CN105713458B - A kind of high rigidity oil resistant antibacterial heat-resistant paint - Google Patents
A kind of high rigidity oil resistant antibacterial heat-resistant paint Download PDFInfo
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- CN105713458B CN105713458B CN201610182759.5A CN201610182759A CN105713458B CN 105713458 B CN105713458 B CN 105713458B CN 201610182759 A CN201610182759 A CN 201610182759A CN 105713458 B CN105713458 B CN 105713458B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D115/00—Coating compositions based on rubber derivatives
- C09D115/02—Rubber derivatives containing halogen
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention discloses a kind of high rigidity oil resistant antibacterial heat-resistant paint, raw material includes fluorinated modified nitrile rubber, nano inorganic antimicrobial powder, styrene-acrylic emulsion, alkyd resin, ethyl acetate, epoxy resin, Corvic, aluminium hydroxide, bentonite, blanc fixe, nitrocotton, zinc oxide, mica powder, zeolite powder, chlorinated paraffin, calcium ferrite, hexamethyl cellulose, citric acid, propyl alcohol, dimethylbenzene and curing agent.The high oil resistant anti-microbial property of paint hardness of the present invention is good, and has excellent heat resistance.
Description
Technical field
The present invention relates to paint field more particularly to a kind of high rigidity oil resistant antibacterial heat-resistant paints.
Background technology
Paint be it is a kind of can securely be covered in body surface, the chemistry for playing protection, decoration, mark and other specific uses is mixed
Close object coating.Belong to organic chemical industry's macromolecular material, is formed by film and belongs to high-molecular compound type.In actual life,
The surface of many articles needs to be handled with paint, not only increases the aesthetic feeling of article, also effectively extends the service life of article.
Paint hardness in the prior art is low, and oil resistant antibacterial heat resistance cannot be satisfied the demand in actual production, because
This needs to develop a kind of paint that the high oil resistant antibacterial heat resistance of hardness is good.
Invention content
To solve technical problem present in background technology, the present invention proposes a kind of high rigidity oil resistant antibacterial heat-resistant paint,
The high oil resistant anti-microbial property of hardness is good, and has excellent heat resistance.
A kind of high rigidity oil resistant antibacterial heat-resistant paint proposed by the present invention, raw material include by weight：Fluorinated modified fourth
80-120 parts of nitrile rubber, 40-80 parts of nano inorganic antimicrobial powder, 5-15 parts of styrene-acrylic emulsion, 2-8 parts of alkyd resin, ethyl acetate
3-9 parts, 1-5 parts of epoxy resin, 2-6 parts of Corvic, 3-9 parts of aluminium hydroxide, 1-5 parts of bentonite, blanc fixe 2-4
Part, 1-4 parts of nitrocotton, 1-3 parts of zinc oxide, 1-5 parts of mica powder, 2-6 parts of zeolite powder, 1-7 parts of chlorinated paraffin, 2-5 parts of calcium ferrite,
3-5 parts of hexamethyl cellulose, 4-8 parts of citric acid, 1-5 parts of propyl alcohol, 2-6 parts of dimethylbenzene, 1-4 parts of curing agent.
Preferably, the raw material of nano inorganic antimicrobial powder includes by weight：2-8 parts of urea, polyvinylpyrrolidone 1-5
Part, 5-15 parts of deionized water, 2-8 parts of sodium chloride solution, 1-6 parts of antifoaming agent, AgNO32-8 parts of solution, 1-4 parts of titanium liquid, zirconium sulfate
3-6 parts of solution, 4-8 parts of disodium phosphate soln.
Preferably, nano inorganic antimicrobial powder is prepared by following technique：By urea, polyvinylpyrrolidone and go from
Sub- water is uniformly mixed, and sodium chloride solution is then added and antifoaming agent stirs 10-30min, then AgNO is added dropwise with separatory funnel3Solution
Obtain material a；Titanium liquid and sulfuric acid zirconium solution are added into material a with separatory funnel, then heating water bath is cooling to 70-90 DEG C
Disodium phosphate soln is added after to room temperature, is then aged, filtration washing is dry, and calcining postcooling to room temperature obtains nanometer nothing
Machine antimicrobial powder.
Preferably, fluorinated modified nitrile rubber, nano inorganic antimicrobial powder, styrene-acrylic emulsion, alkyd resin, ethyl acetate,
The weight ratio of epoxy resin and Corvic is 85-115：45-75：8-12：3-7：4-8：2-4：3-5.
Preferably, urea, polyvinylpyrrolidone, deionized water, sodium chloride solution, antifoaming agent, AgNO3Solution, titanium liquid,
The weight ratio of sulfuric acid zirconium solution, disodium phosphate soln and fluorinated modified nitrile rubber is 3-7：2-4：8-12：3-7：2-5：3-
7：2-3：4-5：5-7：85-115.
Preferably, raw material includes by weight：Fluorinated modified nitrile rubber 85-115 parts, nano inorganic antimicrobial powder
45-75 parts, 8-12 parts of styrene-acrylic emulsion, 3-7 parts of alkyd resin, 4-8 parts of ethyl acetate, 2-4 parts of epoxy resin, Corvic
3-5 parts, 4-8 parts of aluminium hydroxide, 2-4 parts of bentonite, 2.5-3.5 parts of blanc fixe, 2-3 parts of nitrocotton, zinc oxide 1.5-2.5
Part, 2-4 parts of mica powder, 3-5 parts of zeolite powder, 2-6 parts of chlorinated paraffin, 3-4 parts of calcium ferrite, 3.5-4.5 parts of hexamethyl cellulose, lemon
5-7 parts of lemon acid, 2-4 parts of propyl alcohol, 3-5 parts of dimethylbenzene, 2-3 parts of curing agent.
Preferably, raw material includes by weight：100 parts of fluorinated modified nitrile rubber, 60 parts of nano inorganic antimicrobial powder,
10 parts of styrene-acrylic emulsion, 5 parts of alkyd resin, 6 parts of ethyl acetate, 3 parts of epoxy resin, 4 parts of Corvic, 6 parts of aluminium hydroxide,
3 parts of bentonite, 3 parts of blanc fixe, 2.5 parts of nitrocotton, 2 parts of zinc oxide, 3 parts of mica powder, 4 parts of zeolite powder, 4 parts of chlorinated paraffin,
3.5 parts of calcium ferrite, 4 parts of hexamethyl cellulose, 6 parts of citric acid, 3 parts of propyl alcohol, 4 parts of dimethylbenzene, 2.5 parts of curing agent.
A kind of high rigidity oil resistant antibacterial heat-resistant paint of the present invention, raw material includes fluorinated modified nitrile rubber, nanometer nothing
Machine antimicrobial powder, styrene-acrylic emulsion, alkyd resin, ethyl acetate, epoxy resin, Corvic, aluminium hydroxide, bentonite,
Blanc fixe, nitrocotton, zinc oxide, mica powder, zeolite powder, chlorinated paraffin, calcium ferrite, hexamethyl cellulose, citric acid, third
Alcohol, dimethylbenzene and curing agent.Wherein using fluorinated modified nitrile rubber as major ingredient, and add styrene-acrylic emulsion, alkyd resin, acetic acid second
The supporting material of ester, epoxy resin and Corvic as major ingredient, effectively increase the hardness of major ingredient, oil resistant, antibacterial and
Heat-resisting performance；Aluminium hydroxide, bentonite, blanc fixe, nitrocotton, zinc oxide, mica powder, zeolite powder, the chlorination stone of addition
Wax, calcium ferrite, hexamethyl cellulose, citric acid, propyl alcohol, dimethylbenzene and curing agent control and major ingredient as filler and auxiliary agent
Proportioning, effectively increase the hardness and oil resistant antibacterial heat resistance of major ingredient it is resistance to so that present invention paint has hardness high
Oily anti-microbial property is good, and has excellent heat resistance.The nano inorganic antimicrobial powder wherein added is with urea, polyvinyl pyrrole
Alkanone, deionized water, sodium chloride solution, antifoaming agent, AgNO3Solution, titanium liquid, sulfuric acid zirconium solution and disodium phosphate soln are original
Material is the method that sluggish precipitation is combined with coprecipitation in the method for preparing the use of nano inorganic antimicrobial powder.In solution
It is different due to the difference of metal ion to precipitate the condition generated, so that precipitating reagent is slowly given birth in solution using sluggish precipitation
At eliminating the local inhomogeneities of precipitating reagent, recycle coprecipitation that unprecipitated ion precipitation in solution gets off, simultaneously
Also overcome the shortcomings that coprecipitation precipitates tendency respectively.It is first by Ag that the present invention, which prepares nano inorganic antimicrobial powder,+With cl-Instead
Agcl precipitations should be generated, using Agcl as crystal seed, then using urea as the precipitating reagent of reaction, first use sluggish precipitation by reactant
The precipitate metal hydroxides such as Ti, Zr in system are got off, and just form first layer package in seed surface in this way, then using coprecipitated
The Ti that shallow lake method will not completely not reacted in homogeneous precipitation4+、Zr4+Production is got off with calcium phosphate precipitation, then forms second layer package, into
And make present invention paint that there is excellent oil resistant antibacterial heat resistance, and hardness is high.
Specific implementation mode
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent replacement etc. are in this hair
In bright protection domain.
Embodiment 1
A kind of high rigidity oil resistant antibacterial heat-resistant paint proposed by the present invention, raw material include by weight：Fluorinated modified fourth
100 parts of nitrile rubber, 60 parts of nano inorganic antimicrobial powder, 10 parts of styrene-acrylic emulsion, 5 parts of alkyd resin, 6 parts of ethyl acetate, asphalt mixtures modified by epoxy resin
3 parts of fat, 4 parts of Corvic, 6 parts of aluminium hydroxide, 3 parts of bentonite, 3 parts of blanc fixe, 2.5 parts of nitrocotton, zinc oxide 2
Part, 3 parts of mica powder, 4 parts of zeolite powder, 4 parts of chlorinated paraffin, 3.5 parts of calcium ferrite, 4 parts of hexamethyl cellulose, 6 parts of citric acid, propyl alcohol
3 parts, 4 parts of dimethylbenzene, 2.5 parts of curing agent.
Nano inorganic antimicrobial powder is prepared by following technique：By weight by 5 parts of urea, 3 parts of polyvinylpyrrolidines
Ketone and 10 parts of deionized waters are uniformly mixed, and 5 parts of sodium chloride solutions are then added and 3.5 parts of antifoaming agent stir 20min, then use liquid separation
5 parts of AgNO are added dropwise in funnel3Solution obtains material a；2.5 parts of titanium liquid are added into material a and 4.5 parts of zirconium sulfates are molten with separatory funnel
Liquid, then heating water bath is to 80 DEG C, and 6 parts of disodium phosphate solns of addition, are then aged, filtration washing after being cooled to room temperature, and does
Dry, calcining postcooling to room temperature obtains nano inorganic antimicrobial powder.
Embodiment 2
A kind of high rigidity oil resistant antibacterial heat-resistant paint proposed by the present invention, raw material include by weight：Fluorinated modified fourth
80 parts of nitrile rubber, 80 parts of nano inorganic antimicrobial powder, 5 parts of styrene-acrylic emulsion, 8 parts of alkyd resin, 3 parts of ethyl acetate, epoxy resin 5
Part, 2 parts of Corvic, 9 parts of aluminium hydroxide, 1 part of bentonite, 4 parts of blanc fixe, 1 part of nitrocotton, 3 parts of zinc oxide, mica
1 part of powder, 6 parts of zeolite powder, 1 part of chlorinated paraffin, 5 parts of calcium ferrite, 3 parts of hexamethyl cellulose, 8 parts of citric acid, 1 part of propyl alcohol, diformazan
6 parts of benzene, 1 part of curing agent.
Nano inorganic antimicrobial powder is prepared by following technique：By weight by 2 parts of urea, 5 parts of polyvinylpyrrolidines
Ketone and 5 parts of deionized waters are uniformly mixed, and 8 parts of sodium chloride solutions are then added and 1 part of antifoaming agent stirs 30min, then are leaked with liquid separation
2 parts of AgNO are added dropwise in bucket3Solution obtains material a；4 parts of titanium liquid and 3 parts of sulfuric acid zirconium solutions are added into material a with separatory funnel, so
Heating water bath is added 4 parts of disodium phosphate solns, is then aged, filtration washing to 90 DEG C afterwards after being cooled to room temperature, dry, forges
It burns postcooling to room temperature and obtains nano inorganic antimicrobial powder.
Embodiment 3
A kind of high rigidity oil resistant antibacterial heat-resistant paint proposed by the present invention, raw material include by weight：Fluorinated modified fourth
120 parts of nitrile rubber, 40 parts of nano inorganic antimicrobial powder, 15 parts of styrene-acrylic emulsion, 2 parts of alkyd resin, 9 parts of ethyl acetate, asphalt mixtures modified by epoxy resin
1 part of fat, 6 parts of Corvic, 3 parts of aluminium hydroxide, 5 parts of bentonite, 2 parts of blanc fixe, 4 parts of nitrocotton, 1 part of zinc oxide,
5 parts of mica powder, 2 parts of zeolite powder, 7 parts of chlorinated paraffin, 2 parts of calcium ferrite, 5 parts of hexamethyl cellulose, 4 parts of citric acid, 5 parts of propyl alcohol,
2 parts of dimethylbenzene, 4 parts of curing agent.
Nano inorganic antimicrobial powder is prepared by following technique：By weight by 8 parts of urea, 1 part of polyvinylpyrrolidine
Ketone and 15 parts of deionized waters are uniformly mixed, and 2 parts of sodium chloride solutions are then added and 6 parts of antifoaming agent stir 10min, then are leaked with liquid separation
8 parts of AgNO are added dropwise in bucket3Solution obtains material a；1 part of titanium liquid and 6 parts of sulfuric acid zirconium solutions are added into material a with separatory funnel, so
Heating water bath is added 8 parts of disodium phosphate solns, is then aged, filtration washing to 70 DEG C afterwards after being cooled to room temperature, dry, forges
It burns postcooling to room temperature and obtains nano inorganic antimicrobial powder.
Embodiment 4
A kind of high rigidity oil resistant antibacterial heat-resistant paint proposed by the present invention, raw material include by weight：Fluorinated modified fourth
85 parts of nitrile rubber, 75 parts of nano inorganic antimicrobial powder, 8 parts of styrene-acrylic emulsion, 7 parts of alkyd resin, 4 parts of ethyl acetate, epoxy resin 4
Part, 3 parts of Corvic, 8 parts of aluminium hydroxide, 2 parts of bentonite, 3.5 parts of blanc fixe, 2 parts of nitrocotton, 2.5 parts of zinc oxide,
2 parts of mica powder, 5 parts of zeolite powder, 2 parts of chlorinated paraffin, 4 parts of calcium ferrite, 3.5 parts of hexamethyl cellulose, 7 parts of citric acid, propyl alcohol 2
Part, 5 parts of dimethylbenzene, 2 parts of curing agent.
Nano inorganic antimicrobial powder is prepared by following technique：By weight by 3 parts of urea, 4 parts of polyvinylpyrrolidines
Ketone and 8 parts of deionized waters are uniformly mixed, and 7 parts of sodium chloride solutions are then added and 2 parts of antifoaming agent stir 25min, then are leaked with liquid separation
3 parts of AgNO are added dropwise in bucket3Solution obtains material a；3 parts of titanium liquid and 4 parts of sulfuric acid zirconium solutions are added into material a with separatory funnel, so
Heating water bath is added 5 parts of disodium phosphate solns, is then aged, filtration washing to 85 DEG C afterwards after being cooled to room temperature, dry, forges
It burns postcooling to room temperature and obtains nano inorganic antimicrobial powder.
Embodiment 5
A kind of high rigidity oil resistant antibacterial heat-resistant paint proposed by the present invention, raw material include by weight：Fluorinated modified fourth
115 parts of nitrile rubber, 45 parts of nano inorganic antimicrobial powder, 12 parts of styrene-acrylic emulsion, 3 parts of alkyd resin, 8 parts of ethyl acetate, asphalt mixtures modified by epoxy resin
2 parts of fat, 5 parts of Corvic, 4 parts of aluminium hydroxide, 4 parts of bentonite, 2.5 parts of blanc fixe, 3 parts of nitrocotton, zinc oxide 1.5
Part, 4 parts of mica powder, 3 parts of zeolite powder, 6 parts of chlorinated paraffin, 3 parts of calcium ferrite, 4.5 parts of hexamethyl cellulose, 5 parts of citric acid, propyl alcohol
4 parts, 3 parts of dimethylbenzene, 3 parts of curing agent.
Nano inorganic antimicrobial powder is prepared by following technique：By weight by 7 parts of urea, 2 parts of polyvinylpyrrolidines
Ketone and 12 parts of deionized waters are uniformly mixed, and 3 parts of sodium chloride solutions are then added and 5 parts of antifoaming agent stir 15min, then are leaked with liquid separation
7 parts of AgNO are added dropwise in bucket3Solution obtains material a；2 parts of titanium liquid and 5 parts of sulfuric acid zirconium solutions are added into material a with separatory funnel, so
Heating water bath is added 7 parts of disodium phosphate solns, is then aged, filtration washing to 75 DEG C afterwards after being cooled to room temperature, dry, forges
It burns postcooling to room temperature and obtains nano inorganic antimicrobial powder.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (6)
1. a kind of high rigidity oil resistant antibacterial heat-resistant paint, which is characterized in that its raw material includes by weight：Fluorinated modified butyronitrile rubber
80-120 parts of glue, 40-80 parts of nano inorganic antimicrobial powder, 5-15 parts of styrene-acrylic emulsion, 2-8 parts of alkyd resin, ethyl acetate 3-9
Part, 1-5 parts of epoxy resin, 2-6 parts of Corvic, 3-9 parts of aluminium hydroxide, 1-5 parts of bentonite, 2-4 parts of blanc fixe, nitre
Change 1-4 parts of cotton, 1-3 parts of zinc oxide, 1-5 parts of mica powder, 2-6 parts of zeolite powder, 1-7 parts of chlorinated paraffin, 2-5 parts of calcium ferrite, pregnancy
3-5 parts of base cellulose, 4-8 parts of citric acid, 1-5 parts of propyl alcohol, 2-6 parts of dimethylbenzene, 1-4 parts of curing agent；
The raw material of nano inorganic antimicrobial powder includes by weight：2-8 parts of urea, 1-5 parts of polyvinylpyrrolidone, deionized water
5-15 parts, 2-8 parts of sodium chloride solution, 1-6 parts of antifoaming agent, AgNO32-8 parts of solution, 1-4 parts of titanium liquid, 3-6 parts of sulfuric acid zirconium solution,
4-8 parts of disodium phosphate soln.
2. high rigidity oil resistant antibacterial heat-resistant paint according to claim 1, which is characterized in that nano inorganic antimicrobial powder is pressed
It is prepared by following technique：Urea, polyvinylpyrrolidone and deionized water are uniformly mixed, then be added sodium chloride solution and
Antifoaming agent stirs 10-30min, then AgNO is added dropwise with separatory funnel3Solution obtains material a；It is added into material a with separatory funnel
Titanium liquid and sulfuric acid zirconium solution, then heating water bath disodium phosphate soln is added after being cooled to room temperature to 70-90 DEG C, it is then old
Change, filtration washing, dry, calcining postcooling to room temperature obtains nano inorganic antimicrobial powder.
3. according to claim 1-2 any one of them high rigidity oil resistant antibacterial heat-resistant paints, which is characterized in that fluorinated modified fourth
The weight of nitrile rubber, nano inorganic antimicrobial powder, styrene-acrylic emulsion, alkyd resin, ethyl acetate, epoxy resin and Corvic
Amount is than being 85-115：45-75：8-12：3-7：4-8：2-4：3-5.
4. high rigidity oil resistant antibacterial heat-resistant paint according to claim 1, which is characterized in that urea, polyvinylpyrrolidine
Ketone, deionized water, sodium chloride solution, antifoaming agent, AgNO3Solution, titanium liquid, sulfuric acid zirconium solution, disodium phosphate soln and fluorination
Modified butadiene acrylonitrile rubber weight ratio is 3-7：2-4：8-12：3-7：2-5：3-7：2-3：4-5：5-7：85-115.
5. high rigidity oil resistant antibacterial heat-resistant paint according to claim 1, which is characterized in that its raw material wraps by weight
It includes：Fluorinated modified nitrile rubber 85-115 parts, 45-75 parts of nano inorganic antimicrobial powder, 8-12 parts of styrene-acrylic emulsion, alkyd resin 3-
7 parts, 4-8 parts of ethyl acetate, 2-4 parts of epoxy resin, 3-5 parts of Corvic, 4-8 parts of aluminium hydroxide, 2-4 parts of bentonite,
2.5-3.5 parts of blanc fixe, 2-3 parts of nitrocotton, 1.5-2.5 parts of zinc oxide, 2-4 parts of mica powder, 3-5 parts of zeolite powder, chlorination stone
2-6 parts of wax, 3-4 parts of calcium ferrite, 3.5-4.5 parts of hexamethyl cellulose, 5-7 parts of citric acid, 2-4 parts of propyl alcohol, 3-5 parts of dimethylbenzene,
2-3 parts of curing agent.
6. high rigidity oil resistant antibacterial heat-resistant paint according to claim 5, which is characterized in that its raw material wraps by weight
It includes：100 parts of fluorinated modified nitrile rubber, 60 parts of nano inorganic antimicrobial powder, 10 parts of styrene-acrylic emulsion, 5 parts of alkyd resin, acetic acid second
6 parts of ester, 3 parts of epoxy resin, 4 parts of Corvic, 6 parts of aluminium hydroxide, 3 parts of bentonite, 3 parts of blanc fixe, nitrocotton 2.5
Part, 2 parts of zinc oxide, 3 parts of mica powder, 4 parts of zeolite powder, 4 parts of chlorinated paraffin, 3.5 parts of calcium ferrite, 4 parts of hexamethyl cellulose, lemon
6 parts of acid, 3 parts of propyl alcohol, 4 parts of dimethylbenzene, 2.5 parts of curing agent.
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| CN201610182759.5A CN105713458B (en) | 2016-03-24 | 2016-03-24 | A kind of high rigidity oil resistant antibacterial heat-resistant paint |
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| CN105713458B true CN105713458B (en) | 2018-10-12 |
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| CN106433420A (en) * | 2016-08-27 | 2017-02-22 | 安徽天瞳智能科技有限公司 | Composite material with excellent antibiotic and preservative performance |
| CN106366876A (en) * | 2016-08-27 | 2017-02-01 | 安徽天瞳智能科技有限公司 | Antibacterial, uvioresistant, heat-resisting and anticorrosion composite material |
| CN106867372A (en) * | 2016-12-22 | 2017-06-20 | 安徽易有墙纸有限公司 | A kind of high-hardness water-proof wallpaper |
| CN107057437A (en) * | 2017-04-06 | 2017-08-18 | 天长市润达金属防锈助剂有限公司 | A kind of antibacterial modified antirust agent of high resistant |
| CN107254342A (en) * | 2017-04-21 | 2017-10-17 | 天长市润达金属防锈助剂有限公司 | A kind of anti-rust metal cutting fluid with excellent permeance property |
| CN110951306A (en) * | 2019-12-18 | 2020-04-03 | 广东鸿业家具制造有限公司 | Manufacturing method of odorless environment-friendly paint for furniture |
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| CN101475767A (en) * | 2006-03-31 | 2009-07-08 | 中国科学院过程工程研究所 | Coating for collecting formaldehyde |
| CN103897506B (en) * | 2013-10-29 | 2016-04-06 | 东南大学 | A kind of waterborne flame retardant anticorrosive paint |
| CN104449166A (en) * | 2014-11-21 | 2015-03-25 | 无锡市虎皇漆业有限公司 | Single-component primer-topcoat paint commonly used on stainless steel, galvanized sheet and aluminum alloy and preparation method of single-component primer-topcoat paint commonly used on stainless steel, galvanized sheet and aluminum alloy |
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Effective date of registration: 20220906 Address after: 315605 tinggang Industrial Zone, Yuexi Township, Ninghai County, Ningbo City, Zhejiang Province Patentee after: Ningbo Changfa Coatings Co.,Ltd. Address before: 233000 No. 2, Guihua Road, mohekou Industrial Park, Bengbu City, Anhui Province Patentee before: ANHUI PENGFENG NEW BUILDING MATERIALS TECHNOLOGY CO.,LTD. |