CN104738838A - Water-based PU coating glove production method - Google Patents

Water-based PU coating glove production method Download PDF

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CN104738838A
CN104738838A CN 201310727250 CN201310727250A CN104738838A CN 104738838 A CN104738838 A CN 104738838A CN 201310727250 CN201310727250 CN 201310727250 CN 201310727250 A CN201310727250 A CN 201310727250A CN 104738838 A CN104738838 A CN 104738838A
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glove
agent
coating
immersed
pu
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CN 201310727250
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CN104738838B (en )
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沙嫣
沙晓林
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沙嫣
沙晓林
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Abstract

A water-based PU coating glove production method comprises the steps of enabling a knitted glove to be immersed into a coagulating agent to perform coagulating agent coating treatment, enabling the glove to be immersed into a coating agent, enabling the glove to be immersed into a curing agent to perform agent coating and uniformizing treatment, conducting prevulcanization and drying on the glove, conducting water processing on the glove and conducting vulcanization and drying on the grove, wherein the coating agent comprises 80%-90% of water-based PU resin, 2%-10% of filling material, 1%-5% of extinction powder, 0.1%-5% of abrasion resisting agent and 3%-5% of thickening agent.

Description

水性PU涂层手套生产方法 The method of producing an aqueous PU coated gloves

技术领域 FIELD

[0001] 本发明涉及一种涂层手套生产方法,尤其是一种水性PU手套生产方法。 [0001] The present invention relates to a method for producing a coated glove, in particular a method for producing an aqueous PU gloves.

背景技术 Background technique

[0002] 涂层手套又称PU涂胶手套或PU贴指、贴掌手套,是将经特殊处理的聚氨酯完全覆盖在手掌部分,能提供良好的防滑性能,并能防止人体手掌的手汗和微粒污染。 [0002] The adhesive coated gloves known as PU or PU glove finger stick, glove palm paste, is specially treated urethane completely cover palm portion, to provide good slip resistance, and to prevent the body and the palm of the hand sweat particulate contamination. 传统的PU涂层手套生产方法中,需使用二甲基甲酰胺(DMF)作为溶剂,而DMF具有较高的毒性,如手套中有DMF残留,穿戴后能够经皮肤及呼吸道吸收,对肝脏功能造成损害,给劳动者的身体健康带来不利的影响。 PU coated glove conventional production method, need to use dimethylformamide (DMF) as a solvent, but DMF with high toxicity, such as gloves have residual DMF, the respiratory tract and can be absorbed through the skin after the wearer, liver function damage, adverse impact on the health of workers. 因此,其他很多制造领域,DMF含量已经受到了严格的控制,例如: 汽车制造业、皮革业、制鞋业。 Therefore, many other manufacturing areas, DMF content has been strictly controlled, such as: automotive industry, leather industry, the footwear industry. 另外,使用DMF作用溶剂的制造工艺复杂,需水量和能耗量都非常大,造成了资源浪费,不利于环境保护。 In addition, the use of DMF solvent effect of complex manufacturing process, water demand and energy consumption is very large, resulting in a waste of resources, is not conducive to environmental protection.

发明内容 SUMMARY

[0003] 本发明的目的在于提供一种水性涂层手套生产方法,其不使用有毒的二甲基甲酰胺(DMF)作为溶剂,可以避免对劳动者的健康造成损害;而且其制造工艺简单,需水量和能耗量都大大降低,节约资源,保护环境。 [0003] The object of the present invention to provide a method for producing an aqueous coating gloves, without using toxic dimethylformamide (DMF) as solvent, to avoid damage to the health of workers; and simple manufacturing process, water demand and energy consumption are greatly reduced, saving resources and protecting the environment.

[0004] 本发明的又一目的在于提供用于一种水性PU涂层手套生产方法的涂层剂,其不使用有毒的DMF作为溶剂,可以避免对劳动者的健康造成损害,而且其能够简化制造工艺, 大大降低需水量和能耗量,节约资源,保护环境。 [0004] A further object of the present invention to provide a coating agent for producing an aqueous PU coated gloves, without using a toxic solvent as DMF, to avoid damage to the health of workers, which can be simplified and manufacturing process, greatly reducing water demand and energy consumption, saving resources and protecting the environment.

[0005] 本发明的又一目的在于提供一种水性涂层手套,其生产过程中不使用有毒的DMF作为溶剂,没有有毒物质残留,可以避免对劳动者的健康造成损害。 [0005] A further object of the present invention is to provide an aqueous coating glove, its production process does not use toxic in DMF as a solvent, no toxic residues, to avoid damage to the health of workers.

[0006] 为达到以上目的,本发明提供一种水性涂层手套生产方法,包括: [0006] To achieve the above object, the present invention provides an aqueous coating glove production method, comprising:

[0007] 将一针织手套浸入一凝固剂中,进行淋凝固剂处理; [0007] The glove was immersed in a knitting a coagulant, a coagulant leaching process;

[0008] 将该手套浸入一涂层剂中,其中,该涂层剂包括:80~90%水性PU树脂,2~10% 填充料,1~5%消光粉,0. 1~5%耐磨剂,3~5%增稠剂; [0008] The glove was immersed in a coating agent, wherein the coating comprises: 80 to 90% aqueous PU resin, 2-10% filler, 1 to 5% matting 01 resistant to 5% grinding agents, 3-5% thickener;

[0009] 将该手套浸入一固化剂,进行淋浆和匀浆处理; [0009] The glove was immersed in a curing agent, a leaching pulp and homogenized;

[0010] 将手套进行预硫化烘干; [0010] The glove was presulfided drying;

[0011] 将手套进行水洗处理;及 [0011] The treated glove was washed with water; and

[0012] 将该手套进行硫化烘干。 [0012] The vulcanized dry gloves.

[0013] 本发明还提供了用于一种水性涂层手套生产方法的涂层剂,包括:80~90%水性PU树脂,2~10%填充料,1~5%消光粉,0. 1~5%耐磨剂,3~5%增稠剂。 [0013] The present invention further provides an aqueous coating agent for producing coated gloves, comprising: 80 to 90% aqueous PU resin, 2-10% filler, 1 to 5% matting 01. ~ 5% anti-wear agent, a thickening agent 3-5%.

[0014] 本发明还提供了一种根据上述涂层手套生产方法制得的PU涂层手套。 [0014] The present invention also provides a PU coated glove prepared according to the above method for producing coated gloves.

[0015] 本发明提供的水性PU涂层手套生产方法,其不使用有毒的二甲基甲酰胺(DMF)作为溶剂,可以避免对劳动者的健康造成损害;而且其制造工艺简单,需水量和能耗量都大大降低,节约资源,保护环境,为可持续发展做出贡献。 [0015] The aqueous PU coated glove producing method of the present invention provides, without using toxic dimethylformamide (DMF) as solvent, to avoid damage to the health of workers; and its manufacturing process is simple, and water demand energy consumption are greatly reduced, saving resources and protecting the environment and contribute to sustainable development.

[0016] 本发明的这些目的,特点,和优点将会在下面的具体实施方式,附图,和权利要求中详细的揭露。 [0016] These objects, features, and advantages of the present invention will be disclosed in detail in the following detailed description, the drawings, and the appended claims.

附图说明 BRIEF DESCRIPTION

[0017] 图1为根据本发明的一具体实施例的水性涂层手套生产方法的流程图。 [0017] FIG. 1 is a flowchart of a particular embodiment coated gloves aqueous embodiment of the present invention production process.

具体实施方式 detailed description

[0018] 参见图1,一种水性I3U涂层手套生产方法,包括: [0018] Referring to Figure 1, an aqueous coating I3U glove production method, comprising:

[0019]将一针织手套浸入一凝固剂中,进行淋凝固剂处理; [0019] The glove was immersed in a knitting a coagulant, a coagulant leaching process;

[0020] 将该手套浸入一涂层剂中,其中,该涂层剂包括:80~90%水性PU树脂,2~10% 填充料,1~5%消光粉,0. 1~5%耐磨剂,3~5%增稠剂;及 [0020] The glove was immersed in a coating agent, wherein the coating comprises: 80 to 90% aqueous PU resin, 2-10% filler, 1 to 5% matting 01 resistant to 5% grinding agents, 3-5% thickener; and

[0021] 将该手套浸入一固化剂,进行淋浆和匀浆处理。 [0021] The glove was immersed in a curing agent, a leaching pulp and homogenized.

[0022] 优选的,其中,该涂层剂包括:85~87%水性PU树脂,6~8%填充料,1~3%消光粉,0. 5~2. 5%耐磨剂,及3~4. 5%增稠剂。 [0022] Preferably, wherein the coating comprises: 85 to 87% aqueous PU resin, 6-8% filler, 1 to 3% matting 05 ~ 25% anti-wear agent, and 3 ~ 4.5% thickener.

[0023]优选的,该水性涂层手套生产方法进一步包括:在进行淋浆和匀浆处理后,将手套进行预硫化烘干;将手套进行水洗处理;及将该手套进行硫化烘干。 [0023] Preferably, the aqueous coating glove production method further comprising: after performing the leaching pulp and homogenized, and drying the glove presulfided; glove was washed with water; dried and curing the glove.

[0024]优选的,其中,该水洗处理包括:先温水浸泡洗5~10分钟,及再温水漂洗5~10分钟。 [0024] Preferably, wherein the washing treatment comprising: a first soaking wash in warm water 5 to 10 minutes, and then rinsed with warm water for 5 to 10 minutes.

[0025]根据上述涂层手套生产方法制得的PU涂层手套。 [0025] PU coated glove prepared according to the above method for producing coated gloves.

[0026] -种用于I3U涂层手套生产方法的涂层剂,包括:80~90%水性PU树脂,2~10% 填充料,1~5%消光粉,0. 1~5%耐磨剂,及3~5%增稠剂。 [0026] - seed coating agent for producing coated gloves I3U method, comprising: 80 to 90% aqueous PU resin, 2-10% filler, 1 to 5% matting agent, 01 to 5% wear. agent, a thickening agent and 3 to 5%.

[0027]优选的,其中,该涂层剂包括:85~87%水性PU树脂,6~8%填充料,1~3%消光粉,0. 5~2. 5%耐磨剂,及3~4. 5%增稠剂。 [0027] Preferably, wherein the coating comprises: 85 to 87% aqueous PU resin, 6-8% filler, 1 to 3% matting 05 ~ 25% anti-wear agent, and 3 ~ 4.5% thickener.

[0028] 实施例1 :一种水性I3U涂层手套生产方法,包括: 1 [0028] Example: An aqueous coating I3U glove production method, comprising:

[0029]将一针织手套浸入一凝固剂中,进行淋凝固剂处理; [0029] The glove was immersed in a knitting a coagulant, a coagulant leaching process;

[0030]将该手套浸入一涂层剂中,其中,该涂层剂包括:82%水性PU树脂,9%填充料, 1 %消光粉,5 %耐磨剂,及3 %增稠剂; [0030] The glove was immersed in a coating agent, wherein the coating comprises: 82% aqueous PU resin, 9% filler, 1% matting agent, anti-wear agent 5% and 3% thickener;

[0031]将该手套浸入一固化剂,进行淋浆和匀浆处理; [0031] The glove was immersed in a curing agent, a leaching pulp and homogenized;

[0032]将手套进行预硫化烘干; [0032] The glove was presulfided drying;

[0033]将手套用温水浸泡洗5~10分钟,再用温水漂洗5~10分钟;及[0034]将该手套进行硫化烘干。 [0033] The glove was washed with warm water and soaked for 5 to 10 minutes, then rinsed with hot water 5 to 10 minutes; and [0034] drying the glove is vulcanized.

[0035] 实施例2 :-种水性PU涂层手套生产方法,包括: 2 [0035] Example: - Species aqueous PU coated glove production method, comprising:

[0036]将一针织手套浸入一凝固剂中,进行淋凝固剂处理; [0036] The glove was immersed in a knitting a coagulant, a coagulant leaching process;

[0037]将该手套浸入一涂层剂中,其中,该涂层剂包括:88%水性PU树脂,5%填充料, 3 %消光粉,0. 8 %耐磨剂,及3. 2 %增稠剂; [0037] The glove was immersed in a coating agent, wherein the coating comprises: 88% aqueous PU resin, 5% filler, matting 3% 0 8% anti-wear agent, and 3.2%. thickener;

[0038]将该手套浸入一固化剂,进行淋浆和匀浆处理; [0038] The glove was immersed in a curing agent, a leaching pulp and homogenized;

[0039]将手套进行预硫化烘干; [0039] The glove was presulfided drying;

[0040]将手套用温水浸泡洗5~10分钟,再用温水漂洗5~10分钟;及 [0040] The glove was immersed 5 to 10 minutes to wash with warm water, rinsed with warm water for 5-10 minutes; and

[0041] 将该手套进行硫化烘干。 [0041] The vulcanized dry gloves.

[0042] 实施例3 :-种水性PU涂层手套生产方法,包括: 3 [0042] Example: - Species aqueous PU coated glove production method, comprising:

[0043] 将一针织手套浸入一凝固剂中,进行淋凝固剂处理; [0043] The glove was immersed in a knitting a coagulant, a coagulant leaching process;

[0044] 将该手套浸入一涂层剂中,其中,该涂层剂包括:90%水性PU树脂,4 %填充料, 1. 2 %消光粉,1. 3 %耐磨剂,及3. 5 %增稠剂; [0044] The glove was immersed in a coating agent, wherein the coating comprises: 90% aqueous PU resin, 4% filler, 1.2% matting agent, 13% anti-wear agent, and 3. 5% thickener;

[0045] 将该手套浸入一固化剂,进行淋浆和匀浆处理; [0045] The glove was immersed in a curing agent, a leaching pulp and homogenized;

[0046] 将手套进行预硫化烘干; [0046] The glove was presulfided drying;

[0047] 将手套用温水浸泡洗5~10分钟,再用温水漂洗5~10分钟;及 [0047] The glove was immersed 5 to 10 minutes to wash with warm water, rinsed with warm water for 5-10 minutes; and

[0048] 将该手套进行硫化烘干。 [0048] The vulcanized dry gloves.

[0049] 实施例4:一种水性PU涂层手套生产方法,包括: 4 [0049] Example: An aqueous PU coated glove production method, comprising:

[0050] 将一针织手套浸入一凝固剂中,进行淋凝固剂处理; [0050] The glove was immersed in a knitting a coagulant, a coagulant leaching process;

[0051] 将该手套浸入一涂层剂中,其中,该涂层剂包括:86%水性PU树脂,7 %填充料, 2%消光粉,1.5%耐磨剂,及3. 5%增稠剂; [0051] The glove was immersed in a coating agent, wherein the coating comprises: 86% aqueous PU resin, 7% filler, 2% matting agent, 1.5% anti-wear agent, and 3.5% thickening agent;

[0052] 将该手套浸入一固化剂,进行淋浆和匀浆处理; [0052] The glove was immersed in a curing agent, a leaching pulp and homogenized;

[0053] 将手套进行预硫化烘干; [0053] The glove was presulfided drying;

[0054] 将手套用温水浸泡洗5~10分钟,再用温水漂洗5~10分钟;及 [0054] The glove was immersed 5 to 10 minutes to wash with warm water, rinsed with warm water for 5-10 minutes; and

[0055] 将该手套进行硫化烘干。 [0055] The vulcanized dry gloves.

[0056] 对比例:该涂层剂包括:70%PU树脂,20%丁腈胶,1%发泡剂,1%十二烷基磺酸钠,2 %油酸钾,1 %增稠剂,及5 %稳泡剂。 [0056] Comparative Example: The coating comprises: 70% PU resin, 20% nitrile rubber, 1% foaming agent, 1% sodium dodecyl sulfate, 2% potassium oleate, 1% thickener , and 5% of a foam stabilizer.

[0057] 表1对比例与各实施例所采用的涂层剂性能对比 The coating agent used in Comparative Example Properties [0057] Table 1 Comparative respective embodiments

[0058] [0058]

Figure CN104738838AD00051

[0059] 由表1可见,本发明所采用的涂层剂在耐磨性、剥离强度、耐水性方面,都优于该对比例中所采用的涂层剂,且VOC含量大大低于该对比例。 [0059] From Table 1, the coating agent used in the present invention, abrasion resistance, peel strength, water resistance, are better than the comparative coating agents employed, and the VOC content substantially lower than the pair proportion.

[0060] 将实施例1~4进行对比,可以发现,实施例4在剥离强度、耐水性及VOC含量方面都优于其他三个实施例,在耐磨性方面稍逊于实施例1,但优于实施例1和实施例2。 [0060] Examples 1 to 4 were compared, it was found in Example 4 peel strength, water resistance and VOC content are superior to the other three embodiments, the wear resistance is slightly inferior to Example 1, but Example 1 and Example 2 is superior embodiment. 因此,综合来看,实施例4为最佳实施例。 Thus, together, Example 4 is a preferred embodiment.

[0061] 通过上述实施例,本发明的目的已经被完全有效的达到了。 [0061] By the above-described embodiment, the object of the present invention have been fully and effectively accomplished. 熟悉该项技艺的人士应该明白本发明包括但不限于附图和上面具体实施方式中描述的内容。 The person skilled in the art should be understood that the present invention include, but are not limited to the specific embodiments and the drawings in the above described embodiment content. 任何不偏离本发明的功能和结构原理的修改都将包括在权利要求书的范围中。 Any modification without departing from the functional and structural principles of the present invention are included in the scope of the appended claims.

Claims (7)

  1. 1. 一种水性PU涂层手套生产方法,包括: 将一针织手套浸入一凝固剂中,进行淋凝固剂处理; 将该手套浸入一涂层剂中,其中,该涂层剂包括:80~90%水性PU树脂,2~10%填充料,1~5%消光粉,0. 1~5%耐磨剂,及3~5%增稠剂;及将该手套浸入一固化剂,进行淋浆和匀浆处理。 CLAIMS 1. A method for producing an aqueous PU coated glove, comprising: a knitted glove was immersed in a coagulant, a coagulant leaching process; The glove was immersed in a coating agent, wherein the coating comprises: 80 ~ . 90% aqueous PU resin, 2-10% filler, 1 to 5% matting agent, 01 to 5% antiwear agents, and 3-5% thickener; and the glove is immersed in a curing agent, a leaching pulp and homogenized.
  2. 2. 根据权利要求1所述的PU涂层手套生产方法,其中,该涂层剂包括:85~87%水性PU树脂,6~8%填充料,1~3%消光粉,0. 5~2. 5%耐磨剂,及3~4. 5%增稠剂。 2. The method of producing the PU coated glove according to claim 1, wherein the coating comprises: 85 to 87% aqueous PU resin, 6-8% filler, 1 to 3% matting 05 ~. 2.5% anti-wear agent, and 3 to 4.5% thickener.
  3. 3. 根据权利要求1所述的涂层手套生产方法,进一步包括:在进行淋浆和匀浆处理后, 将手套进行预硫化烘干; 将手套进行水洗处理;及将该手套进行硫化烘干。 3. The method of producing coated gloves according to claim 1, further comprising: after performing homogenized pulp and leaching, and drying the glove presulfided; glove was washed with water; dried and vulcanizing the glove .
  4. 4. 根据权利要求3所述的PU涂层手套生产方法,其中,该水洗处理包括:先温水浸泡洗5~10分钟,及再温水漂洗5~10分钟。 4. PU coating production method of a glove according to claim 3, wherein the washing treatment comprising: a first soaking wash in warm water 5 to 10 minutes, and then rinsed with warm water for 5 to 10 minutes.
  5. 5. 根据权利要求1、2、3或4所述的PU涂层手套生产方法制得的PU涂层手套。 PU coated glove prepared producing PU coated glove according to claim 2, 3 or 4.
  6. 6. -种用于I3U涂层手套生产方法的涂层剂,包括:80~90%水性PU树脂,2~10%填充料,1~5%消光粉,0. 1~5%耐磨剂,3~5%增稠剂。 6. - seed coating agent for producing coated gloves I3U method, comprising: 80 to 90% aqueous PU resin, 2-10% filler, 1 to 5% matting agent, 01 to 5% antiwear agents. , 3 to 5% thickener.
  7. 7. 根据权利要求6所述的用于PU涂层手套生产方法的涂层剂,包括:85~87%水性PU 树脂,6~8%填充料,1~3%消光粉,0. 5~2. 5%耐磨剂,及3~4. 5%增稠剂。 7. A coating agent according to claim PU coated glove production process of claim 6, comprising: 85 to 87% aqueous PU resin, 6-8% filler, 1 to 3% matting 05 ~ 2.5% anti-wear agent, and 3 to 4.5% thickener.
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