CN107010875A - A kind of high impact property artificial quartz stone plate and preparation method thereof - Google Patents
A kind of high impact property artificial quartz stone plate and preparation method thereof Download PDFInfo
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- CN107010875A CN107010875A CN201710358728.5A CN201710358728A CN107010875A CN 107010875 A CN107010875 A CN 107010875A CN 201710358728 A CN201710358728 A CN 201710358728A CN 107010875 A CN107010875 A CN 107010875A
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- resin
- high impact
- stone plate
- artificial quartz
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/18—Polyesters; Polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/06—Acrylates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/12—Condensation polymers of aldehydes or ketones
- C04B26/122—Phenol-formaldehyde condensation polymers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/14—Polyepoxides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/16—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00612—Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/34—Non-shrinking or non-cracking materials
- C04B2111/343—Crack resistant materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
- C04B2111/82—Coloured materials
Abstract
A kind of high impact property artificial quartz stone plate of the present invention, including the following raw material：0.075~5mm particulate materials, 0.005~0.045mm silica flours, colored pigment, silane coupler, curing agent, unsaturated polyester resin, soft unsaturated-resin, there is larger humidification to artificial quartz in lump product mechanical property, it has that shock resistance is good, bending strength is high, the advantages of not easy to crack, compactness is good.
Description
Technical field
The invention belongs to artificial quartz stone plate technical field, specifically, it is related to a kind of high impact property synthetic quartz
Stone slab and preparation method thereof.
Background technology
Artificial quartz in lump be by more than 90% natural quartz and 10% or so colorant, resin and other regulations bonding,
The additive composition of solidification etc..It is that, by negative-pressure vacuum, dither shaping, (temperature height is according to curing agent for heating cure
Species depending on the sheet material that processes of production method.Its quality is hard, there are compact structure other ornament materials can not compare
The characteristic such as the wear-resisting, pressure-resistant of plan, high temperature resistant, anticorrosive, impermeable.
Current quartz product is main in kitchen countertop, toilet table top, bar desk, tea table, ground and inner-outer wall head
Deng, due to its rich color, the advantages of product pattern enriches, can substitute lithotome, high-grade ceramic, timber, metal class dress
Exterior material.But artificial quartz in lump generally existing impact resistance is poor, frangibility, the defect in some physical properties of grade easy to crack,
It significantly limit the large-scale popularization and durability of quartz.
It is therefore desirable to carry out upgrading or technological transformation to existing production technology.
The content of the invention
Instant invention overcomes shortcoming of the prior art, there is provided a kind of high impact property artificial quartz stone plate and its system
Preparation Method, it has, and shock resistance is good, bending strength is high, the advantages of not easy to crack, compactness is good.
In order to solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions：
A kind of high impact property artificial quartz stone plate, it is characterised in that：Including major ingredient：0.075~5mm particulate materials,
0.005~0.045mm silica flours, unsaturated polyester resin, inserts：0.075~5mm particulate materials, 0.005~0.045mm
Silica flour, soft unsaturated-resin, it is other：Silane coupler, curing agent, colored pigment.
Further, according to percentage by weight, 0.075~5mm particulate materials 55%~65%, 0.005~0.045mm quartz
Powder 20%~30%；Unsaturated polyester resin 8%~14%；
Inserts：It is 0.005~0.045mm silica flours 2%~10%, 0.075~5mm particulate materials 10%~15%, soft
The soft unsaturated-resin 1%-3% of property unsaturated-resin.
It is other：Curing agent 0.8%~1.4%, colored pigment 0.01%~10%；Silane coupler 0.1%~1%；
Wherein, particulate material is quartz particles or glass particle, or two kinds of mixture.
Further, the colored pigment is the one or more of inorganic pigment or organic pigment or mill base.
Further, the inorganic pigment is titanium white, medium chrome yellow, iron oxide yellow, iron oxide red, barba hispanica, cadmium red, cadmium yellow, carbon black, iron oxide black etc.
Inorganic pigment.
Further, the organic pigment is the organic pigments such as pigment scarlet powder, azophosphine, dark green and phthalocyanine blue.Further, institute
It is the mill bases such as white slurry, black wash, bright red slurry, dark green slurry, phthalocyanine blue slurry to state mill base.
Further, the unsaturated polyester resin can also be epoxy resin, phenolic resin, acrylic resin and polyurethane
One or more in resin.
Further, the curing agent is peroxidating (2 ethyl hexanoic acid) tert-butyl ester, methyl ethyl ketone peroxide, perbenzoic acid
One or more in the tert-butyl ester, dibenzoyl peroxide and fat polyamine.
Further, the silane coupler is γ-methacryloxypropyl trimethoxy silane, γ-(2,3- epoxies
Third oxygen) propyl trimethoxy silicane, N- β (aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane, N- (β-aminoethyl)-γ-
Aminopropyl triethoxysilane, N- β (aminoethyl)-γ-aminopropyltrimethoxysilane, anilinomethyl triethoxysilane, γ-
Aminopropyl triethoxysilane, VTES, vinyltrimethoxy silane and γ-chloropropyl triethoxy silicon
One or more in alkane.
A kind of preparation method of high impact property artificial quartz stone plate, comprises the following steps：
(1) each component is weighed according to formula；
(2) stir：1. step (1) is weighed into major ingredient quartz particles, glass particle, silane coupler to stir in double planetary
It is pre-mixed in bucket；The curing agent mixed, decoration colored pigment and unsaturated polyester resin are poured into double planetary agitator
It is middle to be mixed, then add silica flour and mixed.15~55Hz of stirring frequency, 180~600s of mixing time；
2. inserts：Inserts quartz particles silane coupler is weighed by step (1) to premix in double planetary agitator
Close, the curing agent mixed, decoration colored pigment and soft unsaturated polyester resin are poured into and entered in double planetary agitator
Row mixing.15~55Hz of stirring frequency, 180~600s of mixing time；
(3) cloth：The major ingredient that step (2) is mixed is separately introduced different beaters from inserts and further broken up, and beats
After dissipating, major ingredient enters cloth in material distributing machine through electronic measurement, and tiling 1/2nd adds inserts tiling, adds major ingredient two
/ mono-, it is then sent through in making sheet mould, making sheet mould is sent into moulding press is molded under vacuum, vibration, pressurization；
(4) suppress：After cloth is completed, repressed vibration equipment is compressing under -0.1Mpa vacuum condition, pressure
50~200t, 30~55Hz of vibration frequency, 60~600s of time；
(5) heat cure：After vibration compacting, into curing apparatus, solidify at a temperature of 80~130 DEG C, hardening time
For 30~180 minutes；
(6) after the completion of solidifying, room temperature it is to be cooled completely after enter the fixed thickness of sheet material thicknessing machine, then set by water mill polishing
It is standby to be polished.
Compared with prior art, the beneficial effects of the invention are as follows：
A kind of high impact property artificial quartz stone plate of the present invention, has necessarily to artificial quartz in lump product mechanical property
Humidification, it has, and shock resistance is good, bending strength is high, the advantages of not easy to crack, compactness is good.
Embodiment
The preferred embodiments of the present invention are illustrated below, it will be appreciated that preferred embodiment described herein is only used
In the description and interpretation present invention, it is not intended to limit the present invention.
A kind of high impact property artificial quartz stone plate of the present invention, it is characterised in that：Including major ingredient：0.075~5mm
Particulate material 49.5%, 0.005~0.045mm silica flours 21.5%, unsaturated polyester resin 8.5%, inserts：0.075~
5mm particulate materials 12.5%, 0.005~0.045mm silica flours 5.5%, soft unsaturated-resin 2%, it is other：Silane coupler
0.1%th, curing agent 0.1%, colored pigment 0.3%.
Wherein, particulate material is quartz particles or glass particle, or two kinds of mixture.
Colored pigment is the one or more of organic pigment or mill base, and organic pigment is pigment scarlet powder, dark green and phthalocyanine blue,
Mill base is white slurry, black wash, bright red slurry, dark green slurry, phthalocyanine blue slurry.
Unsaturated polyester resin can also be one in epoxy resin, phenolic resin, acrylic resin and polyurethane resin
Plant or a variety of.
Curing agent is peroxidating (2 ethyl hexanoic acid) tert-butyl ester, methyl ethyl ketone peroxide, peroxidized t-butyl perbenzoate, peroxide
Change the one or more in dibenzoyl and fat polyamine.
Silane coupler is γ-methacryloxypropyl trimethoxy silane, γ-(2,3- the third oxygen of epoxy) propyl group three
Methoxy silane, N- β (aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane, the ethoxy of N- (β-aminoethyl)-γ-aminopropyl three
Base silane, N- β (aminoethyl)-γ-aminopropyltrimethoxysilane, anilinomethyl triethoxysilane, the ethoxy of γ-aminopropyl three
Base silane, VTES, vinyltrimethoxy silane and one kind in γ-chloropropyl triethoxysilane or
It is a variety of.
A kind of preparation method of high impact property artificial quartz stone plate, comprises the following steps：
(1) each component is weighed according to formula；
(2) stir：1. step (1) is weighed into major ingredient quartz particles, glass particle, silane coupler to stir in double planetary
It is pre-mixed in bucket；The curing agent mixed, decoration colored pigment and unsaturated polyester resin are poured into double planetary agitator
It is middle to be mixed, then add silica flour and mixed.15~55Hz of stirring frequency, 180~600s of mixing time；
2. inserts：Inserts quartz particles silane coupler is weighed by step (1) to premix in double planetary agitator
Close, the curing agent mixed, decoration colored pigment and soft unsaturated polyester resin are poured into and entered in double planetary agitator
Row mixing.15~55Hz of stirring frequency, 180~600s of mixing time；
(3) cloth：The major ingredient that step (2) is mixed is separately introduced different beaters from inserts and further broken up, and beats
After dissipating, major ingredient enters cloth in material distributing machine through electronic measurement, and tiling 1/2nd adds inserts tiling, adds major ingredient two
/ mono-, it is then sent through in making sheet mould, making sheet mould is sent into moulding press is molded under vacuum, vibration, pressurization；
(4) suppress：After cloth is completed, repressed vibration equipment is compressing under -0.1Mpa vacuum condition, pressure
50~200t, 30~55Hz of vibration frequency, 60~600s of time；
(5) heat cure：After vibration compacting, into curing apparatus, solidify at a temperature of 80~130 DEG C, hardening time
For 30~180 minutes；
(6) after the completion of solidifying, room temperature it is to be cooled completely after enter the fixed thickness of sheet material thicknessing machine, then set by water mill polishing
It is standby to be polished.
Finally it should be noted that：The preferred embodiments of the present invention are these are only, are not intended to limit the invention, although
The present invention is described in detail with reference to embodiment, for those skilled in the art, it still can be to foregoing
Technical scheme described in each embodiment is modified, or to which part technical characteristic carry out equivalent substitution, but it is all
Within the spirit and principles in the present invention, any modification, equivalent substitution and improvements made etc. should be included in the protection of the present invention
Within the scope of.
Claims (7)
1. a kind of high impact property artificial quartz stone plate, it is characterised in that：Including major ingredient：0.075~5mm particulate materials,
0.005~0.045mm silica flours, unsaturated polyester resin, inserts：0.075~5mm particulate materials, 0.005~0.045mm
Silica flour, soft unsaturated-resin, it is other：Silane coupler, curing agent, colored pigment.
2. a kind of high impact property artificial quartz stone plate according to claim 1, it is characterised in that：According to weight percent
Than major ingredient：0.075~5mm particulate materials 55%~65%, 0.005~0.045mm silica flours 20%~30%；Unsaturation is poly-
Ester resin 8%~14%；
Inserts：0.005~0.045mm silica flours 2%~10%, 0.075~5mm particulate materials 10%~15%, it is soft not
The soft unsaturated-resin 1%-3% of saturated resin,
It is other：Curing agent 0.8%~1.4%, colored pigment 0.01%~10%；Silane coupler 0.1%~1%；
Wherein, particulate material is quartz particles or glass particle, or two kinds of mixture.
3. a kind of high impact property artificial quartz stone plate according to claim 1, it is characterised in that：The colored pigment is
The one or more of inorganic pigment or organic pigment or mill base.
4. a kind of high impact property artificial quartz stone plate according to claim 1, it is characterised in that：The unsaturated polyester (UP)
Resin can also be the one or more in epoxy resin, phenolic resin, acrylic resin and polyurethane resin.
5. a kind of high impact property artificial quartz stone plate according to claim 1, it is characterised in that：The curing agent was
Aoxidize (2 ethyl hexanoic acid) tert-butyl ester, methyl ethyl ketone peroxide, peroxidized t-butyl perbenzoate, dibenzoyl peroxide and fat many
One or more in first amine.
6. a kind of high impact property artificial quartz stone plate according to claim 1, it is characterised in that：The silane coupler
For γ-methacryloxypropyl trimethoxy silane, γ-(2,3- the third oxygen of epoxy) propyl trimethoxy silicane, N- β (ammonia
Ethyl)-γ-aminopropyltriethoxy dimethoxysilane, N- (β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, N- β (ammonia second
Base)-γ-aminopropyltrimethoxysilane, anilinomethyl triethoxysilane, gamma-aminopropyl-triethoxy-silane, vinyl three
One or more in Ethoxysilane, vinyltrimethoxy silane and γ-chloropropyl triethoxysilane.
7. a kind of preparation method of high impact property artificial quartz stone plate, it is characterised in that：Comprise the following steps：
(1) each component is weighed according to formula；
(2) stir：1. step (1) is weighed into major ingredient quartz particles, glass particle, silane coupler in double planetary agitator
Premixing；The curing agent mixed, decoration colored pigment and unsaturated polyester resin are poured into and entered in double planetary agitator
Row mixing, then adds silica flour and is mixed, 15~55Hz of stirring frequency, 180~600s of mixing time；
2. inserts：Inserts quartz particles silane coupler is weighed by step (1) to be pre-mixed in double planetary agitator, will
Curing agent, decoration colored pigment and the soft unsaturated polyester resin mixed is poured into and mixed in double planetary agitator
Close.15~55Hz of stirring frequency, 180~600s of mixing time；
(3) cloth：The major ingredient that step (2) is mixed is separately introduced different beaters from inserts and further broken up, after breaing up,
Major ingredient enters cloth in material distributing machine through electronic measurement, and tiling 1/2nd adds inserts tiling, adds major ingredient 1/2nd
Tiling；
(4) suppress：After cloth is completed, repressed vibration equipment is compressing under -0.1Mpa vacuum condition, and pressure 50~
200t, 30~55Hz of vibration frequency, 60~600s of time；
(5) heat cure：After vibration compacting, into curing apparatus, solidify at a temperature of 80~130 DEG C, hardening time is 30
~180 minutes；
(6) after the completion of solidifying, the room temperature completely rear sheet material thicknessing machine that enters to be cooled determines thickness, then enters by water mill polissoir
Row polishing.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710358728.5A CN107010875A (en) | 2017-05-19 | 2017-05-19 | A kind of high impact property artificial quartz stone plate and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710358728.5A CN107010875A (en) | 2017-05-19 | 2017-05-19 | A kind of high impact property artificial quartz stone plate and preparation method thereof |
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| CN107010875A true CN107010875A (en) | 2017-08-04 |
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ID=59450214
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107805006A (en) * | 2017-11-17 | 2018-03-16 | 枣庄市博源人造石有限公司 | A kind of white glass artificial quartz stone plate of colorful and preparation method thereof |
| CN113492538A (en) * | 2020-03-22 | 2021-10-12 | 王佐亮 | Production and manufacturing process method of quartz stone checkered plate |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103408252A (en) * | 2013-07-29 | 2013-11-27 | 广东中旗新材料科技有限公司 | High-impact toughness man-made quartzite slab and preparation method thereof |
| CN105801003A (en) * | 2016-03-14 | 2016-07-27 | 广东中旗新材料科技有限公司 | Compound-color artificial quartz quartzite board having flowability and production process thereof |
-
2017
- 2017-05-19 CN CN201710358728.5A patent/CN107010875A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103408252A (en) * | 2013-07-29 | 2013-11-27 | 广东中旗新材料科技有限公司 | High-impact toughness man-made quartzite slab and preparation method thereof |
| CN105801003A (en) * | 2016-03-14 | 2016-07-27 | 广东中旗新材料科技有限公司 | Compound-color artificial quartz quartzite board having flowability and production process thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107805006A (en) * | 2017-11-17 | 2018-03-16 | 枣庄市博源人造石有限公司 | A kind of white glass artificial quartz stone plate of colorful and preparation method thereof |
| CN113492538A (en) * | 2020-03-22 | 2021-10-12 | 王佐亮 | Production and manufacturing process method of quartz stone checkered plate |
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| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: 528518 No. 112 Mingcheng Second Road, Gaoming District, Foshan City, Guangdong Province Applicant after: Guangdong Zhongqi New Materials Co., Ltd. Address before: 528518 No. 112 Mingcheng Second Road, Gaoming District, Foshan City, Guangdong Province Applicant before: Guangdong Banner New Material Technology Co., Ltd. |
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Application publication date: 20170804 |
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