CN106867372A - A kind of high-hardness water-proof wallpaper - Google Patents

A kind of high-hardness water-proof wallpaper Download PDF

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Publication number
CN106867372A
CN106867372A CN201611198337.3A CN201611198337A CN106867372A CN 106867372 A CN106867372 A CN 106867372A CN 201611198337 A CN201611198337 A CN 201611198337A CN 106867372 A CN106867372 A CN 106867372A
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China
Prior art keywords
parts
resin
raw material
modified
waterproof layer
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Withdrawn
Application number
CN201611198337.3A
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Chinese (zh)
Inventor
陈少明
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Anhui Easy Wallpaper Co Ltd
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Anhui Easy Wallpaper Co Ltd
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Application filed by Anhui Easy Wallpaper Co Ltd filed Critical Anhui Easy Wallpaper Co Ltd
Priority to CN201611198337.3A priority Critical patent/CN106867372A/en
Publication of CN106867372A publication Critical patent/CN106867372A/en
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0011—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/121—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyesters, polycarbonates, alkyds
    • D06N3/123—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyesters, polycarbonates, alkyds with polyesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D21H19/385—Oxides, hydroxides or carbonates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/46—Non-macromolecular organic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/52—Cellulose; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/80—Paper comprising more than one coating
    • D21H19/82—Paper comprising more than one coating superposed
    • D21H19/822—Paper comprising more than one coating superposed two superposed coatings, both being pigmented
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18—Paper- or board-based structures for surface covering
    • D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00—Coverings or linings, e.g. for walls or ceilings
    • E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paper (AREA)

Abstract

The invention discloses a kind of high-hardness water-proof wallpaper, including substrate layer, waterproof layer and high rigidity overcoat, the periphery of substrate layer is coated with waterproof layer, and waterproof layer is coated with high rigidity overcoat away from the periphery of substrate layer, wherein：The raw material of high rigidity overcoat includes rosin phenolic resin, modified polyurethane, styrene-acrylic emulsion, Corvic, nano inorganic antimicrobial powder, rosin resin, epoxy resin, alkyd resin, butyl acetate, aluminium hydroxide, calcium ferrite, nitrocotton, mica powder, zinc oxide, chlorinated paraffin, calcium ferrite, modified additive, silane coupler KH 570, hexamethyl cellulose, citric acid and curing agent.Wallpaper of the invention has excellent hardness and water resistance.

Description

A kind of high-hardness water-proof wallpaper
Technical field
The present invention relates to wallpaper field, more particularly to a kind of high-hardness water-proof wallpaper.
Background technology
With the raising of people's living standard and quality of life, quality, wind of the increasing consumer to interior decoration Lattice, grade also more and more higher, wallpaper are widely used in interior decoration decoration by people, and wallpaper miscellaneous can meet consumer's Difference is required.The demand when hardness and water resistance of wallpaper cannot meet actually used in the prior art, therefore need design badly A kind of demand when high-hardness water-proof wallpaper is to meet actually used.
The content of the invention
To solve technical problem present in background technology, the present invention proposes a kind of high-hardness water-proof wallpaper, the wall for obtaining Paper has excellent hardness and water resistance.
A kind of high-hardness water-proof wallpaper proposed by the present invention, including substrate layer, waterproof layer and high rigidity overcoat, substrate layer Periphery be coated with waterproof layer, the waterproof layer is coated with high rigidity overcoat away from the periphery of substrate layer, wherein：
Substrate layer is any one in wood pulp paper, non-woven paper, cloth；
The raw material of waterproof layer includes by weight：18-24 parts of water-based hydroxyl acrylic acid modified saturated polyester resin, aqueous third 5-15 parts of olefin(e) acid modified polyester resin, aqueous saturated polyester resin 6-12 parts, HMMM resin 3-15 parts, Aqueous 3-6 parts of pure third resin, Amino resin 1-5 parts, modifying epoxy resin by organosilicon 2-5 parts, organic-silicon-modified alkyd Resin 1-4 parts, carbon black 2-5 parts, modified filler 3-9 parts, 1-3 parts of silane coupler KH-560,2-5 parts of waterproof reinforcing agent, froth breaking Agent 0.5-1.5 parts, levelling agent 1.2-1.6 parts, acetylbutyrylcellulose 2-4 parts, dimethylethanolamine 3-5 parts, diethylene glycol list Butyl ether 1-3 parts, deionized water 4-8 parts；
The raw material of high rigidity overcoat includes by weight：Rosin phenolic resin 25-45 parts, modified polyurethane 2-9 parts, benzene Acrylic emulsion 3-9 parts, Corvic 1-5 parts, 3-9 parts of nano inorganic antimicrobial powder, rosin resin 4-12 parts, epoxy resin 2- 8 parts, alkyd resin 1-5 parts, butyl acetate 3-5 parts, aluminium hydroxide 2-6 parts, calcium ferrite 3-5 parts, nitrocotton 1-4 parts, mica powder 2-6 parts, zinc oxide 1-4 parts, chlorinated paraffin 2-6 parts, calcium ferrite 2-8 parts, modified additive 4-9 parts, Silane coupling reagent KH-570 4- 9 parts, 3-6 parts, citric acid 1-4 parts, curing agent 2-5 parts of hexamethyl cellulose.
Preferably, in the raw material of waterproof layer, the raw material of modified filler includes by weight：Active calcium silicate 10-50 parts, it is hard 3-6 parts of resin acid calcium, Nano carbon white 2-8 parts, calcined kaolin 1-6 parts, magnesium hydroxide 3-9 parts, wood fiber powder 1-6 parts, sky 2-7 parts of heart glass microballoon, tossa 1-3 parts, methacrylate 4-9 parts, 2-5 parts of silane coupler KH570, lubricant 3-8 parts.
Preferably, in the raw material of waterproof layer, modified filler is prepared by following technique：By active calcium silicate and stearic acid Calcium is well mixed, and stirring at low speed 10-25min is sealed at a temperature of 50-60 DEG C, then with Nano carbon white, calcined kaolin, wood Matter fiber powder, hollow glass micropearl and tossa are well mixed, 45-55 DEG C of sealing stirring at low speed 5-10min, add hydrogen-oxygen Change magnesium, methacrylate, silane coupler KH570 and lubricant, be warming up to 135-140 DEG C, stirring at low speed 10-20min goes out Material, is cooled to room temperature and obtains modified filler.
Preferably, in the raw material of waterproof layer, waterproof reinforcing agent is prepared by following technique：Polyvinylpyrrolidone is molten Solution and n-amyl alcohol are well mixed, ultrasonic 40-50min, are subsequently adding the mixing of absolute alcohol, deionized water and sodium citrate solution equal It is even, it is subsequently added into ammoniacal liquor and is well mixed, it is subsequently adding tetraethyl orthosilicate, ultrasonic disperse 1-3min, then in 75-85 DEG C of oil bath Pot in react 16-20h, be washed with deionized 1-3 time simultaneously centrifugation, centrifugal rotational speed is 3800-4200r/min, then in 2-4h is dried in 45-55 DEG C of baking oven and finally obtains waterproof reinforcing agent.
Preferably, in the raw material of waterproof layer, in the preparation technology of waterproof reinforcing agent, polyvinylpyrrolidone, sodium citrate The weight ratio of solution and tetraethyl orthosilicate is 2-5：1-3：2-4.
Preferably, in the raw material of high rigidity overcoat, the raw material of modified additive includes by weight：Methyl methacrylate 4-8 parts, deionized water 2-4 parts, nano silicon 2-5 parts, neopelex 1-3 parts, APES 1-4 parts, ammonium persulfate 2-4 parts, isopropyl titanate 3-6 parts, the 4-8 of silane coupling A -174 parts.
Preferably, in the raw material of high rigidity overcoat, modified additive is prepared by following technique：By methyl methacrylate Ester carries out vacuum distillation, is subsequently adding deionized water, nano silicon, neopelex and alkylphenol-polyethenoxy Ether is well mixed, and ultrasonic agitation 20-40min then heats to 65-85 DEG C, be subsequently adding ammonium persulfate and silane coupling A- 174,5-15min is stirred, then add isopropyl titanate and be well mixed, then pH is adjusted to 7-8 with ammoniacal liquor, normal temperature is cooled to, Filtration under diminished pressure takes filter cake, then with water washing filter cake is distilled 3-4 times, filter cake then is dried into 22-26h in 45-55 DEG C, grinds To modified additive.
A kind of high-hardness water-proof wallpaper of the invention, including substrate layer, waterproof layer and high rigidity overcoat, outside substrate layer It is coated with waterproof layer week, the waterproof layer is coated with high rigidity overcoat away from the periphery of substrate layer, wherein：Substrate layer is wood pulp Any one in paper, non-woven paper, cloth；The raw material of waterproof layer includes water-based hydroxyl acrylic acid modified saturated polyester resin, aqueous Acrylic acid modified polyester resin, aqueous saturated polyester resin, HMMM resin, aqueous pure third resin, first Etherified amino resins, modifying epoxy resin by organosilicon, silicone alkyd, carbon black, modified filler, silane coupler KH-560, waterproof reinforcing agent, defoamer, levelling agent, acetylbutyrylcellulose, dimethylethanolamine, diethylene glycol monobutyl ether and Deionized water, with water-based hydroxyl acrylic acid modified saturated polyester resin, water-borne acrylic acid modified polyester resin, aqueous saturated polyester Resin, HMMM resin, aqueous pure third resin, Amino resin, modifying epoxy resin by organosilicon It is base-material with silicone alkyd, with carbon black and modified filler as filler, is strengthened with silane coupler KH-560, waterproof Agent, defoamer, levelling agent, acetylbutyrylcellulose, dimethylethanolamine, diethylene glycol monobutyl ether and deionized water are auxiliary agent, By the cooperation of base-material, filler and auxiliary agent, rationally control is matched, and the waterproof layer for obtaining has excellent water resistance.Wherein, change Property filler be well mixed by by active calcium silicate and calcium stearate, seal stirring at low speed, it is then high with Nano carbon white, calcining Ridge soil, wood fiber powder, hollow glass micropearl and tossa are well mixed, and seal stirring at low speed, add magnesium hydroxide, first Base acrylate, silane coupler KH570 and lubricant, stirring at low speed after intensification, discharging are cooled to room temperature and obtain modified filling out Material, further effectively increases the water resistance of waterproof layer.The waterproof reinforcing agent for wherein adding is by by polyvinylpyrrolidone Dissolving and n-amyl alcohol are well mixed, ultrasound, are subsequently adding absolute alcohol, deionized water and sodium citrate solution and are well mixed, and connect Addition ammoniacal liquor to be well mixed, be subsequently adding tetraethyl orthosilicate, ultrasonic disperse reacts in oil bath pan, is washed with deionized And centrifugation, then drying finally obtains waterproof reinforcing agent in baking oven.Further it has been improved the water resistance of waterproof layer. The raw material of high rigidity overcoat includes rosin phenolic resin, modified polyurethane, styrene-acrylic emulsion, Corvic, nano inorganic Antimicrobial powder, rosin resin, epoxy resin, alkyd resin, butyl acetate, aluminium hydroxide, calcium ferrite, nitrocotton, mica powder, oxygen Change zinc, chlorinated paraffin, calcium ferrite, modified additive, Silane coupling reagent KH-570, hexamethyl cellulose, citric acid and curing agent, its In with rosin phenolic resin, modified polyurethane, styrene-acrylic emulsion, Corvic, rosin resin, epoxy resin, alkyd resin It is base-material with butyl acetate, with nano inorganic antimicrobial powder, aluminium hydroxide, calcium ferrite, nitrocotton, mica powder, zinc oxide, chlorination Paraffin, calcium ferrite and modified additive are filler, are with Silane coupling reagent KH-570, hexamethyl cellulose, citric acid and curing agent Auxiliary agent, by the cooperation of base-material, filler and auxiliary agent, rationally control is matched, and the high rigidity overcoat hardness for obtaining is high, protective It is good.Wherein modified additive carries out vacuum distillation by by methyl methacrylate, is subsequently adding deionized water, nanometer titanium dioxide Silicon, neopelex and APES are well mixed, ultrasonic agitation, and ammonium persulfate and silicon are added after intensification Alkane coupling agent A-174, adds isopropyl titanate and is well mixed after stirring, then adjust pH with ammoniacal liquor, is cooled to normal temperature, depressurizes Leaching filter cake, then with distillation water washing filter cake, then by filter cake in drying, grinding obtains modified additive, further increases The hardness of high rigidity overcoat.The wallpaper hardness that the present invention is prepared is high, and water resistance is strong.
Brief description of the drawings
Fig. 1 is a kind of structural representation of high-hardness water-proof wallpaper proposed by the present invention.
Specific embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair Bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent etc. are in this hair In bright protection domain.
Embodiment 1
As shown in figure 1, Fig. 1 is a kind of structural representation of high-hardness water-proof wallpaper proposed by the present invention.
Reference picture 1, a kind of high-hardness water-proof wallpaper of the invention, including substrate layer 1, waterproof layer 2 and high rigidity overcoat 3, the periphery of substrate layer 1 is coated with waterproof layer 2, and the waterproof layer 2 is coated with high rigidity overcoat 3 away from the periphery of substrate layer 1, Wherein：
Substrate layer 1 is wood pulp paper；
The raw material of waterproof layer 2 includes by weight：21 parts of water-based hydroxyl acrylic acid modified saturated polyester resin, aqueous acrylamide 10 parts of sour modified polyester resin, 9 parts of aqueous saturated polyester resin, 9 parts of HMMM resin, aqueous pure third tree 4.5 parts of fat, 3 parts of Amino resin, 3.5 parts of modifying epoxy resin by organosilicon, 2.5 parts of silicone alkyd, charcoal Black 3.5 parts, 6 parts of modified filler, 2 parts of silane coupler KH-560,3.5 parts of waterproof reinforcing agent, 1 part of defoamer, levelling agent 1.4 Part, 3 parts of acetylbutyrylcellulose, 4 parts of dimethylethanolamine, 2 parts of diethylene glycol monobutyl ether, 6 parts of deionized water；
The raw material of high rigidity overcoat 3 includes by weight：35 parts of rosin phenolic resin, 5.5 parts of modified polyurethane, phenylpropyl alcohol 6 parts of emulsion, 3 parts of Corvic, 6 parts of nano inorganic antimicrobial powder, 8 parts of rosin resin, 8 parts of epoxy resin, alkyd resin 6 Part, 4 parts of butyl acetate, 4 parts of aluminium hydroxide, 4 parts of calcium ferrite, 2.5 parts of nitrocotton, 4 parts of mica powder, 2.5 parts of zinc oxide, chlorination stone 4 parts of wax, 5 parts of calcium ferrite, 6.5 parts of modified additive, 6.5 parts of Silane coupling reagent KH-570,4.5 parts of hexamethyl cellulose, citric acid 2.5 parts, 3.5 parts of curing agent.
In the raw material of waterproof layer 2, modified filler is prepared by following technique：By weight by 30 parts of active calcium silicates and 4.5 parts of calcium stearates are well mixed, and stirring at low speed 17.5min are sealed at a temperature of 55 DEG C, then with 5 parts of Nano carbon whites, 3.5 Part calcined kaolin, 3.5 parts of wood fiber powders, 4.5 parts of hollow glass micropearls and 2 parts of tossas are well mixed, 50 DEG C of sealings Stirring at low speed 7.5min, adds 6 parts of magnesium hydroxides, 6.5 parts of methacrylates, 3.5 parts of silane coupler KH570 and 5.5 Part lubricant, is warming up to 137.5 DEG C, and stirring at low speed 15min, discharging is cooled to room temperature and obtains modified filler.
In the raw material of waterproof layer 2, waterproof reinforcing agent is prepared by following technique：By weight by 3.5 parts of polyethylene pyrroles Pyrrolidone dissolves and n-amyl alcohol is well mixed, and ultrasonic 45min is subsequently adding absolute alcohol, deionized water and 2 parts of sodium citrates molten Liquid is well mixed, and is subsequently added into ammoniacal liquor and is well mixed, and is subsequently adding 3 parts of tetraethyl orthosilicates, ultrasonic disperse 2min, then in 80 18h is reacted in DEG C oil bath pan, 2 times and centrifugation is washed with deionized, centrifugal rotational speed is 4000r/min, then in 50 DEG C 3h is dried in baking oven and finally obtains waterproof reinforcing agent.
In the raw material of high rigidity overcoat 3, modified additive is prepared by following technique：By weight by 6 parts of methyl-props E pioic acid methyl ester carries out vacuum distillation, is subsequently adding 3 parts of deionized waters, 3.5 parts of nano silicons, 2 parts of DBSAs Sodium and 2.5 parts of APESs are well mixed, and ultrasonic agitation 30min then heats to 75 DEG C, is subsequently adding 3 parts of mistakes Ammonium sulfate and 6 parts of silane coupling A -174, stir 10min, then add 4.5 parts of isopropyl titanates and are well mixed, and then use ammonia Water adjusts pH to 7.5, is cooled to normal temperature, and filtration under diminished pressure takes filter cake, then with distillation water washing filter cake 3 times, then by filter cake in 50 DEG C dry 24h, and grinding obtains modified additive.
Embodiment 2
As shown in figure 1, Fig. 1 is a kind of structural representation of high-hardness water-proof wallpaper proposed by the present invention.
Reference picture 1, a kind of high-hardness water-proof wallpaper of the invention, including substrate layer 1, waterproof layer 2 and high rigidity overcoat 3, the periphery of substrate layer 1 is coated with waterproof layer 2, and the waterproof layer 2 is coated with high rigidity overcoat 3 away from the periphery of substrate layer 1, Wherein：
Substrate layer 1 is non-woven paper；
The raw material of waterproof layer 2 includes by weight：18 parts of water-based hydroxyl acrylic acid modified saturated polyester resin, aqueous acrylamide 15 parts of sour modified polyester resin, 6 parts of aqueous saturated polyester resin, 15 parts of HMMM resin, aqueous pure third 3 parts of resin, 5 parts of Amino resin, 2 parts of modifying epoxy resin by organosilicon, 4 parts of silicone alkyd, carbon black 2 Part, 9 parts of modified filler, 1 part of silane coupler KH-560,5 parts of waterproof reinforcing agent, 0.5 part of defoamer, 1.6 parts of levelling agent, vinegar 2 parts of sour cellulose butyrate, 5 parts of dimethylethanolamine, 1 part of diethylene glycol monobutyl ether, 8 parts of deionized water；
The raw material of high rigidity overcoat 3 includes by weight：25 parts of rosin phenolic resin, 9 parts of modified polyurethane, phenylpropyl alcohol breast 3 parts of liquid, 5 parts of Corvic, 3 parts of nano inorganic antimicrobial powder, 12 parts of rosin resin, 2 parts of epoxy resin, alkyd resin 5 Part, 3 parts of butyl acetate, 6 parts of aluminium hydroxide, 3 parts of calcium ferrite, 4 parts of nitrocotton, 2 parts of mica powder, 4 parts of zinc oxide, chlorinated paraffin 2 Part, 8 parts of calcium ferrite, 4 parts of modified additive, 9 parts of Silane coupling reagent KH-570,3 parts of hexamethyl cellulose, 4 parts of citric acid, solidification 2 parts of agent.
In the raw material of waterproof layer 2, modified filler is prepared by following technique：By weight by 10 parts of active calcium silicates and 6 parts of calcium stearates are well mixed, and stirring at low speed 25min is sealed at a temperature of 50 DEG C, then with 2 parts of Nano carbon whites, 6 parts of calcinings Kaolin, 1 part of wood fiber powder, 7 parts of hollow glass micropearls and 1 part of tossa are well mixed, 55 DEG C of sealing stirring at low speed 5min, adds 9 parts of magnesium hydroxides, 4 parts of methacrylates, 5 parts of silane coupler KH570 and 3 parts of lubricants, is warming up to 140 DEG C, stirring at low speed 10min, discharging is cooled to room temperature and obtains modified filler.
In the raw material of waterproof layer 2, waterproof reinforcing agent is prepared by following technique：By weight by 2 parts of polyvinyl pyrroles Alkanone dissolves and n-amyl alcohol is well mixed, and ultrasonic 50min is subsequently adding absolute alcohol, deionized water and 1 part of sodium citrate solution It is well mixed, it is subsequently added into ammoniacal liquor and is well mixed, it is subsequently adding 4 parts of tetraethyl orthosilicates, ultrasonic disperse 1min, then in 85 DEG C 16h is reacted in oil bath pan, 3 times and centrifugation is washed with deionized, centrifugal rotational speed is 3800r/min, then in 55 DEG C of bakings 2h is dried in case and finally obtains waterproof reinforcing agent.
In the raw material of high rigidity overcoat 3, modified additive is prepared by following technique：By weight by 4 parts of methyl-props E pioic acid methyl ester carries out vacuum distillation, is subsequently adding 4 parts of deionized waters, 2 parts of nano silicons, 3 parts of neopelexes Well mixed with 1 part of APES, ultrasonic agitation 40min then heats to 65 DEG C, is subsequently adding 4 parts of persulfuric acid Ammonium and 4 parts of silane coupling A -174, stir 15min, then add 3 parts of isopropyl titanates and are well mixed, and are then adjusted with ammoniacal liquor PH is cooled to normal temperature to 8, and filtration under diminished pressure takes filter cake, then with water washing filter cake is distilled 3 times, then by filter cake in 55 DEG C of dryings 22h, grinding obtains modified additive.
Embodiment 3
As shown in figure 1, Fig. 1 is a kind of structural representation of high-hardness water-proof wallpaper proposed by the present invention.
Reference picture 1, a kind of high-hardness water-proof wallpaper of the invention, including substrate layer 1, waterproof layer 2 and high rigidity overcoat 3, the periphery of substrate layer 1 is coated with waterproof layer 2, and the waterproof layer 2 is coated with high rigidity overcoat 3 away from the periphery of substrate layer 1, Wherein：
Substrate layer 1 is cloth；
The raw material of waterproof layer 2 includes by weight：24 parts of water-based hydroxyl acrylic acid modified saturated polyester resin, aqueous acrylamide 5 parts of sour modified polyester resin, 12 parts of aqueous saturated polyester resin, 3 parts of HMMM resin, aqueous pure third tree 6 parts of fat, 1 part of Amino resin, 5 parts of modifying epoxy resin by organosilicon, 1 part of silicone alkyd, 5 parts of carbon black, 3 parts of modified filler, 3 parts of silane coupler KH-560,2 parts of waterproof reinforcing agent, 1.5 parts of defoamer, 1.2 parts of levelling agent, acetic acid fourth 4 parts of acid cellulose, 3 parts of dimethylethanolamine, 3 parts of diethylene glycol monobutyl ether, 4 parts of deionized water；
The raw material of high rigidity overcoat 3 includes by weight：45 parts of rosin phenolic resin, 2 parts of modified polyurethane, phenylpropyl alcohol breast 9 parts of liquid, 1 part of Corvic, 9 parts of nano inorganic antimicrobial powder, 4 parts of rosin resin, 8 parts of epoxy resin, alkyd resin 1 Part, 5 parts of butyl acetate, 2 parts of aluminium hydroxide, 5 parts of calcium ferrite, 1 part of nitrocotton, 6 parts of mica powder, 1 part of zinc oxide, chlorinated paraffin 6 Part, 2 parts of calcium ferrite, 9 parts of modified additive, 4 parts of Silane coupling reagent KH-570,6 parts of hexamethyl cellulose, 1 part of citric acid, solidification 5 parts of agent.
In the raw material of waterproof layer 2, modified filler is prepared by following technique：By weight by 50 parts of active calcium silicates and 3 parts of calcium stearates are well mixed, and stirring at low speed 10min is sealed at a temperature of 60 DEG C, then with 8 parts of Nano carbon whites, 1 part of calcining Kaolin, 6 parts of wood fiber powders, 2 parts of hollow glass micropearls and 3 parts of tossas are well mixed, 45 DEG C of sealing stirring at low speed 10min, adds 3 parts of magnesium hydroxides, 9 parts of methacrylates, 2 parts of silane coupler KH570 and 8 parts of lubricants, is warming up to 135 DEG C, stirring at low speed 20min, discharging is cooled to room temperature and obtains modified filler.
In the raw material of waterproof layer 2, waterproof reinforcing agent is prepared by following technique：By weight by 5 parts of polyvinyl pyrroles Alkanone dissolves and n-amyl alcohol is well mixed, and ultrasonic 40min is subsequently adding absolute alcohol, deionized water and 3 parts of sodium citrate solutions It is well mixed, it is subsequently added into ammoniacal liquor and is well mixed, it is subsequently adding 2 parts of tetraethyl orthosilicates, ultrasonic disperse 3min, then in 75 DEG C 20h is reacted in oil bath pan, 1 time and centrifugation is washed with deionized, centrifugal rotational speed is 4200r/min, then in 45 DEG C of bakings 4h is dried in case and finally obtains waterproof reinforcing agent.
In the raw material of high rigidity overcoat 3, modified additive is prepared by following technique：By weight by 8 parts of methyl-props E pioic acid methyl ester carries out vacuum distillation, is subsequently adding 2 parts of deionized waters, 5 parts of nano silicons, 1 part of neopelex Well mixed with 4 parts of APESs, ultrasonic agitation 20min then heats to 85 DEG C, is subsequently adding 2 parts of persulfuric acid Ammonium and 8 parts of silane coupling A -174, stir 5min, then add 6 parts of isopropyl titanates and are well mixed, and are then adjusted with ammoniacal liquor PH is cooled to normal temperature to 7, and filtration under diminished pressure takes filter cake, then with water washing filter cake is distilled 4 times, then by filter cake in 45 DEG C of dryings 26h, grinding obtains modified additive.
Embodiment 4
As shown in figure 1, Fig. 1 is a kind of structural representation of high-hardness water-proof wallpaper proposed by the present invention.
Reference picture 1, a kind of high-hardness water-proof wallpaper of the invention, including substrate layer 1, waterproof layer 2 and high rigidity overcoat 3, the periphery of substrate layer 1 is coated with waterproof layer 2, and the waterproof layer 2 is coated with high rigidity overcoat 3 away from the periphery of substrate layer 1, Wherein：
Substrate layer 1 is wood pulp paper；
The raw material of waterproof layer 2 includes by weight：19 parts of water-based hydroxyl acrylic acid modified saturated polyester resin, aqueous acrylamide 12 parts of sour modified polyester resin, 7 parts of aqueous saturated polyester resin, 14 parts of HMMM resin, aqueous pure third 4 parts of resin, 4 parts of Amino resin, 3 parts of modifying epoxy resin by organosilicon, 3 parts of silicone alkyd, carbon black 3 Part, 8 parts of modified filler, silane coupler KH-5601.5 parts, 4 parts of waterproof reinforcing agent, 0.8 part of defoamer, 1.5 parts of levelling agent, vinegar 2.5 parts of sour cellulose butyrate, 4.5 parts of dimethylethanolamine, 1.5 parts of diethylene glycol monobutyl ether, 7 parts of deionized water；
The raw material of high rigidity overcoat 3 includes by weight：28 parts of rosin phenolic resin, 8 parts of modified polyurethane, phenylpropyl alcohol breast 4 parts of liquid, 4 parts of Corvic, 4 parts of nano inorganic antimicrobial powder, 11 parts of rosin resin, 3 parts of epoxy resin, alkyd resin 4 Part, 3.5 parts of butyl acetate, 5 parts of aluminium hydroxide, 3.5 parts of calcium ferrite, 3 parts of nitrocotton, 3 parts of mica powder, 3 parts of zinc oxide, chlorination stone It is 3 parts of wax, 7 parts of calcium ferrite, 5 parts of modified additive, 8 parts of Silane coupling reagent KH-570,4 parts of hexamethyl cellulose, 3 parts of citric acid, solid 3 parts of agent.
In the raw material of waterproof layer 2, modified filler is prepared by following technique：By weight by 15 parts of active calcium silicates and 5 parts of calcium stearates are well mixed, and stirring at low speed 20min is sealed at a temperature of 52 DEG C, then with 3 parts of Nano carbon whites, 5 parts of calcinings Kaolin, 2 parts of wood fiber powders, 6 parts of hollow glass micropearls and 1.5 parts of tossas are well mixed, 52 DEG C of sealing stirring at low speed 6min, adds 8 parts of magnesium hydroxides, 5 parts of methacrylates, 4 parts of silane coupler KH570 and 4 parts of lubricants, is warming up to 139 DEG C, stirring at low speed 12min, discharging is cooled to room temperature and obtains modified filler.
In the raw material of waterproof layer 2, waterproof reinforcing agent is prepared by following technique：By weight by 3 parts of polyvinyl pyrroles Alkanone dissolves and n-amyl alcohol is well mixed, and ultrasonic 48min is subsequently adding absolute alcohol, deionized water and 1.5 parts of sodium citrates molten Liquid is well mixed, and is subsequently added into ammoniacal liquor and is well mixed, and is subsequently adding 3.5 parts of tetraethyl orthosilicates, ultrasonic disperse 1.5min, then React 17h in 82 DEG C of oil bath pans, 3 times and centrifugation be washed with deionized, centrifugal rotational speed is 3900r/min, then in 2.5h is dried in 52 DEG C of baking ovens finally obtain waterproof reinforcing agent.
In the raw material of high rigidity overcoat 3, modified additive is prepared by following technique：By weight by 5 parts of methyl-props E pioic acid methyl ester carries out vacuum distillation, is subsequently adding 3.5 parts of deionized waters, 3 parts of nano silicons, 2.5 parts of detergent alkylate sulphurs Sour sodium and 2 parts of APESs are well mixed, and ultrasonic agitation 35min then heats to 68 DEG C, is subsequently adding 3.5 parts Ammonium persulfate and 5 parts of silane coupling A -174, stir 12min, then add 4 parts of isopropyl titanates and are well mixed, and then use ammonia Water adjusts pH to 7.8, is cooled to normal temperature, and filtration under diminished pressure takes filter cake, then with distillation water washing filter cake 3 times, then by filter cake in 52 DEG C dry 23h, and grinding obtains modified additive.
Embodiment 5
As shown in figure 1, Fig. 1 is a kind of structural representation of high-hardness water-proof wallpaper proposed by the present invention.
Reference picture 1, a kind of high-hardness water-proof wallpaper of the invention, including substrate layer 1, waterproof layer 2 and high rigidity overcoat 3, the periphery of substrate layer 1 is coated with waterproof layer 2, and the waterproof layer 2 is coated with high rigidity overcoat 3 away from the periphery of substrate layer 1, Wherein：
Substrate layer 1 is any one in wood pulp paper, non-woven paper, cloth；
The raw material of waterproof layer 2 includes by weight：23 parts of water-based hydroxyl acrylic acid modified saturated polyester resin, aqueous acrylamide 8 parts of sour modified polyester resin, 11 parts of aqueous saturated polyester resin, 4 parts of HMMM resin, aqueous pure third tree 5 parts of fat, 2 parts of Amino resin, 4 parts of modifying epoxy resin by organosilicon, 2 parts of silicone alkyd, 4 parts of carbon black, 4 parts of modified filler, 2.5 parts of silane coupler KH-560,3 parts of waterproof reinforcing agent, 1.2 parts of defoamer, 1.3 parts of levelling agent, acetic acid 3.5 parts of cellulose butyrate, 3.5 parts of dimethylethanolamine, 2.5 parts of diethylene glycol monobutyl ether, 5 parts of deionized water；
The raw material of high rigidity overcoat 3 includes by weight：42 parts of rosin phenolic resin, 3 parts of modified polyurethane, phenylpropyl alcohol breast 8 parts of liquid, 2 parts of Corvic, 8 parts of nano inorganic antimicrobial powder, 5 parts of rosin resin, 7 parts of epoxy resin, alkyd resin 2 Part, 4.5 parts of butyl acetate, 3 parts of aluminium hydroxide, 4.5 parts of calcium ferrite, 2 parts of nitrocotton, 5 parts of mica powder, 2 parts of zinc oxide, chlorination stone It is 5 parts of wax, 3 parts of calcium ferrite, 8 parts of modified additive, 5 parts of Silane coupling reagent KH-570,5 parts of hexamethyl cellulose, 2 parts of citric acid, solid 4 parts of agent.
In the raw material of waterproof layer 2, modified filler is prepared by following technique：By weight by 45 parts of active calcium silicates and 4 parts of calcium stearates are well mixed, and stirring at low speed 15min is sealed at a temperature of 58 DEG C, then with 7 parts of Nano carbon whites, 2 parts of calcinings Kaolin, 5 parts of wood fiber powders, 3 parts of hollow glass micropearls and 2.5 parts of tossas are well mixed, 48 DEG C of sealing stirring at low speed 9min, adds 4 parts of magnesium hydroxides, 8 parts of methacrylates, 3 parts of silane coupler KH570 and 7 parts of lubricants, is warming up to 136 DEG C, stirring at low speed 18min, discharging is cooled to room temperature and obtains modified filler.
In the raw material of waterproof layer 2, waterproof reinforcing agent is prepared by following technique：By weight by 4 parts of polyvinyl pyrroles Alkanone dissolves and n-amyl alcohol is well mixed, and ultrasonic 42min is subsequently adding absolute alcohol, deionized water and 2.5 parts of sodium citrates molten Liquid is well mixed, and is subsequently added into ammoniacal liquor and is well mixed, and is subsequently adding 2.5 parts of tetraethyl orthosilicates, ultrasonic disperse 2.5min, then React 19h in 75 DEG C of oil bath pans, 1 time and centrifugation be washed with deionized, centrifugal rotational speed is 4100r/min, then in 3.5h is dried in 48 DEG C of baking ovens finally obtain waterproof reinforcing agent.
In the raw material of high rigidity overcoat 3, modified additive is prepared by following technique：By weight by 7 parts of methyl-props E pioic acid methyl ester carries out vacuum distillation, is subsequently adding 2.5 parts of deionized waters, 4 parts of nano silicons, 1.5 parts of detergent alkylate sulphurs Sour sodium and 3 parts of APESs are well mixed, and ultrasonic agitation 25min then heats to 82 DEG C, is subsequently adding 2.5 parts Ammonium persulfate and 7 parts of silane coupling A -174, stir 8min, then add 5 parts of isopropyl titanates and are well mixed, and then use ammonia Water adjusts pH to 7.2, is cooled to normal temperature, and filtration under diminished pressure takes filter cake, then with distillation water washing filter cake 4 times, then by filter cake in 48 DEG C dry 25h, and grinding obtains modified additive.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, Any one skilled in the art the invention discloses technical scope in, technology according to the present invention scheme and its Inventive concept is subject to equivalent or change, should all be included within the scope of the present invention.

Claims (7)

1. a kind of high-hardness water-proof wallpaper, including substrate layer (1), waterproof layer (2) and high rigidity overcoat (3), substrate layer (1) Periphery is coated with waterproof layer (2), and the waterproof layer (2) is coated with high rigidity overcoat (3) away from the periphery of substrate layer (1), its It is characterised by, wherein：
Substrate layer (1) is wood pulp paper, any one in non-woven paper, cloth；
The raw material of waterproof layer (2) includes by weight：18-24 parts of water-based hydroxyl acrylic acid modified saturated polyester resin, aqueous third 5-15 parts of olefin(e) acid modified polyester resin, aqueous saturated polyester resin 6-12 parts, HMMM resin 3-15 parts, Aqueous 3-6 parts of pure third resin, Amino resin 1-5 parts, modifying epoxy resin by organosilicon 2-5 parts, organic-silicon-modified alkyd Resin 1-4 parts, carbon black 2-5 parts, modified filler 3-9 parts, 1-3 parts of silane coupler KH-560,2-5 parts of waterproof reinforcing agent, froth breaking Agent 0.5-1.5 parts, levelling agent 1.2-1.6 parts, acetylbutyrylcellulose 2-4 parts, dimethylethanolamine 3-5 parts, diethylene glycol list Butyl ether 1-3 parts, deionized water 4-8 parts；
The raw material of high rigidity overcoat (3) includes by weight：Rosin phenolic resin 25-45 parts, modified polyurethane 2-9 parts, benzene Acrylic emulsion 3-9 parts, Corvic 1-5 parts, 3-9 parts of nano inorganic antimicrobial powder, rosin resin 4-12 parts, epoxy resin 2- 8 parts, alkyd resin 1-5 parts, butyl acetate 3-5 parts, aluminium hydroxide 2-6 parts, calcium ferrite 3-5 parts, nitrocotton 1-4 parts, mica powder 2-6 parts, zinc oxide 1-4 parts, chlorinated paraffin 2-6 parts, calcium ferrite 2-8 parts, modified additive 4-9 parts, Silane coupling reagent KH-570 4- 9 parts, 3-6 parts, citric acid 1-4 parts, curing agent 2-5 parts of hexamethyl cellulose.
2. high-hardness water-proof wallpaper according to claim 1, it is characterised in that in the raw material of waterproof layer (2), modified filler Raw material include by weight：Active calcium silicate 10-50 parts, calcium stearate 3-6 parts, Nano carbon white 2-8 parts, calcined kaolin 1-6 parts, magnesium hydroxide 3-9 parts, wood fiber powder 1-6 parts, hollow glass micropearl 2-7 parts, tossa 1-3 parts, metering system Acid esters 4-9 parts, 2-5 parts, lubricant 3-8 parts of silane coupler KH570.
3. high-hardness water-proof wallpaper according to claim 1 and 2, it is characterised in that in the raw material of waterproof layer (2), is modified Filler is prepared by following technique：Active calcium silicate and calcium stearate are well mixed, low speed is sealed at a temperature of 50-60 DEG C Stirring 10-25min, then mixes with Nano carbon white, calcined kaolin, wood fiber powder, hollow glass micropearl and tossa Close uniform, 45-55 DEG C of sealing stirring at low speed 5-10min adds magnesium hydroxide, methacrylate, silane coupler KH570 And lubricant, 135-140 DEG C is warming up to, stirring at low speed 10-20min, discharging is cooled to room temperature and obtains modified filler.
4. the high-hardness water-proof wallpaper according to claim any one of 1-3, it is characterised in that in the raw material of waterproof layer (2), Waterproof reinforcing agent is prepared by following technique：Polyvinylpyrrolidone dissolving and n-amyl alcohol are well mixed, ultrasonic 40- 50min, is subsequently adding absolute alcohol, deionized water and sodium citrate solution and is well mixed, and is subsequently added into ammoniacal liquor and is well mixed, so After add tetraethyl orthosilicate, ultrasonic disperse 1-3min that 16-20h is then reacted in 75-85 DEG C of oil bath pan, deionized water is used Washing 1-3 times and centrifugation, centrifugal rotational speed is 3800-4200r/min, 2-4h is then dried in 45-55 DEG C of baking oven last Obtain waterproof reinforcing agent.
5. the high-hardness water-proof wallpaper according to claim any one of 1-4, it is characterised in that in the raw material of waterproof layer (2), In the preparation technology of waterproof reinforcing agent, the weight ratio of polyvinylpyrrolidone, sodium citrate solution and tetraethyl orthosilicate is 2- 5：1-3：2-4.
6. the high-hardness water-proof wallpaper according to claim any one of 1-5, it is characterised in that high rigidity overcoat (3) In raw material, the raw material of modified additive includes by weight：Methyl methacrylate 4-8 parts, deionized water 2-4 parts, nano-silica SiClx 2-5 parts, neopelex 1-3 parts, APES 1-4 parts, ammonium persulfate 2-4 parts, metatitanic acid isopropyl Ester 3-6 parts, the 4-8 of silane coupling A -174 parts.
7. the high-hardness water-proof wallpaper according to claim any one of 1-6, it is characterised in that high rigidity overcoat (3) In raw material, modified additive is prepared by following technique：Methyl methacrylate is carried out into vacuum distillation, deionization is subsequently adding Water, nano silicon, neopelex and APES are well mixed, ultrasonic agitation 20-40min, 65-85 DEG C is then heated to, ammonium persulfate and silane coupling A -174 are subsequently adding, 5-15min is stirred, metatitanic acid is then added Isopropyl ester is well mixed, and then adjusts pH to 7-8 with ammoniacal liquor, is cooled to normal temperature, and filtration under diminished pressure takes filter cake, is then washed with distillation Wash filter cake 3-4 times, filter cake is then dried into 22-26h in 45-55 DEG C, grinding obtains modified additive.
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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107722829A (en) * 2017-10-25 2018-02-23 成都纽兰晶茂商贸有限公司 A kind of wood furniture is painted with flame-proof antibiotic
CN107805447A (en) * 2017-10-25 2018-03-16 成都纽兰晶茂商贸有限公司 The preparation method that a kind of wood furniture is painted with flame-proof antibiotic
CN108518033A (en) * 2018-04-18 2018-09-11 肥西县碧涛建材有限公司 A kind of ornament materials with antimildew function
CN108611925A (en) * 2018-05-17 2018-10-02 安徽银兔装饰材料有限公司 Environmental protection wall paper and preparation method thereof
CN108611927A (en) * 2018-04-04 2018-10-02 东莞顺裕纸业有限公司 A kind of waterproof and dampproof corrugated paper and preparation method thereof
CN108677595A (en) * 2018-05-17 2018-10-19 安徽银兔装饰材料有限公司 Environmental protection wall paper and preparation method thereof
CN109096844A (en) * 2018-09-05 2018-12-28 合肥久新不锈钢厨具有限公司 A kind of waterproof heat-insulating coating and preparation method thereof
CN109505389A (en) * 2018-11-21 2019-03-22 无锡高强特种纺织有限公司 A kind of water-proof environmental protection wallpaper and preparation method thereof
CN109837006A (en) * 2017-09-19 2019-06-04 南京加瑞尔自动化设备有限公司 A kind of wear-resisting conveyer belt for automatic box packing machine
CN110734691A (en) * 2019-10-18 2020-01-31 华北理工大学 coastal environment wooden ancient building waterproof anticorrosive paint and preparation method thereof
CN111231424A (en) * 2020-02-20 2020-06-05 上海乐盈纸业有限公司 Corrugated board and production process thereof
CN112323541A (en) * 2020-08-20 2021-02-05 安徽紫荆花墙饰材料股份有限公司 Production method of antibacterial and antibacterial wallpaper
CN112323534A (en) * 2020-08-20 2021-02-05 安徽紫荆花墙饰材料股份有限公司 Production method of high-hardness waterproof antibacterial wallpaper
CN112708294A (en) * 2020-12-30 2021-04-27 广东嘉宝莉科技材料有限公司 Inorganic silicate interior wall coating and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN204112168U (en) * 2014-08-15 2015-01-21 北京市金龙腾装饰设计有限公司 A kind of wallpaper
CN105088877A (en) * 2014-04-25 2015-11-25 哈建薇 Diatomite-type waterproof wear-resistant wallpaper
CN105713458A (en) * 2016-03-24 2016-06-29 安徽鹏峰新型建材科技有限公司 High-hardness, oil-resistant, antibacterial and heat-resisting paint
CN105969130A (en) * 2016-06-12 2016-09-28 蚌埠市禹会区贵宾装饰材料商行 Waterproof heat-resistant stoving varnish for photo frame
CN205662785U (en) * 2016-05-19 2016-10-26 浙江新中环建筑装饰工程有限公司 Wallpaper

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105088877A (en) * 2014-04-25 2015-11-25 哈建薇 Diatomite-type waterproof wear-resistant wallpaper
CN204112168U (en) * 2014-08-15 2015-01-21 北京市金龙腾装饰设计有限公司 A kind of wallpaper
CN105713458A (en) * 2016-03-24 2016-06-29 安徽鹏峰新型建材科技有限公司 High-hardness, oil-resistant, antibacterial and heat-resisting paint
CN205662785U (en) * 2016-05-19 2016-10-26 浙江新中环建筑装饰工程有限公司 Wallpaper
CN105969130A (en) * 2016-06-12 2016-09-28 蚌埠市禹会区贵宾装饰材料商行 Waterproof heat-resistant stoving varnish for photo frame

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109837006A (en) * 2017-09-19 2019-06-04 南京加瑞尔自动化设备有限公司 A kind of wear-resisting conveyer belt for automatic box packing machine
CN107805447A (en) * 2017-10-25 2018-03-16 成都纽兰晶茂商贸有限公司 The preparation method that a kind of wood furniture is painted with flame-proof antibiotic
CN107722829A (en) * 2017-10-25 2018-02-23 成都纽兰晶茂商贸有限公司 A kind of wood furniture is painted with flame-proof antibiotic
CN108611927A (en) * 2018-04-04 2018-10-02 东莞顺裕纸业有限公司 A kind of waterproof and dampproof corrugated paper and preparation method thereof
CN108518033A (en) * 2018-04-18 2018-09-11 肥西县碧涛建材有限公司 A kind of ornament materials with antimildew function
CN108611925A (en) * 2018-05-17 2018-10-02 安徽银兔装饰材料有限公司 Environmental protection wall paper and preparation method thereof
CN108677595A (en) * 2018-05-17 2018-10-19 安徽银兔装饰材料有限公司 Environmental protection wall paper and preparation method thereof
CN109096844A (en) * 2018-09-05 2018-12-28 合肥久新不锈钢厨具有限公司 A kind of waterproof heat-insulating coating and preparation method thereof
CN109505389A (en) * 2018-11-21 2019-03-22 无锡高强特种纺织有限公司 A kind of water-proof environmental protection wallpaper and preparation method thereof
CN110734691A (en) * 2019-10-18 2020-01-31 华北理工大学 coastal environment wooden ancient building waterproof anticorrosive paint and preparation method thereof
CN111231424A (en) * 2020-02-20 2020-06-05 上海乐盈纸业有限公司 Corrugated board and production process thereof
CN112323541A (en) * 2020-08-20 2021-02-05 安徽紫荆花墙饰材料股份有限公司 Production method of antibacterial and antibacterial wallpaper
CN112323534A (en) * 2020-08-20 2021-02-05 安徽紫荆花墙饰材料股份有限公司 Production method of high-hardness waterproof antibacterial wallpaper
CN112708294A (en) * 2020-12-30 2021-04-27 广东嘉宝莉科技材料有限公司 Inorganic silicate interior wall coating and preparation method thereof

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