, stir 50min at 80 DEG C；
S3: camphortree leaf 0.8g, Japan cypress 0.3g, honeysuckle 0.3g and aloe 0.6g being added into S2 in solution obtained,
20min is stirred at 40 DEG C, is stood 20min, is obtained except formaldehyde spray.
Embodiment 16:
Present embodiments provide a kind of indoor preparation method for removing formaldehyde spray.
S1: the 2- imidazolidinone of 75g is added in 864.9g water, is stirred 180min, is dissolved 2- imidazolidinone sufficiently；
S2: nano-titanium dioxide 20g, nano silica 30g, alpha-methyl-naphthalene sulfonic acid and formaldehyde are added in the solution into S1
Condensation product 0.07g and ethylene oxide and propylene oxide block copolymer 0.03g, stir 42min at 73 DEG C；
S3: camphortree leaf 4g, Japan cypress 3.5g, honeysuckle 0.5g and aloe 2g is added in solution obtained into S2, at 33 DEG C
Lower stirring 180min stands 16min, obtains except formaldehyde spray.
The present invention is not limited to above-mentioned optional embodiment, anyone can show that other are each under the inspiration of the present invention
The product of kind form.Above-mentioned specific embodiment should not be understood the limitation of pairs of protection scope of the present invention, protection of the invention
Range should be subject to be defined in claims, and specification can be used for interpreting the claims.
Claims (8)
1. a kind of indoor except formaldehyde spray, which is characterized in that the ingredient including following mass percent:
2- imidazolidinone 5~10%；
Nano-titanium dioxide 0.5~2%；
Nano silica 1~3%；
Plant extracts 0.2~3%；
Dispersing agent 0.01~0.1%；
Surplus is water.
2. according to claim 1 indoor except formaldehyde spray, which is characterized in that the ingredient including following mass percent:
2- imidazolidinone 8%；
Nano-titanium dioxide 1.2%；
Nano silica 2%；
Plant extracts 1.6%；
Dispersing agent 0.05%；
Water 87.15%.
3. according to claim 1 indoor except formaldehyde spray, which is characterized in that the plant extracts includes following quality
The ingredient of percentage:
Camphortree leaf 20~40%；
Japan cypress 15~35%；
Honeysuckle 5~15%；
Aloe 20~30%.
4. according to claim 3 indoor except formaldehyde spray, which is characterized in that the plant extracts includes following quality
The ingredient of percentage:
Camphortree leaf 35%；
Japan cypress 30%；
Honeysuckle 10%；
Aloe 25%.
5. according to claim 1 indoor except formaldehyde spray, it is characterised in that: the dispersing agent includes following quality percentage
The ingredient of ratio:
Alpha-methyl-naphthalene sulfonic formaldehyde condensation compound 40~70%；
Ethylene oxide and propylene oxide block copolymer 30~60%.
6. according to claim 5 indoor except formaldehyde spray, it is characterised in that: the dispersing agent includes following quality percentage
The ingredient of ratio:
Alpha-methyl-naphthalene sulfonic formaldehyde condensation compound 55%；
Ethylene oxide and propylene oxide block copolymer 45%.
7. a kind of indoor preparation method for removing formaldehyde spray as claimed in any one of claims 1 to 6, which is characterized in that including with
Lower step:
S1: 2- imidazolidinone is added to the water, and is stirred 10~20min, is dissolved 2- imidazolidinone sufficiently；
S2: nano-titanium dioxide, nano silica and dispersing agent are added in the solution into S1, stirs 30 at 60~80 DEG C
~50min；
S3: being added plant extracts in solution obtained into S2, and 10~20min is stirred at 30~40 DEG C, stand 10~
20min is obtained except formaldehyde spray.
8. the indoor preparation method for removing formaldehyde spray according to claim 7, which comprises the following steps:
S1: 2- imidazolidinone is added to the water, and is stirred 15min, is dissolved 2- imidazolidinone sufficiently；
S2: nano-titanium dioxide, nano silica and dispersing agent are added in the solution into S1, stirs 40min at 70 DEG C；
S3: being added plant extracts in solution obtained into S2, and 150min is stirred at 35 DEG C, stands 15min, obtains and remove
Formaldehyde spray.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811512581.1A CN109351165A (en) | 2018-12-11 | 2018-12-11 | It is a kind of indoor except formaldehyde spray |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811512581.1A CN109351165A (en) | 2018-12-11 | 2018-12-11 | It is a kind of indoor except formaldehyde spray |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109351165A true CN109351165A (en) | 2019-02-19 |
Family
ID=65330393
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811512581.1A Pending CN109351165A (en) | 2018-12-11 | 2018-12-11 | It is a kind of indoor except formaldehyde spray |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109351165A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109758894A (en) * | 2019-02-27 | 2019-05-17 | 乔伟 | One kind removing the formaldehyde scraps of paper except formaldehyde formulations and its using said preparation is manufactured |
| CN109794151A (en) * | 2019-03-01 | 2019-05-24 | 陈丹 | Methanal trapping agent is spraying and preparation method thereof |
| CN110270208A (en) * | 2019-03-01 | 2019-09-24 | 湖北格瑞乐环保工程有限公司 | A kind of detection of room air pollution and administering method |
| CN110270383A (en) * | 2019-03-01 | 2019-09-24 | 湖北格瑞乐环保工程有限公司 | A kind of improvement indoor pollution nano-photo catalytic plant biological catalyst and preparation method |
| CN110801709A (en) * | 2019-12-19 | 2020-02-18 | 绍兴市上虞区理工高等研究院 | Plant aldehyde-cleaning essence, plant aldehyde-cleaning coating and preparation method thereof |
| CN111229000A (en) * | 2019-11-21 | 2020-06-05 | 班反平 | Formaldehyde cleaner |
| CN112023687A (en) * | 2020-08-13 | 2020-12-04 | 江苏卓高环保科技有限公司 | Korean pine seed nano-catalyst compound formaldehyde-removing spray and preparation method thereof |
| CN112625568A (en) * | 2021-01-08 | 2021-04-09 | 成都彰铭启科技有限公司 | Preparation method of aldehyde-removing composite coating for artificial board |
| CN113769549A (en) * | 2021-08-16 | 2021-12-10 | 创钛中科广至材料(苏州)有限公司 | Aldehyde removing agent |
| CN114307586A (en) * | 2022-01-13 | 2022-04-12 | 广州天与地投资服务有限公司 | Formaldehyde scavenger combining photocatalyst with plant enzyme |
| CN114558433A (en) * | 2022-01-21 | 2022-05-31 | 江苏富氧岛新材料有限公司 | Formaldehyde-removing spray and production process thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006149900A (en) * | 2004-11-30 | 2006-06-15 | Sato Kankyo Gijutsu Kk | Indoor antibacterial deodorization method and medical solution |
| CN105921008A (en) * | 2016-05-10 | 2016-09-07 | 保护伞环保科技成都有限公司 | Photocatalyst formaldehyde removal spray |
| CN106731766A (en) * | 2016-11-16 | 2017-05-31 | 无锡五棵树环保科技有限公司 | It is a kind of environmentally friendly except formaldehyde spray |
| CN106719928A (en) * | 2016-12-30 | 2017-05-31 | 南宁天亮精细化工有限责任公司 | House is sterilized except formaldehyde is sprayed with fast-growing eucalyptus |
| CN107821458A (en) * | 2017-10-30 | 2018-03-23 | 胡国剑 | It is a kind of except air-atomizing agent of formaldehyde and preparation method thereof |
| CN108619906A (en) * | 2018-05-31 | 2018-10-09 | 李兵峰 | Environmentally friendly finishing eliminating smell agent and preparation method thereof |
-
2018
- 2018-12-11 CN CN201811512581.1A patent/CN109351165A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006149900A (en) * | 2004-11-30 | 2006-06-15 | Sato Kankyo Gijutsu Kk | Indoor antibacterial deodorization method and medical solution |
| CN105921008A (en) * | 2016-05-10 | 2016-09-07 | 保护伞环保科技成都有限公司 | Photocatalyst formaldehyde removal spray |
| CN106731766A (en) * | 2016-11-16 | 2017-05-31 | 无锡五棵树环保科技有限公司 | It is a kind of environmentally friendly except formaldehyde spray |
| CN106719928A (en) * | 2016-12-30 | 2017-05-31 | 南宁天亮精细化工有限责任公司 | House is sterilized except formaldehyde is sprayed with fast-growing eucalyptus |
| CN107821458A (en) * | 2017-10-30 | 2018-03-23 | 胡国剑 | It is a kind of except air-atomizing agent of formaldehyde and preparation method thereof |
| CN108619906A (en) * | 2018-05-31 | 2018-10-09 | 李兵峰 | Environmentally friendly finishing eliminating smell agent and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 《化工百科全书》编辑委员会编: "《化工百科全书 第4卷 发光材料-氟 fa-fu》", 30 September 1993, 北京：化学工业出版社 * |
| 国家安全生产监督管理总局，中国职业安全健康协会组织编写: "《职业卫生监督管理培训教材》", 31 May 2014, 北京：煤炭工业出版社 * |
| 张晓阳主编: "《新手装修1000问 预算 施工 质量 后期》", 30 April 2013, 华中科技大学出版社 * |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109758894A (en) * | 2019-02-27 | 2019-05-17 | 乔伟 | One kind removing the formaldehyde scraps of paper except formaldehyde formulations and its using said preparation is manufactured |
| CN109794151A (en) * | 2019-03-01 | 2019-05-24 | 陈丹 | Methanal trapping agent is spraying and preparation method thereof |
| CN110270208A (en) * | 2019-03-01 | 2019-09-24 | 湖北格瑞乐环保工程有限公司 | A kind of detection of room air pollution and administering method |
| CN110270383A (en) * | 2019-03-01 | 2019-09-24 | 湖北格瑞乐环保工程有限公司 | A kind of improvement indoor pollution nano-photo catalytic plant biological catalyst and preparation method |
| CN111229000A (en) * | 2019-11-21 | 2020-06-05 | 班反平 | Formaldehyde cleaner |
| CN110801709A (en) * | 2019-12-19 | 2020-02-18 | 绍兴市上虞区理工高等研究院 | Plant aldehyde-cleaning essence, plant aldehyde-cleaning coating and preparation method thereof |
| CN112023687A (en) * | 2020-08-13 | 2020-12-04 | 江苏卓高环保科技有限公司 | Korean pine seed nano-catalyst compound formaldehyde-removing spray and preparation method thereof |
| CN112625568A (en) * | 2021-01-08 | 2021-04-09 | 成都彰铭启科技有限公司 | Preparation method of aldehyde-removing composite coating for artificial board |
| CN113769549A (en) * | 2021-08-16 | 2021-12-10 | 创钛中科广至材料(苏州)有限公司 | Aldehyde removing agent |
| CN114307586A (en) * | 2022-01-13 | 2022-04-12 | 广州天与地投资服务有限公司 | Formaldehyde scavenger combining photocatalyst with plant enzyme |
| CN114558433A (en) * | 2022-01-21 | 2022-05-31 | 江苏富氧岛新材料有限公司 | Formaldehyde-removing spray and production process thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109351165A (en) | It is a kind of indoor except formaldehyde spray | |
| CN103059679A (en) | Odorless anti-formaldehyde environment-friendly internal wall latex paint and preparation method thereof | |
| TWI793333B (en) | Production method of material having bactericidal effect and product having bactericidal effect including preparation having the same effect as that obtained under light irradiation without light irradiation | |
| CN108395775A (en) | A kind of phenylpropyl alcohol negative ion paint containing formaldehyde catching agent | |
| CN103190442A (en) | Composite antibacterial anion air cleanser and preparation method thereof | |
| CN105220579A (en) | The pollution-free anion facing paper of a kind of environment-friendly novel | |
| CN107325730A (en) | A kind of multifunctional low-carbon health coating | |
| CN109221251A (en) | A kind of indoor air purification efficient sterilizing photocatalyst material and preparation method | |
| CN105802414A (en) | Preparation method of formaldehyde adsorption water-based environmental protection coating | |
| CN104073072A (en) | Nano functional ecological environmental-friendly coating | |
| CN109705639A (en) | A kind of shell powder paint and preparation method thereof | |
| CN107867810A (en) | Purification of air, damping are self-cleaning, antibacterial health-care type oyster shell whiting biomass dry powder paint | |
| CN107793812A (en) | Finish materials, finish materials preparation method | |
| CN107999032B (en) | Can a variety of odorous organic compounds of efficient degradation environmentally protective macromolecule eliminating smell agent, and its application in air cleaning | |
| KR20060114159A (en) | The functional water paint composition and method for preparing the same | |
| CN103468049B (en) | Adsorbable, decompose difunctional coating except formaldehyde and preparation method thereof | |
| JP2006081971A (en) | Function material, filter, composition for cosmetic raw material and food additive, and manufacturing method for functional material | |
| CN103496884A (en) | Formaldehyde eliminating coating with dual functions of adsorption and decomposition and preparation method thereof | |
| WO2018074270A1 (en) | White deodorant, chemical product with deodorant function, method for using white deodorant and method for manufacturing white deodorant | |
| CN106882946A (en) | A kind of preparation method of modified diatom ooze | |
| CN106280763A (en) | Kieselguhr photocatalytic spray liquid can be cleaned | |
| CN107699009A (en) | Finish materials, finish materials preparation method | |
| CN105969195A (en) | Aloe wall film and production process thereof | |
| CN106221414A (en) | Chlorite photocatalytic spray liquid can be cleaned | |
| CN106221438A (en) | Serpentine photocatalytic spray liquid can be cleaned |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190219 |
|
| RJ01 | Rejection of invention patent application after publication |