CN106868885A - A kind of processing method of polyamide fibre Graphene white dipped gloves - Google Patents

A kind of processing method of polyamide fibre Graphene white dipped gloves Download PDF

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Publication number
CN106868885A
CN106868885A CN201710158892.1A CN201710158892A CN106868885A CN 106868885 A CN106868885 A CN 106868885A CN 201710158892 A CN201710158892 A CN 201710158892A CN 106868885 A CN106868885 A CN 106868885A
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Prior art keywords
gloves
minutes
drying
printing paste
temperature
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CN201710158892.1A
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Chinese (zh)
Inventor
黄雪红
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Nantong Textile Vocational Technology College
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Nantong Textile Vocational Technology College
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Priority to CN201710158892.1A priority Critical patent/CN106868885A/en
Publication of CN106868885A publication Critical patent/CN106868885A/en
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/30—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of articles, e.g. stockings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D06M15/3562—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D06P3/24—Polyamides; Polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Gloves (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a kind of processing method of polyamide fibre Graphene white dipped gloves, comprise the following steps：Woven gloves core pre-treatment configuration white coating printing paste front printing paste drying-back side printing paste dry-is repeated once above four step impregnations drying washing drying.The present invention uses coating printing paste method, by Graphene gloves on rotary ready-made clothes printing machine, using the method for full ground printing paste, make to cover one layer of white coating on gloves, cover background color, and fixation, produce white graphite alkene polyamide fibre gloves core, then impregnation, solve the problems, such as that Graphene polyamide fibre dipped gloves can not produce white colour, for the light Graphene polyamide fibre dipped gloves of production provide method, be graphene composite material in home textile, the application of garment industry, widened thinking.

Description

A kind of processing method of polyamide fibre Graphene white dipped gloves
Technical field
The invention belongs to gloves process field, and in particular to a kind of processing method of polyamide fibre Graphene white dipped gloves.
Background technology
Terylene dipped gloves are, using polyamide fibre graphene composite material, on seamless gloves machine, to be woven into gloves core, herein On the basis of impregnate natural emulsion produce.The gloves belong to the one kind in dipped gloves, safety and industrial gloves.Gloves inherit polyamide fibre hand The comfortableness and gas permeability of set, glue surface inherit the advantage of natural emulsion, soft abrasion-resistant.Gloves core also added except polyamide fibre 0.5% graphene oxide, makes gloves have some specific functions, such as anti-cutting, fire-retardant gloves, antibacterial, antistatic, uvioresistant Deng.The compound nylon fibre true qualities of Graphene are middle grey, can only produce the deeper color of grey than in, constrain industry metaplasia Produce, the present invention is directed to this problem, it is proposed that solution.
The compound nylon fibre true qualities of Graphene are middle grey, can only produce the deeper color of grey than in, constrain graphite The industrialization production of alkene gloves.Graphene is carbon atom, and the black of graphite is very difficult to remove, and to produce white graphite alkene gloves, solution Method certainly only has physics cladding process.
The content of the invention
Goal of the invention：The present invention provides a kind of processing method of polyamide fibre Graphene white dipped gloves, solves Graphene Polyamide fibre dipped gloves can not produce the problem of white colour, for the light Graphene polyamide fibre dipped gloves of production provide method.
Technical scheme：A kind of processing method of polyamide fibre Graphene white dipped gloves, comprises the following steps：Woven gloves -- -- -- front printing paste -- drying-back side printing paste -- is before dry-being repeated once for configuration white coating printing paste for pre-treatment for core -- impregnation -- drying -- washing -- drying of four steps；Concrete operations are as follows：
(1) woven gloves core：4 strand of 70 danier Graphene polyamide fibre false-twist textured yarn is first made into seamless gloves core；
(2) pre-treatment：Processed before being carried out by degreaser in the garment dyeing machine, 10 are washed by 90 DEG C -95 DEG C - 8-10min is washed in 15min, draining in cold water, is dehydrated 6-8 minutes in centrifugal dehydrator, and the control containing damp rate is easy in 6-8% Slurry penetration below；The degreaser includes：Degreaser 2-4G/L, soaping agent 4-6G/L；
(3) white coating printing paste is configured：Whiting：30--40KG, adhesive：20--30kg, thickener：4--6kg、 Crosslinking agent：3--5kg, balance of water, are made into 100kg altogether；
(4) front printing paste：Whiting mill base is printed on automatic rotary ready-made clothes platform version printing machine, wherein, decorative pattern：Full bottom, Scraping slurry pressure is：7-9kg, temperature：20-30℃；
(5) dry：First dry：Drying temperature is 95-100 DEG C, and drying time is 10--15 minutes；Bake again：Bake temperature It is 150---160 DEG C to spend, and the time is 3--5 minutes；
(6) back side printing paste：Gloves are turned over, the gloves dried of slurry are scraped into front is translated into reverse side and scrape slurry again, wherein, decorative pattern：It is full Bottom, scraping slurry pressure is：7-9kg, temperature：20-30℃；
(7) dry：First dry：Drying temperature is 95-100 DEG C, and drying time is 10--15 minutes；Bake again：Bake temperature It is 150---160 DEG C to spend, and the time is 3--5 minutes；
(8) repeat step (4), (5), (6), (7) are each once；
(9) impregnation：Liquid fourth fine latex of the dipping to after reconciling, the fine latex of liquid fourth is by butadiene and acrylonitrile A kind of synthetic rubber of copolymerization, with excellent oil resistivity, preferable heat resistance and wearability, and very strong bonding energy Power；Then glue surface is slightly blown using fan, temperature is 100-105 DEG C, and blow-time is 8-10 minutes；
(10) dry：By oven cooking cycle, temperature is 120--130 DEG C, and the time is 40-60 minutes；
(11) wash；Normal temperature is washed 15-20 minutes；
(12) dry；Drying temperature is 102-105 DEG C, and drying time is 15--20 minutes.
Beneficial effect：Specific advantage of the invention is as follows：
1st, the present invention uses coating printing paste method, by Graphene gloves on rotary ready-made clothes printing machine, using full ground printing paste Method, make to cover one layer of white coating on gloves, cover background color, and fixation produces white graphite alkene polyamide fibre gloves core, then Impregnation.
2nd, the present invention solves the problems, such as that Graphene polyamide fibre dipped gloves can not produce white colour, is the light Graphene of production Polyamide fibre dipped gloves provide method.
3rd, the present invention be graphene composite material in home textile, the application of garment industry, widened thinking.
Specific embodiment
With reference to specific embodiment, the present invention will be described in detail.
Specific embodiment one：
A kind of processing method of polyamide fibre Graphene white dipped gloves, comprises the following steps：Woven gloves core -- preceding place Reason -- -- -- soak front printing paste configuration white coating printing paste by drying-back side printing paste -- dry-being repeated once above four step -- Glue -- drying -- washing -- drying；Concrete operations are as follows：
(1) woven gloves core：4 strand of 70 danier Graphene polyamide fibre false-twist textured yarn is first made into seamless gloves core；
(2) pre-treatment：Processed before being carried out by degreaser in the garment dyeing machine, by 90 DEG C of washing 10min, draining, 8min is washed in cold water, is dehydrated 6 minutes in centrifugal dehydrator, the control containing damp rate is easy to slurry penetration below 6%；It is described Degreaser includes：Degreaser 2G/L, soaping agent 4G/L；
(3) white coating printing paste is configured：Whiting：30KG, adhesive：20kg, thickener：4kg, crosslinking agent：3kg、 Balance of water, is made into 100kg altogether；
(4) front printing paste：Whiting mill base is printed on automatic rotary ready-made clothes platform version printing machine, wherein, decorative pattern：Full bottom, Scraping slurry pressure is：7kg, temperature：20℃；
(5) dry：First dry：Drying temperature is 95 DEG C, and drying time is 10 minutes；Bake again：Baking temperature is 150 DEG C, the time is 3 minutes；
(6) back side printing paste：Gloves are turned over, the gloves dried of slurry are scraped into front is translated into reverse side and scrape slurry again, wherein, decorative pattern：It is full Bottom, scraping slurry pressure is：7kg, temperature：20℃；
(7) dry：First dry：Drying temperature is 95 DEG C, and drying time is 10 minutes；Bake again：Baking temperature is 150 DEG C, the time is 3 minutes；
(8) repeat step (4), (5), (6), (7) are each once；
(9) impregnation：Liquid fourth fine latex of the dipping to after reconciling, the fine latex of liquid fourth is by butadiene and acrylonitrile A kind of synthetic rubber of copolymerization, with excellent oil resistivity, preferable heat resistance and wearability, and very strong bonding energy Power；Then glue surface is slightly blown using fan, temperature is 100 DEG C, and blow-time is 8 minutes；
(10) dry：By oven cooking cycle, temperature is 120 DEG C, and the time is 40 minutes；
(11) wash；Normal temperature is washed 15 minutes；
(12) dry；Drying temperature is 102 DEG C, and drying time is 15 minutes.
Specific embodiment two：
A kind of processing method of polyamide fibre Graphene white dipped gloves, comprises the following steps：Woven gloves core -- preceding place Reason -- -- -- soak front printing paste configuration white coating printing paste by drying-back side printing paste -- dry-being repeated once above four step -- Glue -- drying -- washing -- drying；Concrete operations are as follows：
(1) woven gloves core：4 strand of 70 danier Graphene polyamide fibre false-twist textured yarn is first made into seamless gloves core；
(2) pre-treatment：Processed before being carried out by degreaser in the garment dyeing machine, by 95 DEG C of washing 15min, draining, 10min is washed in cold water, is dehydrated 8 minutes in centrifugal dehydrator, the control containing damp rate is easy to slurry penetration below 8%；It is described Degreaser includes：Degreaser 4G/L, soaping agent 6G/L；
(3) white coating printing paste is configured：Whiting：40KG, adhesive：30kg, thickener：6kg, crosslinking agent：5kg、 Balance of water, is made into 100kg altogether；
(4) front printing paste：Whiting mill base is printed on automatic rotary ready-made clothes platform version printing machine, wherein, decorative pattern：Full bottom, Scraping slurry pressure is：9kg, temperature：30℃；
(5) dry：First dry：Drying temperature is 100 DEG C, and drying time is 15 minutes；Bake again：Baking temperature is 160 DEG C, the time is 5 minutes；
(6) back side printing paste：Gloves are turned over, the gloves dried of slurry are scraped into front is translated into reverse side and scrape slurry again, wherein, decorative pattern：It is full Bottom, scraping slurry pressure is：9kg, temperature：30℃；
(7) dry：First dry：Drying temperature is 100 DEG C, and drying time is 15 minutes；Bake again：Baking temperature is 160 DEG C, the time is 5 minutes；
(8) repeat step (4), (5), (6), (7) are each once；
(9) impregnation：Liquid fourth fine latex of the dipping to after reconciling, the fine latex of liquid fourth is by butadiene and acrylonitrile A kind of synthetic rubber of copolymerization, with excellent oil resistivity, preferable heat resistance and wearability, and very strong bonding energy Power；Then glue surface is slightly blown using fan, temperature is 105 DEG C, and blow-time is 10 minutes；
(10) dry：By oven cooking cycle, temperature is 130 DEG C, and the time is 60 minutes；
(11) wash；Normal temperature is washed 20 minutes；
(12) dry；Drying temperature is 105 DEG C, and drying time is 20 minutes.
Specific embodiment three：
A kind of processing method of polyamide fibre Graphene white dipped gloves, comprises the following steps：Woven gloves core -- preceding place Reason -- -- -- soak front printing paste configuration white coating printing paste by drying-back side printing paste -- dry-being repeated once above four step -- Glue -- drying -- washing -- drying；Concrete operations are as follows：
(1) woven gloves core：4 strand of 70 danier Graphene polyamide fibre false-twist textured yarn is first made into seamless gloves core；
(2) pre-treatment：Processed before being carried out by degreaser in the garment dyeing machine, by 93 DEG C of washing 13min, draining, 9min is washed in cold water, is dehydrated 7 minutes in centrifugal dehydrator, the control containing damp rate is easy to slurry penetration below 7%；It is described Degreaser includes：Degreaser 3G/L, soaping agent 5G/L；
(3) white coating printing paste is configured：Whiting：34KG, adhesive：24kg, thickener：5kg, crosslinking agent：4kg、 Balance of water, is made into 100kg altogether；
(4) front printing paste：Whiting mill base is printed on automatic rotary ready-made clothes platform version printing machine, wherein, decorative pattern：Full bottom, Scraping slurry pressure is：8kg, temperature：24℃；
(5) dry：First dry：Drying temperature is 97 DEG C, and drying time is 13 minutes；Bake again：Baking temperature is 154 DEG C, the time is 4 minutes；
(6) back side printing paste：Gloves are turned over, the gloves dried of slurry are scraped into front is translated into reverse side and scrape slurry again, wherein, decorative pattern：It is full Bottom, scraping slurry pressure is：8kg, temperature：26℃；
(7) dry：First dry：Drying temperature is 97 DEG C, and drying time is 13 minutes；Bake again：Baking temperature is 153 DEG C, the time is 4 minutes；
(8) repeat step (4), (5), (6), (7) are each once；
(9) impregnation：Liquid fourth fine latex of the dipping to after reconciling, the fine latex of liquid fourth is by butadiene and acrylonitrile A kind of synthetic rubber of copolymerization, with excellent oil resistivity, preferable heat resistance and wearability, and very strong bonding energy Power；Then glue surface is slightly blown using fan, temperature is 104 DEG C, and blow-time is 9 minutes；
(10) dry：By oven cooking cycle, temperature is 127 DEG C, and the time is 50 minutes；
(11) wash；Normal temperature is washed 19 minutes；
(12) dry；Drying temperature is 104 DEG C, and drying time is 19 minutes.
The present invention uses coating printing paste method, by Graphene gloves on rotary ready-made clothes printing machine, using full ground printing paste Method, makes to cover one layer of white coating on gloves, covers background color, and fixation, produces white graphite alkene polyamide fibre gloves core, then soak Glue.The present invention solves the problems, such as that Graphene polyamide fibre dipped gloves can not produce white colour, is the light Graphene polyamide fibre leaching of production Rubber gloves provide method.The present invention be graphene composite material in home textile, the application of garment industry, widened thinking.
The present invention is not limited to above-mentioned preferred forms, and anyone can show that other are various under enlightenment of the invention The product of form, however, make any change in its shape or structure, it is every with skill identical or similar to the present application Art scheme, is within the scope of the present invention.

Claims (1)

1. the processing method of a kind of polyamide fibre Graphene white dipped gloves, it is characterised in that：Comprise the following steps：Woven gloves -- -- -- front printing paste -- drying-back side printing paste -- is before dry-being repeated once for configuration white coating printing paste for pre-treatment for core -- impregnation -- drying -- washing -- drying of four steps；Concrete operations are as follows：
(1) woven gloves core：4 strand of 70 danier Graphene polyamide fibre false-twist textured yarn is first made into seamless gloves core；
(2) pre-treatment：Processed before being carried out by degreaser in the garment dyeing machine, 10-15min washed by 90 DEG C-95 DEG C, Draining, washes 8-10min in cold water, is dehydrated 6-8 minutes in centrifugal dehydrator, and the control containing damp rate is easy to slurry below in 6-8% Material infiltration；The degreaser includes：Degreaser 2-4G/L, soaping agent 4-6G/L；
(3) white coating printing paste is configured：Whiting：30--40KG, adhesive：20--30kg, thickener：4--6kg, crosslinking Agent：3--5kg, balance of water, are made into 100kg altogether；
(4) front printing paste：Whiting mill base is printed on automatic rotary ready-made clothes platform version printing machine, wherein, decorative pattern：Full bottom, scrapes slurry Pressure is：7-9kg, temperature：20-30℃；
(5) dry：First dry：Drying temperature is 95-100 DEG C, and drying time is 10--15 minutes；Bake again：Baking temperature is 150---160 DEG C, the time is 3--5 minutes；
(6) back side printing paste：Gloves are turned over, the gloves dried of slurry are scraped into front is translated into reverse side and scrape slurry again, wherein, decorative pattern：Full bottom, scrapes Starching pressure is：7-9kg, temperature：20-30℃；
(7) dry：First dry：Drying temperature is 95-100 DEG C, and drying time is 10--15 minutes；Bake again：Baking temperature is 150---160 DEG C, the time is 3--5 minutes；
(8) repeat step (4), (5), (6), (7) are each once；
(9) impregnation：Liquid fourth fine latex of the dipping to after reconciling, the fine latex of liquid fourth is by butadiene and acrylonitrile compolymer A kind of synthetic rubber, with excellent oil resistivity, preferable heat resistance and wearability, and very strong cementability； Then glue surface is slightly blown using fan, temperature is 100-105 DEG C, and blow-time is 8-10 minutes；
(10) dry：By oven cooking cycle, temperature is 120--130 DEG C, and the time is 40-60 minutes；
(11) wash；Normal temperature is washed 15-20 minutes；
(12) dry；Drying temperature is 102-105 DEG C, and drying time is 15--20 minutes.
CN201710158892.1A 2017-03-16 2017-03-16 A kind of processing method of polyamide fibre Graphene white dipped gloves Pending CN106868885A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108642884A (en) * 2018-05-18 2018-10-12 江南大学 The preparation method and its resulting materials of a kind of painted graphite alkene fiber and application

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CN102429331A (en) * 2011-10-16 2012-05-02 张晖 Manufacturing technique for aqueous PU (Polyurethane) glove
CN104738838A (en) * 2013-12-25 2015-07-01 沙嫣 Water-based PU coating glove production method
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CN105113082A (en) * 2015-09-07 2015-12-02 南通强生安全防护科技有限公司 Anti-cutting cladding yarn and preparation method and purpose
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108642884A (en) * 2018-05-18 2018-10-12 江南大学 The preparation method and its resulting materials of a kind of painted graphite alkene fiber and application

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Application publication date: 20170620