CN106963658A - A kind of cosmetic composition containing nanometer platinum - Google Patents
A kind of cosmetic composition containing nanometer platinum Download PDFInfo
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- CN106963658A CN106963658A CN201710185779.2A CN201710185779A CN106963658A CN 106963658 A CN106963658 A CN 106963658A CN 201710185779 A CN201710185779 A CN 201710185779A CN 106963658 A CN106963658 A CN 106963658A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8176—Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
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Abstract
The invention belongs to cosmetic technical field, and in particular to contain nanometer platinum in a kind of cosmetic composition containing nanometer platinum, said composition；Nanometer platinum of the present invention has effects that to remove whole active oxygens in vivo, and sustainable in vivo plays a role.Meanwhile, nanometer platinum colorless and odorless is identified as safe and harmless, can be used as cosmetic active ingredient.The present invention is added in various cosmetics, used as active component, these cosmetics include but is not limited to using nanometer platinum colloid as active component：Toner, facial treatment milk, face cream, facial mask, elite, face cleaning cream, mildy wash, face cleaning jelly, face cleaning foam, makeup remover, foundation cream, muffin, lipstick etc..
Description
Technical field
The invention belongs to cosmetic technical field, and in particular to a kind of cosmetic composition containing nanometer platinum.
Background technology
The skin of human health has natural defencive function, can resist the environment such as dust storm, cold, humidity, drying to skin
In the infringement of skin, keratoderma, the moisture containing 10%-20%, it, which is originated, is mainly the sweat of sweat gland secretion, to keep table
The plasticity of skin cuticula, soft and smooth, the moistening and elasticity of maintenance skin.But there are some researches show the skin of, the mankind is from 25-30
Year after will aging with advancing age and gradually, just occur about after 35-40 Sui comparison it is detailed aging change
Change, now, fibroblastic quantity is gradually decreased in human body skin, its secrete collagen and elastic fibers albumen also because
Gradually decrease, be broken to be oxidized, the supporting role to epidermis is just disappeared, skin corium start it is thinning, skin elasticity variation because
This cause it is inhomogenous collapse, generate wrinkle, wrinkle with skin metabolism hypofunction, blood supply reduces, sebum
Secretion reduction is closely related, causes skin dry, thinning；In addition, the skin of aging also has the elastic fibers and collagen of skin corium
Fiber is reduced, thicker, aging, and skin elasticity lowers；Subcutaneous fat is reduced, and skin is reduced support.Show old fell
The feature of skin structural change：It is dry, coarse, corrugate, the increase of loose and benign or malignant neoplasm incidence.
The skin of beautiful health, gradually fails in growing up jointly with the age.The face cleaning of mistake, skin care method, city
Air pollution, frequently color make-up can all hurt skin, accelerate the deterioration of skin state.Also, the skin regeneration once declined
Difficulty than larger.Therefore selection as early as possible, using the cosmetics and skin care method for being adapted to oneself skin, is to prevent skin aging, guarantor
Hold the key of beautiful health.Up to the present, as oxidation resistant main flow composition Co-Q10, substantially disposable play is made
With, that is, enter in vivo once having carried out antioxidation, just lose effect.But have 7 kinds of active oxygens in human body, it is auxiliary
The compositions such as enzyme Q10 can only remove a kind of active oxygen.Therefore, in cosmetics, Co-Q10 is replaced using new active component, is had
It is significant.
The content of the invention
For these reasons, applicant has found that nanometer platinum has and removes internal whole active oxygens by studying for many years
Effect, and sustainable in vivo play a role.Meanwhile, nanometer platinum colorless and odorless, be identified as it is safe and harmless, can as change
Cosmetic active component is used.
The present invention is added in various cosmetics, used as active component using nanometer platinum colloid as active component, these
Cosmetics include but is not limited to：It is toner, facial treatment milk, face cream, facial mask, elite, face cleaning cream, mildy wash, face cleaning jelly, clean
Papula foam, makeup remover, foundation cream, muffin, lipstick etc..
The present invention prepare nanometer platinum colloid method be：Using potassium chloroplatinate as raw material, KBr, polyvinyl pyrrole are added
Certain temperature is cooled to after being reacted under alkanone, HTHP, L-arginine is added, nanometer platinum glue is obtained by ladder cooling
Body.
Of the present invention pair of nanometer platinum colloid can be used for the active component of cosmetics, with antioxidation.
What the present invention was achieved through the following technical solutions.
Contain nanometer platinum in a kind of cosmetic composition, said composition.Or contain nanometer platinum glue in said composition
Body
Wherein cosmetic composition includes：Toner, facial treatment milk, face cream, facial mask, elite, face cleaning cream, mildy wash,
Face cleaning jelly, face cleaning foam, makeup remover, foundation cream, muffin, lipstick.
Wherein nanometer platinum is 1-100nm.
Wherein nanometer platinum 1-10nm.
Wherein composition contains a nanometer platinum colloid.
Nanometer platinum colloid preparation method be：
Potassium chloroplatinate is taken, deionized water is added, is well mixed, KBr is added, stirs 0.5-2 hours, then adds poly-
Vinylpyrrolidone, reaction solution is entered in reactor, is started to warm up, and continues to react 3h afterwards to 130 DEG C；80-90 DEG C is cooled to,
Place 20-40 minutes, be cooled to 40-50 DEG C, add L-arginine, place 15-25 minutes, be cooled to 20-25 DEG C, obtain nanometer
Platinum colloid.Wherein the mol ratio of potassium chloroplatinate and KBr is 1:66；Wherein potassium chloroplatinate and polyvinylpyrrolidone rubs
You are than being 1:10；Wherein the mol ratio of potassium chloroplatinate and L-arginine is 1:0.15-0.35.
Wherein nanometer platinum colloid is 0.01%-1% in cosmetic composition percentage by weight.
Wherein nanometer platinum colloid is 0.05-0.2% in cosmetic composition percentage by weight.
Wherein the parts by weight of facial treatment milk, which are constituted, is：Nanometer platinum colloid 0.001-0.03, propane diols 4-8, glycerine 2-6,
Carbonic acid dioctyl ester 1-5, Nexbase 2004 1-4, dimethyl silicone polymer 1-4, pentaerythrite four (thylhexoic acid) ester 1-3, glycerine
Polyethers -260.5-2.5, stearine 0.1-1.5, tapioca 0.1-1.5, PEG-45 stearate 0.1-1.5, sucrose
Distearate 0.1-1.0, trehalose 0.1-1.0, double many 0.1-1.0 of acyl group adipate ester -2 of-two glycerine, double-PEG-18 first
Base ether dimethylsilane 0.1-1.0, cetanol 0.1-1.0,1,3- propane diols 0.1-1.0,1,2- hexylene glycol 0.1-1.0, card ripple
Nurse 0.1-0.5, hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers 0.1-0.5, arginine 0.1-0.5, saualane
0.1-0.5, xanthans 0.01-0.2, tocopherol (vitamin E) 0.01-0.2, dipotassium glycyrrhizinate 0.01-0.2, poly- methyl silicon times
Half oxygen alkane 0.01-0.2, butanediol 0.01-0.2, decoyl hydroximic acid 0.01-0.2, polysorbate -60 0.01-0.2 are transparent
Matter acid sodium 0.01-0.1, EDETATE SODIUM 0.001-0.05, the smooth isostearate 0.001-0.05 of sorb, the section shepherd's purse of deep-sea two
(CRAMBE ABYSSINICA) seed oil 0.001-0.05, wineberry (VACCINIUM MYRTILLUS) seed oil 0.001-
0.05, Pseudoalteromonas tunning extract 0.001-0.05, silver-colored 0.0001-0.005, purslane (PORTULACA
OLERACEA) extract 0.0001-0.005, adder-wort (POLYGONUM BISTORTA) root extract 0.0001-0.005, close sieve
Wood (MYROTHAMNUS FLABELLIFOLIA) leaf/stem extraction 0.0001-0.005, hexylene glycol 0.0001-0.005, hydrolysis
Vegetable protein 0.0001-0.005, atriphos 0.0001-0.005, sodium chondroitin sulfate 0.0001-0.005, pungent glycol
0.0001-0.005, Denatonium Benzoate 0.0001-0.005, citric acid 0.00001-0.0002, ascorbic acid (vitamin C)
0.00001-0.0002, lichee (LITCHI CHINENSIS) pericarp extract 0.00001-0.0002, sodium hydroxide
0.00001-0.0002, polyvinylpyrrolidone 0.00001-0.0002, plus deionized water is to 100.
Wherein the parts by weight of facial mask, which are constituted, is：Nanometer platinum colloid 0.001-0.03, white fungus (TREMELLA
FUCIFORMIS) extract 0.001-0.1, silver-colored 0.0001-0.005, decoyl hydroximic acid 0.01-0.1, pungent glycol 0.0001-
0.002, Sodium Hyaluronate 0.001-0.01, tamarind (TAMARINDUS INDICA) seed glue 0.0001-0.002, hydrolyzing plant egg
White 0.0001-0.002, hydrolyzes monkey-bread tree (ADANSONIA DIGITATA) extract 0.0001-0.002, hydrolyzes royal jelly
Albumen 0.001-0.01, deep-sea two section shepherd's purse (CRAMBE ABYSSINICA) seed oil 0.001-0.02, atriphos 0.0001-
0.002, sodium chondroitin sulfate 0.0001-0.002, adder-wort (POLYGONUM BISTORTA) root extract 0.0001-0.002,
Sodium hydroxide 0.00001-0.0002, wineberry (VACCINIUM MYRTILLUS) seed oil 0.001-0.02, citric acid
0.00001-0.0002, Mi Luomu (MYROTHAMNUS FLABELLIFOLIA) leaf/stem extraction 0.0001-0.002, dent
Amaranth (PORTULACA OLERACEA) extract 0.0001-0.002, ascorbic acid (vitamin C) 0.00001-0.0002, poly- second
Alkene pyrrolidone 0.00001-0.0002, the 0.5-4.0 of polyethylene glycol -32, dimethyl silicone polymer 0.1-2.0, arginine
0.01-1.0, Pseudoalteromonas tunning extract 0.001-0.03, hexylene glycol 0.0001-0.02, xanthans
0.00001-0.0002, glyceryl acrylate/acrylic copolymer 0.0001-0.005, glycerine 2-8, butanediol 0.01-1.0,
AVC 0.1-2.0, acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymerics
Thing 0.01-1.0, propane diols 2-8, Denatonium Benzoate 0.00001-0.0002, EDETATE SODIUM 0.00001-0.0002,1,3- the third two
Alcohol 0.1-2.0,1,2- pentanediol 0.0001-0.002,1,2- hexylene glycol 0.1-2.0, plus deionized water is to 100.
Specific embodiment
Illustrate technical scheme, but protection scope of the present invention not limited to this with specific embodiment below.
Content described in this specification embodiment is only enumerating to the way of realization of inventive concept, protection of the invention
Scope is not construed as being only limitted to the concrete form that embodiment is stated, protection scope of the present invention is also and in art technology
Personnel according to present inventive concept it is conceivable that equivalent technologies mean.Although embodiment of the invention below is retouched
State, but the invention is not limited in above-mentioned specific embodiments and applications field, following specific embodiments is only to show
It is meaning property, directiveness rather than restricted.One of ordinary skill in the art is under the enlightenment of this specification and is not taking off
In the case of the scope protected from the claims in the present invention, the form of many kinds can also be made, these belong to the present invention
The row of protection.
The following experiments of the present invention, are on the basis of multiple creative experiment, with claimed technical scheme of the invention
Based on, the conclusive experiment of the research staff of summary.
First, stability test
1st, facial treatment milk stability test
Test 1 group：0.1mol potassium chloroplatinates are taken, deionized water 10mL is added, are well mixed, KBr 6.6mol is added,
Stirring 1 hour, then adds polyvinylpyrrolidone 1mol, reaction solution is entered in reactor, started to warm up, to after 130 DEG C
Continue to react 3h, be cooled to 20-25 DEG C, obtain a nanometer platinum colloid.Using nano-particle size analysis instrument (Photon
Correlation Spectroscopy, INSTRUMENT MODEL：Zetasizer Nano S, manufacturer：Malvern companies of Britain)
Platinum size distribution is analyzed in more than 0.1-100nm, 90% platinum size distributions in 1-50nm.
Test 2 groups：0.1mol potassium chloroplatinates are taken, deionized water 10mL is added, are well mixed, KBr 6.6mol is added,
Stirring 1 hour, then adds polyvinylpyrrolidone 1mol, reaction solution is entered in reactor, started to warm up, to after 130 DEG C
Continue to react 3h, be cooled to 85 DEG C, place 30 minutes, be cooled to 45 DEG C, add L-arginine 0.02mol, place 20 minutes, drop
Temperature obtains a nanometer platinum colloid to 25 DEG C.Using nano-particle size analysis instrument (Photon Correlation Spectroscopy,
INSTRUMENT MODEL：Zetasizer Nano S, manufacturer：Malvern companies of Britain) platinum size distribution is analyzed in 0.1-
100nm, more than 90% platinum size distribution is in 1-10nm.
Cosmetics quality detection experiment：
First group of facial treatment milk：Test 1 group of nanometer platinum colloid 0.005, propane diols 5, glycerine 4, carbonic acid dioctyl ester 3, hydrogen
Change the dimethyl silicone polymer 2 of poly decene 2.5, pentaerythrite four (thylhexoic acid) ester 1.5, glycerin polyether -26 1.0, glyceryl stearate
Acid esters 0.9, tapioca 0.8, PEG-45 stearates 0.6, sucrose distearate 0.5, trehalose 0.5, double-two glycerine are more
Acyl group adipate ester -2 0.3, double-PEG-18 methyl ethers dimethylsilanes 0.3, cetanol 0.3,1,3- propane diols 0.27,1,2-
Hexylene glycol 0.2, carbomer 0.18, hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers 0.15, arginine 0.14,
Saualane 0.11, xanthans 0.08, tocopherol (vitamin E) 0.05, dipotassium glycyrrhizinate 0.05, polymethylsilsesquioxane
0.05, butanediol 0.04, decoyl hydroximic acid 0.03, polysorbate -60 0.02, Sodium Hyaluronate 0.01, EDETATE SODIUM
0.009, the smooth isostearate 0.006 of sorb, section shepherd's purse (CRAMBE ABYSSINICA) the seed oil 0.005, wineberry of deep-sea two
(VACCINIUM MYRTILLUS) seed oil 0.005, Pseudoalteromonas tunning extract 0.002, silver-colored 0.0001-
0.005, purslane (PORTULACA OLERACEA) extract 0.0006, adder-wort (POLYGONUM BISTORTA) root extract
0.0006, Mi Luomu (MYROTHAMNUS FLABELLIFOLIA) leaf/stem extraction 0.0003, hexylene glycol 0.0003, hydrolysis is planted
Thing albumen 0.0003, atriphos 0.0003, sodium chondroitin sulfate 0.0003, pungent glycol 0.0001, Denatonium Benzoate
0.0001, citric acid 0.00001-0.0002, ascorbic acid (vitamin C) 0.00001-0.0002, lichee (LITCHI
CHINENSIS) pericarp extract 0.00004, sodium hydroxide 0.00003, polyvinylpyrrolidone 0.00002, plus deionized water
To 100.(above-mentioned is grams g)
Preparation method：1st, component A raw material is weighed by formula【Water, propane diols, glycerine, 1,2- hexylene glycols, glycerin polyether -26,
Carbomer, xanthans, trehalose, EDETATE SODIUM】, aqueous phase pot is added, is heated to after 70-75 DEG C, stirs, vacuum breast is pumped into
In change machine；
2nd, B component raw material is weighed by formula【Carbonic acid dioctyl ester, Nexbase 2004, dimethyl silicone polymer, pentaerythrite four
(thylhexoic acid) ester, stearine SE, PEG-45 stearate, sucrose distearate, (hydroxy-ethyl acrylate/propylene
Acyl dimethyltaurine sodium copolymer, saualane, polysorbate -60, the smooth isostearate of sorb, water), double-PEG-18 first
Base ether dimethylsilane, cetanol, many acyl group adipate esters -2 of double-two glycerine, tocopherol (vitamin E), the section shepherd's purse of deep-sea two
(CRAMBE ABYSSINICA) seed oil, wineberry (VACCINIUM MYRTILLUS) seed oil】, oil phase pot is added, is heated to
70-75 DEG C, stir, be pumped into vacuum emulsifying machine；
3rd, start is uniformly mixed (about 30 minutes, 1000rpm/ points), stops stirring, is cooled to 40 DEG C；Add【(wood
Sweet potato starch, water, polymethylsilsesquioxane), (water, pungent glycol, Pseudoalteromonas tunning extract), (butanediol, litchi
Branch (LITCHI CHINENSIS) pericarp extract), arginine, (water, adder-wort (POLYGONUM BISTORTA) root extract,
Hexylene glycol, pungent glycol, xanthans), (water, 1,3- propane diols, ascorbic acid (vitamin C), Mi Luomu (MYROTHAMNUS
FLABELLIFOLIA) leaf/stem extraction, citric acid), (1,3- propane diols, decoyl hydroximic acid), (silver, water), (water, butanediol,
Purslane (PORTULACA OLERACEA) extract, silver), dipotassium glycyrrhizinate, Sodium Hyaluronate, (water, butanediol, hydrolysis plant
Thing albumen, atriphos, sodium chondroitin sulfate, sodium hydroxide, EDETATE SODIUM, polyvinylpyrrolidone), (water, platinum powder), benzene
First denatonium】, continue to stir, be cooled to room temperature；
4th, discharging is positioned in stainless steel material storage tube, as semi-finished product；
5th, it is filling using bottle placer after half examination and test of products is qualified, it is unqualified to destroy；
6th, pack, lot number is marked using ink jet numbering machine and the date is limited the use of, case to be checked；
7th, after product inspection is qualified, storage；It is unqualified to destroy.
Second group of facial treatment milk：Test 2 groups of nanometer platinum colloids 0.005, propane diols 5, glycerine 4, carbonic acid dioctyl ester 3, hydrogen
Change the dimethyl silicone polymer 2 of poly decene 2.5, pentaerythrite four (thylhexoic acid) ester 1.5, glycerin polyether -26 1.0, glyceryl stearate
Acid esters 0.9, tapioca 0.8, PEG-45 stearates 0.6, sucrose distearate 0.5, trehalose 0.5, double-two glycerine are more
Acyl group adipate ester -2 0.3, double-PEG-18 methyl ethers dimethylsilanes 0.3, cetanol 0.3,1,3- propane diols 0.27,1,2-
Hexylene glycol 0.2, carbomer 0.18, hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers 0.15, arginine 0.14,
Saualane 0.11, xanthans 0.08, tocopherol (vitamin E) 0.05, dipotassium glycyrrhizinate 0.05, polymethylsilsesquioxane
0.05, butanediol 0.04, decoyl hydroximic acid 0.03, polysorbate -60 0.02, Sodium Hyaluronate 0.01, EDETATE SODIUM
0.009, the smooth isostearate 0.006 of sorb, section shepherd's purse (CRAMBE ABYSSINICA) the seed oil 0.005, wineberry of deep-sea two
(VACCINIUM MYRTILLUS) seed oil 0.005, Pseudoalteromonas tunning extract 0.002, silver-colored 0.0001-
0.005, purslane (PORTULACA OLERACEA) extract 0.0006, adder-wort (POLYGONUM BISTORTA) root extract
0.0006, Mi Luomu (MYROTHAMNUS FLABELLIFOLIA) leaf/stem extraction 0.0003, hexylene glycol 0.0003, hydrolysis is planted
Thing albumen 0.0003, atriphos 0.0003, sodium chondroitin sulfate 0.0003, pungent glycol 0.0001, Denatonium Benzoate
0.0001, citric acid 0.00001-0.0002, ascorbic acid (vitamin C) 0.00001-0.0002, lichee (LITCHI
CHINENSIS) pericarp extract 0.00004, sodium hydroxide 0.00003, polyvinylpyrrolidone 0.00002, plus deionized water
To 100.(above-mentioned is grams g)
Preparation method：1st, component A raw material is weighed by formula【Water, propane diols, glycerine, 1,2- hexylene glycols, glycerin polyether -26,
Carbomer, xanthans, trehalose, EDETATE SODIUM】, aqueous phase pot is added, is heated to after 70-75 DEG C, stirs, vacuum breast is pumped into
In change machine；
2nd, B component raw material is weighed by formula【Carbonic acid dioctyl ester, Nexbase 2004, dimethyl silicone polymer, pentaerythrite four
(thylhexoic acid) ester, stearine SE, PEG-45 stearate, sucrose distearate, (hydroxy-ethyl acrylate/propylene
Acyl dimethyltaurine sodium copolymer, saualane, polysorbate -60, the smooth isostearate of sorb, water), double-PEG-18 first
Base ether dimethylsilane, cetanol, many acyl group adipate esters -2 of double-two glycerine, tocopherol (vitamin E), the section shepherd's purse of deep-sea two
(CRAMBE ABYSSINICA) seed oil, wineberry (VACCINIUM MYRTILLUS) seed oil】, oil phase pot is added, is heated to
70-75 DEG C, stir, be pumped into vacuum emulsifying machine；
3rd, start is uniformly mixed (about 30 minutes, 1000rpm/ points), stops stirring, is cooled to 40 DEG C；Add【(wood
Sweet potato starch, water, polymethylsilsesquioxane), (water, pungent glycol, Pseudoalteromonas tunning extract), (butanediol, litchi
Branch (LITCHI CHINENSIS) pericarp extract), arginine, (water, adder-wort (POLYGONUM BISTORTA) root extract,
Hexylene glycol, pungent glycol, xanthans), (water, 1,3- propane diols, ascorbic acid (vitamin C), Mi Luomu (MYROTHAMNUS
FLABELLIFOLIA) leaf/stem extraction, citric acid), (1,3- propane diols, decoyl hydroximic acid), (silver, water), (water, butanediol,
Purslane (PORTULACA OLERACEA) extract, silver), dipotassium glycyrrhizinate, Sodium Hyaluronate, (water, butanediol, hydrolysis plant
Thing albumen, atriphos, sodium chondroitin sulfate, sodium hydroxide, EDETATE SODIUM, polyvinylpyrrolidone), (water, platinum powder), benzene
First denatonium】, continue to stir, be cooled to room temperature；
4th, discharging is positioned in stainless steel material storage tube, as semi-finished product；
5th, it is filling using bottle placer after half examination and test of products is qualified, it is unqualified to destroy；
6th, pack, lot number is marked using ink jet numbering machine and the date is limited the use of, case to be checked；
7th, after product inspection is qualified, storage；It is unqualified to destroy.
Test method：Emulsion is taken, 40 DEG C of storage 24h is placed in, 24h is deposited in room temperature, then at -5 DEG C of storage 24h, is followed successively
Ring 3 times, has seen whether whether layering, oil slick, color and luster change.
Result of the test：It is shown in Table 1.
The stability test result of table 1
| Group | Whether it is layered | Whether oil slick | Whether color and luster changes |
| Control group | It is no | It is no | It is no |
| First group | It is | It is | It is no |
| Second group | It is no | It is no | It is no |
Conclusion (of pressure testing)：Stability test result shows：Control group does not add a nanometer platinum colloid, with preferable stable
Property, and first group of addition is tested after 1 group of nanometer platinum colloid, after thermal cycling test, has layering and oil slick phenomenon to produce,
Second group of emulsion is added after the nanometer platinum colloid of 2 groups of experiment, by thermal cycling test, stability and control group stability phase
Together, its reason is analyzed, it may be possible to caused by the crystal formation of nanometer platinum colloid is different, therefore, it is applicant's understanding that present invention process side
The nanometer platinum colloid that method is obtained is adapted to use in cosmetics.
2nd, facial mask stability test
First group of facial mask：Test 1 group of nanometer platinum colloid 0.002g, white fungus (TREMELLA FUCIFORMIS) extract
0.01g, silver-colored 0.0006g, decoyl hydroximic acid 0.033g, pungent glycol 0.0001g, Sodium Hyaluronate 0.005g, tamarind
(TAMARINDUS INDICA) seed glue 0.0003g, hydrolyzed vegetable protein 0.00025g, hydrolysis monkey-bread tree (ADANSONIA
DIGITATA) extract 0.0001g, hydrolyzes royal jelly albumen 0.0045g, section shepherd's purse (CRAMBE ABYSSINICA) seed of deep-sea two
Oily 0.005g, atriphos 0.00025g, sodium chondroitin sulfate 0.00025g, adder-wort (POLYGONUM BISTORTA) root are carried
Take thing 0.0003g, sodium hydroxide 0.00003g, wineberry (VACCINIUM MYRTILLUS) seed oil 0.005g, citric acid
0.000055g, Mi Luomu (MYROTHAMNUS FLABELLIFOLIA) leaf/stem extraction 0.0003g, purslane
(PORTULACA OLERACEA) extract 0.0006g, ascorbic acid (vitamin C) 0.000055g, polyvinylpyrrolidone
0.00002g, the 2g of polyethylene glycol -32, dimethyl silicone polymer 0.5g, arginine 0.08g, Pseudoalteromonas tunning is carried
Take thing 0.0025g, hexylene glycol 0.0003g, xanthans 0.000055g, glyceryl acrylate/acrylic copolymer 0.009g is sweet
Oily 4.2025g, butanediol 0.08175g, AVC 0.2g, acrylic acid (ester) class/C10-
30 alkylol acrylamide acid esters cross-linked polymer 0.11g, propane diols 5g, Denatonium Benzoate 0.00003g, EDETATE SODIUM 0.00001g, 1,
Ammediol 0.27384g, 1,2- pentanediol 0.00065g, 1,2- hexylene glycol 0.2g, plus deionized water is to 100g.
Preparation method：1st, component A raw material is weighed by formula【Water, glycerine, propane diols, polyethylene glycol -32,1,2- hexylene glycols,
AVC, acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymer, (water,
Glycerine, glyceryl acrylate/acrylic copolymer)】, aqueous phase pot is added, 75-80 DEG C is heated to, is pumped into vacuum emulsifying machine；
2nd, B component raw material is weighed by formula【Dimethyl silicone polymer, section shepherd's purse (CRAMBE ABYSSINICA) seed of deep-sea two
Oil, wineberry (VACCINIUM MYRTILLUS) seed oil】, oil phase pot is added, 65-70 DEG C is heated to, stirs, is pumped into
In vacuum emulsifying machine, after 3000-3500rpm emulsifyings 3-5 minutes, start cooling；
3rd, start is uniformly mixed (about 30 minutes, 1000rpm/ points), stops stirring, is cooled to 40 DEG C；Add【(water,
Adder-wort (POLYGONUM BISTORTA) root extract, hexylene glycol, pungent glycol, xanthans), arginine, (water, 1,3- propane diols,
Ascorbic acid (vitamin C), Mi Luomu (MYROTHAMNUS FLABELLIFOLIA) leaf/stem extraction, citric acid), (1,3-
Propane diols, decoyl hydroximic acid), (water, pungent glycol, Pseudoalteromonas tunning extract), (silver, water), (water, hydrolysis honeybee
Royal jelly protein, butanediol), (water, 1,2- pentanediols, tamarind (TAMARINDUS INDICA) seed glue), (water, butanediol, dent
Amaranth (PORTULACA OLERACEA) extract, silver), white fungus (TREMELLA FUCIFORMIS) extract, Sodium Hyaluronate,
(water, butanediol, hydrolyzed vegetable protein, atriphos, sodium chondroitin sulfate, sodium hydroxide, EDETATE SODIUM, polyvinyl pyrrole
Alkanone), (water, glycerine, hydrolysis monkey-bread tree (ADANSONIA DIGITATA) extract), (water, platinum powder), Denatonium Benzoate】,
Continue to stir, be cooled to room temperature；
4th, discharging is positioned in stainless steel material storage tube, as semi-finished product；
5th, it is filling using bottle placer after half examination and test of products is qualified, it is unqualified to destroy；
6th, pack, lot number is marked using ink jet numbering machine and the date is limited the use of, case to be checked；
7th, after product inspection is qualified, storage；It is unqualified to destroy.
Second group of facial mask：Test 2 groups of nanometer platinum colloid 0.002g, white fungus (TREMELLA FUCIFORMIS) extract
0.01g, silver-colored 0.0006g, decoyl hydroximic acid 0.033g, pungent glycol 0.0001g, Sodium Hyaluronate 0.005g, tamarind
(TAMARINDUS INDICA) seed glue 0.0003g, hydrolyzed vegetable protein 0.00025g, hydrolysis monkey-bread tree (ADANSONIA
DIGITATA) extract 0.0001g, hydrolyzes royal jelly albumen 0.0045g, section shepherd's purse (CRAMBE ABYSSINICA) seed of deep-sea two
Oily 0.005g, atriphos 0.00025g, sodium chondroitin sulfate 0.00025g, adder-wort (POLYGONUM BISTORTA) root are carried
Take thing 0.0003g, sodium hydroxide 0.00003g, wineberry (VACCINIUM MYRTILLUS) seed oil 0.005g, citric acid
0.000055g, Mi Luomu (MYROTHAMNUS FLABELLIFOLIA) leaf/stem extraction 0.0003g, purslane
(PORTULACA OLERACEA) extract 0.0006g, ascorbic acid (vitamin C) 0.000055g, polyvinylpyrrolidone
0.00002g, the 2g of polyethylene glycol -32, dimethyl silicone polymer 0.5g, arginine 0.08g, Pseudoalteromonas tunning is carried
Take thing 0.0025g, hexylene glycol 0.0003g, xanthans 0.000055g, glyceryl acrylate/acrylic copolymer 0.009g is sweet
Oily 4.2025g, butanediol 0.08175g, AVC 0.2g, acrylic acid (ester) class/C10-
30 alkylol acrylamide acid esters cross-linked polymer 0.11g, propane diols 5g, Denatonium Benzoate 0.00003g, EDETATE SODIUM 0.00001g, 1,
Ammediol 0.27384g, 1,2- pentanediol 0.00065g, 1,2- hexylene glycol 0.2g, plus deionized water is to 100g.
Preparation method：1st, component A raw material is weighed by formula【Water, glycerine, propane diols, polyethylene glycol -32,1,2- hexylene glycols,
AVC, acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymer, (water,
Glycerine, glyceryl acrylate/acrylic copolymer)】, aqueous phase pot is added, 75-80 DEG C is heated to, is pumped into vacuum emulsifying machine；
2nd, B component raw material is weighed by formula【Dimethyl silicone polymer, section shepherd's purse (CRAMBE ABYSSINICA) seed of deep-sea two
Oil, wineberry (VACCINIUM MYRTILLUS) seed oil】, oil phase pot is added, 65-70 DEG C is heated to, stirs, is pumped into
In vacuum emulsifying machine, after 3000-3500rpm emulsifyings 3-5 minutes, start cooling；
3rd, start is uniformly mixed (about 30 minutes, 1000rpm/ points), stops stirring, is cooled to 40 DEG C；Add【(water,
Adder-wort (POLYGONUM BISTORTA) root extract, hexylene glycol, pungent glycol, xanthans), arginine, (water, 1,3- propane diols,
Ascorbic acid (vitamin C), Mi Luomu (MYROTHAMNUS FLABELLIFOLIA) leaf/stem extraction, citric acid), (1,3-
Propane diols, decoyl hydroximic acid), (water, pungent glycol, Pseudoalteromonas tunning extract), (silver, water), (water, hydrolysis honeybee
Royal jelly protein, butanediol), (water, 1,2- pentanediols, tamarind (TAMARINDUS INDICA) seed glue), (water, butanediol, dent
Amaranth (PORTULACA OLERACEA) extract, silver), white fungus (TREMELLA FUCIFORMIS) extract, Sodium Hyaluronate,
(water, butanediol, hydrolyzed vegetable protein, atriphos, sodium chondroitin sulfate, sodium hydroxide, EDETATE SODIUM, polyvinyl pyrrole
Alkanone), (water, glycerine, hydrolysis monkey-bread tree (ADANSONIADIGITATA) extract), (water, platinum powder), Denatonium Benzoate】,
Continue to stir, be cooled to room temperature；
4th, discharging is positioned in stainless steel material storage tube, as semi-finished product；
5th, it is filling using bottle placer after half examination and test of products is qualified, it is unqualified to destroy；
6th, pack, lot number is marked using ink jet numbering machine and the date is limited the use of, case to be checked；
7th, after product inspection is qualified, storage；It is unqualified to destroy.
Test method：Facial mask is taken, 40 DEG C of storage 24h is placed in, 24h is deposited in room temperature, then at -5 DEG C of storage 24h, is followed successively
Ring 3 times, has seen whether whether layering, oil slick, color and luster change.
Result of the test：It is shown in Table 2.
The stability test result of table 2
| Group | Whether it is layered | Whether oil slick | Whether color and luster changes |
| Control group | It is no | It is no | It is no |
| First group | It is | It is | It is no |
| Second group | It is no | It is no | It is no |
Conclusion (of pressure testing)：Facial mask result of the test is identical with Emulsion Test result, further illustrates prepared by present invention process method
Nanometer platinum colloid can be used in cosmetics.
2nd, Oxidation Resistance Test
Test 1 group：0.1mol potassium chloroplatinates are taken, deionized water 10mL is added, are well mixed, KBr 6.6mol is added,
Stirring 1 hour, then adds polyvinylpyrrolidone 1mol, reaction solution is entered in reactor, started to warm up, to after 130 DEG C
Continue to react 3h, be cooled to 20-25 DEG C, obtain a nanometer platinum colloid.Using nano-particle size analysis instrument (Photon
Correlation Spectroscopy, INSTRUMENT MODEL：Zetasizer Nano S, manufacturer：Malvern companies of Britain)
Platinum size distribution is analyzed in more than 0.1-100nm, 90% platinum size distributions in 1-10nm.
Test 2 groups：0.1mol potassium chloroplatinates are taken, deionized water 10mL is added, are well mixed, KBr 6.6mol is added,
Stirring 1 hour, then adds polyvinylpyrrolidone 1mol, reaction solution is entered in reactor, started to warm up, to after 130 DEG C
Continue to react 3h, be cooled to 85 DEG C, place 30 minutes, be cooled to 45 DEG C, add L-arginine 0.02mol, place 20 minutes, drop
Temperature obtains a nanometer platinum colloid to 25 DEG C.Using nano-particle size analysis instrument (Photon Correlation Spectroscopy,
INSTRUMENT MODEL：Zetasizer Nano S, manufacturer：Malvern companies of Britain) platinum size distribution is analyzed in 0.1-
100nm, more than 90% platinum size distribution is in 1-10nm.
Test method：Antioxidation activity is represented with scavenging ability of DPPH free radical size.Take 1 group of experiment, 2 groups of nanometers of experiment
Each 0.05g of sample of platinum colloid, and Co-Q10 0.05g, add 15mL1.52 × 10-4Mmol/L DPPH absolute ethyl alcohols
Solution is fully mixed, and room temperature lucifuge is stood after 30min, using solvent as blank control, and absorbance A 1 is surveyed at 517nm；With same volume
Solvent does negative control instead of sample solution, determines absorbance A 2；Blank group is done instead of DPPH solution with same volume absolute ethyl alcohol,
Determine absorbance A 3.Using Co-Q10 as control, every group is done 3 repetitions, seeks its average value.Clearance rate is calculated as follows：
Clearance rate (%)=[1- (A1-A3)/A2] × 100% of the sample to DPPH.
Conclusion (of pressure testing) is shown in Table 3.
Influence of the table 3 to DPPH free radical scavenging activities
Conclusion (of pressure testing)：Oxidation Resistance Test shows that the crystal formation of nanometer platinum colloid is different, and oxidation resistance is significantly different, this
The nanometer platinum colloid antioxidant effect of invention is 1 group more than 1.5 times of experiment.
Prepare embodiment
Embodiment 1
A kind of cosmetics, contain nanometer platinum colloid；
Nanometer platinum colloid preparation method be：
Potassium chloroplatinate 1mol is taken, deionized water 100mL is added, is well mixed, KBr 66mol is added, stirring 0.5 is small
When, polyvinylpyrrolidone 10mol is then added, reaction solution is entered in reactor, started to warm up, continues anti-afterwards to 130 DEG C
Answer 3h；80 DEG C are cooled to, is placed 40 minutes, 40 DEG C are cooled to, L-arginine 0.15mol is added, places 15 minutes, is cooled to 25
DEG C, obtain a nanometer platinum colloid.
Using nano-particle size analysis instrument (Photon Correlation Spectroscopy, INSTRUMENT MODEL：Zetasizer
Nano S, manufacturer：Malvern companies of Britain) platinum size distribution is analyzed in more than 0.1-100nm, 70% platinum granularities
It is distributed in 1-10nm.
Embodiment 2
A kind of cosmetics, contain nanometer platinum colloid；
Nanometer platinum colloid preparation method be：
1mol potassium chloroplatinates are taken, deionized water 100mL is added, are well mixed, KBr 66mol is added, stirred 1 hour,
Then polyvinylpyrrolidone 10mol is added, reaction solution is entered in reactor, started to warm up, continues to react afterwards to 130 DEG C
3h, is cooled to 85 DEG C, places 30 minutes, is cooled to 45 DEG C, adds L-arginine 0.2mol, places 20 minutes, is cooled to 25 DEG C,
Obtain a nanometer platinum colloid.Using nano-particle size analysis instrument (Photon Correlation Spectroscopy, INSTRUMENT MODEL：
Zetasizer Nano S, manufacturer：Malvern companies of Britain) analysis platinum size distribution in 0.1-100nm, 90% with
Upper platinum size distribution is in 1-10nm.
Embodiment 3
A kind of cosmetics, contain nanometer platinum colloid；
Nanometer platinum colloid preparation method be：
Potassium chloroplatinate 1mol is taken, deionized water 100mL is added, is well mixed, KBr 66mol is added, stirred 2 hours,
Then polyvinylpyrrolidone 10mol is added, reaction solution is entered in reactor, started to warm up, continues to react afterwards to 130 DEG C
3h；90 DEG C are cooled to, is placed 20 minutes, 50 DEG C are cooled to, L-arginine 0.35mol is added, places 25 minutes, is cooled to 20
DEG C, obtain a nanometer platinum colloid.Using nano-particle size analysis instrument (Photon Correlation Spectroscopy, instrument type
Number：Zetasizer Nano S, manufacturer：Malvern companies of Britain) platinum size distribution is analyzed in 0.1-100nm, 75%
Above platinum size distribution is in 1-10nm.
Embodiment 1-3 nanometer platinum colloid, can be used in cosmetics, include but is not limited to：Toner, skin care milk
Liquid, face cream, facial mask, elite, face cleaning cream, mildy wash, face cleaning jelly, face cleaning foam, makeup remover, foundation cream, muffin, lipstick.
Embodiment 4
The parts by weight of facial treatment milk are constituted：Embodiment 1 nanometer of platinum colloid 0.01g, olive oil 20g, lipoic acid 0.1g,
Dipotassium glycyrrhizinate 0.1g, citric acid 0.1g, stearic acid 8.0g, Chinese wax 10.0g, borax 0.5-g, lecithin 1.0g, methyl is different
Thiazolinone 0.1g, Sensiva SC50 0.1g, plus deionized water is to 100g.
Preparation method：(1) a nanometer platinum colloid is taken, is added in olive oil, is shaken 30 minutes at 35 DEG C, makes a nanometer platinum
Colloid is substantially dissolved in olive oil；(2) oiliness such as Chinese wax raw material is added into emulsification pot, stirring is warming up to 60 degrees Celsius, guarantor
Temperature stirring 20 minutes (3) adds olive oil nanometer platinum colloid in oil phase, insulated and stirred 20 minutes；(4) by water and aqueous original
Material is heated to 60 degree, meanwhile, it is slowly added to melt in the reactor of oiliness raw material, uses homogeneous emulsifying machine stirring and emulsifying, continue to stir
Mix cooling, you can.
Embodiment 5
The parts by weight of facial treatment milk are constituted：Embodiment 2 nanometers of platinum colloid 0.05g, olive oil 25g, lipoic acid 0.3g,
Dipotassium glycyrrhizinate 0.3g, citric acid 0.25g, stearic acid 10g, Chinese wax 13g, borax 0.8g, lecithin 2g, methylisothiozoline
Ketone 0.15g, Sensiva SC50 0.15g, plus deionized water is to 100g.
Preparation method：(1) a nanometer platinum colloid is taken, is added in olive oil, is shaken 30 minutes at 35 DEG C, makes a nanometer platinum
Colloid is substantially dissolved in olive oil；(2) oiliness such as Chinese wax raw material is added into emulsification pot, stirring is warming up to 60 degrees Celsius, guarantor
Temperature stirring 20 minutes (3) adds olive oil nanometer platinum colloid in oil phase, insulated and stirred 20 minutes；(4) by water and aqueous original
Material is heated to 60 degree, meanwhile, it is slowly added to melt in the reactor of oiliness raw material, uses homogeneous emulsifying machine stirring and emulsifying, continue to stir
Mix cooling, you can.
Embodiment 6
The parts by weight of facial treatment milk are constituted：Embodiment nanometer platinum colloid 0.1g, olive oil 40g, lipoic acid 0.5g are sweet
Oxalic acid dipotassium 0.5g, citric acid 0.5g, stearic acid 12g, Chinese wax 15.0g, borax 1.0g, lecithin 3.0g, methyl-isothiazol
Quinoline ketone 0.2g, Sensiva SC50 0.2g, plus deionized water is to 100g.
Preparation method：(1) a nanometer platinum colloid is taken, is added in olive oil, is shaken 30 minutes at 35 DEG C, makes a nanometer platinum
Colloid is substantially dissolved in olive oil；(2) oiliness such as Chinese wax raw material is added into emulsification pot, stirring is warming up to 60 degrees Celsius, guarantor
Temperature stirring 20 minutes (3) adds olive oil nanometer platinum colloid in oil phase, insulated and stirred 20 minutes；(4) by water and aqueous original
Material is heated to 60 degree, meanwhile, it is slowly added to melt in the reactor of oiliness raw material, uses homogeneous emulsifying machine stirring and emulsifying, continue to stir
Mix cooling, you can.
Embodiment 7
The parts by weight of facial mask are constituted：Embodiment 1 nanometer of platinum colloid 0.02g, olive oil 6g, lipoic acid 0.2g, nicotinoyl
Amine 0.15g, beta glucan 0.15g, vitamin B60.15g, vitamin C 1.5g, vitamin B20.2g, dipotassium glycyrrhizinate
0.2g, citric acid 0.2g, vitamin E 0.8g, 1,2-PD 6g, 1,3-BDO 2g, polyglutamic acid 3.5g, ethoxy are fine
Tie up element 0.15g, glycerine polymethacrylates/1,2-PD/Gantrez AN-119 4.5g, triethanolamine 0.2g, sodium lactate
1.5g, Phenoxyethanol 0.1g, Sensiva SC50 0.1g, plus deionized water is to 100g.
Preparation method：(1) by water, 1,3-BDO, polyglutamic acid, hydroxyethyl cellulose and water mixing are heated to 85 DEG C,
Dissolving is complete；(2) olive oil is added, triethanolamine, glycerine polymethacrylates/propane diols/PVM/MA are added at 50 DEG C
Copolymer, sodium lactate, niacinamide usp, beta glucan, lipoic acid, dipotassium glycyrrhizinate, stirring is to being completely dissolved；Less than (3) 45 DEG C add
Enter vitamin C, vitamin B6, citric acid, Phenoxyethanol, other raw materials such as Sensiva SC50, stirring is to being completely dissolved；(4)
Let cool, filter, pour into infused film cloth in the container equipped with facial present situation bonded fabric, packed after infiltration.
Embodiment 8
The parts by weight of facial mask are constituted：Nanometer platinum colloid 0.05g, olive oil 8g, lipoic acid 0.25g, niacinamide
0.25g, beta glucan 0.25g, vitamin B60.25g, vitamin C 2g, vitamin B20.25g, dipotassium glycyrrhizinate 0.25g,
Citric acid 0.25g, vitamin E 1.2g, 1,2-PD 8g, 1,3-BDO 2.5g, polyglutamic acid 4g, hydroxyethyl cellulose
0.2g, glycerine polymethacrylates/1,2-PD/Gantrez AN-119 6g, triethanolamine 0.25g, sodium lactate 2.5g, benzene
Oxyethanol 0.2g, Sensiva SC50 0.2g, plus deionized water is to 100g.
Preparation method：(1) by water, 1,3-BDO, polyglutamic acid, hydroxyethyl cellulose and water mixing are heated to 85 DEG C,
Dissolving is complete；(2) add olive oil, added at 50 DEG C triethanolamine, glycerine polymethacrylates/1,2-PD/
Gantrez AN-119, sodium lactate, niacinamide usp, beta glucan, lipoic acid, dipotassium glycyrrhizinate, stirring is to being completely dissolved；(3)45℃
Vitamin C, vitamin B are added below6, citric acid, Phenoxyethanol, other raw materials such as Sensiva SC50, stirring is to completely molten
Solution；(4) let cool, filter, pour into infused film cloth in the container equipped with facial present situation bonded fabric, packed after infiltration.
Embodiment 9
The parts by weight of facial mask are constituted：Embodiment 3 nanometers of platinum colloid 0.09g, olive oil 9.5g, lipoic acid 0.4g, cigarette
Acid amides 0.4g, beta glucan 0.45g, vitamin B60.45g, vitamin C 2.5g, vitamin B20.45g, dipotassium glycyrrhizinate
0.45g, citric acid 0.45g, vitamin E 1.8g, 1,2-PD 9.5g, 1,3-BDO 4.5g, polyglutamic acid 4.5g, hydroxyl
Ethyl cellulose 0.25g, glycerine polymethacrylates/1,2-PD/Gantrez AN-119 7.5g, triethanolamine 0.45g,
Sodium lactate 3.0g, Phenoxyethanol 0.25g, Sensiva SC50 0.25g, plus deionized water is to 100g.
Preparation method：(1) by water, 1,3-BDO, polyglutamic acid, hydroxyethyl cellulose and water mixing are heated to 85 DEG C,
Dissolving is complete；(2) add olive oil, added at 50 DEG C triethanolamine, glycerine polymethacrylates/1,2-PD/
Gantrez AN-119, sodium lactate, niacinamide usp, beta glucan, lipoic acid, dipotassium glycyrrhizinate, stirring is to being completely dissolved；(3)45℃
Vitamin C, vitamin B are added below6, citric acid, Phenoxyethanol, other raw materials such as Sensiva SC50, stirring is to completely molten
Solution；(4) let cool, filter, pour into infused film cloth in the container equipped with facial present situation bonded fabric, packed after infiltration.
1st, stability test：
Test method：The emulsion of Example 4- embodiments 6, Example 7-9 facial masks are respectively placed in 40 DEG C of storage 24h, in
Room temperature deposits 24h, then at -5 DEG C of storage 24h, circulates 3 times successively, has seen whether whether layering, oil slick, color and luster change.
Result of the test is shown in Table 4.
The stability test result of table 4
Conclusion (of pressure testing)：Stability test shows that emulsion or facial mask of the invention has good stability.
2nd, hydroxyl radical free radical activity test is removed
Test method：Antioxidation activity is represented with removing hydroxyl radical free radical capacity of water.By 15mL1.8mol/L salicylic acids
Solution and 20mL1.8mol/L FeSO4After solution is mixed in triangular flask (500ml), 100g embodiment 5, reality is separately added into
The sample of example 10 (not pouring into before film cloth) is applied, 1mL0.03%H is then added2O2, shake up, 30min, 510nm be incubated in 37 DEG C
Place measures sample sets absorbance A i；Simultaneously by H in sample sets2O2Change 1mL distilled water into, measure sample reference group absorbance A j；Will
Sample changes same volume solvent into sample sets, measures blank group absorbance A 0.It is control with Co-Q10 (0.05g), every group is done 3
Individual repetition, seeks its average value.Clearance rate is calculated as follows：
OH clearance rates (%)=[A0- (Ai-Aj)]/A0 × 100%.
Result of the test is shown in Table 5.
Influence of the table 5 to hydroxyl radical free radical clearance rate
Conclusion (of pressure testing)：In the cosmetics that the nanometer platinum colloid of the present invention is added, with more preferable antioxidation.
Prepare embodiment including but not limited to above-mentioned.
Claims (10)
1. a kind of cosmetic composition, it is characterised in that contain nanometer platinum in said composition.
2. a kind of cosmetic composition according to claim 1, wherein cosmetic composition includes：Toner, skin care milk
Liquid, face cream, facial mask, elite, face cleaning cream, mildy wash, face cleaning jelly, face cleaning foam, makeup remover, foundation cream, muffin, lipstick.
3. a kind of cosmetic composition according to claim 1, wherein nanometer platinum are 1-100nm.
4. a kind of cosmetic composition according to claim 1, wherein nanometer platinum 1-10nm.
5. a kind of cosmetic composition according to claim 1 or 2, wherein composition contain a nanometer platinum colloid.
6. a kind of cosmetic composition according to claim 5, it is characterised in that the preparation method of nanometer platinum colloid is：
Potassium chloroplatinate is taken, deionized water is added, is well mixed, KBr is added, stirs 0.5-2 hours, then adds polyethylene
Pyrrolidones, reaction solution is entered in reactor, is started to warm up, and continues to react 3h afterwards to 130 DEG C；It is cooled to 80-90 DEG C, placement
20-40 minutes, 40-50 DEG C is cooled to, L-arginine is added, is placed 15-25 minutes, is cooled to 20-25 DEG C, obtains a nanometer platinum
Colloid.
7. a kind of cosmetic composition according to claim any one of 1-6, wherein nanometer platinum colloid is in cosmetics group
Polymer weight percentage is 0.01%-1%.
8. a kind of cosmetic composition according to claim any one of 1-6, wherein nanometer platinum colloid is in cosmetics group
Polymer weight percentage is 0.05-0.2%.
9. a kind of cosmetic composition according to claim any one of 1-6, it is characterised in that：The wherein weight of facial treatment milk
Amount part, which constitutes, is：Nanometer platinum colloid 0.001-0.03, propane diols 4-8, glycerine 2-6, carbonic acid dioctyl ester 1-5, Nexbase 2004
1-4, dimethyl silicone polymer 1-4, pentaerythrite four (thylhexoic acid) ester 1-3, glycerin polyether -260.5-2.5, glycerol stearate
Ester 0.1-1.5, tapioca 0.1-1.5, PEG-45 stearate 0.1-1.5, sucrose distearate 0.1-1.0, trehalose
0.1-1.0, double many 0.1-1.0 of acyl group adipate ester -2 of-two glycerine, double-PEG-18 methyl ethers dimethylsilane 0.1-1.0, whale
Ceryl alcohol 0.1-1.0,1,3- propane diols 0.1-1.0,1,2- hexylene glycol 0.1-1.0, carbomer 0.1-0.5, hydroxy-ethyl acrylate/the third
Alkene acyl dimethyltaurine sodium copolymer 0.1-0.5, arginine 0.1-0.5, saualane 0.1-0.5, xanthans 0.01-0.2 are raw
Educate phenol (vitamin E) 0.01-0.2, dipotassium glycyrrhizinate 0.01-0.2, polymethylsilsesquioxane 0.01-0.2, butanediol 0.01-
0.2, decoyl hydroximic acid 0.01-0.2, the 0.01-0.2 of polysorbate -60, Sodium Hyaluronate 0.01-0.1, EDETATE SODIUM
0.001-0.05, the smooth isostearate 0.001-0.05 of sorb, section shepherd's purse (CRAMBE ABYSSINICA) the seed oil 0.001- of deep-sea two
0.05, wineberry (VACCINIUM MYRTILLUS) seed oil 0.001-0.05, Pseudoalteromonas tunning extract
0.001-0.05, silver-colored 0.0001-0.005, purslane (PORTULACA OLERACEA) extract 0.0001-0.005, adder-wort
(POLYGONUM BISTORTA) root extract 0.0001-0.005, Mi Luomu (MYROTHAMNUS FLABELLIFOLIA) leaf/
Stem extraction 0.0001-0.005, hexylene glycol 0.0001-0.005, hydrolyzed vegetable protein 0.0001-0.005, atriphos
0.0001-0.005, sodium chondroitin sulfate 0.0001-0.005, pungent glycol 0.0001-0.005, Denatonium Benzoate 0.0001-
0.005, citric acid 0.00001-0.0002, ascorbic acid (vitamin C) 0.00001-0.0002, lichee (LITCHI
CHINENSIS) pericarp extract 0.00001-0.0002, sodium hydroxide 0.00001-0.0002, polyvinylpyrrolidone
0.00001-0.0002, plus deionized water is to 100.
10. a kind of cosmetic composition according to claim any one of 1-6, it is characterised in that：The wherein weight of facial mask
Part constitutes：Nanometer platinum colloid 0.001-0.03, white fungus (TREMELLA FUCIFORMIS) extract 0.001-0.1, silver
0.0001-0.005, decoyl hydroximic acid 0.01-0.1, pungent glycol 0.0001-0.002, Sodium Hyaluronate 0.001-0.01, tamarind
(TAMARINDUS INDICA) seed glue 0.0001-0.002, hydrolyzed vegetable protein 0.0001-0.002, hydrolyze monkey-bread tree
(ADANSONIA DIGITATA) extract 0.0001-0.002, hydrolyzes royal jelly albumen 0.001-0.01, the section shepherd's purse of deep-sea two
(CRAMBE ABYSSINICA) seed oil 0.001-0.02, atriphos 0.0001-0.002, sodium chondroitin sulfate 0.0001-
0.002, adder-wort (POLYGONUM BISTORTA) root extract 0.0001-0.002, sodium hydroxide 0.00001-0.0002, Europe
Continent blueberry (VACCINIUM MYRTILLUS) seed oil 0.001-0.02, citric acid 0.00001-0.0002, Mi Luomu
(MYROTHAMNUS FLABELLIFOLIA) leaf/stem extraction 0.0001-0.002, purslane (PORTULACA OLERACEA)
Extract 0.0001-0.002, ascorbic acid (vitamin C) 0.00001-0.0002, polyvinylpyrrolidone 0.00001-
0.0002, the 0.5-4.0 of polyethylene glycol -32, dimethyl silicone polymer 0.1-2.0, arginine 0.01-1.0, Pseudoalteromonas
Tunning extract 0.001-0.03, hexylene glycol 0.0001-0.02, xanthans 0.00001-0.0002, glyceryl acrylate/
Acrylic copolymer 0.0001-0.005, glycerine 2-8, butanediol 0.01-1.0, AVC
0.1-2.0, acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymer 0.01-1.0, propane diols 2-8, benzene first ground that
Ammonium 0.00001-0.0002, EDETATE SODIUM 0.00001-0.0002,1,3-PD 0.1-2.0,1,2- pentanediol 0.0001-
0.002,1,2- hexylene glycol 0.1-2.0, plus deionized water is to 100.
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| CN107951730A (en) * | 2018-01-11 | 2018-04-24 | 江西登云健康美业互联有限公司 | Application of the nanometer gold in face cream and the face cream that is made from it and preparation method thereof |
| CN108272680A (en) * | 2018-03-28 | 2018-07-13 | 广州科玛大健康产业有限公司 | It is a kind of to repair tender skin jelly film and preparation method thereof |
| CN108309839A (en) * | 2018-04-23 | 2018-07-24 | 广州赛莱拉干细胞科技股份有限公司 | Composition containing coral algae extract and its cosmetics |
| GB2571416A (en) * | 2017-12-21 | 2019-08-28 | Henkel Ag & Co Kgaa | Hair oils for conditioning keratin fibres |
| US11179781B2 (en) | 2018-10-15 | 2021-11-23 | Tripod Nano Technology Corporation | Method of making colloidal platinum nanoparticles |
| CN113747949A (en) * | 2019-04-26 | 2021-12-03 | 大塚制药株式会社 | O/W type low viscosity emulsified composition containing adenosine phosphate |
| CN115737499A (en) * | 2022-11-18 | 2023-03-07 | 杭州心悦化妆品有限公司 | Self-heating type moistening and moisturizing bath oil and preparation method thereof |
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| SE544655C2 (en) * | 2020-11-18 | 2022-10-04 | Lantmaennen Oats Ab | Anti-microbial skin-care composition comprising beta-glucan, hydrogen peroxide and lactic acid |
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| CN106963658B (en) | 2018-04-10 |
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Address after: Panyu District Hualong Town Guangzhou city Guangdong province 511434 Liu Wai Street No. 13 (No. 1 building) Patentee after: Hua An Tang biotech Group Co., Ltd. Address before: Panyu District Hualong Town Guangzhou city Guangdong province 511434 Liu Wai Street No. 13 (No. 1 building) Patentee before: City flower An Tang bio tech ltd, Guangzhou |
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