CN106999418A - Include the composition of hydrocarbon ils, aromatics silicone oil, wax and paste fat matter - Google Patents
Include the composition of hydrocarbon ils, aromatics silicone oil, wax and paste fat matter Download PDFInfo
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- CN106999418A CN106999418A CN201580065329.9A CN201580065329A CN106999418A CN 106999418 A CN106999418 A CN 106999418A CN 201580065329 A CN201580065329 A CN 201580065329A CN 106999418 A CN106999418 A CN 106999418A
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- aromatics
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- YIEIMGAENVRDAJ-UHFFFAOYSA-N C[Si+](c1ccccc1)(c1ccccc1)O[Si+](C)(c1ccccc1)O[Si+](C)(c1ccccc1)c1ccccc1 Chemical compound C[Si+](c1ccccc1)(c1ccccc1)O[Si+](C)(c1ccccc1)O[Si+](C)(c1ccccc1)c1ccccc1 YIEIMGAENVRDAJ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/001—Preparations for care of the lips
Abstract
The present invention relates to a kind of composition, it is included：(a) at least one hydrocarbon ils, (b) at least one aromatics silicone oil, (c) at least one wax, at least one paste fat matter (d), wherein (d) paste fat matter includes the ester of the dimer of aliphatic acid and branched chain polyol or polyalcohol, wherein the only a part hydroxyl of the dimer of the polyalcohol or polyalcohol is esterified with the aliphatic acid.
Description
Technical field
The present invention relates to a kind of composition, relate more particularly to the cosmetic for cosmetic and/or nursing skin and/or lip
Product solid composite, it includes hydrocarbon ils, aromatics silicone oil, wax and the paste fat matter of certain content.
The invention further relates to the purposes that this composition is used for cosmetic and/or nursing skin and/or lip.
Background technology
In general, when women uses cosmetic product, especially lip product such as lipstick or during lip gloss, they wish
The product is difficult transfer upon application, and the deposit of product is glossiness.
So far, delivered some be related to for make up and/or nursing skin and/or lip cosmetics solid compositions
The prior art literature of thing.
WO 2013/191300 disclose it is a kind of be used for make up and/or nursing skin and/or lip Solic cosmetic group
Compound, it includes at least one fatty phase in physiologically acceptable medium, and the fat is mutually included：
- relative to the gross weight of the composition, 5 weight % to 30 weight % non-volatile hydrocarbonylation non-polar oil or its
Mixture,
- relative to the gross weight of the composition, total content is 43 weight % to 90 weight % non-volatile silicone oil, its
At least one of the non-volatile silicone oil be non-volatile phenylating silicone oil, and
- relative to the gross weight of the composition, 3 weight % to 30 weight % wax or its mixture.
WO 2012/165130 discloses a kind of cosmetics for lip, it is characterised in that include：(a) 5 mass % are extremely
30 mass % Parleam；(b) 30 mass % to 70 mass % one or more of Methylphenylsilanones, its with
(a) separated when being mixed at 25 DEG C；(c) 0.5 mass % to 15 mass % oil content, its：When being mixed with (a) and；With (b)
Separated when being mixed at 25 DEG C；4 mass %s to 12 mass %s wax (d).
JP-A-2012-82188 discloses a kind of Solic cosmetic for lip, and it adheres to oil comprising (a)
(adhesion oil)；(b) oil seepage (exudation oil), the viscosity that oil is adhered to described in its ratio of viscosities is low；Wax (c), when
When at least being mixed with oil seepage, it disperses and solidified at 25 DEG C at 90 DEG C, and when the mixing (a) at 25 DEG C and (b) when institute
The Solic cosmetic separation for lip is stated, and is characterised by that (a) adhesion oil is scattered in (b) oil seepage or (b) oil seepage
It is distributed in (a) adhesion oil.
But, the need for still suffering to obtaining the cosmetic product for skin and/or lip, the cosmetics, which are provided, to be had
Resistance to color transfer well and the deposit for effectively showing gloss.
The content of the invention
It is an object of the present invention to provide the composition for cosmetic and/or nursing skin and/or lip, it produces tool
There is good resistance to color transfer and effectively show the deposit of gloss.
It is another object of the present invention to the purposes that this composition is used for cosmetic and/or nursing skin and/or lip.
It can be provided with good according to the composition of the present invention present inventor has performed the research of effort and being surprised to find
Resistance to metastatic glossiness deposit.
Therefore, object above of the invention can realize that the composition is included by a kind of composition：
- (a) at least one hydrocarbon ils,
- (b) at least one aromatics silicone oil,
- (c) at least one waxes, and
- (d) at least one paste fat matters,
Wherein (d) paste fat matter includes the ester of the dimer of aliphatic acid and branched chain polyol or polyalcohol, wherein institute
The only a part hydroxyl for stating the dimer of polyalcohol or polyalcohol is esterified with the aliphatic acid.
Preferably, the aliphatic acid includes the aliphatic acid of two or more types.
Preferably, the aliphatic acid further includes branched chain fatty acid and/or hydroxy fatty acid.
In one embodiment, the polyalcohol has 3 to 12 hydroxyls, preferably 4 to 10 hydroxyls, and more preferably 5
To 8 hydroxyls.
It is preferred that (a) hydrocarbon oil contains nonpolar hydrocarbon ils, preferably non-volatile nonpolar hydrocarbon ils, and more preferably hydrogenate poly- isobutyl
Alkene.
In a preferred embodiment, (b) aromatics silicone oil includes non-volatile aromatic silicone oil, preferably trimethyl pentaphene
Base trisiloxanes.
Relative to the gross weight of the composition, 5 weight % to 30 weight %, preferably 5 weight % to 25 weights can be included
%, more preferably 8 weight % is measured to (a) hydrocarbon ils of 25 weight % amount.
Relative to the gross weight of the composition, 43 weight % to 90 weight %, preferably 45 weight % to 70 weights can be included
%, more preferably 50 weight % is measured to (b) aromatics silicone oil of 70 weight % amount.
Relative to the gross weight of the composition, 3 weight % to 30 weight %, preferably 4 weight % to 20 weights can be included
%, more preferably 5 weight % is measured to (c) wax of 10 weight % amount.
Relative to the gross weight of the composition, 0.5 weight % to 20 weight %, preferably 1 weight % to 18 weights can be included
%, more preferably 5 weight % is measured to (d) paste fat matter of 15 weight % amount.
Preferably, it is solid according to the composition of the present invention.
Preferably, it is the cosmetic combinations for cosmetic and/or nursing skin and/or lip according to the composition of the present invention
Thing.
Be used to make up the invention further relates to the composition and/or nursing skin and/or lip purposes, including to skin
And/or lip applies the composition.
Preferred embodiment of the present invention
Included according to the composition of the present invention：
- (a) at least one hydrocarbon ils,
- (b) at least one aromatics silicone oil,
- (c) at least one waxes, and
- (d) at least one paste fat matters,
Wherein (d) paste fat matter includes the ester of the dimer of aliphatic acid and branched chain polyol or polyalcohol, wherein institute
The only a part hydroxyl for stating the dimer of polyalcohol or polyalcohol is esterified with the aliphatic acid.
The deposit of gloss can be produced with improved resistance to color transfer and effectively shown according to the composition of the present invention.
Hereinafter, the composition according to the present invention will be explained in more detailed manner.
[composition]
Can be the form of solid composite according to the composition of the present invention.In addition, the composition can be used for cosmetic skin
And/or lip, particularly for skin of face or body skin；It can be colour of skin product, such as foundation cream, face powder or eye shadow；Lip
Portion's product, such as lipstick or lip care product；Hide flaw product；Rouge；Informer；Liner or eyeliner；Body cosmetic product.
According to a favourable embodiment of the invention, the composition be intended for cosmetic lip and its more particularly
Lipstick (lipstick stick).
According to the present invention under consideration and be solid shape at 20 DEG C for the composition in the method according to the invention
Formula.
For purposes of the present invention, term " solid " characterizes state of the composition at a temperature of 20 DEG C.Especially, according to
The solid composite of the present invention has at 20 DEG C of temperature and atmospheric pressure (760mmHg) is more than 30Nm-1And preferably greater than 40Nm-1Hardness.
Determine the scheme of hardness：
The hardness of the composition especially composition of lipstick stick type is determined according to following scheme.
Lipstick stick is stored 24 hours at 20 DEG C, hardness is determined afterwards.
Hardness can be at 20 DEG C via " cheese silk (cheese wire) " method measure, and methods described is by a diameter of
250 μm of rigid tungsten filament, by moving the silk with 100mm/min speed come transverse cuts rod (its relative to product rod
Preferably cylinder).
The hardness of the composition sample of the present invention is (with Nm-1Represent) using from Indelco-Chatillon companies
DFGS2 tensile testing machines are determined.
Replication 3 times is simultaneously then averaged.The average value for three values that use above tensile testing machine is read (is designated as
Y) provided with gram.The average value is changed into newton and subsequent divided by L, L represent the longest distance that this thread passes through.In cylindrical bar
In the case of, L is equal to diameter (in meters).
Hardness is changed into by Nm by below equation-1：
(Y×10-3×9.8)/L
For measure at different temperatures, rod is stored 24 hours at the new temperature, is measured afterwards.
As previously noted, according to the assay method, had according to the solid composite of the present invention at 20 DEG C and be more than
Or equal to 30Nm-1, preferably greater than 40Nm-1Hardness.
Preferably, especially had at 20 DEG C according to the composition of the present invention and be less than 500Nm-1, especially less than 400Nm-1And
Preferably smaller than 300Nm-1Hardness.
Preferably, especially had according to the composition of the present invention at 20 DEG C between 40Nm-1And 200Nm-1Between hardness
Value.
Preferably, the hardness is between 45Nm-1And 100Nm-1Between.
Advantageously, the composition according to the present invention under consideration is oily bag oil type composition.In the oil bag oil of the present invention
In type of composition, (b) aromatics silicone oil and (a) hydrocarbon ils are before application in stable oily bag oil condition, without dividing each other
From (macroscopic view for not having (a) and (b) compound is separated).Upon application, (b) aromatics silicone oil reaches the surface of deposit,
And the aromatics silicone oil of the separation covers the adhesion coating of hydrocarbon ils.Therefore, resulting composition has good resistance to metastatic (particularly
Resistance to color transfer).
Except good resistance to metastatic, present inventor is surprised to find and can effectively carried according to the composition of the present invention
For deposit with significant gloss, and complete the present invention.
Preferably, the oily bag oil condition of the present composition is not (b) aromatics silicone oil bag (a) hydrocarbon ils state.
Preferably, the oily bag oil condition of the present composition is (a) hydrocarbon oil (b) aromatics silicone oil state.
(a) hydrocarbon ils
(a) at least one hydrocarbon ils is included according to the composition of the present invention.It can be combined and use two or more type hydrocarbon ils.
More specifically, relative to the gross weight of composition, 5% to 30% gross weight is included according to the composition of the present invention
Hydrocarbon ils.Preferably, relative to the gross weight of composition, the composition includes 5 weight % to 25 weight %, more preferably 8 weights
Measure % to 25 weight % hydrocarbon ils.
Term " oil " used herein represents not mix for the water of liquid under room temperature (25 DEG C) and atmospheric pressure (760mmHg)
Dissolubility nonaqueous compound.
Term " hydrocarbon ils " used herein (also referred to as " oil based on hydrocarbon " or " alkymer ") represent substantially by carbon and
Hydrogen atom, and optional oxygen and nitrogen-atoms are formed or even by the oil of above-mentioned atomic building.It can include alcohol, ester, ether, carboxylic
Acid, amine and/or amide group.
Preferably, the hydrocarbon ils is nonvolatile oil.Term " nonvolatile oil " represents steaming at room temperature and atmospheric pressure
Vapour pressure is non-zero and is less than 0.02mmHg (2.66Pa) and preferably also less than 10-3MmHg (0.13Pa) oil.
Preferably, the hydrocarbon ils is non-polar oil.Terms used herein " non-polar oil " represents the solubility at 25 DEG C
Parameter δ a are equal to 0 (J/cm3)1/2Oil.In the three-dimensional solubility space (Hansenthree-dimensional of Hansen
Solubilityspace paper of the definition and calculating of the solubility parameter in) in C.M.Hansen：”Thethree-
Dimensional solubility parameters ", J.Paint Technol., described in 39,105 (1967).
(a) hydrocarbon ils can be plant, mineral or synthesis source.Preferably, (a) hydrocarbon ils may be selected from mineral or synthesis source
Straight or branched, saturation or unsaturated hydrocarbons.Preferably, (a) hydrocarbon ils contains more than 16 carbon atoms.
Especially, (a) hydrocarbon ils may be selected from：
- atoleine or derivatives thereof,
- saualane,
- Isoeicosane,
- naphtalene oil,
- polybutene, Indopol H-100 (molal weight or the MW=965g/ for for example being sold or being manufactured by Amoco companies
Mol), Indopol H-300 (MW=1340g/mol) and Indopol H-1500 (MW=2160g/mol),
- polyisobutene,
- Parleam, for example, sold by Nippon Oil Fats companiesSold by Amoco companies
Or Panalane H-300E (MW=1340g/mol), the Viseal 20000 that is sold or manufactured by Synteal companies of manufacture
(MW=6000g/mol) the Rewopal PIB 1000 (MW=1000g/mol) for and by Witco companies selling or manufacturing, or
The Parleam Lite sold for the election by NOF Corporation,
- decene/butylene copolymer, polybutene/polyisobutene co-polymer, especially Indopol L-14,
- poly decene and Nexbase 2004, the Puresyn 10 for for example being sold by Mobil Chemicals companies or being manufactured
(MW=723g/mol) and Puresyn 150 (MW=9200g/mol), or for the election by ExxonMobil Chemical sell
The Puresyn 6 sold, and
- its mixture.
Preferably, (a) hydrocarbon ils be selected from polybutene, polyisobutene, Parleam, poly decene and Nexbase 2004 and its
Mixture.It is highly preferred that (a) hydrocarbon ils is Parleam.
(b) aromatics silicone oil
(b) at least one aromatics silicone oil is included according to the composition of the present invention.It can be combined and use two or more types
Aromatics silicone oil.
Specifically, relative to the gross weight of composition, 43 weight % to 90 weight % are included according to the composition of the present invention
Aromatics silicone oil, be preferably between 45 weight % and 70 weight %, be more preferably between 50 weight % and 70 weight %
Aromatics silicone oil.
Statement " aromatics silicone oil " (also referred to as " phenyl silicone oil " or " phenylating silicone oil ") used herein represents have
The silicone oil of at least one phenyl substituent.
Preferably, the aromatics silicone oil is nonvolatile oil.
In addition, the aromatics silicone is preferably selected from the compound incompatible with (a).
Compatibility test
For purposes of the present invention, to represent that both oily mixing will not be produced uniform single-phase for term " incompatible oil "
Solution.Described each oil for being used in mixed way identical weight is carried out.
More particularly, when causing to be separated by oil mixing according to following scheme, the oil is referred to as " incompatible ".
It is less than for viscosity at 25 DEG C for 10,000cPs (10Pa.s) oil, at room temperature by two kinds of oil to be assessed
Introduce the plastic centrifuge tube (ref. of the conical points (with the weight ratio needed for composition)15mL PET centrifuge tubes, use post
The support (Rack Packed with Plug Seal Cap) that plug closure is tightened, will in sterile (Product#430055)
The centrifuge tube is placed in the machines of Vortex Genie 2.It is stirred with speed 10, continues 10 seconds, the subsequent manual overturning pipe,
It is placed back into afterwards in Vortex machines.The circulation is continuously repeated 3 times.Then mixture is set to place at room temperature 48 hours.
If at least one oil has the viscosity more than or equal to 10,000cPs (10Pa.s) at 25 DEG C, then by two kinds of oil
The mixture of (5g/5g) is placed in the baking oven at 50 DEG C, continues 30 minutes, and three foregoing agitation cycles are carried out afterwards.
Then observe mixture.
When the separation profile that mixture is divided into two-phase and two-phase is clearly limited to interface, the phase be referred to as " point
From " and therefore the oil be incompatible.
In the con-trary case, mixture is observed under room temperature (about 25 DEG C) using phase contrast microscope.If it was observed that continuous phase
With the dispersed phase of drops, the phase is referred to as " separation " and the oil is considered as incompatible.
If the observation of mixture only shows single-phase, the phase is referred to as " non-separation " and the oil is considered as
Compatible.
It is preferred that the composition includes at least one (b) aromatics silicone, it is incompatible with (a).
(b) aromatics silicone oil may be selected from：
A) the aromatics silicone oil of lower formula (I) is corresponded to：
Wherein R group represents methyl or phenyl independently of one another, and condition is that at least one R group represents phenyl.Preferably,
In the formula, the aromatics silicone oil includes at least three phenyl, for example, at least 4, at least five or at least six phenyl.
B) the aromatics silicone oil of lower formula (II) is corresponded to：
Wherein R group represents methyl or phenyl independently of one another, and condition is that at least one R group represents phenyl.Preferably,
In the formula, the aromatics silicone oil includes at least three phenyl, for example, at least 4 or at least five phenyl.
C) the aromatics silicone oil of lower formula (III) is corresponded to：
Wherein Me represents methyl, and y is between 1 and 1,000 and X representatives-CH2-CH(CH3)(Ph)。
D) the aromatics silicone oil of lower formula (IV) is corresponded to：
Wherein Me is methyl and Ph is phenyl, and OR' represents group-OSiMe3And y be 0 or between 1 and 1000 in the range of,
And z between 1 and 1000 in the range of.Especially, y and z cause compound (IV) to be nonvolatile oil.
According to the first embodiment, y between 1 and 1000 in the range of.It can be used, such as trimethylsiloxyphenyl
Dimethyl silicone polymer, it is especially sold by what Wacker companies sold with referring to Belsil PDM 1000.
According to the second embodiment, y is equal to 0.It can be used, such as phenyl trimethicone siloxy trisiloxanes, its is outstanding
It is with reference to Dow Corning 556Cosmetic Grade Fluid (DC556) sale.
E) the aromatics silicone oil of lower formula (V), and its mixture are corresponded to：
Wherein：
-R1To R10Be independently of one another saturation or undersaturated, straight chain, ring-type or side chain based on C1-C30The group of hydrocarbon,
- m, n, p and q are independently of one another the integer between 0 and 900, and condition is that m+n+q sums are not 0.
Preferably, m+n+q sums are between 1 and 100.Preferably, m+n+p+q sums are between 1 and 900 and also more
Well between 1 and 800.Preferably, q is equal to 0.
Preferably, R1To R10Saturation or undersaturated straight or branched C are represented independently of one another1-C30Alkyl, preferably saturation
, and it is based especially on C1-C12The group of hydrocarbon, particularly C3-C16And more particularly C4-C10, monocyclic or polycyclic C6-C14And it is outstanding
It is C10-C13Aryl, or aralkyl.Preferably, R1To R10Methyl, ethyl, propyl group, butyl, isopropyl, the last of the ten Heavenly stems can each be represented
Base, dodecyl or octadecyl, or be phenyl, tolyl, benzyl or phenethyl for the election.R1To R10Can be in particular identical
, and can be methyl in addition.
F) the aromatics silicone oil and its mixture of lower formula (VI) are corresponded to：
Wherein：
-R1To R6Be independently of one another saturation or undersaturated, straight chain, ring-type or side chain based on C1-C30The group of hydrocarbon,
It is preferred that R1To R6For C1-C30Alkyl, aryl or aralkyl
- m, n and p are independently of one another the integer between 0 and 100, and condition is n+m sums between 1 and 100.
Preferably, R1To R6Saturation or undersaturated straight or branched C are represented independently of one another1-C30Alkyl, preferably saturation
, and it is based especially on C1-C12The group of hydrocarbon, particularly C3-C16And more particularly C4-C10, monocyclic or polycyclic C6-C14And it is outstanding
It is C10-C13Aryl, or aralkyl.Preferably, R1To R6Methyl, ethyl, propyl group, butyl, isopropyl, the last of the ten Heavenly stems can each be represented
Base, dodecyl or octadecyl, or be phenyl, tolyl, benzyl or phenethyl for the election.
R1To R6Can in particular identical, and can be methyl in addition.Preferably, m=1 or 2 or 3, and/or n=0 and/or
P=0 or 1 is applicable to formula (VI).
G) the aromatics silicone oil and its mixture of lower formula (VII) are corresponded to：
Wherein：
R1、R2、R5And R6It is together or individually the alkyl containing 1 to 6 carbon atom,
R3And R4It is together or individually the alkyl containing 1 to 6 carbon atom, or aryl, condition is R3And R4In at least
One is phenyl,
X is the alkyl containing 1 to 6 carbon atom, hydroxyl or vinyl,
N and p is that equal to 1 or bigger integer, it is selected to obtain weight average molecular weight less than 200,000g/mol, excellent
Choosing is less than 150,000g/mol and more preferably less than 100,000g/mol oil.
As preferred aromatics silicone oil, the example that can be mentioned that includes silicone oil, for example：
- phenyl silicone oil, is preferably selected from：Tetramethyl tetraphenyl trisiloxanes (such as PH- from Dow Corning
1554HRI or Dow Corning 554Cosmetic Fluid), trimethylsiloxyphenyl dimethyl silicone polymer (example
Belsil PDM 1000 (referring to upper formula (IV)) such as from Wacker companies), phenyl trimethicone is (such as by Dow
The phenyl trimethicone that Corning is sold with trade name DC556), phenyl dimethicones, phenyl trimethicone first
Silane epoxide diphenyl siloxane, diphenyl dimethicone (such as KF-54 (400cSt) from Shin Etsu, come
KF54HV (5000cSt) from Shin Etsu, the KF-50-300CS (300cSt) from Shin Etsu, from Shin Etsu
KF-53 (175cSt), the KF-50-100CS (100cSt) from Shin Etsu), diphenyl methyl diphenyl trisiloxanes,
2- phenylethyls trimethylsiloxysilicate, trimethyl pentaphenyltrisiloxane are (such as by Dow Corning with title
Dow Corning PH-1555HRI Cosmetic fluid sale product), the poly- trimethyl of diphenyl silicon phenyl
Siloxanes (such as the KF56A from Shin Etsu), and
- its mixture.
The aromatics silicone is more preferably selected from：
- phenyl trimethicone,
The poly- trimethicone of-diphenyl silicon phenyl,
- diphenyl silicon phenyl dimethyl silicone polymer,
- trimethyl pentaphenyltrisiloxane,
- phenyl dimethicones,
- phenyl trimethicone siloxy diphenyl siloxane,
- diphenyl dimethicone,
- diphenyl methyl diphenyl trisiloxanes, and
- 2- phenylethyl trimethylsiloxysilicates, and
- its mixture.
Preferably, according to the weight average molecular weight of the aromatics silicone oil of the present invention in the range of 500 to 10,000g/mol.
On the one hand, (b) aromatics silicone oil is selected from one or more of aromatics silicone oil for being free of polydimethylsiloxane moieties,
Or one or more of aromatics silicone oil and one or more without polydimethylsiloxane moieties gather with least one
The mixture of the aromatics silicone oil of dimethylsiloxane portion.
If the composition is comprising the aromatics silicone oil without polydimethylsiloxane moieties and with dimethyl silicone polymer
The mixture of partial aromatics silicone oil, then the aromatics silicone oil without polydimethylsiloxane moieties with least one poly- two
The weight ratio of the aromatics silicone oil of methylsiloxane part can be 1:1 to 10:1st, preferably 2:1 to 7:1 and more preferably 3:1 to 5:1.
Most preferably, (b) aromatics silicone oil is the trimethyl pentaphenyltrisiloxane represented by lower formula (VIII)：
Wherein Me represents methyl and Ph represents phenyl.
Trimethyl pentaphenyltrisiloxane is for example by Dow Corning with reference to PH-1555HRI or Dow Corning
555Cosmetic Fluid (chemical names：1,3,5- trimethyl -1,1,3,5,5- pentaphenyltrisiloxanes；INCI：Trimethyl
Pentaphenyltrisiloxane) manufacture, or by Dow Corning with reference to Dow Corning 554Cosmetic Fluid sale.
The example of aromatics silicone oil with least one polydimethylsiloxane moieties is as described above, for example by with following formula generation
The compound of table：Formula (IV), wherein y is not 0；Formula (V), wherein p is not 0 and R3And R4For CH3；With formula (VI), wherein p is not 0
And R3And R4For CH3, for example trimethylsiloxyphenyl dimethyl silicone polymer is (such as from Wacker companies
Belsil PDM 1000 (referring to upper formula (IV))), phenyl dimethicones, diphenyl dimethicone (for example come
KF-54 (400cSt) from Shin Etsu, KF54HV (5000cSt), the KF- from Shin Etsu from Shin Etsu
50-300CS (300cSt), the KF-53 (175cSt) from Shin Etsu and the KF-50-100CS from Shin Etsu
(100cSt))。
According to a preferred embodiment of the invention, aromatics silicone oil (b), which is selected from, does not have polydimethylsiloxane moieties
Aromatics silicone oil and its mixture.
It is particularly preferred that (b) aromatics silicone oil is that trimethyl pentaphenyltrisiloxane and diphenyl silicon phenyl are poly-
The mixture of trimethicone.
(c) wax
(c) at least one wax is included according to the composition of the present invention.It can be combined and use two or more waxes.
Relative to the gross weight of composition, 3 weight % to 30 weight % wax is included according to the composition of the present invention, preferably
4 weight % to 20 weight %, more preferably 5 weight % to 10 weight % wax.
Term " wax " used herein represents lipophilic compound at room temperature for solid, and it has liquid/solid
Reversible state changes, the fusing point with more than or equal to 30 DEG C, and the fusing point may be up to 200 DEG C its especially up to 120 DEG C.
Especially, (c) wax for being suitable for the present invention can be with more than or equal to 45 DEG C and particularly greater than or equal to 55 DEG C
Fusing point.
By make wax turn into liquid (fusing), may cause its with may be present it is oily miscible, and formed it is microcosmic it is upper uniformly
Mixture, but recover by the temperature of the mixture to room temperature, it was observed that recrystallization of the wax in the oil of mixture.
For purposes of the present invention, fusing point is corresponded to the pass such as standard ISO 11357-3；Heat analysis described in 1999
(DSC) temperature for the maximum endothermic peak observed.
Differential scanning calorimetry (DSC) (DSC) can be used (such as by TA Instruments companies with title MDSC in the fusing point of wax
The calorimeters of 2920 sale) ordinary technical knowledge in this area determines.
The wax can especially have the hardness that scope is 0.05MPa to 15MPa and preferred scope is 6MPa to 15MPa.Institute
Hardness is stated by determining compression stress to determine, the compression stress is used at 20 DEG C and sold with title TA-TX2i by Rheo companies
Texturometer (texturometer) determine, the texturometer is equipped with a diameter of 2mm stainless steel cylinder, with
0.1mm/s finding speed movement, and penetrate the penetration depth of 0.3mm in wax.
According to a preferred embodiment, the wax is non-polar waxes.Term " nonpolar wax " table used herein
Show the solubility parameter δ at 25 DEG C as previously definedaEqual to 0 (J/cm3)1/2Wax.It is molten in the three-dimensional solubility space of Hansen
Paper of the definition and calculating of solution degree parameter in C.M.Hansen：”Thethree-dimensional solubility
Parameters ", J.Paint Technol., described in 39,105 (1967).
Especially, term " nonpolar wax " represent only formed by nonpolar wax and not by also comprising not be nonpolar wax its
The wax of the mixture formation of its type wax.
As the illustration for the nonpolar wax for being suitable for the present invention, the wax based on hydrocarbon, such as microwax, stone can be especially referred to
Wax, ceresine and Tissuemat E.
" chloroflo " used herein is represented and only formed by carbon and hydrogen atom, and without hetero atom such as N, O and P
Wax.
The Tissuemat E that can be mentioned that includes the Performalene 500-L sold by NewPhase Technologies
Polyethylene and Performalene400Polyethylene.The ceresine that can be mentioned that is Ozokerite Wax SP
1020P.As workable microwax, the Multiwax W sold by Sonneborn companies are can be mentioned thatWith by
The Microwax of Paramelt companies saleWith Base Wax
(d) paste fat matter
(d) at least one paste fat matter is included according to the composition of the present invention.It can be combined and use two or more
Paste fat matter.
Relative to the gross weight of composition, 0.5 weight % to 20 weight % pasty state is included according to the composition of the present invention
The paste fat matter of fatty material, preferably 1 weight % to 18 weight %, more preferably 5 weight % to 15 weight %.
In meaning of the present invention, term " paste fat matter " is understood to mean that with reversible solid state/liquid condition
The lipophilicity fatty compound of change, it shows aeolotropic crystal arrangement and liquid is included at a temperature of 23 DEG C in the solid state
Body portion and solid portion.
Term " pasty state " used herein be understood to mean that at 20 DEG C have scope be 0.001MPa to 0.5MPa,
It is preferred that the compound of 0.002MPa to 0.4MPa hardness.
The ester of dimer of (d) paste fat matter of the present invention comprising aliphatic acid and branched chain polyol or polyalcohol.Separately
Outside, in ester, the only a part hydroxyl of the dimer of the branched chain polyol or polyalcohol is esterified with aliphatic acid.
Polyalcohol in the ester includes branched chain polyol.It can be combined and use two or more different polyalcohols.
The branched chain polyol can be aliphatic series, ring-type or aromatics.Preferably, the branched chain polyol is that aliphatic side chain is more
First alcohol.
The branched chain polyol can include 2 to 24 carbon atoms, preferably 4 to 20 carbon atoms and more preferably 6 to 16 carbon
Atom.
Branched chain polyol in the ester can have 3 to 12 hydroxyls, preferably 4 to 10 hydroxyls and more preferably 5 to 8 hydroxyls
Base.
Preferably, the branched chain polyol is selected from side chain sugar alcohol.
The dimer of the polyalcohol can be the dimer of straight or branched polyalcohol.Preferably, the two of the polyalcohol
Aggressiveness is the dimer of branched chain polyol described herein.
The non-limiting examples of branched chain polyol or its dimer in the ester include ethylene glycol, penta triol, Ji Wusi
Alcohol, dipentaerythritol, neopentyl glycol and combinations thereof, and preferably dipentaerythritol.
According to the present invention, (d) paste fat matter includes wherein only a part branched chain polyol or its dimer and fat
The ester that acid is esterified.
The ester compounds that wherein only a part branched chain polyol or its dimer are esterified correspond to wherein polyalcohol or
The ester compounds that the hydroxyl of its dimer is not esterified completely.That is, described ester compounds include the branched chain polyol not being esterified completely
Or the dimer of polyhydric alcohol residue.In other words, the ester include derived from branched chain polyol/its dimer at least one not
The hydroxyl of reaction.Preferably, the ester includes two unreacted hydroxyls derived from polyalcohol or its dimer.
Terminology used in this article " polyhydric alcohol residue " or " dimer of polyhydric alcohol residue " represent to remove from its hydroxyl
Remove polyalcohol/dimer of hydrogen atom.Terminology used in this article " fatty acid residue " represents to remove hydroxyl from its carboxyl
Aliphatic acid.
Aliphatic acid in the ester can include the aliphatic acid of two or more types.Preferably, the aliphatic acid includes
At least one branched chain fatty acid.The branched chain fatty acid can be saturation or undersaturated branched aliphatic aliphatic acid.The side chain fat
The number of the carbon atom of fat acid can be 4 to 30, preferably 8 to 26 and more preferably 12 to 22.Such aliphatic acid includes, but not limited to
Isostearic acid, Isoeicosane acid and octyldodecanoic acid, and its mixture.
Preferably, the aliphatic acid in the ester includes at least one hydroxy fatty acid.The hydroxy fatty acid represents hydroxyl
The aliphatic aliphatic acid of change.Such hydroxy fatty acid can have 4 to 30 carbon atoms, such as 8 to 26 carbon atoms or 12 to 22
Carbon atom, and with 1 to 20 hydroxyl, such as 1 to 10 hydroxyl or 1 to 6 hydroxyl.It can be combined using two or more not
Same hydroxy fatty acid.Preferably, the hydroxy fatty acid is monohydroxylated aliphatic acid, for example 12- hydroxy stearic acids.
In another aspect of the present invention, the aliphatic acid in the ester may include linear aliphatic aliphatic acid.Such straight chain fat
Fat acid can be saturation or undersaturated, and the number of the carbon atom of the aliphatic acid can be 4 to 30, preferably 8 to 26 and more preferably
12 to 22.
The non-limiting examples of other straight chain fatty acid include caproic acid, enanthic acid, octanoic acid, 2 ethyl hexanoic acid, n-nonanoic acid, the last of the ten Heavenly stems
Acid, hendecanoic acid, dodecylic acid, tridecanoic acid, tetradecanoic acid, pentadecanoic acid, hexadecanoic acid, hexyldecanoic acid, Heptadecanoic acide, ten
Eight alkanoic acids, nonadecylic acid, arachic acid, heneicosanoic acid, behenic acid, palmitoleic acid and its mixture.
The present invention it is another preferred in terms of in, the aliphatic acid in the ester compounds is that branched chain fatty acid is (such as different
Stearic acid, Isoeicosane acid and octyldodecanoic acid) and hydroxy fatty acid (such as 12- hydroxy stearic acids) mixture.Especially
Ground, the aliphatic acid is the mixture of 12- hydroxy stearic acids and isostearic acid.
According to the particular of the present invention, (d) paste fat matter be dipentaerythritol with 12- hydroxy stearic acids and
Four esters of the mixture of isostearic acid, such as dipentaerythritol tetrahydroxy-stearic acid ester/pentaerythritol tetraisostearate (trade name：
Salacos-168EV, from NISSHIN OILLIO).
(e) other components
The cosmetic combinations for cosmetic and/or nursing skin and/or lip are can be included according to the composition of the present invention
Usually used other components in thing.Other components may include, but be not limited to physiologically acceptable medium, except component
(a) with oil, filler, dyestuff and the various additives beyond (b).
Physiologically acceptable medium
For purposes of the present invention, term " physiologically acceptable medium " is intended to refer to be suitable for skin and/or lip
Apply the medium of cosmetic composition, such as water, water-miscible solvent or be generally used for organic molten in cosmetic composition
Agent.
The physiologically acceptable medium (acceptable tolerance, toxicology and sensation) generally adapts to apply above
Plus the property of the supporter of the composition, and it is also adapted to the form that composition to be conditioned is taken.
According to a preferred embodiment, especially be intended for nursing and/or cosmetic lip composition situation
Under, composition used according to the invention to be anhydrous or, relative to the gross weight of the composition, containing less than 3 weights
Amount % water and preferably smaller than 1 weight % water.
Term " anhydrous " especially represents that water is not preferably deliberately added into composition, but can be present in trace and be used for
In the various compounds of the composition.
Other oil
(non-aromatic silicone oil)
At least one non-aromatic silicone oil can also be included according to the composition of the present invention.
State " non-aromatic silicone oil " and represent the silicone oil without phenyl substituent.
The representative example for these the non-aromatic silicone oil that can be mentioned that includes dimethyl silicone polymer；Alkyl polydimethylsiloxanes
Alkane；Vinyl methyl polymethyl siloxane；And the silicone that the also useful aliphatic group that is optionally fluorinated is modified, or with functional group
Such as the silicone of hydroxyl, sulfydryl and/or amino modified." dimethyl silicone polymer (dimethicone) " (INCI) corresponds to poly-
Dimethyl siloxane (polydimethylsiloxane) (chemical name).
Non-aromatic silicone oil may be selected from：
- non-volatile dimethicones (PDMS),
- the PDMS comprising alkyl or alkoxy, alkyl or the alkoxy pendency is in silicone chains and/or in silicone chains
End, these groups are each containing 2 to 24 carbon atoms, such as from Evonik Goldschmidt with business reference ABIL
The cetyl dimethicone that WAX 9801 is sold,
- comprising aliphatic series and/or aromatic group or such as PDMS of the functional group of hydroxyl, sulfydryl and/or amido,
- poly- alkyl methyl siloxane, such as from Evonik Goldschmidt with business reference ABIL WAX 9801
The cetyl dimethicone of sale, or optionally it is fluorinated the poly- alkyl methyl siloxane of substituent group, such as poly- methyl
Trifluoro propyl dimethyl siloxane,
- poly- the alkyl methyl siloxane replaced by the functional group of such as hydroxyl, sulfydryl and/or amido,
- use aliphatic acid, fatty alcohol or polyoxyalkylene-modified polysiloxanes, and its mixture.
(fluoro oil)
At least one fluoro oil can also be included according to the composition of the present invention.
Term " fluoro oil " represents the oil for including at least one fluorine atom.
Available for the present invention fluoro oil may be selected from fluorosilicon oil, the fluoropolyether as described in document EP-A-847752 and
Fluorosilicone, and perfluorochemical.
Term " perfluorochemical " represents the compound that wherein all hydrogen atom has been replaced by fluorine atoms.As available for
The example of the perfluor oil of the present invention, can be mentioned that perfluorodecalin and perfluor perhydro are luxuriant and rich with fragrance.
Filler
One or more of fillers can also be included according to the composition of the present invention.
Term " filler " is understood to mean that the colourless or white of any shape, mineral or synthesis particle, no matter manufacture should
How is the temperature of composition, and it is insoluble in the medium of the composition.Stream of these fillers particularly for improvement composition
Denaturation or quality.
The filler can be mineral or organically and be any shape, be laminar, spherical or Long Circle, regardless of
Crystal formation (such as sheet, cube, six sides, it is orthogonal).It can be mentioned that talcum, mica, silica, kaolin, clay, titanium dioxide
Titanium, tin oxide, bentone, fire are into method silica dioxide granule, optionally through hydrophilic or hydrophobic treatment polyamidePowder
(from Atochem's), poly- Beta-alanine powder and polyethylene powders, tetrafluoro ethylene polymerPowder
End, lauroyl lysine, starch, boron nitride, hollow polymer microsphere such as polyvinylidene chloride/acrylonitrile microspheres, for example(Nobel Industrie), acrylic copolymer microballoon are (from Dow Corning companies) and
Silicones microballon is (such as from Toshiba's), boron sikicate aluminum calcium, winnofil, magnesium carbonate, magnesium bicarbonate,
Hydroxyapatite, the hollow silicon dioxide microballoon (Silica from Maprecos), elastomer polysiloxane
Grain, glass or ceramic microcapsules, and derived from the organic carboxyl acid containing 8 to 22 carbon atoms and preferably 12 to 18 carbon atoms
Metallic soap, such as zinc stearate, magnesium stearate, lithium stearate, zinc laurate or magnesium myristate, and its mixture.
They can also be the particle comprising copolymer, and the copolymer includes trihydroxy methyl caprolactone.Especially, it can be
The copolymer of hexamethylene diisocyanate/trihydroxy methyl caprolactone.Such trihydroxy methyl caprolactone crosslinked copolymer particles are outstanding
It is commercially available, for example, with title Plastic PowderOr Plastic PowderFrom Toshiki
Commercially available from company.
Relative to the gross weight of composition, the filler can by 0.1 weight % of scope to 20 weight % and also better
Exist for 1 weight % to 10 weight % content.
Dyestuff
Can be comprising at least one dyestuff (also referred to as colouring agent) according to the composition of the present invention, it may be selected from art technology
Pigment, water-soluble or lipid-soluble dye, nacre and flash of light color lake known to personnel, and its mixture.
Term " pigment " it should be understood that the white or coloured, mineral being insoluble in the aqueous solution or organic
Grain.
As the coloring earth available for the present invention, titanium oxide, zirconium oxide or cerium oxide are can be mentioned that, and also have oxidation
Zinc, iron oxide or chromium oxide, barba hispanica, manganese violet, ultramarine blue and chromium hydrate.
It can also be with the face that can be such as structure of sericite/brown iron oxide/titania/silica type
Material.Such pigment is for example sold by Chemicals and Catalysts companies with reference CoverleafNS or JS, and 30
Region in have contrast ratio.
The dyestuff can also include with can for the structure of silicon dioxide microsphere type for example containing iron oxide pigment.
The example of pigment with the structure is the product to be sold with reference to PC Ball PC-LL-100P, the face by Miyoshi companies
Material is made up of the silicon dioxide microsphere containing yellow iron oxide.
In the organic pigment available for the present invention, carbon black, the pigment of D＆C types can be mentioned that, based on alkermes or base
In the color lake of barium, strontium, calcium or aluminium, or document EP-A-542669, EP-A-787730, EP-A-787731 are described in for the election
With the diketopyrrolopyrrolecocrystals (DPP) in WO-A-96/08537.
Term " nacre " it should be understood that any type of coloured particle, and its possible yes or no is irised,
Especially produced by some mollusks in its shell, or be for the election synthesis, and it has face via optical interference
Color effect.
The nacre may be selected from pearlescent pigment, for example, be coated with the odenite of iron oxide, be coated with the cloud of bismoclite
It is female, be coated with the odenite of chromium oxide, be coated with the odenite of organic dyestuff and also have the pearlescent pigment based on bismoclite.
They can also be the mica particles for being superimposed at least two pantostrat metal oxides and/or organic dyestuff in its surface.
Commercially in obtainable nacre, can be mentioned that sold by Engelhard companies nacre Timica,
Flamenco and Duochrome (being based on mica), the Timiron nacres sold by Merck companies, sold by Eckart companies
Prestige mica-based nacres, and by Sun Chemical companies sell Sunshine synthetic mica base nacres.
Term " dyestuff " it should be understood that usually organic compound, its dissolve in fatty material for example oil in or
In water-alcohol phase.
Water-soluble or lipid-soluble dye can also be included according to the composition of the present invention.The lipid-soluble dye is, for example, the Sudan
Red, DC Red 17, DC Green 6, beta carotene, brown the Sudan, DC Yellow 11, DC Violet 2, DC Orange5
And quinoline yellow.The water-soluble dye is, for example, beet root juice or methylene blue.
At least one material with specific optical effect can also be contained as dyestuff according to the composition of the present invention.
The effect is different from simple conventional tone effect, i.e., the unification such as produced by standard dyes (such as solid color pigments)
And stabilization effect.For purposes of the present invention, term " stabilisation " represents to lack with the change of viewing angle or for selecting
The effect for the color change that ground response temperature changes.
For example, the material may be selected from the particle with metallochrome, angle heterochromatosis (goniochromatic) colouring agent, diffraction
Pigment, thermotropic toner, fluorescent whitening agent and also fiber, especially interference fibers.Without superfluous words, these various materials can
Combine and shown to provide while two kinds of effects, or even according to the display of the novel effect of the present invention.
Relative to the gross weight of composition, the dyestuff can be by 0.01 weight % of scope to 30 weight %, preferably 0.1 weight
Amount % to 20 weight % content are present in the composition.
Additive
According to the intended use of the composition, being generally used for of at least one can also be included according to the composition of the present invention
Additive in cosmetic, it is selected from, for example reducing agent, thickener, film forming agent (especially hydrophobic), silicone elastomer, softening
Agent, emollient, defoamer, antioxidant, NMF, UV- screeners, preservative, ceramide, cosmetic active agent, modeling solution
Agent, nertralizer, spices, protein, vitamin, propellant, hydrophily or lipophilicity, film forming or non film-forming polymers；Lipophilicity
Or hydrophily gelling agent.
Above additive generally each with the gross weight relative to composition between 0.01 weight % and 10 weight % it
Between amount exist.
Preparation method
Each composition can be mixed by using mixer well known in the art to manufacture according to the composition of the present invention.It is general and
Speech, mixes (c) wax to reduce its viscosity under heating.
It is preferred that adding (b) aromatics silicone oil after (a) hydrocarbon ils, (c) wax and (d) paste fat matter are sufficiently mixed.
[purposes of cosmetics solid composite]
The invention further relates to be used for the purposes of cosmetic and/or nursing skin and/or lip, bag according to the composition of the present invention
Include to skin and/or lip and apply the composition.
The present invention also provides the cosmetic method for cosmetic and/or nursing skin and/or lip, including will be according to the present invention
At least one composition apply to skin and/or lip.
It can be provided according to the such purposes and method of the present invention to skin and/or lip with good resistance to color transfer
Glossiness deposit.
Embodiment
The present invention will be more fully described by embodiment, but embodiment is not necessarily to be construed as the model of the limitation present invention
Enclose.
The cosmetic formulations of solid lip product (lipstick)
Solid lip cosmetic product will be prepared into according to the composition of embodiment 1 and comparative example 1 to 5.Each composition shows
It is shown in table 1 below.In table 1, all components are based on " the weight % " of active raw material.
Following component is used as the component (a) to (d) in embodiment.
(a) Parleam (PARLEAM V)
(b) the poly- trimethicone of diphenyl silicon phenyl (KF-56A)
(b) trimethyl pentaphenyltrisiloxane (DOW CORNING PH-1555HRI COSMETIC FLUID)
(c) polyethylene (PERFORMALENE 500-L POLYETHYLENE)
(c) ceresine (OZOKERITE WAX SP 1020P)
(d1)：Dipentaerythritol tetrahydroxy-stearic acid ester/pentaerythritol tetraisostearate (Salacos-168EV, from NISSIN
OILLIO)
(d’1)：Dipentaerythritol hexahydroxystearic acid ester (Salacos-168M, from NISSIN OILLIO)
(d’2)：The sub- oleyl alcohol dimerized linoleic acid ester (Plandol-G) of double-behenyl alcohols/isooctadecanol/phytosterol dimerization
(d’3)：Double many acyl group adipate esters -2 (SOFTISAN 649) of-two glycerine
(d’4)：Vaseline (ULTIMA WHITE PET USP)
(d’5)：Phytosterol Queensland nut oleate (YOFCO MAS)
Preparation method
The composition of embodiment 1 and comparative example 1 to 5 is obtained according to following scheme：
In the first phase, by (a) Parleam, pentaerythritol tetraoctyl stearate, filler and the pigment of half
Milled in three-roll mill, to obtain dye material.
Abreast, remaining (a) Parleam, (c) wax and component (d) or (d ') are introduced into heating dish, and
Mixed at a temperature of about 100 DEG C using Rayneri, to obtain uniform mixture.Confirm all additions into
Divide after being all sufficiently mixed, introduce component (b).The dye material is incorporated into the mixture, isohexadecane is subsequently introduced,
And it is stirred continuously until that mixture is uniform.
Finally, composition is poured into and be preheated in 45 DEG C of mould, to produce a diameter of 11.5mm rod.To entirely it be placed in
5 minutes at room temperature, and it is cooled down in freezer unit about 15 minutes, to obtain test lipstick.
Evaluate
(resistance to color transfer)
Applying composition and lower lip and upper lip are rubbing 5 seconds together, and applying by composition to lip
By evaluating resistance to color transfer after lip is pressed into whiteware cup 5 minutes.
(gloss property)
Gloss is evaluated according to following scheme：
Composition is applied on Bio Skin (Beaulax) using the stroke (stroke) of fixed qty, and passes through light
Pool meter (GM-268, MINOLTA), gloss is determined using the condition of 60 ° of illumination angles and 60 ° of acceptance angles.
Sediment yield is determined by putting on after Bio Skin its weight loss.
(organoleptic properties)
The lipstick obtained according to embodiment 1 is just following aesthetic according to sense organ consumer tests by 10 panelists
Matter is evaluated：
- sliding (gliding),
- to the sense of touch of lip, and
- adherence just upon application.
They are interviewed by the expert of just judge after a test.
As a result
(resistance to color transfer and gloss property)
The result of resistance to color transfer and gloss property is shown in table 2 below.
As shown in table 2, embodiment 1 has good resistance to color transfer and good gloss property, and therefore it can
Glossiness deposit is provided on lip.Especially, although the sediment yield of embodiment 1 is compared with those of comparing embodiment
Relatively low, it shows good gloss.Therefore, it could be assumed that：Effectively can above it be carried in lip according to the composition of embodiment 1
For gloss.
By contrast, using the compound of (d ' 1) to any one of (d ' 5) as paste fat matter, (it does not include it
In branched chain polyol part that only part of hydroxyl is esterified) comparative example 1 to 5 do not produce required resistance to color transfer
And/or not yet in effect gloss is produced on lip.
(organoleptic properties)
Spoken highly of according to the lipstick that embodiment 1 is obtained according to sense organ consumer tests, because it is produced：
- smooth sliding (smoothgliding),
- to the sense of touch of lip softness, and
- just upon application without adhesion sense.
In addition, panelist evaluates the lipstick according to embodiment 1 as follows：
- color fully shows, without adding extra coating.
- its provide gloss with cause lip just upon application seem moistening.
- color is for a long time.
- it will not cause lip feel to dry during daytime.
Claims (13)
1. a kind of composition, it is included：
(a) at least one hydrocarbon ils,
(b) at least one aromatics silicone oil,
(c) at least one wax, and
(d) at least one paste fat matter,
Wherein (d) paste fat matter includes the ester of the dimer of aliphatic acid and branched chain polyol or polyalcohol, wherein described many
The only a part hydroxyl of the dimer of first alcohol or polyalcohol is esterified with the aliphatic acid.
2. composition according to claim 1, wherein the aliphatic acid includes the aliphatic acid of two or more types.
3. composition according to claim 1 or 2, wherein the aliphatic acid includes branched chain fatty acid and/or hydroxy aliphatic
Acid.
4. composition according to any one of the preceding claims, wherein the polyalcohol has 3 to 12 hydroxyls, preferably
4 to 10 hydroxyls, and more preferably 5 to 8 hydroxyls.
5. composition according to any one of the preceding claims, wherein (a) hydrocarbon oil contains nonpolar hydrocarbon ils, it is preferably non-to wave
The nonpolar hydrocarbon ils of hair property, and even more preferably from Parleam.
6. composition according to any one of the preceding claims, wherein (b) aromatics silicone oil includes non-volatile aromatic silicon
Oil, preferably trimethyl pentaphenyltrisiloxane.
7. composition according to any one of the preceding claims, wherein relative to the gross weight of the composition, including 5
(a) hydrocarbon ils of weight % to 30 weight %, preferably 5 weight % to 25 weight %, more preferably 8 weight % to 25 weight % amount.
8. composition according to any one of the preceding claims, wherein relative to the gross weight of the composition, comprising
(b) aromatics silicon of 43 weight % to 90 weight %, preferably 45 weight % to 70 weight %, more preferably 50 weight % to 70 weight % amount
Oil.
9. composition according to any one of the preceding claims, wherein relative to the gross weight of the composition, comprising
3 weight % to 30 weight %, preferably 4 weight % (c) wax to 20 weight %, more preferably described in 5 weight % to 10 weight % amount.
10. composition according to any one of the preceding claims, wherein relative to the gross weight of the composition, bag
(d) pasty state fat containing 0.5 weight % to 20 weight %, preferably 1 weight % to 18 weight %, more preferably 5 weight % to 15 weight % amount
Fat material.
11. composition according to any one of the preceding claims, it is solid.
12. composition according to any one of the preceding claims, it is for cosmetic and/or nursing skin and/or mouth
The cosmetic composition of lip.
13. composition according to any one of the preceding claims is used for the use of cosmetic and/or nursing skin and/or lip
On the way, it includes applying the cosmetics solid composite to skin and/or lip.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014247790A JP6723684B2 (en) | 2014-12-08 | 2014-12-08 | Compositions containing hydrocarbon oils, aromatic silicone oils, waxes and pasty fatty substances |
| JP2014-247790 | 2014-12-08 | ||
| PCT/JP2015/084225 WO2016093184A1 (en) | 2014-12-08 | 2015-12-01 | Composition comprising hydrocarbon oil, aromatic silicone oil, wax, and pasty fatty substance |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106999418A true CN106999418A (en) | 2017-08-01 |
| CN106999418B CN106999418B (en) | 2021-12-07 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580065329.9A Active CN106999418B (en) | 2014-12-08 | 2015-12-01 | Composition comprising hydrocarbon oil, aromatic silicone oil, wax and pasty fatty substance |
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| Country | Link |
|---|---|
| JP (1) | JP6723684B2 (en) |
| KR (1) | KR102092087B1 (en) |
| CN (1) | CN106999418B (en) |
| WO (1) | WO2016093184A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111556777A (en) * | 2017-12-22 | 2020-08-18 | Lvmh研究公司 | Cosmetic composition comprising anhydrous spheroids dispersed in a silicone phase |
| CN114630649A (en) * | 2019-10-31 | 2022-06-14 | 莱雅公司 | Solid anhydrous composition for caring for and/or making up keratin materials |
Citations (1)
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| WO2008012442A2 (en) * | 2006-07-28 | 2008-01-31 | Stearinerie Dubois Fils | Mixture of partial esters of monopentaerythritol, dipentaerythritol and tripentaerythritol, process for obtaining same and cosmetic product containing them |
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| FR2894471B1 (en) * | 2005-12-08 | 2008-02-15 | Oreal | COSMETIC COMPOSITION COMPRISING A DIMERDILINOLEIC ACID ESTER AND POLYOL (S), A VOLATILE OIL AND A FILMOGENIC AGENT |
| US20070134181A1 (en) * | 2005-12-08 | 2007-06-14 | L'oreal | Cosmetic composition comprising an ester of dimerdilinoleic acid and of polyol(s) and a silicone surfactant |
| FR2917614B1 (en) * | 2007-06-21 | 2009-10-02 | Oreal | COSMETIC COMPOSITION COMPRISING A POLYESTER AND A BRANCHED HYDROCARBON COMPOUND. |
| WO2010109409A2 (en) * | 2009-03-23 | 2010-09-30 | L'oreal | Cosmetic composition comprising a diester wax |
| FR2943244B1 (en) * | 2009-03-23 | 2011-08-19 | Oreal | COSMETIC COMPOSITION COMPRISING A DIESTER WAX, POLAR OIL AND APOLAR OIL |
| WO2011013174A1 (en) * | 2009-07-30 | 2011-02-03 | 高級アルコール工業株式会社 | Oil base for cosmetics and cosmetics containing the same |
| US20130231403A1 (en) * | 2010-11-08 | 2013-09-05 | The Nisshin Oillio Group, Ltd. | Esterification reaction product and cosmetic product |
| WO2013190703A1 (en) * | 2012-06-21 | 2013-12-27 | L'oreal | Cosmetic solid composition comprise a non volatile hydrocarbonated oil, waxes and a high content from non volatile phenylated silicone oil |
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2014
- 2014-12-08 JP JP2014247790A patent/JP6723684B2/en active Active
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2015
- 2015-12-01 KR KR1020177014683A patent/KR102092087B1/en active IP Right Grant
- 2015-12-01 WO PCT/JP2015/084225 patent/WO2016093184A1/en active Application Filing
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| WO2008012442A2 (en) * | 2006-07-28 | 2008-01-31 | Stearinerie Dubois Fils | Mixture of partial esters of monopentaerythritol, dipentaerythritol and tripentaerythritol, process for obtaining same and cosmetic product containing them |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111556777A (en) * | 2017-12-22 | 2020-08-18 | Lvmh研究公司 | Cosmetic composition comprising anhydrous spheroids dispersed in a silicone phase |
| CN111556777B (en) * | 2017-12-22 | 2023-08-22 | Lvmh研究公司 | Cosmetic composition comprising anhydrous spheroids dispersed in silicone phase |
| CN114630649A (en) * | 2019-10-31 | 2022-06-14 | 莱雅公司 | Solid anhydrous composition for caring for and/or making up keratin materials |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106999418B (en) | 2021-12-07 |
| JP2016108280A (en) | 2016-06-20 |
| KR20170075790A (en) | 2017-07-03 |
| KR102092087B1 (en) | 2020-03-23 |
| JP6723684B2 (en) | 2020-07-15 |
| WO2016093184A1 (en) | 2016-06-16 |
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