CN103408252A - High-impact toughness man-made quartzite slab and preparation method thereof - Google Patents
High-impact toughness man-made quartzite slab and preparation method thereof Download PDFInfo
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- CN103408252A CN103408252A CN2013103232186A CN201310323218A CN103408252A CN 103408252 A CN103408252 A CN 103408252A CN 2013103232186 A CN2013103232186 A CN 2013103232186A CN 201310323218 A CN201310323218 A CN 201310323218A CN 103408252 A CN103408252 A CN 103408252A
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Abstract
The invention provides a high-impact toughness man-made quartzite slab and a preparation method thereof. The man-made quartzite slab comprises the following components in percentage by weight: 58-75 percent of particle raw materials, 15-33 percent of quartz powder, 0.01-10 percent of paint, 0.1-1 percent of coupling agent, 8-12 percent of adhesive and 0.8-2 percent of curing agent, wherein the particle raw materials are quartz particles, glass particles, or a mixture of the two. The man-made quartzite slab provided by the invention has the characteristics of low probability of cracking and deformation, and the like.
Description
Technical field
The present invention relates to artificial quartz stone plate and preparation method, be specifically related to a kind of artificial quartz stone plate with high impact toughness.
Background technology
Artificial quartz in lump belongs to the fragility polymer composite, and it has the extremely strong characteristic such as acidproof, corrosion-resistant, wear-resistant, high temperature resistant.The formula that prior art is manufactured artificial quartz in lump is mainly that quartzite, silica powder and resin collocation form after hardened forming.Because artificial quartz in lump also has the characteristic of expanding with heat and contract with cold simultaneously, exist the mechanical properties such as certain string stress, impelling strength, elongation at break, produce at present the formula of synthetic quartz and the artificial quartz in lump of technology manufacturing and also exist some defects, particularly impelling strength is not good, when material, bear the internal stress of bringing because expanding with heat and contract with cold, or during the external impact power be subject to, cracking, distortion easily appear in material.Therefore, be necessary to provide a kind of artificial quartz stone plate that has high impact toughness, is difficult for craze and transfiguration.
Summary of the invention
In order to make up the deficiencies in the prior art, the invention provides a kind of artificial quartz stone plate with high impact-resistant toughness, it has characteristics such as not being prone to cracking, distortion.
The technical solution adopted for the present invention to solve the technical problems is as follows:
First aspect present invention provides a kind of high impact toughness artificial quartz stone plate, and its formula comprises the each component of following mass content: particulate material 58～75%; Silica powder 15～33%; Pigment 0.01～10%; Coupling agent 0.1～1%; Tackiness agent 8～12%; Solidifying agent 0.8～2%; Wherein, described particulate material is quartz particles or glass particle, or the mixing of quartz particles and glass particle.
Preferably, the particle diameter of described silica powder is 0.005～0.18mm, and silica powder is one or both the combination in the silica powder of micropin shape or near-spherical structure.
Preferably, the particle diameter of described quartz particles is 0.18～10mm, and the particle diameter of described glass particle is 0.18～10mm.
Preferably, described tackiness agent is flexible unsaturated polyester resin, and flexible unsaturated polyester resin used does not contain promotor cobalt water.
Its solid content of described flexible unsaturated polyester resin >=65%, viscosity are 0.5～1Pas(25 ℃), acid number is 15～26mgKOH/g.
Further, described flexible unsaturated polyester resin also has following characteristic: the Barcol hardness of its virgin resin pour mass of flexible unsaturated polyester resin >=45 °, tension set>3.0%, flexural strength >=120Mpa, heat-drawn wire >=60 ℃, shock strength >=90Mpa.
Preferably, described coupling agent is silane coupling agent.By silane coupler modified quartz powder materials surface polarity, make material surface more fine and close carefully clean, can be distributed in resin material fully, equably, make the surface of filler that the resin parcel be arranged, the tight cross-linked network of filler is in a macromolecular mass the most at last, the organic-inorganic cross-linked structure of formation more firmly, more stable.
Described solidifying agent is one or more the combination in peroxidation (2 ethyl hexanoic acid) tert-butyl ester, methylethyl ketone peroxide, peroxidized t-butyl perbenzoate or fat polyamine.
Second aspect present invention also provides a kind of method for preparing high impact toughness artificial quartz stone plate as described above, comprise the steps: to take each component by formula, each component is fully mixed to rear injection mould extrusion molding, be cured afterwards, determine thick polishing.
Preferably, described curing its solidification value is 60～300 ℃, and be 30～50 minutes set time.
Concrete, artificial quartz stone plate of the present invention can be prepared in accordance with the following steps:
(1) according to formula, take each component;
(2) raw material step 1 taken is poured double-planet formula agitation vat into and is stirred, stirring frequency 45-55Hz, churning time 180-600s;
(3) material stirred is sent in charge car by distributing belt, then by charge car by material be evenly arranged cloth framed in;
(4) after cloth, repressed vibration equipment compression moulding under the vacuum condition of-0.1Mpa, pressure 50-100t, vibrational frequency 30-55Hz, time 180-600s.
(5) after the compacting, enter curing apparatus, solidify at the temperature of 60-300 ℃, be 30～50 minutes set time.
(6) after having solidified, normal temperature places that to be cooled fully laggard to enter the sheet material thicknessing machine fixed thick, then carries out polishing through 20 water mill polissoirs.
In the present invention, described pigment refers in the art the conventional painted various pigment of rostone, for example iron oxide black, titanium dioxide, iron oxide red, middle bloom etc. of can be used for.
Compared with prior art, the present invention has following beneficial effect:
(1) artificial quartz stone plate of the present invention has high impact-resistant toughness, the problems such as artificial quartz in lump cracking, distortion have been solved, product of the present invention, in test, with the 1kg solid steel ball, impacting specification from the height free-falling more than 200cm is the sheet material central authorities of 250mm*250mm*15mm, does not produce and breaks.
(2) formula of the present invention has rational Jiao Ji ratio and makes product be easier to moulding, not yielding, density is high, without bubble, larger to tolerance range and the deformation subject range of external force and internal stress, make quartzite slate have good impelling strength.
(3) select shrinking percentage is little, elongation at break is large flexible unsaturated polyester resin as sizing agent, adopt the silica powder of micropin shape, near-spherical structure as filler, utilize the theoretical model of continuous distribution of sizes particle packing to carry out the granulometric composition design, select rational granular size collocation, make each component assembled arrangement, thickness collocation regularly, make whole formula system density maximum, the hole minimum, not only can greatly reduce the consumption of resin, more environmental protection, the while can obtain the artificial quartz stone plate of high impact toughness.
(4) artificial quartz stone plate of the present invention not yielding, ftracture, bubble, fade, tarnish etc., have a production cost low, good decorating effect, indeformable, can prepare both artistic and practical quartzite table top.
Embodiment
Below by embodiment, technical scheme of the present invention is described further.
The embodiment I
A kind of high impact toughness artificial quartz stone plate, preparation in accordance with the following steps:
(1) according to the corresponding embodiment I of following table 1 formula, take each component, wherein, the particle diameter of quartz particles is 0.18～2mm, and the particle diameter of glass particle is 0.18～2mm; The silica powder particle diameter is 0.005～0.01mm, and silica powder is the mixing of the silica powder of micropin shape and near-spherical structure; Coupling agent is silane coupling agent; Tackiness agent is flexible unsaturated polyester resin, its solid content >=65%, viscosity 0.5～1Pas(25 ℃), acid number 15～26mgKOH/g, virgin resin pour mass Barcol hardness >=45 °, tension set>3.0%, flexural strength >=120Mpa, heat-drawn wire >=60 ℃, shock strength >=90Mpa.Solidifying agent is peroxidation (2 ethyl hexanoic acid) tert-butyl ester.
(2) raw material step 1 taken is poured double-planet formula agitation vat into and is stirred, stirring frequency 45-55Hz, churning time 180-190s.
(3) material stirred is sent in charge car by distributing belt, then by charge car by material be evenly arranged cloth framed in.
(4) after cloth, repressed vibration equipment compression moulding under the vacuum condition of-0.1Mpa, pressure 50-60t, vibrational frequency 30-35Hz, time 180-200s.
(5) after the compacting, enter curing apparatus, solidify at the temperature of 60-80 ℃, be 50 minutes set time.
(6) after having solidified, normal temperature places that to be cooled fully laggard to enter the sheet material thicknessing machine fixed thick, then carries out polishing through 20 water mill polissoirs.
The embodiment II
A kind of high impact toughness artificial quartz stone plate, preparation in accordance with the following steps:
(1) according to the corresponding embodiment II of following table 1 formula, take each component, wherein, the particle diameter of quartz particles is 3～6mm, and the particle diameter of glass particle is 3～6mm; Silica powder is that particle diameter 0.01～0.1mm and pattern are the silica powder of micropin shape; Coupling agent is silane coupling agent; Tackiness agent is flexible unsaturated polyester resin, its solid content >=65%, viscosity 0.5～1Pas(25 ℃), acid number 15～26mgKOH/g, virgin resin pour mass Barcol hardness >=45 °, tension set>3.0%, flexural strength >=120Mpa, heat-drawn wire >=60 ℃, shock strength >=90Mpa; Solidifying agent is methylethyl ketone peroxide.
(2) raw material step 1 taken is poured double-planet formula agitation vat into and is stirred, stirring frequency 50-55Hz, churning time 200-250s.
(3) material stirred is sent in charge car by distributing belt, then by charge car by material be evenly arranged cloth framed in.
(4) after cloth, repressed vibration equipment compression moulding under the vacuum condition of-0.1Mpa, pressure 60-70t, vibrational frequency 40-45Hz, time 250-300s.
(5) after the compacting, enter curing apparatus, solidify at the temperature of 150-160 ℃, be 35-40 minute set time.
(6) after having solidified, normal temperature places that to be cooled fully laggard to enter the sheet material thicknessing machine fixed thick, then carries out polishing through 20 water mill polissoirs.
The embodiment III
A kind of high impact toughness artificial quartz stone plate, preparation in accordance with the following steps:
(1) according to the corresponding embodiment III of following table 1 formula, take each component, wherein, the particle diameter of quartz particles is 5～10mm, and the particle diameter of glass particle is 5～10mm; Silica powder is that particle diameter 0.1～0.18mm and pattern are the silica powder of micropin shape and near-spherical structure; Coupling agent is silane coupling agent; Tackiness agent is flexible unsaturated polyester resin, its solid content >=65%, viscosity 0.5～1Pas(25 ℃), acid number 15～26mgKOH/g, virgin resin pour mass Barcol hardness >=45 °, tension set>3.0%, flexural strength >=120Mpa, heat-drawn wire >=60 ℃, shock strength >=90Mpa; Solidifying agent is peroxidized t-butyl perbenzoate.
(2) raw material step 1 taken is poured double-planet formula agitation vat into and is stirred, stirring frequency 50-55Hz, churning time 550-600s.
(3) material stirred is sent in charge car by distributing belt, then by charge car by material be evenly arranged cloth framed in.
(4) after cloth, repressed vibration equipment compression moulding under the vacuum condition of-0.1Mpa, pressure 90-100t, vibrational frequency 50-55Hz, time 550-600s.
(5) after the compacting, enter curing apparatus, solidify at the temperature of 280-300 ℃, be 30-35 minute set time.
(6) after having solidified, normal temperature places that to be cooled fully laggard to enter the sheet material thicknessing machine fixed thick, then carries out polishing through 20 water mill polissoirs.
The embodiment IV
According to the corresponding embodiment IV of following table 1 formula, take each component, all the other are identical with the embodiment I, do not repeat them here.
The embodiment V
According to the corresponding embodiment V of following table 1 formula, take each component, all the other are identical with the embodiment II, do not repeat them here.
The embodiment VI
According to the corresponding embodiment VI of following table 1 formula, take each component, all the other are identical with the embodiment III, do not repeat them here.
The embodiment VII
According to the corresponding embodiment VI of following table 1 formula, take each component, all the other are identical with the embodiment III, do not repeat them here.
The formula table (being mass percent) of table 1 embodiment I～VII
The artificial quartz stone plate that above-described embodiment I～VII is prepared, through test, all find: with the 1kg solid steel ball, impacting specification from the height free-falling more than 200cm is the sheet material central authorities of 250mm*250mm*15mm, does not produce and breaks.
The above, it is only preferred embodiment of the present invention, not the present invention is done to any pro forma restriction, the content that does not break away from technical solution of the present invention therefore all, according to technical spirit of the present invention, to any simple modification made for any of the above embodiments, equivalent variations and modification, all still belong in the scope of technical solution of the present invention.
Claims (10)
1. a high impact toughness artificial quartz stone plate, is characterized in that, its formula comprises the each component of following mass content: particulate material 58～75%, silica powder 15～33%, pigment 0.01～10%, coupling agent 0.1～1%, tackiness agent 8～12%, solidifying agent 0.8～2%; Wherein, described particulate material is selected from one or both in quartz particles and glass particle.
2. high impact toughness artificial quartz stone plate according to claim 1, is characterized in that, the particle diameter of described silica powder is 0.005～0.18mm, and silica powder is one or both the combination in the silica powder of micropin shape or near-spherical structure.
3. high impact toughness artificial quartz stone plate according to claim 1, is characterized in that, the particle diameter of described quartz particles is 0.18～10mm, and the particle diameter of described glass particle is 0.18～10mm.
4. high impact toughness artificial quartz stone plate according to claim 1, is characterized in that, described tackiness agent is flexible unsaturated polyester resin.
5. high impact toughness artificial quartz stone plate according to claim 4, is characterized in that, its solid content of described flexible unsaturated polyester resin >=65%, viscosity are 0.5～1Pas(25 ℃), acid number is 15～26mgKOH/g.
6. high impact toughness artificial quartz stone plate according to claim 5, it is characterized in that, described flexible unsaturated polyester resin also has following characteristic: the Barcol hardness of its virgin resin pour mass of flexible unsaturated polyester resin >=45 °, tension set>3.0%, flexural strength >=120Mpa, heat-drawn wire >=60 ℃, shock strength >=90Mpa.
7. according to the described high impact toughness artificial quartz stone plate of claim 1～6 any one, it is characterized in that, described coupling agent is silane coupling agent.
8. according to the described high impact toughness artificial quartz stone plate of claim 1～6 any one, it is characterized in that, described solidifying agent is one or more the combination in peroxidation (2 ethyl hexanoic acid) tert-butyl ester, methylethyl ketone peroxide, peroxidized t-butyl perbenzoate or fat polyamine.
9. method for preparing high impact toughness artificial quartz stone plate as described as claim 1～8 any one, it is characterized in that, comprise the steps: to take each component by formula, each component is fully mixed to rear injection mould extrusion molding, be cured afterwards, determine thick polishing.
10. method according to claim 9, is characterized in that, described curing its solidification value is 60～300 ℃, and be 30～50 minutes set time.
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| CN103601422A (en) * | 2013-12-06 | 2014-02-26 | 王晓云 | Production method of anti-radiation artificial quartz stone plate |
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