CN1069626A - A kind of fruit trees water retaining and antifreezing agent and production and preparation method thereof - Google Patents
A kind of fruit trees water retaining and antifreezing agent and production and preparation method thereof Download PDFInfo
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- CN1069626A CN1069626A CN 91105998 CN91105998A CN1069626A CN 1069626 A CN1069626 A CN 1069626A CN 91105998 CN91105998 CN 91105998 CN 91105998 A CN91105998 A CN 91105998A CN 1069626 A CN1069626 A CN 1069626A
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- agent
- fruit trees
- water retaining
- antifreezing
- trees water
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Abstract
The present invention proposes a kind of protective plant safe overwintering; avoid plant fruit trees water retaining and antifreezing agent of stripping death and production and preparation method thereof to occur, by the emulsification fruit trees water retaining and antifreezing agent of making in proportion of pertroleum wax, mineral oil, natural resin, gelating agent, compound emulsifying agent and water.Use this water retaining and antifreezing agent can prevent stripping and freeze injury effectively.
Description
Doing cold windy area, especially during the Winter-Spring joins in the winter time, plant begins to sprout, quickened the moisture transpiration effect of self, and the soil frozen soil layer does not thaw as yet fully, and this moment, root system of plant can only absorb small amount of moisture, even was difficult to absorb moisture, caused moisture disequilibrium in the plant thus, physiological drought occurs, and then stripping, the lighter's undergrowth take place, tree-like disorder, postpone the fruiting period of fruit tree, the whole strain of weight person is withered, for living fruit tree and forest of less developed low year of root system, situation is particularly serious, and Here it is does the low main cause of sapling survival rate in cold windy area fruit growing and the afforestation.
For protective plant is avoided the influence of climatic factor, Russian Patent SU483859 discloses and has a kind ofly mixed as the fruit tree protective coating with petrolatum (64-66%wt) and low melt wax (34-36%wt), because it must the heat coating, and the field operation inconvenience.Japan Patent J4812768 discloses the emulsifying wax of being made up of paraffin, petrolatum, emulsifier and water, and is bad to the plant surface tack because of its not gelation processing, is difficult to form the uniform film of thickness.Japan Patent J4612926 adopts and to add divalent metal salt in the emulsion or cationic surfactant is realized gelation, but solid content matter content is at 2%(wt) below, transportation and store comparatively difficult.Deutsches Wirtschafts Patent DD-214518 and Japan Patent J61212231 then adopt special mineral wax (montanin wax) or vegetable wax (Ka Naba wax) to make raw material, do not possess universal significance, and preparation is complicated, and cost is also high.
It is strong to the objective of the invention is to propose a kind of adhesiveness, and film forming is even, easy to use, with low cost, makes easy agent of fruit trees water retaining and antifreezing and method of manufacture and use thereof with extensive raw material sources.
The composition of the fruit trees water retaining and antifreezing agent that the present invention proposes is: (percentage by weight, down together)
The 8-45% pertroleum wax
1.5-8.5% mineral oil
The 0.1-1.8% gelating agent
The 5-40% natural resin
The 1-10% compound emulsifying agent
Excess water
The agent of fruit trees water retaining and antifreezing preferably is made up of following:
8-40% paraffin (fusing point 52-60 ℃) or ceresine (dropping point 67-80 ℃) or the mixture of the two with microstructure;
1.5-8% sweat oil, 20# machinery oil, 40# machinery oil or their mixture;
The gelating agent that 0.5-1.6% aliphatic amine, acid amides or their mixture are formed;
The natural resin that 5-35% rosin, hydrogenated rosin or their mixture are formed;
The compound emulsifying agent that 2-10% is made up of anion surfactant and non-ionic surface active agent.Wherein anion surfactant is preferentially recommended with C
5-C
30Saturated or unsaturated fatty acid or their mixture are formed; Non-ionic surface active agent is preferentially recommended with C
8-C
28The contract mixture of oxygen ether or derivatives thereof of fatty alcohol form.
Surplus is a water, recommends to use soft water, but optional.
The preparation method of fruit trees water retaining and antifreezing of the present invention agent carries out under heating condition, in order with the 8-40% pertroleum wax, 1.5-8% mineral oil, the 1.5-1.6% gelating agent, the 5-35% natural resin, the 2-10% compound emulsifying agent drops in stainless steel or the enamel hybrid reaction jar, temperature preferably is controlled between 60-140 ℃, through mixing reaction after about 1-3 hour, its adding is equipped with in the stainless steel or enamel mechanical agitation emulsifier or homogenizer or colloid mill or ultrasonic emulsator of 50-100 ℃ of water, emulsification 0.5-5 hour, is cooled to room temperature then, aging through 10-20 hour again, can produce fruit trees water retaining and antifreezing of the present invention agent.
Fruit trees water retaining and antifreezing of the present invention agent adopts the wide pertroleum wax in source to make main raw material, thereby with low cost; Adopt compound emulsifying agent, thereby average grain diameter is less than 1 μ m, maximum particle diameter is no more than 3 μ m, good stability, and leaving standstill did not still influence result of use in 1 year, good with the water affinity, need not to prepare specially deionized water, and available various natural waters directly dilute use; Adopt mineral oil and natural resin that pertroleum wax has been carried out modification, and carried out the gelation processing, thereby adhesivity is strong, good film-forming property very easily attached on the fruit trees surface, forms uniform film.Adopted the emulsifying technology processing, thereby can spray with various Spray painting tools easily or be coated with.
Be described more specifically the present invention with embodiment below.
Embodiment 1
The paraffin that 15.0% fusing point is 54 ℃ (percentage by weight, down together)
1.0% sweat oil
0.8 20# machinery oil
0.3 the CD-10(lauric acid acyl diethanolamine)
0.2% diethanol amine
10.0% hydrogenated rosin
2.0% cocinic acid
3.0% 0-20(lauric acid and ethylene oxide condensate)
The 1.0% octadecyl fatty alcohol oxygen ether that contracts
120 ℃ of its addings are had in the stainless steel or enamel reaction mixer of agitator by tab sequential, through stirring reaction about 2.5 hours, after mixing, excess water is equipped with in its adding, temperature is that about 4 hours of emulsification is cooled to room temperature then in 85-95 ℃ the stainless steel machinery stirring and emulsifying device, aging about 20 hours again, promptly make a kind of fruit trees water retaining and antifreezing of the present invention agent.
Embodiment 2
The paraffin that 12.0% fusing point is 58 ℃
67 ℃ of ceresine of 7.0% dropping point with microstructure
1.5% sweat oil
0.5% LOM-11(coconut acyl list diethanol amine)
0.2% triethanolamine
10.0% rosin
1.2 the condensation product of MOA(fatty alcohol and oxirane)
6.8% gaidic acid
The 0.9% cetyl fatty alcohol oxygen ether that contracts
Excess water is pressed embodiment 1 described method manufacturing, and different is that emulsion process was formed by colloid mill emulsification in 2.5 hours.
Embodiment 3
75 ℃ of ceresine of 22.0% dropping point
2.0% sweat oil
1.3% 20# machinery oil
4.5% 40# machinery oil
0.3 the two diethanol amine of NIL-12(lauric acid)
1.2% BS-12
3.0% hydrogenated rosin
5.0% rosin
2.0% octadecanoid acid
6.0% gaidic acid
1.0% 0-10(fatty alcohol and ethylene oxide condensate)
0.3% anhydrous sorbitol olein APEO
Excess water is pressed embodiment 1 described method manufacturing, and different is that emulsion process was formed by homogenizer emulsification in 1.5 hours.
Embodiment 4
54 ℃ of paraffin of 8.0% fusing point
60 ℃ of paraffin of 2.5% fusing point
67 ℃ of ceresine of 3.0% dropping point
75 ℃ of ceresine of 13.0% dropping point
3.5% sweat oil
1.5% 40# machinery oil
1.0% LOM-11(coconut acyl list diethanol amine)
0.3% NIL-11(lauroyl list diethanol amine)
0.1% pair of oxygen azo-cycle hexane
10.0% rosin
1.0% hydrogenated rosin
4.5% octadecanoid acid
2.5% SA-20(fatty alcohol and ethylene oxide condensate)
1.0% OS-15(fatty alcohol and ethylene oxide condensate)
Excess water, according to embodiment 1 described method manufacturing, different is that emulsion process adopts ultrasonic emulsification to form in 1 hour.
With fruit trees water retaining and antifreezing of the present invention agent in treelet fallen leaves back or before germinateing next year with after the 5-10 times of water dilution, directly spray or coat the treelet surface, prevent stripping and freeze injury to have positive effect to treelet.
Following result of the test is used for illustrating the applicable cases of embodiment.
The fruit trees water retaining and antifreezing agent application result of embodiment 1 manufacturing is as follows: (to biennial fuji apple sapling)
Annotate: 1,0 grade of branch is drained based on nothing, grows normal;
1 grade of branch drains 1/5;
2 grades of branches drain 2/5;
3 grades of branches drain 1/2;
4 grades of branches are all drained basically.
2, stripping index (%)=(∑ (progression * branch number))/(highest number * total branch number) * 100%
3, same under the stripping Index for Calculation.
The fruit trees water retaining and antifreezing agent application result of embodiment 2 manufacturings is as follows: (Huang is revealed the peach treelet)
The fruit trees water retaining and antifreezing agent application result of embodiment 3 manufacturings is as follows: (influence of Huang being revealed the peach bud freeze injury)
The fruit trees water retaining and antifreezing agent application result of embodiment 4 manufacturings is as follows:
Influence for biennial apple sapling stripping
Influence for serious 3 years green apple treelet strippings of big green leafhopper harm:
Claims (9)
1, a kind of fruit trees water retaining and antifreezing agent that is used to regulate the plant surface transpiration by: pertroleum wax, mineral oil, compound emulsifying agent and water are formed, and it is characterized in that also containing: natural resin and gelating agent.Characteristic formula is as follows: (percentage by weight)
Pertroleum wax 8-45%
Mineral oil 1.5-8.5%
Gelating agent 0.1-1.8%
Natural resin 5-40%
Compound emulsifying agent 1-10%
Water surplus
2, it is characterized in that according to the agent of the described fruit trees water retaining and antifreezing of claim 1 said pertroleum wax is: paraffin, ceresine or the mixture of the two.
3, it is characterized in that according to the agent of the described fruit trees water retaining and antifreezing of claim 1 said mineral oil is sweat oil, machinery oil or the mixture of the two.
4, it is characterized in that according to the agent of the described fruit trees water retaining and antifreezing of claim 1 said gelating agent is: aliphatic amine, acid amides or the mixture of the two.
5, it is characterized in that according to the agent of the described fruit trees water retaining and antifreezing of claim 1 said natural resin is: rosin, hydrogenated rosin or the two mixture.
6, it is characterized in that according to the agent of the described fruit trees water retaining and antifreezing of claim 1 said compound emulsifying agent is: form by anion surfactant and non-ionic surface active agent.
7, a kind of fruit trees water retaining and antifreezing agent manufacture method is characterized in that: under 60-140 ℃ of condition, with the fusing earlier of pertroleum wax, mineral oil, gelating agent, natural resin and compound emulsifying agent, mix with 50-100 ℃ of water after hybrid reaction 1.0-3.0 hour and carry out emulsification 0.5-5 hour, and be cooled to room temperature, aging through 10-25 hour again.
8, in accordance with the method for claim 7, can adopt mechanical agitation, homogenizer homogenizing, colloid mill or ultrasonic emulsification.
9, the using method of a kind of fruit trees water retaining and antifreezing agent is characterized in that the agent of fruit trees water retaining and antifreezing is sprayed or coated the surface of plant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91105998 CN1033199C (en) | 1991-08-29 | 1991-08-29 | A moisture-retentive freeze-proof agent for fruit tree and its production and use method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91105998 CN1033199C (en) | 1991-08-29 | 1991-08-29 | A moisture-retentive freeze-proof agent for fruit tree and its production and use method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1069626A true CN1069626A (en) | 1993-03-10 |
| CN1033199C CN1033199C (en) | 1996-11-06 |
Family
ID=4907438
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 91105998 Expired - Lifetime CN1033199C (en) | 1991-08-29 | 1991-08-29 | A moisture-retentive freeze-proof agent for fruit tree and its production and use method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1033199C (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1056265C (en) * | 1995-04-17 | 2000-09-13 | 樊双泉 | Flower bud antifreezing dope for vegetables and fruit trees |
| CN102027897A (en) * | 2010-11-26 | 2011-04-27 | 庄河市林业技术推广中心 | Cold-proof agent for chestnut trees |
| CN101485340B (en) * | 2009-02-18 | 2012-01-04 | 宫玲玲 | Nutrient solution for preventing frost damage of plant and production method |
| CN101485341B (en) * | 2009-02-18 | 2012-01-04 | 宫玲玲 | Agent for repairing frozen injury of plant cell and production method |
| CN102498987A (en) * | 2011-10-10 | 2012-06-20 | 凤县花椒产业发展局 | Frost prevention method for wild pepper and special aerosol |
| CN103102875A (en) * | 2011-11-10 | 2013-05-15 | 中国石油化工股份有限公司 | Oilfield oil extraction additive and preparation method thereof |
| CN103733924A (en) * | 2013-11-22 | 2014-04-23 | 陕西开新宇农业科技有限公司 | Multi-functional liquid plant protection film agent |
| CN103788874A (en) * | 2012-11-05 | 2014-05-14 | 中国石油化工股份有限公司 | Ginseng seed treatment agent and preparation method thereof |
| CN104472285A (en) * | 2015-01-13 | 2015-04-01 | 薛金国 | Preparation and method for preventing freezing damage to plants |
| CN105340677A (en) * | 2015-12-02 | 2016-02-24 | 丹阳市保得生态农林开发有限公司 | Anti-freezing method for Chinese tallow trees |
| CN106495832A (en) * | 2016-09-30 | 2017-03-15 | 广西绿泰农业投资有限公司 | A kind of Caulis Sacchari sinensis water-retention fertilizer and preparation method thereof |
| CN108605962A (en) * | 2018-06-27 | 2018-10-02 | 葛博文 | A kind of pomegranate antifreezing agent and preparation method thereof |
| CN111213632A (en) * | 2019-11-19 | 2020-06-02 | 长春中医药大学 | Method and equipment for making animal medicine epoxy resin specimen |
| CN111670738A (en) * | 2020-06-12 | 2020-09-18 | 山西省蚕业科学研究院 | Preparation method and application of fruit tree antifreezing material |
-
1991
- 1991-08-29 CN CN 91105998 patent/CN1033199C/en not_active Expired - Lifetime
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1056265C (en) * | 1995-04-17 | 2000-09-13 | 樊双泉 | Flower bud antifreezing dope for vegetables and fruit trees |
| CN101485340B (en) * | 2009-02-18 | 2012-01-04 | 宫玲玲 | Nutrient solution for preventing frost damage of plant and production method |
| CN101485341B (en) * | 2009-02-18 | 2012-01-04 | 宫玲玲 | Agent for repairing frozen injury of plant cell and production method |
| CN102027897A (en) * | 2010-11-26 | 2011-04-27 | 庄河市林业技术推广中心 | Cold-proof agent for chestnut trees |
| CN102498987A (en) * | 2011-10-10 | 2012-06-20 | 凤县花椒产业发展局 | Frost prevention method for wild pepper and special aerosol |
| CN103102875A (en) * | 2011-11-10 | 2013-05-15 | 中国石油化工股份有限公司 | Oilfield oil extraction additive and preparation method thereof |
| CN103788874B (en) * | 2012-11-05 | 2016-08-03 | 中国石油化工股份有限公司 | A kind of ginseng seed's inorganic agent and preparation method thereof |
| CN103788874A (en) * | 2012-11-05 | 2014-05-14 | 中国石油化工股份有限公司 | Ginseng seed treatment agent and preparation method thereof |
| CN103733924A (en) * | 2013-11-22 | 2014-04-23 | 陕西开新宇农业科技有限公司 | Multi-functional liquid plant protection film agent |
| CN104472285A (en) * | 2015-01-13 | 2015-04-01 | 薛金国 | Preparation and method for preventing freezing damage to plants |
| CN105340677A (en) * | 2015-12-02 | 2016-02-24 | 丹阳市保得生态农林开发有限公司 | Anti-freezing method for Chinese tallow trees |
| CN106495832A (en) * | 2016-09-30 | 2017-03-15 | 广西绿泰农业投资有限公司 | A kind of Caulis Sacchari sinensis water-retention fertilizer and preparation method thereof |
| CN108605962A (en) * | 2018-06-27 | 2018-10-02 | 葛博文 | A kind of pomegranate antifreezing agent and preparation method thereof |
| CN111213632A (en) * | 2019-11-19 | 2020-06-02 | 长春中医药大学 | Method and equipment for making animal medicine epoxy resin specimen |
| CN111670738A (en) * | 2020-06-12 | 2020-09-18 | 山西省蚕业科学研究院 | Preparation method and application of fruit tree antifreezing material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1033199C (en) | 1996-11-06 |
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Legal Events
| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C53 | Correction of patent for invention or patent application | ||
| CB02 | Change of applicant information |
Applicant after: China Petrochemical Corporation Applicant after: Fushun Research Inst. of Petroleum Processing, China Petro-chem. Corp. Applicant before: Fushun Research Inst. of Petroleum Processing, China Petro-chem. Corp. |
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| COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: CHINA PETRO-CHEMICAL CORP.; FUSHUN PETROCHEMICAL RESEARCH INSTITUTE TO: CHINA PETRO-CHEMICAL CORP.; CHINA PETRO-CHEMICAL CORP.; FUSHUN PETROCHEMICAL RESEARCH INSTITUTE |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee |
Owner name: CHINA PETROCHEMICAL CORPORATION; CHINA PETROLEUM & Free format text: FORMER NAME OR ADDRESS: CHINA PETRO-CHEMICAL CORP.; FUSHUN PETROCHEMICAL INSTITUTE., CHINA PETROCHEMICAL CORP. |
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| CP01 | Change in the name or title of a patent holder |
Patentee after: China Petrochemical Group Corp. Patentee after: Sinopec Group Fushun Research Institute of Petroleum and Petrochemicals Patentee before: China Petrochemical Corporation Patentee before: Fushun Research Inst. of Petroleum Processing, China Petro-chem. Corp. |
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| C15 | Extension of patent right duration from 15 to 20 years for appl. with date before 31.12.1992 and still valid on 11.12.2001 (patent law change 1993) | ||
| OR01 | Other related matters | ||
| C17 | Cessation of patent right | ||
| CX01 | Expiry of patent term |
Expiration termination date: 20110829 Granted publication date: 19961106 |