CN102139551B - Composite acryl artificial stone with natural coral pattern and manufacturing method thereof - Google Patents
Composite acryl artificial stone with natural coral pattern and manufacturing method thereof Download PDFInfo
- Publication number
- CN102139551B CN102139551B CN 201010620169 CN201010620169A CN102139551B CN 102139551 B CN102139551 B CN 102139551B CN 201010620169 CN201010620169 CN 201010620169 CN 201010620169 A CN201010620169 A CN 201010620169A CN 102139551 B CN102139551 B CN 102139551B
- Authority
- CN
- China
- Prior art keywords
- finished product
- raw material
- semi
- acryl
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Polymerisation Methods In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a composite acryl artificial stone with a natural coral pattern and a manufacturing method thereof. The manufacturing method comprises the following steps of: step one, preparing raw materials by the following weigh mixture ratio: (a) 100 parts of acrylic resin paste, (b) 10 to 30 parts of acryl, (c) 1 to 10 parts of pearly-lustre materials, (d) 1 to 60 parts of fire retardants (e), 1 to 10 parts of dispersing agents and (f) 0.2 to 10 parts of polymerization initiators; step two, stirring the raw materials so as to lead the raw materials to be fully and evenly mixed; step three, carrying out the vacuum extraction on the raw material evenly stirred so as to eliminate air bubbles in the raw materials; step four, pouring the raw materials which undergo the vacuum extraction treatment to a mould in which base materials are arranged, after polymerization reaction, solidifying the poured raw materials on the surfaces of the base materials so as to form the semi-finished product, and for the time being, forming a similar coral pattern toward the periphery in a diffuse way on the surface of the semi-finished product with a dispersing agent as the core; step five, carrying out the after-treatment on the semi-finished product so as to obtain the finished product; after the invention adopts the technical scheme, an acryl layer is formed on the base materials in a composite way and a modeling similar to the natural coral pattern is formed on the surface of the base material.
Description
Technical field:
The present invention relates to artificial stone product and preparation method thereof technical field, refer in particular to a kind of composite acryl artificial stone with natural coral pattern and preparation method thereof.
Background technology:
Artificial stone is a kind of novel composite, is to mix with filler, pigment with unsaturated polyester resin, adds a small amount of initator, makes through certain procedure.In manufacture process, be equipped with different colorants and can be made into and have artificial stone product beautiful in colour, if need good gloss, similar goods like natural marble, usually can add therein acrylic material.
Acrylic is the polymer that the methyl methacrylate monomer polymerization forms, and it is a kind of high molecular synthetic resin, is widely used in the industry-by-industry at present.With respect to other synthetic resin series products, acrylic has following advantage:
1, the high grade of transparency, light transmittance reaches 92%, and the good reputation of " plastic cement is quartzy " is arranged.
2, good weatherability can be applicable to outdoorly, and has good case hardness and gloss long service life concurrently, compares with other material product, and the life-span is long more than 3 years
3, good mechanical performance, and have good cracking resistance, processing plasticity is large, can be made into various needed shapes and product.
4, can make and be various colors.
5, good chemical resistance performance.
6, from heavy and light, than simple glass light half, it is little to the support load to be used for the building decoration field.
7, environmental protection, recovery rate is high, and easy to maintenance, easy to clean.
Because the excellent properties of acrylic product, it also is widely used in the artificial stone product.But there is shortcomings in present acrylic artificial stone, because the price of acrylic is more expensive, it is lower that content is made every effort to overcome in its Central Asia of many so-called acrylic artificial stones, usually fills by other acrylic resins, and properties of product are relatively poor.The another one aspect, present acrylic artificial stone on the market and the compatibility between the other materials are relatively poor, and this situation is particularly evident when making composite, and it is difficult to other materials compound.Moreover how the color in the acrylic artificial stone realizes by the pigment that adds at present, so just causes its color can't present the pattern of nature.
Summary of the invention:
Technical problem to be solved by this invention is exactly not enough in order to overcome in the present product, and a kind of composite acryl artificial stone with natural coral pattern is provided.
For solving the problems of the technologies described above, the present invention has adopted following technical scheme: it comprises: base material and be compound in acrylic layer on the substrate, and it is characterized in that: the raw material of this acrylic layer and weight proportion are:
(a), acrylic resin syrup is 100 parts;
(b), acryl 10-30 part;
(c), iridescent is 1 ~ 40 part;
(d), fire retardant 1-60 part;
(e), dispersant 1-10 part;
(f), polymerization initiator 0.2-10 part.
In the technique scheme, described acrylic resin syrup is the mixture after the copolymerization of esters of acrylic acid and methyl, ethyl propylene acid esters, unsaturated-resin monomer.
In the technique scheme, described iridescent is the powdery pearl powder, and its granularity is between the 200-1200 order.
In the technique scheme, described fire retardant is aluminium hydrate powder.
In the technique scheme, described polymerization initiator is radical initiator.
In the technique scheme, described dispersant is the inorganic dispersant that contains element silicon.
In the technique scheme, described acrylic is: methyl methacrylate monomer.
Another technical problem to be solved by this invention just is to provide a kind of preparation method with composite acryl artificial stone of natural coral pattern.
For solving the problems of the technologies described above, the present invention has adopted following technical scheme, and this preparation method comprises the steps: the first step, prepares raw material according to following weight proportion:
(a), acrylic resin syrup is 100 parts;
(b), acryl 10-30 part;
(c), iridescent is 1 ~ 40 part;
(d), fire retardant 1-60 part;
(e), dispersant 1-10 part;
(f), polymerization initiator 0.2-10 part;
Second step stirs above-mentioned raw materials, makes raw material fully mix;
The 3rd step vacuumized processing to the raw material after above-mentioned the stirring, to eliminate the bubble in the raw material;
The 4th step, the raw material that above-mentioned process is vacuumized processing is poured in the mould that is placed with base material, and through after the polymerisation, the raw material of casting solidifies in substrate surface, form semi-finished product, this moment surface of semi-finished take dispersant as core will to around disperse the pattern of a kind of similar coral of formation;
In the 5th step, semi-finished product are carried out post processing namely obtain finished product;
In the above-mentioned steps, described acrylic resin syrup is the mixture after the copolymerization of esters of acrylic acid and methyl, ethyl propylene acid esters, unsaturated-resin monomer; Described iridescent is the powdery pearl powder, and its granularity is between the 200-1200 order; Described fire retardant is aluminium hydrate powder; Described polymerization initiator is radical initiator; Described dispersant is the inorganic dispersant that contains element silicon; Described acrylic is: methyl methacrylate monomer.
Furthermore, in the technique scheme, in described the 5th step, the post processing that semi-finished product are carried out comprises: sanding processing and coated side oil.
After the present invention adopted technique scheme, it was compounded to form one deck Ya Like layer at base material, and this acrylic layer can form good compound with base material.Simultaneously, the moulding that the artificial stone surface forms similar natural coral pattern is made every effort to overcome in the compound Asia of the present invention's making.Apply the present invention in various decorations, decoration or the other field, it can promote the taste of made product, the consumption concept of compound present consumer's back to nature.
The specific embodiment:
Embodiment one
Present embodiment is preferred embodiment of the present invention.
At first, raw material is mixed according to following composition and weight proportion:
(a), acrylic resin 100kg;
(b), acryl 20kg;
(c), iridescent 20kg;
(d), fire retardant 10kg;
(e), dispersant 5kg;
(f), polymerization initiator 4kg;
Wherein, described acrylic resin syrup is the mixture after the copolymerization of esters of acrylic acid and methyl, ethyl propylene acid esters, unsaturated-resin monomer; Described acrylic is: methyl methacrylate monomer.
Iridescent is pearl powder, and its granularity is 200 orders.
Fire retardant is aluminium hydrate powder.
Polymerization initiator is radical initiator, specifically adopts the persulfate of mineral-type.
Dispersant is sodium metasilicate.
Above-mentioned raw materials is poured in the mixer, stirred, make raw material fully mix.Then the raw material after above-mentioned the stirring is vacuumized processing, eliminating the bubble in the raw material, as still residual in the raw material bubble arranged, can add an amount of defoamer, such as organosiloxane.Then, the raw material that above-mentioned process is vacuumized processing is poured in the mould that is placed with base material, obtains semi-finished product through solidifying after the polymerisation, and this raw material will be compounded to form the acrylic layer at substrate surface.At last, semi-finished product are carried out sanding processing and coated side oil, face oil can adopt UV face oil, applies once to get final product.
Form the moulding of similar natural coral pattern in the acrylic plate that adopts present embodiment to make.
Base material can adopt the general on the market artificial stone product of buying, such as artificial slabstone etc.
Add among the present invention " pure acrylic " material is arranged: methyl methacrylate monomer.Because methyl methacrylate monomer not only can form rigid polymer with the acrylic syrup polymerization, it also has the bonding effect of rubber like, thereby makes this acrylic layer form firm composite artificial stone with the complete combination of base material.
Embodiment two
According to making such as the method for embodiment one, difference is that its raw material proportioning is
At first, raw material is mixed according to following composition and weight proportion:
(a), acrylic resin 100kg;
(b), methyl methacrylate monomer 30kg;
(c), iridescent 30kg;
(d), aluminium hydrate powder 40kg;
(e), sodium metasilicate 8kg;
(f), persulfate 10kg;
Wherein, iridescent is pearl powder, and its granularity is 1000 orders.
Embodiment three
According to making such as the method for embodiment one, difference is that its raw material proportioning is
At first, raw material is mixed according to following composition and weight proportion:
(a), acrylic resin 100kg;
(b), methyl methacrylate monomer 10kg;
(c), iridescent 10kg;
(d), aluminium hydrate powder 15kg;
(e), sodium metasilicate 2kg;
(f), persulfate 3kg;
Certainly, the above only is example of the present invention, is not to limit the scope of the present invention, and all equivalences of doing according to the described structure of the present patent application claim, feature and principle change or modify, and all should be included in the present patent application claim.
Claims (2)
1. preparation method with composite acryl artificial stone of natural coral pattern, it is characterized in that: this preparation method comprises the steps:
The first step, prepare raw material according to following weight proportion:
(a), acrylic resin syrup is 100 parts;
(b), acryl 10-30 part;
(c), iridescent is 1 ~ 40 part;
(d), fire retardant 1-60 part;
(e), dispersant 1-10 part;
(f), polymerization initiator 0.2-10 part;
Second step stirs above-mentioned raw materials, makes raw material fully mix;
The 3rd step vacuumized processing to the raw material after above-mentioned the stirring, to eliminate the bubble in the raw material;
The 4th step, the raw material that above-mentioned process is vacuumized processing is poured in the mould that is placed with base material, and through after the polymerisation, the raw material of casting solidifies in substrate surface, form semi-finished product, this moment surface of semi-finished take dispersant as core will to around disperse the pattern of a kind of similar coral of formation;
In the 5th step, semi-finished product are carried out post processing namely obtain finished product;
In the above-mentioned steps, described acrylic resin syrup is the mixture after the copolymerization of esters of acrylic acid and methyl, ethyl propylene acid esters, unsaturated-resin monomer; Described iridescent is the powdery pearl powder, and its granularity is between the 200-1200 order; Described fire retardant is aluminium hydrate powder; Described polymerization initiator is radical initiator; Described dispersant is the inorganic dispersant that contains element silicon; Described acrylic is: methyl methacrylate monomer.
2. the preparation method with composite acryl artificial stone of natural coral pattern according to claim 1 is characterized in that: in described the 5th step, the post processing that semi-finished product are carried out comprises: sanding processing and coated side oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010620169 CN102139551B (en) | 2010-12-31 | 2010-12-31 | Composite acryl artificial stone with natural coral pattern and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010620169 CN102139551B (en) | 2010-12-31 | 2010-12-31 | Composite acryl artificial stone with natural coral pattern and manufacturing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102139551A CN102139551A (en) | 2011-08-03 |
| CN102139551B true CN102139551B (en) | 2013-02-13 |
Family
ID=44407455
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010620169 Expired - Fee Related CN102139551B (en) | 2010-12-31 | 2010-12-31 | Composite acryl artificial stone with natural coral pattern and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102139551B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111847987A (en) * | 2020-08-04 | 2020-10-30 | 广东原创新材料科技有限公司 | Whole-body pearl artificial stone and preparation method thereof |
| CN112321196A (en) * | 2020-10-22 | 2021-02-05 | 浙江摩尔舒卫生设备股份有限公司 | Artificial stone material for manufacturing counter basin and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000327389A (en) * | 1999-05-19 | 2000-11-28 | Mitsubishi Rayon Co Ltd | Composition for artificial marble and artificial marble |
| CN101184706A (en) * | 2005-05-30 | 2008-05-21 | 第一毛织株式会社 | Composition for artificial stone, an article including the same, and a method of forming the same |
| CN101570413A (en) * | 2008-12-30 | 2009-11-04 | 上海新天和树脂有限公司 | Acrylic artificial stone and method for preparing same |
-
2010
- 2010-12-31 CN CN 201010620169 patent/CN102139551B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000327389A (en) * | 1999-05-19 | 2000-11-28 | Mitsubishi Rayon Co Ltd | Composition for artificial marble and artificial marble |
| CN101184706A (en) * | 2005-05-30 | 2008-05-21 | 第一毛织株式会社 | Composition for artificial stone, an article including the same, and a method of forming the same |
| CN101570413A (en) * | 2008-12-30 | 2009-11-04 | 上海新天和树脂有限公司 | Acrylic artificial stone and method for preparing same |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102139551A (en) | 2011-08-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US9012532B2 (en) | Acrylic artificial marble having granite pattern and method of manufacturing the same | |
| EP2578552B1 (en) | Preparation method of artificial marble | |
| EP2388241A2 (en) | Artificial chip having texture of natural granite and artificial marble including same | |
| JP2008524020A (en) | Artificial marble having crack pattern and manufacturing method thereof | |
| EP2791075B1 (en) | Method of manufacturing a synthetic marble with high hardness | |
| CN103189327B (en) | There is acrylic acid synthesizing marble containing pearly-lustre pattern and preparation method thereof | |
| EP2336241B1 (en) | Resin syrup, artificial marble containing a hardened form of the resin syrup, and a production method for the same | |
| CN105504627B (en) | Raw material and its manufacture method for preparing three-dimensional pattern pearly-lustre decorative panel | |
| CN101500960A (en) | Marble chip, method for preparing the same and artificial marble using the same | |
| CN101323673A (en) | Chemical resistance table slab rubber, preparation and use thereof | |
| AU2006346574A1 (en) | Marble chip, method for preparing the same and artificial marble using the same | |
| CN105315595B (en) | A kind of recovery method of waste plastics | |
| CN102139551B (en) | Composite acryl artificial stone with natural coral pattern and manufacturing method thereof | |
| KR20130052162A (en) | Artificial marble with random shape pattern and method for preparing the same | |
| KR101141023B1 (en) | Marble chip with marbling pattern and synthetic marble using same, and method of preparing the artificial marble | |
| WO2012008689A2 (en) | Artificial marble including plate-shaped chips of waste glass, and method for fabricating same | |
| CN102040796B (en) | Acrylic plate with natural coral patterns and method for producing same | |
| CN109096738B (en) | Resin type artificial stone and preparation method thereof | |
| CN100500606C (en) | Synthesized mirror granite and its preparation | |
| CN102732072A (en) | Preparation method and product of high-adhesion polishing-free PE (Poly Ethylene) top-coat | |
| RU2734197C1 (en) | Method of producing epoxy translucent artificial stone imitating onyx | |
| CN102040349A (en) | Artificial quartz stone and preparation method thereof | |
| CN105271932B (en) | The production method of synthetic quartz jade | |
| CN1616563A (en) | Natural color sand paint and its producing method | |
| JPH01257153A (en) | Artificial granite and production thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130213 Termination date: 20131231 |