CN106939515A - The preparation of ball warp mercerization and efficient silkete penetrating agent in a kind of denim fabric production - Google Patents

The preparation of ball warp mercerization and efficient silkete penetrating agent in a kind of denim fabric production Download PDF

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Publication number
CN106939515A
CN106939515A CN201710290518.7A CN201710290518A CN106939515A CN 106939515 A CN106939515 A CN 106939515A CN 201710290518 A CN201710290518 A CN 201710290518A CN 106939515 A CN106939515 A CN 106939515A
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warp
mercerization
ball warp
yarn
denim fabric
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CN106939515B (en
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黄友洪
高建峰
黄敏
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Zhejiang Xin Lan Textile Co Ltd
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Zhejiang Xin Lan Textile Co Ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B7/00—Mercerising, e.g. lustring by mercerising
    • D06B7/04—Mercerising, e.g. lustring by mercerising of yarns, threads or filaments
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/438—Sulfonamides ; Sulfamic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Coloring (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Treatment Of Fiber Materials (AREA)

Abstract

The invention discloses the preparation of ball warp mercerization and efficient silkete penetrating agent in a kind of production of denim fabric, it is characterised in that in the preceding working procedure that denim fabric is produced, the warp thread after warping is made into Shu Jing, ball warp is prepared into a warp beam per beam；Without refining procedure, not dyed preceding alkali immerging process after mercerized finish, mercerization finish directly is carried out to ball warp, rope-dyeing is directly carried out.The production technology of the present invention, traditional denim fabric post-mercerizing is arranged and is improved in preceding working procedure carry out mercerization finish to warp thread in advance, on the premise of the denim fabric quality of production is ensured, eliminate 2 road dyeing and finishing manufacturing procedures, mercerization effect more preferably, dyeing after yarn lustrous surface it is good, coloured light is uniform, and suitable power saving emission reduction clean manufacturing.

Description

The preparation of ball warp mercerization and efficient silkete penetrating agent in a kind of denim fabric production
Technical field：
The present invention relates to the preparation of ball warp mercerization and efficient silkete penetrating agent in a kind of production of denim fabric, belong to spinning Knit dyeing and finishing technique field.
Background technology：
Since American invention jeans, cowboy is tight with its rough, bold and unconstrained, graceful, generous, natural style and structure It is close it is abundant, wear the characteristics of soft comfortable, quality are firm wear-resisting, liked by numerous teenagers and numerous consumers, as generation Most successful and the dress-goods being most widely known by the people, very huge market is occupied in International Textile in the market in boundary's rag trade history Share.Cowboy's industry product forward direction is superior, personalized, functionalization, fashion-orientation direction are developed.
In recent years, it has been found that jean warp crosses the mill white effect of cloth cover comfortable feel, gloss preferably, distinct after mercerized finish Fruit and clearly cloth style, impart denim fabric high added value, are the preferred fabrics of high-grade jeans.But in cowboy In fabric production process be usually beam dyeing starching after weaved again with weft yarn, mercerized finish is carried out afterwards.Because of conventional cowboy Fabric typically uses indigo dye and dyeing, and bipseudoindoxyl dye fastness is poor, and post-mercerizing, which is arranged, can make the lighter that cloth cover has contaminated, Waste dyestuff and whard to control to color, mercerising liquid containing color because that can not be recycled, the increase of colorful wastewater discharge capacity is unfavorable In energy-saving and emission-reduction clean manufacturing.And in existing denim fabric mercerized finish technology, a certain amount of bleeding agent need to be added.Use at present Phosphoric acid ester alkali-resistant penetrant because of the composition of also phosphorus, its application is restricted under current environmental requirement；Also some Bleeding agent is because of the alkali containing high concentration in mercerising liquid, and osmotic effect is not good in the short time so that glossiness is expected behind mercerising and soft Softness is undesirable, and irregular colour is even aberration occurs, influences denim fabric quality.
The content of the invention：
The problem of existing for above-mentioned prior art, the first aspect of the present invention purpose is that a kind of mercerization effect of offer is good Yarn lustrous surface is good after good, dyeing, and coloured light is uniform, and ball warp silk in the denim fabric production of suitable power saving emission reduction clean manufacturing Light technique.
To achieve these goals, the technical solution adopted by the present invention is：
Ball warp mercerization in a kind of denim fabric production, it is characterised in that in the preceding working procedure that denim fabric is produced, Shu Jing is made in warp thread after warping, ball warp is prepared into a warp beam per beam；Without refining procedure, directly to ball warp Not dyed preceding alkali immerging process after mercerized finish, mercerization finish is carried out, i.e., directly carries out rope-dyeing.
The production technology of the present invention, traditional denim fabric post-mercerizing is arranged and is improved in preceding working procedure in advance to warp thread Mercerization finish is carried out, is dyed afterwards, is weaved.On the premise of the denim fabric quality of production is ensured, 2 road dyeing and finishing processing are eliminated Process, wherein：In preceding working procedure, Shu Jing is made in the warp thread after warping, ball warp is prepared into a warp beam per beam, Mercerized finish directly is carried out to ball warp, traditional refining procedure is eliminated；After mercerization finish, beam dyeing work is directly carried out Sequence, rope-dyeing is completed through multiple tracks oxidation operation, then through weaving into finished product, rear road eliminates alkali immerging work before traditional dyeing Sequence.Meanwhile, the use of a big chunk dyestuff and auxiliary agent is saved, the discharge of waste water is reduced, the purpose of energy-saving and emission-reduction is reached, Effectively reduce production cost.
The production process of denim fabric after improvement is as follows：--- --- ball warp --- mercerising --- contaminates warping yarn Color --- dividing sinker --- starching --- weaving ------- enzyme desizing --- Final finishing --- finished product of singing.
It is used as further setting：
Ball warp yams of the present invention are related to 10s, 12s, 16s cotton, cotton/viscous 80/20, cotton/tencel 80/ 20th, 70/30,60/40 etc.；
Described each ball warp beam yarn contains 400-500 root warp thread；
Described ball warp mercerization formula is：
The second aspect of the present invention purpose is that there is provided a kind of efficient mercerising infiltration for being applicable above-mentioned ball warp mercerization Agent, improves yarn mercerization effect, improves fabric quality.
A kind of efficient silkete penetrating agent, including following compositions by weight percentage：
A kind of preparation method of efficient silkete penetrating agent, it is characterised in that comprise the following steps：
A kind of preparation method of efficient silkete penetrating agent, comprises the following steps：
(1) the accurate isomerous tridecanol polyoxyethylene ether for weighing parts by weight is placed in three with thermometer mouthful being completely dried In flask；
(2) agitating device is loaded onto, starts agitator, is started to warm up after stirring to 100-160 DEG C, then meter is added dropwise Measured sulfamic acid, isothermal reaction 120min；
(3) system is cooled to 50 DEG C after reacting and adds a certain amount of butyl glycol ether and dodecyl sodium sulfate stirring 30min；
(4) system temperature is down to room temperature, adds after measured deionized water high-speed stirred 30min and discharge.
The beneficial effects of the present invention are：
1st, the present invention is right in preceding working procedure using New Processing on the basis of traditional denim manufacturing technique Ball warp carries out mercerising, and dyed rear colour brightness, the more conventional yarn of depth are far better.Woven fabric has preferable light Pool, distinct mill white effect, clearly cloth style and comfortable feel.Denim yarn mercerising is arranged with denim fabric post-mercerizing Compare, final product quality is close, belong to medium-to-high grade fabric, improve added value；And the more traditional denim fabric processing of ball warp mercerising Technique eliminates caustic dip process before one of refining procedure is dyed with together with so that once color success rate is improved, dyestuff is saved And auxiliary agent, dye forecourt and be free of dyestuff in raffinate after mercerising, recoverable reduces wastewater discharge, reduces production Cost, is conducive to energy-saving and emission-reduction clean manufacturing.
2nd, present invention also offers a kind of efficient silkete penetrating agent of new preparation, it instead of the infiltration of phosphoric acid ester alkali resistant Agent, resisting high-concentration alkali lye is functional, makes the surface tension of alkali lye and reduces, and promotes the infiltration of alkali lye, makes mercerization uniform, contracting The time of short mercerising.It can quickly be permeated in a short time to yarn interior after ball warp alkali immerging aborning, improve life Speed is produced, and mercerization effect is good, dyed rear yarn lustrous surface is good, and coloured light irregularity is reduced, and improves finished product fabric Quality stability.
With reference to embodiment, the present invention is described in further detail, but protection scope of the present invention is not limited In this.
Embodiment：
Embodiment 1：
By 16s cottons/yarn of tencel 70/30 by warping, coiling in warp beam, by warp beam yarn apply some tension Beam yarn is made, each beam yarn contains 400-500 one threads, after each beam yarn reel be wound in a warp beam be prepared into ball warp, will Beam yarn overall alignment in 12-25 ball warp, while feeding cord roller, directly carries out mercerized finish, laggard axle of passing through to ball warp Dyeing process, rope-dyeing is finally completed through multiple tracks oxidation operation.
Ball warp mercerization formula is in such scheme：
The preparation method of efficient silkete penetrating agent in such scheme is：
Accurately 30g isomerous tridecanol polyoxyethylene ethers are weighed to be placed in the there-necked flask with thermometer being completely dried； Agitating device is loaded onto, starts agitator, stirring degree is that 800r/min is started to warm up to 100-160 DEG C after stirring, then by It is added dropwise to 25g sulfamic acid, isothermal reaction 120min；After reaction by system cool to 50 DEG C add 5.5g butyl glycol ethers and 6.5g dodecyl sodium sulfates stir 30min；
System temperature is down to room temperature, adds after 33g deionized water high-speed stirreds 30min and discharges.
Performance detection：
Respectively to the embodiment of above-mentioned process ball warp mercerising, with being contrasted without the yarn of mercerized finish, contrast knot Fruit is as shown in table 1.
Table 1, properties test result：
As can be seen from Table 1：
The efficient silkete penetrating agent of addition can quickly permeate in 8s to yarn interior, by 16s cottons/tencel of mercerising 70/30, mercerizing barium value obtains preferable gloss up to 136%, and dyed rear colour brightness, the more conventional yarn of depth good will be obtained It is many.Woven denim fabric obtains preferable gloss, distinct mill white effect, clearly cloth style and comfortable feel.
Embodiment 2：
12s cottons/viscous 80/20 yarn in warp beam, the yarn in warp beam is applied into certain tension force by warping, coiling Beam yarn is made, each beam yarn contains 400-500 one threads, after each beam yarn reel be wound in a warp beam be prepared into ball warp, will Beam yarn overall alignment in 12-25 ball warp, while feeding cord roller, directly carries out mercerized finish, laggard axle of passing through to ball warp Dyeing process, rope-dyeing is finally completed through multiple tracks oxidation operation.
Ball warp mercerization formula is in such scheme：
The preparation method of efficient silkete penetrating agent in such scheme is：
Accurately 36g isomerous tridecanol polyoxyethylene ethers are weighed to be placed in the there-necked flask with thermometer being completely dried； Agitating device is loaded onto, starts agitator, stirring degree is that 800r/min is started to warm up to 100-160 DEG C after stirring, then by It is added dropwise to 28g sulfamic acid, isothermal reaction 120min；After reaction by system cool to 50 DEG C add 6.5g butyl glycol ethers and 7g dodecyl sodium sulfates stir 30min；
System temperature is down to room temperature, adds after 22.5g deionized water high-speed stirreds 30min and discharges.
Performance detection：
Respectively by the embodiment of above-mentioned process mercerising, with being contrasted without the yarn arranged at mercerising, comparing result As shown in table 2.
The properties test result of table 2：
As can be seen from Table 2：
The efficient silkete penetrating agent of addition can quickly permeate in 10s to yarn interior, by the 16s of ball warp mercerising Cotton/viscous 80/20, mercerizing barium value obtains preferable gloss up to 118%, and dyed rear colour brightness, the more conventional yarn of depth will It is much better.Woven denim fabric obtains preferable gloss, distinct mill white effect, clearly cloth style and comfortable hand Sense.
Obviously, the above embodiment of the present invention is only to clearly demonstrate examples of the invention, not to of the invention real Apply the restriction of mode.For those of ordinary skill in the field, other can also be made on the basis of the above description Various forms of changes or variation.Here all embodiments can not be exhaustive.Every technical side for belonging to the present invention Row of the obvious change or variation that case is extended out still in protection scope of the present invention.

Claims (8)

1. ball warp mercerization in a kind of denim fabric production, it is characterised in that in the preceding working procedure that denim fabric is produced, will Shu Jing is made in warp thread after warping, and ball warp is prepared into a warp beam per beam；Without refining procedure, directly ball warp is entered Not dyed preceding alkali immerging process, directly carries out rope-dyeing after row mercerized finish, mercerization finish.
2. ball warp mercerization in a kind of denim fabric production according to claim 1, it is characterised in that：Described ball warp Yams are related to 10s, 12s, 16s cotton, cotton/viscous 80/20, one kind of cotton/tencel 80/20,70/30,60/40.
3. ball warp mercerization in a kind of denim fabric production according to claim 1, it is characterised in that：Described is each Ball warp beam yarn contains 400-500 root warp thread.
4. ball warp mercerization in a kind of denim fabric production according to claim 1, it is characterised in that：Described ball warp Mercerization formula is：
Caustic soda 100-200g/L,
Efficient silkete penetrating agent 1-5g/L,
60-90 DEG C of temperature,
Speed 10-35m/min.
5. ball warp mercerization in a kind of denim fabric production according to claim 1, it is characterised in that：By 16s cottons/day Yarn in warp beam in warp beam, is applied some tension and beam yarn is made, each beam yarn contains by 70/30 yarn of silk by warping, coiling Have 400-500 one threads, after each beam yarn reel be wound in a warp beam be prepared into ball warp, by the beam yarn in 12-25 ball warp Overall alignment, while feeding cord roller, directly carries out mercerized finish, laggard axle dyeing process of passing through is aoxidized through multiple tracks to ball warp Process is finally completed rope-dyeing；
Ball warp mercerization formula is in such scheme：
Caustic soda 180g/L,
Efficient silkete penetrating agent 3g/L,
85 DEG C of temperature,
Speed 20m/min；
The preparation method of efficient silkete penetrating agent in such scheme is：
Accurately 30g isomerous tridecanol polyoxyethylene ethers are weighed to be placed in the there-necked flask with thermometer being completely dried；Load onto Agitating device, starts agitator, stirring degree is that 800r/min is started to warm up to 100-160 DEG C after stirring, then adds dropwise Enter 25g sulfamic acid, isothermal reaction 120min；System is cooled to 50 DEG C after reaction and adds 5.5g butyl glycol ethers and 6.5g Dodecyl sodium sulfate stirs 30min；
System temperature is down to room temperature, adds after 33g deionized water high-speed stirreds 30min and discharges.
6. ball warp mercerization in a kind of denim fabric production according to claim 1, it is characterised in that：12s cottons/viscous Yarn in warp beam in warp beam, is applied certain tension force and beam yarn is made, each beam yarn contains by 80/20 yarn by warping, coiling Have 400-500 one threads, after each beam yarn reel be wound in a warp beam be prepared into ball warp, by the beam yarn in 12-25 ball warp Overall alignment, while feeding cord roller, directly carries out mercerized finish, laggard axle dyeing process of passing through is aoxidized through multiple tracks to ball warp Process is finally completed rope-dyeing；
Ball warp mercerization formula is in such scheme：
Caustic soda 160g/L
Efficient silkete penetrating agent 2.5g/L
85 DEG C of temperature
Speed 20m/min；
The preparation method of efficient silkete penetrating agent in such scheme is：
Accurately 36g isomerous tridecanol polyoxyethylene ethers are weighed to be placed in the there-necked flask with thermometer being completely dried；Load onto Agitating device, starts agitator, stirring degree is that 800r/min is started to warm up to 100-160 DEG C after stirring, then adds dropwise Enter 28g sulfamic acid, isothermal reaction 120min；System is cooled to 50 DEG C after reaction and adds 6.5g butyl glycol ethers and 7g ten Dialkyl sulfonates stir 30min；
System temperature is down to room temperature, adds after 22.5g deionized water high-speed stirreds 30min and discharges.
7. the efficient silkete penetrating agent described in a kind of claim 4, it is characterised in that：Including following groups by weight percentage Into：
Isomerous tridecanol polyoxyethylene ether 30-40%
Sulfamic acid 30-35%
Butyl glycol ether 1-5%
Dodecyl sodium sulfate 1-10%
Deionized water surplus.
8. the preparation method of efficient silkete penetrating agent described in a kind of claim 7, it is characterised in that：Comprise the following steps：
(1) the accurate isomerous tridecanol polyoxyethylene ether for weighing parts by weight is placed in the there-necked flask with thermometer being completely dried In；
(2) agitating device is loaded onto, starts agitator, is started to warm up after stirring to 100-160 DEG C, then metering is added dropwise Good sulfamic acid, isothermal reaction 120min；
(3) system is cooled to 50 DEG C after reacting and adds butyl glycol ether and dodecyl sodium sulfate stirring 30min；
(4) system temperature is down to room temperature, adds after deionized water high-speed stirred 30min and discharge.
CN201710290518.7A 2017-04-28 2017-04-28 The preparation of ball warp mercerization and efficient silkete penetrating agent in a kind of production of denim fabric Active CN106939515B (en)

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Cited By (6)

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CN107988730A (en) * 2017-12-06 2018-05-04 何炽斌 A kind of production method of new softening yarn
CN108796895A (en) * 2018-06-21 2018-11-13 浙江美欣达纺织印染科技有限公司 It is a kind of based on the tencel production technology for padding silkete penetrating agent
CN109023646A (en) * 2018-08-21 2018-12-18 中纺院（浙江）技术研究院有限公司 A kind of Lyocell polyethylene cool feeling denim fabric and its processing technology
CN113668262A (en) * 2021-08-02 2021-11-19 浙江鑫兰纺织有限公司 Production process of anti-aging jean fabric
CN113668119A (en) * 2021-08-02 2021-11-19 浙江鑫兰纺织有限公司 Processing method of double-layer warm-keeping jean fabric
CN115748151A (en) * 2022-11-17 2023-03-07 山东兰雁纺织服装有限公司 Environment-friendly mercerizing process of jean fabric

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CN101654860A (en) * 2009-08-31 2010-02-24 杨洋 Padding type yarn continuous mercerizing bleaching and dyeing process and device thereof
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