CN106928633A - 一种阻燃塑料 - Google Patents

一种阻燃塑料 Download PDF

Info

Publication number
CN106928633A
CN106928633A CN201511012961.5A CN201511012961A CN106928633A CN 106928633 A CN106928633 A CN 106928633A CN 201511012961 A CN201511012961 A CN 201511012961A CN 106928633 A CN106928633 A CN 106928633A
Authority
CN
China
Prior art keywords
parts
flame retardant
retardant plastics
foaming agent
abs
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201511012961.5A
Other languages
English (en)
Inventor
不公告发明人
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cixi Changhe Yuan Rubber Products Factory
Original Assignee
Cixi Changhe Yuan Rubber Products Factory
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cixi Changhe Yuan Rubber Products Factory filed Critical Cixi Changhe Yuan Rubber Products Factory
Priority to CN201511012961.5A priority Critical patent/CN106928633A/zh
Publication of CN106928633A publication Critical patent/CN106928633A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/102—Azo-compounds
    • C08J9/103—Azodicarbonamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2355/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2323/00 - C08J2353/00
    • C08J2355/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2433/10—Homopolymers or copolymers of methacrylic acid esters
    • C08J2433/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明公开了一种阻燃塑料，包括以下重量份组分：ABS 50份，硅烷偶联剂 5份，增韧剂 10份，分散剂 1份，发泡剂 2份，阻燃剂12份，所述抗菌剂包括重量比为1：2的三氧化二锑与三聚磷酸铝。加入发泡剂与阻燃剂， ABS 塑料的阻燃性得到了较大的提高。

Description

一种阻燃塑料
技术领域
本发明涉及一种阻燃塑料。
背景技术
ABS树脂是重要的通用合成树脂，主要是丙烯腈、丁二烯和苯乙烯的共混物或三元共聚物，是一种坚韧而有刚性的热塑料塑料，用途非常广泛，汽车工业常用于制造汽车零部件如仪表板、车身外板、内装饰板、方向盘等等，家电行业常用于制造如电冰箱、电视机、真空吸尘器等等，建筑行业常用语制造如卫生器具、游泳池衬里、管材和管件等，另外还用于制造安全帽、摩托车挡板、玩具、时钟、化妆品盒等等。
尽管ABS应用广泛，但由于ABS本身分子结构性能的特性，使得ABS在阻燃方面不足。
发明内容
为了解决上述现有技术的不足，本发明的目的是提供一种阻燃塑料。
为了实现上述目的，本发明所设计的一种阻燃塑料，包括以下重量份组分：ABS 50份，硅烷偶联剂 5份，增韧剂 10份，分散剂 1份，发泡剂 2份，阻燃剂12份，所述阻燃剂包括重量比为1：2的三氧化二锑与三聚磷酸铝。
优选的，所述硅烷偶联剂为γ-氨丙基三乙氧基硅烷、γ-缩水甘油醚氧丙基三甲氧基硅烷、γ-（甲基丙烯酰氧）丙基三甲氧基硅烷中的一种或几种。
优选的，所述增韧剂为甲基丙烯酸甲酯-丁二烯-苯乙烯共聚物、甲基丙烯酸甲酯-丁二烯-苯乙烯共聚物、氢化苯乙烯/丁二烯/苯乙烯嵌段共聚物中的一种或多种。
优选的，所述分散剂为硬脂酸单甘油脂、三硬脂酸甘油酯、乙撑双硬脂酰胺、低分子量离聚物、乙烯-丙烯酸共聚物中的一种或几种。
优选的，所述发泡剂为AC发泡剂。
本发明得到的一种阻燃塑料，其技术效果是：加入发泡剂与阻燃剂， ABS 塑料的阻燃效果有了显著的提高。
具体实施方式
下面结合实施例对本发明进一步说明。
本发明提供的一种阻燃塑料，包括以下重量份组分：ABS 50份，硅烷偶联剂 5份，增韧剂 10份，分散剂 1份，发泡剂 2份，阻燃剂12份，所述阻燃剂包括重量比为1：2的三氧化二锑与三聚磷酸铝。
本实施例中，硅烷偶联剂为γ-氨丙基三乙氧基硅烷，增韧剂为甲基丙烯酸甲酯-丁二烯-苯乙烯共聚物，分散剂为硬脂酸单甘油脂，发泡剂为AC发泡剂。
将上述重量份ABS、硅烷偶联剂、增韧剂、分散剂、发泡剂以及阻燃剂一起在高混机或密炼机内搅拌混合，混合均匀后加入双螺杆挤出机中，双螺杆挤出机的加工温度 ：一区温度180℃，二区温度185℃，三区温度190℃，四区温度195℃，五区温度210℃，六区温度215℃，七区温度230℃，八区温度240℃，九区温度245℃，挤出后冷却牵条、风干切粒制得本发明的ABS阻燃塑料。

Claims (5)

1.一种阻燃塑料，其特征在于，包括以下重量份组分：ABS 50份，硅烷偶联剂 5份，增韧剂 10份，分散剂 1份，发泡剂 2份，阻燃剂12份，所述阻燃剂包括重量比为1：2的三氧化二锑与三聚磷酸铝。
2.根据权利要求1所述的阻燃塑料，其特征在于：所述硅烷偶联剂为γ-氨丙基三乙氧基硅烷、γ-缩水甘油醚氧丙基三甲氧基硅烷、γ-（甲基丙烯酰氧）丙基三甲氧基硅烷中的一种或几种。
3.根据权利要求1所述的阻燃塑料，其特征在于：所述增韧剂为甲基丙烯酸甲酯-丁二烯-苯乙烯共聚物、甲基丙烯酸甲酯-丁二烯-苯乙烯共聚物、氢化苯乙烯/丁二烯/苯乙烯嵌段共聚物中的一种或多种。
4.根据权利要求1所述的阻燃塑料，其特征在于：所述分散剂为硬脂酸单甘油脂、三硬脂酸甘油酯、乙撑双硬脂酰胺、低分子量离聚物、乙烯-丙烯酸共聚物中的一种或几种。
5.根据权利要求1所述的阻燃塑料，其特征在于：所述发泡剂为AC发泡剂。
CN201511012961.5A 2015-12-31 2015-12-31 一种阻燃塑料 Pending CN106928633A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201511012961.5A CN106928633A (zh) 2015-12-31 2015-12-31 一种阻燃塑料

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201511012961.5A CN106928633A (zh) 2015-12-31 2015-12-31 一种阻燃塑料

Publications (1)

Publication Number Publication Date
CN106928633A true CN106928633A (zh) 2017-07-07

Family

ID=59457979

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201511012961.5A Pending CN106928633A (zh) 2015-12-31 2015-12-31 一种阻燃塑料

Country Status (1)

Country Link
CN (1) CN106928633A (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114561078A (zh) * 2022-02-28 2022-05-31 惠州市欣瑞森电子科技有限公司 高耐候性抗菌塑料
CN115197530A (zh) * 2022-09-01 2022-10-18 苏州润佳高分子材料有限公司 一种耐热低取向abs材料及应用

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114561078A (zh) * 2022-02-28 2022-05-31 惠州市欣瑞森电子科技有限公司 高耐候性抗菌塑料
CN115197530A (zh) * 2022-09-01 2022-10-18 苏州润佳高分子材料有限公司 一种耐热低取向abs材料及应用

Similar Documents

Publication Publication Date Title
CN104327530B (zh) 阻燃抗静电木塑复合材料的制备方法
CN104250406B (zh) Cpe/cpvc橡塑保温材料及其制备方法
CN106398018A (zh) 用于聚氯乙烯电缆料的制备工艺
CN103333450B (zh) 一种高强度塑料
CN106928633A (zh) 一种阻燃塑料
CN106928627A (zh) 一种abs塑料的制备方法
CN103342873B (zh) 一种易降解环保塑料
CN106928636A (zh) 一种高强度塑料的制备方法
CN106566070A (zh) 改性聚丙烯材料及其制备方法
KR101213568B1 (ko) 시공시 표면 오염 방지 특성이 우수한 고무발포 단열 제품 및 그 제조 방법
CN106928629A (zh) 一种abs塑料
CN103333451B (zh) 一种高强度塑料的制备方法
CN106928635A (zh) 一种抗静电塑料的制备方法
CN106928631A (zh) 一种抗菌塑料的制备方法
CN103360757A (zh) 一种可导电的尼龙的制备方法
CN106928638A (zh) 一种高强度塑料
CN106928634A (zh) 一种阻燃塑料的制备方法
CN103351567A (zh) 一种高电导率的导电塑料的制备方法
CN108949064A (zh) 一种高发泡率汽车用pvc发泡底涂胶及其制备方法
CN103509333B (zh) 抗静电阻燃尼龙的制备方法
CN106928637A (zh) 一种抗静电塑料
CN106928630A (zh) 一种抗菌塑料
CN106928628A (zh) 抗菌塑料
CN106928632A (zh) 抗菌塑料的制备方法
CN105219014A (zh) 抗静电abs塑料及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170707