CN105713458A - High-hardness, oil-resistant, antibacterial and heat-resisting paint - Google Patents
High-hardness, oil-resistant, antibacterial and heat-resisting paint Download PDFInfo
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- CN105713458A CN105713458A CN201610182759.5A CN201610182759A CN105713458A CN 105713458 A CN105713458 A CN 105713458A CN 201610182759 A CN201610182759 A CN 201610182759A CN 105713458 A CN105713458 A CN 105713458A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D115/00—Coating compositions based on rubber derivatives
- C09D115/02—Rubber derivatives containing halogen
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
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Abstract
The invention discloses high-hardness, oil-resistant, antibacterial and heat-resisting paint. Raw materials of the paint comprise fluorination modified nitrile rubber, nano inorganic antibacterial powder, a styrene-acrylic emulsion, alkyd resin, ethyl acetate, epoxy resin, polyvinyl chloride resin, aluminum hydroxide, bentonite, barite powder, nitrocotton, zinc oxide, mica powder, zeolite powder, chlorinated paraffin, calcium ferrite, hexamethyl cellulose, citric acid, propanol, xylene and a curing agent. The paint has high hardness, good oil resistance and antibacterial property and excellent heat resistance.
Description
Technical field
The present invention relates to paint field, particularly relate to a kind of antibacterial heat-resistant paint of high rigidity oil resistant.
Background technology
Paint is that one can firmly cover body surface, plays the chemical mixture coating of protection, decoration, mark and other specific uses.Belonging to organic chemical industry's macromolecular material, the film formed belongs to macromolecular compound type.In actual life, the surface of a lot of article needs to paint to process, and not only increases the aesthetic feeling of article, also effectively extends the life-span of article.
Paint hardness of the prior art is low, and the antibacterial heat resistance of oil resistant all cannot meet the demand in actual production, it is therefore desirable to develop the paint that a kind of hardness antibacterial heat resistance of height oil resistant is good.
Summary of the invention
For solving the technical problem existed in background technology, the present invention proposes a kind of antibacterial heat-resistant paint of high rigidity oil resistant, and hardness height oil resistant anti-microbial property is good, and has the heat resistance of excellence.
A kind of antibacterial heat-resistant paint of high rigidity oil resistant that the present invention proposes, its raw material includes by weight: fluorinated modified nitrile rubber 80-120 part, nano inorganic antimicrobial powder 40-80 part, styrene-acrylic emulsion 5-15 part, alkyd resin 2-8 part, ethyl acetate 3-9 part, epoxy resin 1-5 part, Corvic 2-6 part, aluminium hydroxide 3-9 part, bentonite 1-5 part, blanc fixe 2-4 part, nitrocotton 1-4 part, zinc oxide 1-3 part, mica powder 1-5 part, zeolite powder 2-6 part, chlorinated paraffin 1-7 part, calcium ferrite 2-5 part, hexamethyl cellulose 3-5 part, citric acid 4-8 part, propanol 1-5 part, dimethylbenzene 2-6 part, firming agent 1-4 part.
Preferably, the raw material of nano inorganic antimicrobial powder includes by weight: carbamide 2-8 part, polyvinylpyrrolidone 1-5 part, deionized water 5-15 part, sodium chloride solution 2-8 part, defoamer 1-6 part, AgNO3Solution 2-8 part, titanium liquid 1-4 part, Disulfatozirconic acid. solution 3-6 part, disodium phosphate soln 4-8 part.
Preferably, nano inorganic antimicrobial powder is prepared by following technique: by carbamide, polyvinylpyrrolidone and deionized water mix homogeneously, is subsequently adding sodium chloride solution and defoamer stirring 10-30min, then drips AgNO with separatory funnel3Solution obtains material a；Adding titanium liquid and Disulfatozirconic acid. solution with separatory funnel in material a, then heating in water bath is to 70-90 DEG C, adds disodium phosphate soln, then ageing, filtration washing, dry, be cooled to room temperature and obtain nano inorganic antimicrobial powder after calcining after being cooled to room temperature.
Preferably, the weight ratio of fluorinated modified nitrile rubber, nano inorganic antimicrobial powder, styrene-acrylic emulsion, alkyd resin, ethyl acetate, epoxy resin and Corvic is 85-115:45-75:8-12:3-7:4-8:2-4:3-5.
Preferably, carbamide, polyvinylpyrrolidone, deionized water, sodium chloride solution, defoamer, AgNO3The weight ratio of solution, titanium liquid, Disulfatozirconic acid. solution, disodium phosphate soln and fluorinated modified nitrile rubber is 3-7:2-4:8-12:3-7:2-5:3-7:2-3:4-5:5-7:85-115.
Preferably, its raw material includes by weight: fluorinated modified nitrile rubber 85-115 part, nano inorganic antimicrobial powder 45-75 part, styrene-acrylic emulsion 8-12 part, alkyd resin 3-7 part, ethyl acetate 4-8 part, epoxy resin 2-4 part, Corvic 3-5 part, aluminium hydroxide 4-8 part, bentonite 2-4 part, blanc fixe 2.5-3.5 part, nitrocotton 2-3 part, zinc oxide 1.5-2.5 part, mica powder 2-4 part, zeolite powder 3-5 part, chlorinated paraffin 2-6 part, calcium ferrite 3-4 part, hexamethyl cellulose 3.5-4.5 part, citric acid 5-7 part, propanol 2-4 part, dimethylbenzene 3-5 part, firming agent 2-3 part.
Preferably, its raw material includes by weight: fluorinated modified nitrile rubber 100 parts, nano inorganic antimicrobial powder 60 parts, styrene-acrylic emulsion 10 parts, alkyd resin 5 parts, ethyl acetate 6 parts, epoxy resin 3 parts, Corvic 4 parts, aluminium hydroxide 6 parts, bentonite 3 parts, blanc fixe 3 parts, nitrocotton 2.5 parts, zinc oxide 2 parts, mica powder 3 parts, zeolite powder 4 parts, chlorinated paraffin 4 parts, calcium ferrite 3.5 parts, hexamethyl cellulose 4 parts, citric acid 6 parts, propanol 3 parts, dimethylbenzene 4 parts, 2.5 parts of firming agent.
A kind of antibacterial heat-resistant paint of high rigidity oil resistant of the present invention, its raw material includes fluorinated modified nitrile rubber, nano inorganic antimicrobial powder, styrene-acrylic emulsion, alkyd resin, ethyl acetate, epoxy resin, Corvic, aluminium hydroxide, bentonite, blanc fixe, nitrocotton, zinc oxide, mica powder, zeolite powder, chlorinated paraffin, calcium ferrite, hexamethyl cellulose, citric acid, propanol, dimethylbenzene and firming agent.Wherein with fluorinated modified nitrile rubber for major ingredient, and add styrene-acrylic emulsion, alkyd resin, ethyl acetate, epoxy resin and the Corvic supporting material as major ingredient, be effectively increased the hardness of major ingredient, oil resistant, antibacterial and heat-resisting performance；The aluminium hydroxide, bentonite, blanc fixe, nitrocotton, zinc oxide, mica powder, zeolite powder, chlorinated paraffin, calcium ferrite, hexamethyl cellulose, citric acid, propanol, dimethylbenzene and the firming agent that add are as filler and auxiliary agent, and the proportioning of control and major ingredient, it is effectively increased hardness and the antibacterial heat resistance of oil resistant of major ingredient, and then the present invention is painted there is hardness height, oil resistant anti-microbial property is good, and has the heat resistance of excellence.The nano inorganic antimicrobial powder wherein added is with carbamide, polyvinylpyrrolidone, deionized water, sodium chloride solution, defoamer, AgNO3Solution, titanium liquid, Disulfatozirconic acid. solution and disodium phosphate soln are raw material, prepare nano inorganic antimicrobial powder adopt method be the method that sluggish precipitation combines with coprecipitation.The condition precipitating generation in solution is different because of the difference of metal ion, sluggish precipitation is utilized to make precipitant generate lentamente in solution, eliminate the local inhomogeneities of precipitant, ion precipitation unprecipitated in solution is got off by recycling coprecipitation, also overcomes the shortcoming that coprecipitation precipitates tendency respectively simultaneously.It is first by Ag that the present invention prepares nano inorganic antimicrobial powder+With cl-Reaction generates Agcl precipitation, with Agcl for crystal seed, precipitant using carbamide as reaction again, sluggish precipitation is first adopted the precipitate metal hydroxides such as Ti, the Zr in reaction system to be got off, so just define ground floor parcel at seed surface, then adopt coprecipitation by the Ti of complete reaction non-in homogeneous precipitation4+、Zr4+Product calcium phosphate precipitation gets off, then define second layer parcel, and then make the present invention paint the antibacterial heat resistance of oil resistant with excellence, and hardness is high.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail; it is understood that; embodiment is served only for the present invention is described, rather than is used for limiting the invention, any make on basis of the present invention amendment, equivalent replacement etc. is all in protection scope of the present invention.
Embodiment 1
A kind of antibacterial heat-resistant paint of high rigidity oil resistant that the present invention proposes, its raw material includes by weight: fluorinated modified nitrile rubber 100 parts, nano inorganic antimicrobial powder 60 parts, styrene-acrylic emulsion 10 parts, alkyd resin 5 parts, ethyl acetate 6 parts, epoxy resin 3 parts, Corvic 4 parts, aluminium hydroxide 6 parts, bentonite 3 parts, blanc fixe 3 parts, nitrocotton 2.5 parts, zinc oxide 2 parts, mica powder 3 parts, zeolite powder 4 parts, chlorinated paraffin 4 parts, calcium ferrite 3.5 parts, hexamethyl cellulose 4 parts, citric acid 6 parts, propanol 3 parts, dimethylbenzene 4 parts, 2.5 parts of firming agent.
Nano inorganic antimicrobial powder is prepared by following technique: by weight by 5 parts of carbamide, 3 parts of polyvinylpyrrolidones and 10 parts of deionized water mix homogeneously, it is subsequently adding 5 parts of sodium chloride solutions and 3.5 parts of defoamer stirring 20min, then drips 5 parts of AgNO with separatory funnel3Solution obtains material a；Adding 2.5 parts of titanium liquid and 4.5 parts of Disulfatozirconic acid. solution with separatory funnel in material a, then heating in water bath is to 80 DEG C, adds 6 parts of disodium phosphate solns after being cooled to room temperature, then ageing, filtration washing, dry, it is cooled to room temperature after calcining and obtains nano inorganic antimicrobial powder.
Embodiment 2
A kind of antibacterial heat-resistant paint of high rigidity oil resistant that the present invention proposes, its raw material includes by weight: fluorinated modified nitrile rubber 80 parts, nano inorganic antimicrobial powder 80 parts, styrene-acrylic emulsion 5 parts, alkyd resin 8 parts, ethyl acetate 3 parts, epoxy resin 5 parts, Corvic 2 parts, aluminium hydroxide 9 parts, bentonite 1 part, blanc fixe 4 parts, nitrocotton 1 part, zinc oxide 3 parts, mica powder 1 part, zeolite powder 6 parts, chlorinated paraffin 1 part, calcium ferrite 5 parts, hexamethyl cellulose 3 parts, citric acid 8 parts, propanol 1 part, dimethylbenzene 6 parts, 1 part of firming agent.
Nano inorganic antimicrobial powder is prepared by following technique: by weight by 2 parts of carbamide, 5 parts of polyvinylpyrrolidones and 5 parts of deionized water mix homogeneously, is subsequently adding 8 parts of sodium chloride solutions and 1 part of defoamer stirring 30min, then drips 2 parts of AgNO with separatory funnel3Solution obtains material a；Adding 4 parts of titanium liquid and 3 parts of Disulfatozirconic acid. solution with separatory funnel in material a, then heating in water bath is to 90 DEG C, adds 4 parts of disodium phosphate solns, then ageings, filtration washing, dry, be cooled to room temperature and obtain nano inorganic antimicrobial powder after calcining after being cooled to room temperature.
Embodiment 3
A kind of antibacterial heat-resistant paint of high rigidity oil resistant that the present invention proposes, its raw material includes by weight: fluorinated modified nitrile rubber 120 parts, nano inorganic antimicrobial powder 40 parts, styrene-acrylic emulsion 15 parts, alkyd resin 2 parts, ethyl acetate 9 parts, epoxy resin 1 part, Corvic 6 parts, aluminium hydroxide 3 parts, bentonite 5 parts, blanc fixe 2 parts, nitrocotton 4 parts, zinc oxide 1 part, mica powder 5 parts, zeolite powder 2 parts, chlorinated paraffin 7 parts, calcium ferrite 2 parts, hexamethyl cellulose 5 parts, citric acid 4 parts, propanol 5 parts, dimethylbenzene 2 parts, 4 parts of firming agent.
Nano inorganic antimicrobial powder is prepared by following technique: by weight by 8 parts of carbamide, 1 part of polyvinylpyrrolidone and 15 parts of deionized water mix homogeneously, it is subsequently adding 2 parts of sodium chloride solutions and 6 parts of defoamer stirring 10min, then drips 8 parts of AgNO with separatory funnel3Solution obtains material a；Adding 1 part of titanium liquid and 6 parts of Disulfatozirconic acid. solution with separatory funnel in material a, then heating in water bath is to 70 DEG C, adds 8 parts of disodium phosphate solns, then ageings, filtration washing, dry, be cooled to room temperature and obtain nano inorganic antimicrobial powder after calcining after being cooled to room temperature.
Embodiment 4
A kind of antibacterial heat-resistant paint of high rigidity oil resistant that the present invention proposes, its raw material includes by weight: fluorinated modified nitrile rubber 85 parts, nano inorganic antimicrobial powder 75 parts, styrene-acrylic emulsion 8 parts, alkyd resin 7 parts, ethyl acetate 4 parts, epoxy resin 4 parts, Corvic 3 parts, aluminium hydroxide 8 parts, bentonite 2 parts, blanc fixe 3.5 parts, nitrocotton 2 parts, zinc oxide 2.5 parts, mica powder 2 parts, zeolite powder 5 parts, chlorinated paraffin 2 parts, calcium ferrite 4 parts, hexamethyl cellulose 3.5 parts, citric acid 7 parts, propanol 2 parts, dimethylbenzene 5 parts, 2 parts of firming agent.
Nano inorganic antimicrobial powder is prepared by following technique: by weight by 3 parts of carbamide, 4 parts of polyvinylpyrrolidones and 8 parts of deionized water mix homogeneously, is subsequently adding 7 parts of sodium chloride solutions and 2 parts of defoamer stirring 25min, then drips 3 parts of AgNO with separatory funnel3Solution obtains material a；Adding 3 parts of titanium liquid and 4 parts of Disulfatozirconic acid. solution with separatory funnel in material a, then heating in water bath is to 85 DEG C, adds 5 parts of disodium phosphate solns, then ageings, filtration washing, dry, be cooled to room temperature and obtain nano inorganic antimicrobial powder after calcining after being cooled to room temperature.
Embodiment 5
A kind of antibacterial heat-resistant paint of high rigidity oil resistant that the present invention proposes, its raw material includes by weight: fluorinated modified nitrile rubber 115 parts, nano inorganic antimicrobial powder 45 parts, styrene-acrylic emulsion 12 parts, alkyd resin 3 parts, ethyl acetate 8 parts, epoxy resin 2 parts, Corvic 5 parts, aluminium hydroxide 4 parts, bentonite 4 parts, blanc fixe 2.5 parts, nitrocotton 3 parts, zinc oxide 1.5 parts, mica powder 4 parts, zeolite powder 3 parts, chlorinated paraffin 6 parts, calcium ferrite 3 parts, hexamethyl cellulose 4.5 parts, citric acid 5 parts, propanol 4 parts, dimethylbenzene 3 parts, 3 parts of firming agent.
Nano inorganic antimicrobial powder is prepared by following technique: by weight by 7 parts of carbamide, 2 parts of polyvinylpyrrolidones and 12 parts of deionized water mix homogeneously, it is subsequently adding 3 parts of sodium chloride solutions and 5 parts of defoamer stirring 15min, then drips 7 parts of AgNO with separatory funnel3Solution obtains material a；Adding 2 parts of titanium liquid and 5 parts of Disulfatozirconic acid. solution with separatory funnel in material a, then heating in water bath is to 75 DEG C, adds 7 parts of disodium phosphate solns, then ageings, filtration washing, dry, be cooled to room temperature and obtain nano inorganic antimicrobial powder after calcining after being cooled to room temperature.
The above; it is only the present invention preferably detailed description of the invention; but protection scope of the present invention is not limited thereto; any those familiar with the art is in the technical scope that the invention discloses; it is equal to replacement according to technical scheme and inventive concept thereof or is changed, all should be encompassed within protection scope of the present invention.
Claims (7)
1. the antibacterial heat-resistant paint of high rigidity oil resistant, it is characterized in that, its raw material includes by weight: fluorinated modified nitrile rubber 80-120 part, nano inorganic antimicrobial powder 40-80 part, styrene-acrylic emulsion 5-15 part, alkyd resin 2-8 part, ethyl acetate 3-9 part, epoxy resin 1-5 part, Corvic 2-6 part, aluminium hydroxide 3-9 part, bentonite 1-5 part, blanc fixe 2-4 part, nitrocotton 1-4 part, zinc oxide 1-3 part, mica powder 1-5 part, zeolite powder 2-6 part, chlorinated paraffin 1-7 part, calcium ferrite 2-5 part, hexamethyl cellulose 3-5 part, citric acid 4-8 part, propanol 1-5 part, dimethylbenzene 2-6 part, firming agent 1-4 part.
2. the antibacterial heat-resistant paint of high rigidity oil resistant according to claim 1, it is characterized in that, the raw material of nano inorganic antimicrobial powder includes by weight: carbamide 2-8 part, polyvinylpyrrolidone 1-5 part, deionized water 5-15 part, sodium chloride solution 2-8 part, defoamer 1-6 part, AgNO3Solution 2-8 part, titanium liquid 1-4 part, Disulfatozirconic acid. solution 3-6 part, disodium phosphate soln 4-8 part.
3. the antibacterial heat-resistant paint of high rigidity oil resistant according to claim 1 and 2, it is characterized in that, nano inorganic antimicrobial powder is prepared by following technique: by carbamide, polyvinylpyrrolidone and deionized water mix homogeneously, it is subsequently adding sodium chloride solution and defoamer stirring 10-30min, then drips AgNO with separatory funnel3Solution obtains material a；Adding titanium liquid and Disulfatozirconic acid. solution with separatory funnel in material a, then heating in water bath is to 70-90 DEG C, adds disodium phosphate soln, then ageing, filtration washing, dry, be cooled to room temperature and obtain nano inorganic antimicrobial powder after calcining after being cooled to room temperature.
4. the antibacterial heat-resistant paint of high rigidity oil resistant according to any one of claim 1-3, it is characterized in that, the weight ratio of fluorinated modified nitrile rubber, nano inorganic antimicrobial powder, styrene-acrylic emulsion, alkyd resin, ethyl acetate, epoxy resin and Corvic is 85-115:45-75:8-12:3-7:4-8:2-4:3-5.
5. the antibacterial heat-resistant paint of high rigidity oil resistant according to any one of claim 1-4, it is characterised in that carbamide, polyvinylpyrrolidone, deionized water, sodium chloride solution, defoamer, AgNO3Solution, titanium liquid, Disulfatozirconic acid. solution, disodium phosphate soln and fluorinated modified nitrile rubber weight ratio are 3-7:2-4:8-12:3-7:2-5:3-7:2-3:4-5:5-7:85-115.
6. the antibacterial heat-resistant paint of high rigidity oil resistant according to any one of claim 1-5, it is characterized in that, its raw material includes by weight: fluorinated modified nitrile rubber 85-115 part, nano inorganic antimicrobial powder 45-75 part, styrene-acrylic emulsion 8-12 part, alkyd resin 3-7 part, ethyl acetate 4-8 part, epoxy resin 2-4 part, Corvic 3-5 part, aluminium hydroxide 4-8 part, bentonite 2-4 part, blanc fixe 2.5-3.5 part, nitrocotton 2-3 part, zinc oxide 1.5-2.5 part, mica powder 2-4 part, zeolite powder 3-5 part, chlorinated paraffin 2-6 part, calcium ferrite 3-4 part, hexamethyl cellulose 3.5-4.5 part, citric acid 5-7 part, propanol 2-4 part, dimethylbenzene 3-5 part, firming agent 2-3 part.
7. the antibacterial heat-resistant paint of high rigidity oil resistant according to any one of claim 1-6, it is characterized in that, its raw material includes by weight: fluorinated modified nitrile rubber 100 parts, nano inorganic antimicrobial powder 60 parts, styrene-acrylic emulsion 10 parts, alkyd resin 5 parts, ethyl acetate 6 parts, epoxy resin 3 parts, Corvic 4 parts, aluminium hydroxide 6 parts, bentonite 3 parts, blanc fixe 3 parts, nitrocotton 2.5 parts, zinc oxide 2 parts, mica powder 3 parts, zeolite powder 4 parts, chlorinated paraffin 4 parts, calcium ferrite 3.5 parts, hexamethyl cellulose 4 parts, citric acid 6 parts, propanol 3 parts, dimethylbenzene 4 parts, 2.5 parts of firming agent.
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| CN106366876A (en) * | 2016-08-27 | 2017-02-01 | 安徽天瞳智能科技有限公司 | Antibacterial, uvioresistant, heat-resisting and anticorrosion composite material |
| CN106433420A (en) * | 2016-08-27 | 2017-02-22 | 安徽天瞳智能科技有限公司 | Composite material with excellent antibiotic and preservative performance |
| CN106867372A (en) * | 2016-12-22 | 2017-06-20 | 安徽易有墙纸有限公司 | A kind of high-hardness water-proof wallpaper |
| CN107057437A (en) * | 2017-04-06 | 2017-08-18 | 天长市润达金属防锈助剂有限公司 | A kind of antibacterial modified antirust agent of high resistant |
| CN107254342A (en) * | 2017-04-21 | 2017-10-17 | 天长市润达金属防锈助剂有限公司 | A kind of anti-rust metal cutting fluid with excellent permeance property |
| CN110951306A (en) * | 2019-12-18 | 2020-04-03 | 广东鸿业家具制造有限公司 | Manufacturing method of odorless environment-friendly paint for furniture |
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| CN106284883A (en) * | 2016-08-09 | 2017-01-04 | 浙江长兴科创金属制品有限公司 | A kind of antirust outdoor metal hand rail |
| CN106366876A (en) * | 2016-08-27 | 2017-02-01 | 安徽天瞳智能科技有限公司 | Antibacterial, uvioresistant, heat-resisting and anticorrosion composite material |
| CN106433420A (en) * | 2016-08-27 | 2017-02-22 | 安徽天瞳智能科技有限公司 | Composite material with excellent antibiotic and preservative performance |
| CN106867372A (en) * | 2016-12-22 | 2017-06-20 | 安徽易有墙纸有限公司 | A kind of high-hardness water-proof wallpaper |
| CN107057437A (en) * | 2017-04-06 | 2017-08-18 | 天长市润达金属防锈助剂有限公司 | A kind of antibacterial modified antirust agent of high resistant |
| CN107254342A (en) * | 2017-04-21 | 2017-10-17 | 天长市润达金属防锈助剂有限公司 | A kind of anti-rust metal cutting fluid with excellent permeance property |
| CN110951306A (en) * | 2019-12-18 | 2020-04-03 | 广东鸿业家具制造有限公司 | Manufacturing method of odorless environment-friendly paint for furniture |
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| CN105713458B (en) | 2018-10-12 |
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