CN107057802A - 一种含有bola型表面活性剂的玻璃磨削液及制备方法和使用方法 - Google Patents

一种含有bola型表面活性剂的玻璃磨削液及制备方法和使用方法 Download PDF

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CN107057802A
CN107057802A CN201710295625.9A CN201710295625A CN107057802A CN 107057802 A CN107057802 A CN 107057802A CN 201710295625 A CN201710295625 A CN 201710295625A CN 107057802 A CN107057802 A CN 107057802A
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grinding fluid
glass grinding
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陈磊
尹树花
鲍玮
王晓菲
崔建保
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TARRANT BIOLOGICAL ENGINEERING Co Ltd
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Abstract

本发明涉及一种含有bola型表面活性剂的玻璃磨削液，原料由润滑剂、bola型表面活性剂、防锈剂、缓蚀剂、硬水软化剂、消泡剂、防腐剂和去离子水构成，先将润滑剂、bola型表面活性剂、防锈剂、缓蚀剂和防腐剂溶于去离子水中，再加入硬水软化剂和消泡剂后制得成品。本发明使用时，将玻璃磨削液与水按照一定的重量比混合，即可以进行磨削加工，磨削加工完毕后玻璃表面光洁度好、无划伤、磨削速率快、易清洗、加工过程安全环保。

Description

一种含有bola型表面活性剂的玻璃磨削液及制备方法和使用 方法
技术领域
本发明属于富含表面活性剂废水净化技术领域，尤其是一种用于降解富含表面活性剂废水的复合菌剂及其制备方法。
背景技术
玻璃切削液使用在玻璃、树脂玻璃、光学玻璃、平板玻璃、相机镜片、眼镜镜片、等材料的切削、切割、磨削工艺中，实现冷却、清洗、润滑、防锈及灰分沉降的作用，有利于提高功效及工件表面效果。随着信息产业、光学技术产业的发展，国内、国际市场对高端精密加工玻璃的需求量越来越大，而在玻璃磨削加工行业，普遍存在使用的玻璃磨削液润滑性差，磨削液沉降性差，工件表面划伤比较多等问题。厂家为了改变这些问题，在玻璃磨削液中加入表面活性剂来促进磨削液润滑和沉降，这些表面活性剂较多使用阴离子型的表面活性剂，但实际使用中发现，这些表面活性剂加入后，玻璃磨削液的润滑和沉降性能还有待提高，较常出现玻璃碎屑在加工过程划伤工件表面的问题，导致加工效率的下降。通过实践可知，目前急需一种具有优良润滑剂沉降性的玻璃磨削液。
发明内容
本发明的目的在于克服现有技术的不足，提供具有更加优良的冷却性、润滑性及对磨屑的清洗性和沉降性、提高磨削效率的一种含有bola型表面活性剂的玻璃磨削液及制备方法和使用方法。
本发明采取的技术方案是：
一种含有bola型表面活性剂的玻璃磨削液，其特征在于：包括按照重量份数比混合的以下组分：
而且，所述润滑剂为植物油酸。
而且，所述bola型表面活性剂包括聚丙二醇二乙酸钠、聚丙二醇二硫酸钠、磺化脱氢松香酸二钠盐、N-N’-十二亚甲基双麦芽糖酰胺、N-N’-十二亚甲基双葡萄糖醛酰胺、1-(12-(P,P,P-三丁基膦)十二烷基)-3-丁基咪唑溴盐或1-(10-(P,P,P-三丁基膦)癸烷基)-3-丁基咪唑溴盐中的任意一种。
而且，所述防锈剂A和防锈剂B均选自三乙醇胺、癸二酸、失水山梨醇单油酸酯、季戊四醇酯、硫代磷酸酯或油酸咪唑啉中的任意一种且二者不相同。
而且，所述缓蚀剂为苯三唑、膦酸、膦盐、膦羧酸、琉基苯并噻唑或磺化木质素中的任意一种。
而且，所述硬水软化剂为EDTA、氨基三乙酸、多磷酸盐、1,3-二酮或羟基羧酸中的任意一种。
而且，所述消泡剂为有机硅消泡剂。
而且，所述防腐剂为苯并异噻唑啉酮。
本发明的另一个目的是提供一种含有bola型表面活性剂的玻璃磨削液的制备方法，其特征在于：包括以下步骤：
⑴将润滑剂、bola型表面活性剂、防锈剂，缓蚀剂和防腐剂在45～55摄氏度的温度下溶于去离子水中；
⑵在步骤⑴的产物中加入硬水软化剂，搅拌均匀；
⑶在步骤⑵的产物中加入消泡剂，搅拌均匀后制得成品。
本发明的另一个目的是提供一种含有bola型表面活性剂的玻璃磨削液的使用方法，其特征在于：所述玻璃磨削液与水按照1:10～15的重量比混合后使用。
本发明的优点和积极效果是：
本发明中，原料由润滑剂、bola型表面活性剂、防锈剂、缓蚀剂、硬水软化剂、消泡剂、防腐剂和去离子水构成，先将润滑剂、bola型表面活性剂、防锈剂、缓蚀剂和防腐剂溶于去离子水中，再加入硬水软化剂和消泡剂后制得成品。使用时，将玻璃磨削液与水按照一定的重量比混合，即可以进行磨削加工，磨削加工完毕后玻璃表面光洁度好、无划伤、磨削速率快、易清洗、加工过程安全环保。
具体实施方式
下面结合实施例，对本发明进一步说明，下述实施例是说明性的，不是限定性的，不能以下述实施例来限定本发明的保护范围。
一种含有bola型表面活性剂的玻璃磨削液，本发明的创新在于：包括按照重量份数比混合的以下组分：
更优选的方案是：所述润滑剂为植物油酸。该植物油酸为椰子油酸、妥尔油酸、蓖麻油酸或大豆油酸中的任意一种。
所述bola型表面活性剂包括聚丙二醇二乙酸钠、聚丙二醇二硫酸钠、磺化脱氢松香酸二钠盐、N-N’-十二亚甲基双麦芽糖酰胺、N-N’-十二亚甲基双葡萄糖醛酰胺、1-(12-(P,P,P-三丁基膦)十二烷基)-3-丁基咪唑溴盐或1-(10-(P,P,P-三丁基膦)癸烷基)-3-丁基咪唑溴盐中的任意一种。
所述防锈剂A和防锈剂B均选自三乙醇胺、癸二酸、失水山梨醇单油酸酯、季戊四醇酯、硫代磷酸酯或油酸咪唑啉中的任意一种，但是防锈剂A和防锈剂B不能同时选择相同的组分。
所述缓蚀剂为苯三唑、膦酸、膦盐、膦羧酸、琉基苯并噻唑或磺化木质素中的任意一种。
所述硬水软化剂为EDTA、氨基三乙酸、多磷酸盐、1,3-二酮或羟基羧酸中的任意一种。
所述消泡剂为有机硅消泡剂。所述防腐剂为苯并异噻唑啉酮。
上述含有bola型表面活性剂的玻璃磨削液的制备方法包括以下步骤：
⑴将润滑剂、bola型表面活性剂、防锈剂，缓蚀剂和防腐剂在45～55摄氏度的温度下溶于去离子水中；
⑵在步骤⑴的产物中加入硬水软化剂，搅拌均匀；
⑶在步骤⑵的产物中加入消泡剂，搅拌均匀后制得成品。
上述含有bola型表面活性剂的玻璃磨削液的使用方法：所述玻璃磨削液与水按照1:10～15的重量比混合后使用。
实施例1
将椰子油酸、聚丙二醇二乙酸钠、三乙醇胺，癸二酸，苯三唑，防腐剂在50度温度下溶于去离子水中，待溶液搅拌均匀后，边搅拌边加入EDTA，至溶液稳定，最后加入消泡剂，制得磨削液产品。
将磨削液与水按照1∶12的比例搅拌均匀后，进行磨削加工，能使金刚石刀头具有更好的自锐性，明显提高磨削效率，对磨屑的清洗性和沉降性显著提高。
实施例2
制备方法和使用方法与实施例1相同。
实施例3
制备方法和使用方法与实施例1相同。
实施例4
制备方法和使用方法与实施例1相同。
实施例5
制备方法和使用方法与实施例1相同。
实施例6
制备方法和使用方法与实施例1相同。
实施例7
制备方法和使用方法与实施例1相同。
实施例8
制备方法和使用方法与实施例1相同。
上述各实施例按照表1的指标及试验方法进行检验，各配方的指标均符合标准，而且经过实际的磨削加工实验，压力为2Psi，磨盘转速150r/s时去除率395nm/s，表面粗糙度Ra：1.2um。
表1：指标及试验方法
以实施例一为例与传统市售玻璃磨削液的性能测试对照如下：
表2：实施例一与现有技术的比较
经过实际的磨削加工实验，压力为2Psi，磨盘转速150r/s，实验结果如下：
去除率(nm/s) 表面粗糙度(um)
实施例一(5％稀释) 395 1.2
传统市售玻璃磨削液(5％稀释) 352 1.7
表3：实施例一与现有技术的比较
说明实施例一与传统市售玻璃磨削液相比磨削速率更快，表面质量更好。
本发明中，原料由润滑剂、bola型表面活性剂、防锈剂、缓蚀剂、硬水软化剂、消泡剂、防腐剂和去离子水构成，先将润滑剂、bola型表面活性剂、防锈剂、缓蚀剂和防腐剂溶于去离子水中，再加入硬水软化剂和消泡剂后制得成品。使用时，将玻璃磨削液与水按照一定的重量比混合，即可以进行磨削加工，磨削加工完毕后玻璃表面光洁度好、无划伤、磨削速率快、易清洗、加工过程安全环保。

Claims (10)

1.一种含有bola型表面活性剂的玻璃磨削液，其特征在于：包括按照重量份数比混合的以下组分：
2.根据权利要求1所述的一种含有bola型表面活性剂的玻璃磨削液，其特征在于：所述润滑剂为植物油酸。
3.根据权利要求1所述的一种含有bola型表面活性剂的玻璃磨削液，其特征在于：所述bola型表面活性剂包括聚丙二醇二乙酸钠、聚丙二醇二硫酸钠、磺化脱氢松香酸二钠盐、N-N’-十二亚甲基双麦芽糖酰胺、N-N’-十二亚甲基双葡萄糖醛酰胺、1-(12-(P,P,P-三丁基膦)十二烷基)-3-丁基咪唑溴盐或1-(10-(P,P,P-三丁基膦)癸烷基)-3-丁基咪唑溴盐中的任意一种。
4.根据权利要求1所述的一种含有bola型表面活性剂的玻璃磨削液，其特征在于：所述防锈剂A和防锈剂B均选自三乙醇胺、癸二酸、失水山梨醇单油酸酯、季戊四醇酯、硫代磷酸酯或油酸咪唑啉中的任意一种且二者不相同。
5.根据权利要求1所述的一种含有bola型表面活性剂的玻璃磨削液，其特征在于：所述缓蚀剂为苯三唑、膦酸、膦盐、膦羧酸、琉基苯并噻唑或磺化木质素中的任意一种。
6.根据权利要求1所述的一种含有bola型表面活性剂的玻璃磨削液，其特征在于：所述硬水软化剂为EDTA、氨基三乙酸、多磷酸盐、1,3-二酮或羟基羧酸中的任意一种。
7.根据权利要求1所述的一种含有bola型表面活性剂的玻璃磨削液，其特征在于：所述消泡剂为有机硅消泡剂。
8.根据权利要求1所述的一种含有bola型表面活性剂的玻璃磨削液，其特征在于：所述防腐剂为苯并异噻唑啉酮。
9.一种如权利要求1～8任意一项所述的含有bola型表面活性剂的玻璃磨削液的制备方法，其特征在于：包括以下步骤：
⑴将润滑剂、表面活性剂、防锈剂，缓蚀剂和防腐剂在45～55摄氏度的温度下溶于去离子水中；
⑵在步骤⑴的产物中加入硬水软化剂，搅拌均匀；
⑶在步骤⑵的产物中加入消泡剂，搅拌均匀后制得成品。
10.一种如权利要求1～8任意一项所述的含有bola型表面活性剂的玻璃磨削液的使用方法，其特征在于：所述玻璃磨削液与水按照1:10～15的重量比混合后使用。
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113527974A (zh) * 2021-07-14 2021-10-22 湖北敏捷志成标识科技有限公司 一种用于无机玻璃面板的光油及其制备方法
CN114644956A (zh) * 2022-04-29 2022-06-21 泰伦特生物工程股份有限公司 一种镝铁合金线切割液及其制备方法和使用方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005113039A (ja) * 2003-10-09 2005-04-28 Kohjin Co Ltd 水性切削液、水性スラリー及びこれを用いる硬脆性難削材料の切断方法
CN102240521A (zh) * 2011-04-25 2011-11-16 苏州大学 一种Bola型表面活性剂
CN102559354A (zh) * 2010-12-30 2012-07-11 安集微电子（上海）有限公司 一种水基玻璃磨削液
CN102690718A (zh) * 2011-03-22 2012-09-26 南通飞拓界面工程科技有限公司 一种玻璃磨削液
CN103525533A (zh) * 2013-10-23 2014-01-22 东莞太平洋博高润滑油有限公司 一种全合成玻璃磨削液

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005113039A (ja) * 2003-10-09 2005-04-28 Kohjin Co Ltd 水性切削液、水性スラリー及びこれを用いる硬脆性難削材料の切断方法
CN102559354A (zh) * 2010-12-30 2012-07-11 安集微电子（上海）有限公司 一种水基玻璃磨削液
CN102690718A (zh) * 2011-03-22 2012-09-26 南通飞拓界面工程科技有限公司 一种玻璃磨削液
CN102240521A (zh) * 2011-04-25 2011-11-16 苏州大学 一种Bola型表面活性剂
CN103525533A (zh) * 2013-10-23 2014-01-22 东莞太平洋博高润滑油有限公司 一种全合成玻璃磨削液

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113527974A (zh) * 2021-07-14 2021-10-22 湖北敏捷志成标识科技有限公司 一种用于无机玻璃面板的光油及其制备方法
CN113527974B (zh) * 2021-07-14 2022-07-26 湖北敏捷志成标识科技有限公司 一种用于无机玻璃面板的光油及其制备方法
CN114644956A (zh) * 2022-04-29 2022-06-21 泰伦特生物工程股份有限公司 一种镝铁合金线切割液及其制备方法和使用方法
CN114644956B (zh) * 2022-04-29 2023-05-09 泰伦特生物工程股份有限公司 一种镝铁合金线切割液及其制备方法和使用方法

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