CN108677595A - Environmental protection wall paper and preparation method thereof - Google Patents
Environmental protection wall paper and preparation method thereof Download PDFInfo
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- CN108677595A CN108677595A CN201810471677.1A CN201810471677A CN108677595A CN 108677595 A CN108677595 A CN 108677595A CN 201810471677 A CN201810471677 A CN 201810471677A CN 108677595 A CN108677595 A CN 108677595A
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
- D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
- D21H15/10—Composite fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/34—Ignifugeants
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
- E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
- E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
- E04F2290/045—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire against fire
Landscapes
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Paper (AREA)
Abstract
The invention discloses a kind of environmental protection wall paper and preparation method thereof, the preparation method includes:Plant fiber is placed in aqueous acetic acid, is ground after immersion, plant fiber powder is obtained;The first mixing material is obtained after plant fiber powder, Amino resin, polyurethane, Corvic, butyl glycol ether and coupling agent are mixed;The second mixing material is obtained after wood pulp, calcium ferrite, chlorinated paraffin, lignocellulose, polyethylene glycol, nano zine oxide, dibutyl tin laurate, thickener and water are mixed;After first mixing material and the second mixing material are mixed, environmental protection wall paper is obtained through hot press molding;Solves in the prior art the problem of flame retardant property of wallpaper and anti-microbial property are poor, cannot be satisfied demand in actual use.
Description
Technical field
The present invention relates to wallpaper fields, and in particular, to a kind of environmental protection wall paper and preparation method thereof.
Background technology
Wallpaper usually produces body paper, then the working process through different processes, such as coating, printing, pressure with bleached wood pulp
Modeling is covered on line or surface, is dispatched from the factory after last cut, packaging.Because with certain intensity, beautiful appearance and good water resistant
Performance is widely used in the interior decoration etc. of house, office, hotel.The flame retardant property and antibacterial of wallpaper in the prior art
Performance is poor, cannot be satisfied demand in actual use.
Invention content
The object of the present invention is to provide a kind of environmental protection wall paper and preparation method thereof, solve the fire-retardant of wallpaper in the prior art
Performance and anti-microbial property are poor, the problem of cannot be satisfied demand in actual use.
To achieve the goals above, the present invention provides a kind of preparation method of environmental protection wall paper, the preparation method includes:
(1) plant fiber is placed in aqueous acetic acid, is ground after immersion, obtain plant fiber powder;
(2) by plant fiber powder, Amino resin, polyurethane, Corvic, butyl glycol ether and coupling
The first mixing material is obtained after agent mixing;
(3) by wood pulp, calcium ferrite, chlorinated paraffin, lignocellulose, polyethylene glycol, nano zine oxide, tin dilaurate two
The second mixing material is obtained after butyl tin, thickener and water mixing;
(4) after mixing the first mixing material and the second mixing material, environmental protection wall paper is obtained through hot press molding;Wherein, hot
Molded condition includes:Temperature is 70-120 DEG C, time 5-20min.
The present invention also provides a kind of environmental protection wall paper, the environmental protection wall paper is made by above-mentioned preparation method.
Through the above technical solutions, the present invention provides a kind of environmental protection wall paper and preparation method thereof, the preparation method packet
It includes:Plant fiber is placed in aqueous acetic acid, is ground after immersion, plant fiber powder is obtained;By plant fiber powder,
The first mixing material is obtained after Amino resin, polyurethane, Corvic, butyl glycol ether and coupling agent mixing;
By wood pulp, calcium ferrite, chlorinated paraffin, lignocellulose, polyethylene glycol, nano zine oxide, dibutyl tin laurate, thickening
The second mixing material is obtained after agent and water mixing;After first mixing material and the second mixing material are mixed, through hot press molding
To environmental protection wall paper;Pass through the synergistic effect between each raw material so that environmental protection wall paper obtained has excellent anti-microbial property and resistance
Performance is fired, while the method for being used to prepare the environmental protection wall paper is simple, raw material is easy to get.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Specific implementation mode
The specific implementation mode of the present invention is described in detail below.It should be understood that described herein specific
Embodiment is merely to illustrate and explain the present invention, and is not intended to restrict the invention.
The endpoint of disclosed range and any value are not limited to the accurate range or value herein, these ranges or
Value should be understood as comprising the value close to these ranges or value.For numberical range, between the endpoint value of each range, respectively
It can be combined with each other between the endpoint value of a range and individual point value, and individually between point value and obtain one or more
New numberical range, these numberical ranges should be considered as specific open herein.
The present invention provides a kind of preparation method of environmental protection wall paper, the preparation method includes:
(1) plant fiber is placed in aqueous acetic acid, is ground after immersion, obtain plant fiber powder;
(2) by plant fiber powder, Amino resin, polyurethane, Corvic, butyl glycol ether and coupling
The first mixing material is obtained after agent mixing;
(3) by wood pulp, calcium ferrite, chlorinated paraffin, lignocellulose, polyethylene glycol, nano zine oxide, tin dilaurate two
The second mixing material is obtained after butyl tin, thickener and water mixing;
(4) after mixing the first mixing material and the second mixing material, environmental protection wall paper is obtained through hot press molding;Wherein, hot
Molded condition includes:Temperature is 70-120 DEG C, time 5-20min.
In a kind of preferred embodiment of the present invention, in order to further increase the anti-microbial property of environmental protection wall paper obtained
And flame retardant property, relative to the plant fiber of 100 parts by weight, the dosage of the aqueous acetic acid is 400-500 parts by weight;With/
Or
The volumetric concentration of aqueous acetic acid is 30-50%.
In a kind of preferred embodiment of the present invention, in order to further increase the anti-microbial property of environmental protection wall paper obtained
And flame retardant property, relative to the plant fiber powder of 100 parts by weight, the dosage of the Amino resin is 10-30 weight
Part, the dosage of the polyurethane is 2-15 parts by weight, and the dosage of the Corvic is 5-15 parts by weight, the ethylene glycol
The dosage of butyl ether is 50-90 parts by weight, and the dosage of the coupling agent is 2-8 parts by weight;
Relative to the wood pulp of 100 parts by weight, the dosage of the calcium ferrite is 10-20 parts by weight, the use of the chlorinated paraffin
Amount is 5-15 parts by weight, and the dosage of the lignocellulose is 3-10 parts by weight, and the dosage of the polyethylene glycol is 30-80 weights
Part is measured, the dosage of the nano zine oxide is 2-7 parts by weight, and the dosage of the dibutyl tin laurate is 2-10 parts by weight,
The dosage of the thickener is 3-9 parts by weight, and the dosage of the water is 200-400 parts by weight.
In a kind of preferred embodiment of the present invention, in order to further increase the anti-microbial property of environmental protection wall paper obtained
And flame retardant property, the first mixing material and the second mixing material are 1 according to mass ratio:The ratio of 2-4 is mixed.
In a kind of preferred embodiment of the present invention, in order to further increase the anti-microbial property of environmental protection wall paper obtained
And flame retardant property, in step (1), the condition of immersion includes:Temperature is 40-50 DEG C, time 20-30min.
In a kind of preferred embodiment of the present invention, in order to further increase the anti-microbial property of environmental protection wall paper obtained
And flame retardant property, in step (2), mixed condition includes:Temperature is 30-50 DEG C, time 40-60min.
In a kind of preferred embodiment of the present invention, in order to further increase the anti-microbial property of environmental protection wall paper obtained
And flame retardant property, in step (3), mixed condition includes:Temperature is 50-60 DEG C, time 1-2h.
In a kind of preferred embodiment of the present invention, in order to further increase the anti-microbial property of environmental protection wall paper obtained
And flame retardant property, coupling agent are one or more in coupling agent KH550, coupling agent KH560 and coupling agent KH570;And/or
Thickener is one or more in methylcellulose, hydroxypropyl methyl cellulose and sodium carboxymethylcellulose.
In a kind of preferred embodiment of the present invention, in order to further increase the anti-microbial property of environmental protection wall paper obtained
And flame retardant property, the weight average molecular weight of Corvic is 7000-9000, and the weight average molecular weight of polyethylene glycol is 5000-
7000;And/or
The average grain diameter of nano zine oxide is 30-50nm.
The present invention also provides a kind of environmental protection wall paper, the environmental protection wall paper is made by above-mentioned preparation method.
The present invention will be described in detail by way of examples below.In following embodiment, the weight of Corvic is equal
Molecular weight is 7000-9000, and the weight average molecular weight of polyethylene glycol is 5000-7000, and the average grain diameter of nano zine oxide is 30-
50nm。
Embodiment 1
100g plant fibers are placed in 400g aqueous acetic acids (volumetric concentration 30%), is ground, obtains after immersion
To plant fiber powder;By 100g plant fibers powder, 10g Amino resins, 2g polyurethane, 5g Corvics,
The first mixing material is obtained after 50g butyl glycol ethers and 2g coupling agents KH550 mixing (temperature is 40 DEG C, time 20min);It will
100g wood pulps, 10g calcium ferrites, 5g chlorinated paraffins, 3g lignocelluloses, 30g polyethylene glycol, 2g nano zine oxides, 2g February
The second mixing material is obtained after dilaurylate, 3g methylcellulose and 200g water mixing (temperature is 30 DEG C, time 40min)
Material;(it is 1 according to mass ratio after first mixing material and the second mixing material are mixed:2 are mixed, and mixed condition includes:
Temperature is 50 DEG C, time 1h), obtaining environmental protection wall paper A1 through hot press molding, (hot-forming condition includes:Temperature is 70 DEG C,
Time is 5min).The flame retardant rating of environmental protection wall paper A1 obtained is B1, and degerming rate is 79%.
Embodiment 2
100g plant fibers are placed in 500g aqueous acetic acids (volumetric concentration 50%), is ground, obtains after immersion
To plant fiber powder;By 100g plant fibers powder, 30g Amino resins, 15g polyurethane, 15g polyvinyl chloride trees
The first mixing material is obtained after fat, 90g butyl glycol ethers and 8g coupling agents KH560 mixing (temperature is 50 DEG C, time 30min)
Material;By 100g wood pulps, 20g calcium ferrites, 15g chlorinated paraffins, 10g lignocelluloses, 80g polyethylene glycol, 7g nano zine oxides,
After 10g dibutyl tin laurates, 9g hydroxypropyl methyl celluloses and 400g water mixing (temperature is 50 DEG C, time 60min)
Obtain the second mixing material;(it is 1 according to mass ratio after first mixing material and the second mixing material are mixed:4 are mixed,
Mixed condition includes:Temperature is 60 DEG C, time 2h), environmental protection wall paper A2 (hot-forming condition packets are obtained through hot press molding
It includes:Temperature is 120 DEG C, time 20min).The flame retardant rating of environmental protection wall paper A2 obtained is B1, and degerming rate is 74%.
Embodiment 3
100g plant fibers are placed in 450g aqueous acetic acids (volumetric concentration 40%), is ground, obtains after immersion
To plant fiber powder;By 100g plant fibers powder, 20g Amino resins, 7g polyurethane, 10g Corvics,
The first mixing material is obtained after 70g butyl glycol ethers and 6g coupling agents KH570 mixing (temperature is 45 DEG C, time 25min);It will
100g wood pulps, 15g calcium ferrites, 10g chlorinated paraffins, 7g lignocelluloses, 50g polyethylene glycol, 5g nano zine oxides, 6g February
It is mixed that second is obtained after dilaurylate, 6g sodium carboxymethylcelluloses and 300g water mixing (temperature is 40 DEG C, time 50min)
Condensation material;(it is 1 according to mass ratio after first mixing material and the second mixing material are mixed:3 are mixed, mixed condition
Including:Temperature is 55 DEG C, time 1.5h), obtaining environmental protection wall paper A3 through hot press molding, (hot-forming condition includes:Temperature
It is 90 DEG C, time 12min).The flame retardant rating of environmental protection wall paper A3 obtained is B1, and degerming rate is 71%.
Comparative example 1
It is carried out according to the method for embodiment 3, unlike, plant fiber powder is not contained in raw material, obtains environmental protection wall paper
The flame retardant rating of D1, environmental protection wall paper D1 obtained are B2, and degerming rate is 60%.
Comparative example 2
It is carried out according to the method for embodiment 3, unlike, calcium ferrite and chlorinated paraffin are not contained in raw material, obtain environmental protection
The flame retardant rating of wallpaper D2, environmental protection wall paper D2 obtained are B2, and degerming rate is 62%.
The preferred embodiment of the present invention has been described above in detail, still, during present invention is not limited to the embodiments described above
Detail can carry out a variety of simple variants to technical scheme of the present invention within the scope of the technical concept of the present invention, this
A little simple variants all belong to the scope of protection of the present invention.
It is further to note that specific technical features described in the above specific embodiments, in not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to it is various can
The combination of energy no longer separately illustrates.
In addition, various embodiments of the present invention can be combined randomly, as long as it is without prejudice to originally
The thought of invention, it should also be regarded as the disclosure of the present invention.
Claims (10)
1. a kind of preparation method of environmental protection wall paper, which is characterized in that the preparation method includes:
(1) plant fiber is placed in aqueous acetic acid, is ground after immersion, obtain plant fiber powder;
(2) plant fiber powder, Amino resin, polyurethane, Corvic, butyl glycol ether and coupling agent are mixed
The first mixing material is obtained after conjunction;
(3) by wood pulp, calcium ferrite, chlorinated paraffin, lignocellulose, polyethylene glycol, nano zine oxide, di lauric dibutyl
The second mixing material is obtained after tin, thickener and water mixing;
(4) after mixing the first mixing material and the second mixing material, environmental protection wall paper is obtained through hot press molding;Wherein, it is hot pressed into
The condition of type includes:Temperature is 70-120 DEG C, time 5-20min.
2. preparation method according to claim 1, wherein relative to the plant fiber of 100 parts by weight, the acetic acid is water-soluble
The dosage of liquid is 400-500 parts by weight;And/or
The volumetric concentration of aqueous acetic acid is 30-50%.
3. preparation method according to claim 1, wherein relative to the plant fiber powder of 100 parts by weight, the methyl ether
The dosage for changing amino resins is 10-30 parts by weight, and the dosage of the polyurethane is 2-15 parts by weight, the Corvic
Dosage is 5-15 parts by weight, and the dosage of the butyl glycol ether is 50-90 parts by weight, and the dosage of the coupling agent is 2-8 weight
Part;
Relative to the wood pulp of 100 parts by weight, the dosage of the calcium ferrite is 10-20 parts by weight, and the dosage of the chlorinated paraffin is
The dosage of 5-15 parts by weight, the lignocellulose is 3-10 parts by weight, and the dosage of the polyethylene glycol is 30-80 weight
Part, the dosage of the nano zine oxide is 2-7 parts by weight, and the dosage of the dibutyl tin laurate is 2-10 parts by weight, institute
The dosage for stating thickener is 3-9 parts by weight, and the dosage of the water is 200-400 parts by weight.
4. preparation method according to claim 1, wherein the first mixing material and the second mixing material are according to mass ratio
1:The ratio of 2-4 is mixed.
5. preparation method according to claim 1, wherein in step (1), the condition of immersion includes:Temperature is 40-50
DEG C, time 20-30min.
6. preparation method according to claim 1, wherein in step (2), mixed condition includes:Temperature is 30-50
DEG C, time 40-60min.
7. preparation method according to claim 1, wherein in step (3), mixed condition includes:Temperature is 50-60
DEG C, time 1-2h.
8. preparation method according to claim 1, wherein coupling agent is selected from coupling agent KH550, coupling agent KH560 and idol
Join one or more in agent KH570;And/or
Thickener is one or more in methylcellulose, hydroxypropyl methyl cellulose and sodium carboxymethylcellulose.
9. preparation method according to claim 1, wherein the weight average molecular weight of Corvic is 7000-9000, is gathered
The weight average molecular weight of ethylene glycol is 5000-7000;And/or
The average grain diameter of nano zine oxide is 30-50nm.
10. a kind of environmental protection wall paper, which is characterized in that the environmental protection wall paper is by the preparation described in any one of claim 1-9
Method is made.
Priority Applications (1)
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CN201810471677.1A CN108677595A (en) | 2018-05-17 | 2018-05-17 | Environmental protection wall paper and preparation method thereof |
Applications Claiming Priority (1)
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CN201810471677.1A CN108677595A (en) | 2018-05-17 | 2018-05-17 | Environmental protection wall paper and preparation method thereof |
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Publication Number | Publication Date |
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CN108677595A true CN108677595A (en) | 2018-10-19 |
Family
ID=63806426
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CN201810471677.1A Withdrawn CN108677595A (en) | 2018-05-17 | 2018-05-17 | Environmental protection wall paper and preparation method thereof |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106638132A (en) * | 2016-08-17 | 2017-05-10 | 福建农林大学 | Polyvinyl chloride flame-retardant wallpaper taking plant fiber paper as base material, and preparation method thereof |
CN106703311A (en) * | 2016-12-22 | 2017-05-24 | 安徽易有墙纸有限公司 | Heat-resisting waterproof wallpaper and production method thereof |
CN106867327A (en) * | 2016-12-22 | 2017-06-20 | 安徽易有墙纸有限公司 | A kind of resistant oil resistant wallpaper and preparation method thereof |
CN106867372A (en) * | 2016-12-22 | 2017-06-20 | 安徽易有墙纸有限公司 | A kind of high-hardness water-proof wallpaper |
CN107245911A (en) * | 2017-08-02 | 2017-10-13 | 合肥市大卓电力有限责任公司 | A kind of preparation method of novel environment friendly wallpaper |
-
2018
- 2018-05-17 CN CN201810471677.1A patent/CN108677595A/en not_active Withdrawn
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106638132A (en) * | 2016-08-17 | 2017-05-10 | 福建农林大学 | Polyvinyl chloride flame-retardant wallpaper taking plant fiber paper as base material, and preparation method thereof |
CN106703311A (en) * | 2016-12-22 | 2017-05-24 | 安徽易有墙纸有限公司 | Heat-resisting waterproof wallpaper and production method thereof |
CN106867327A (en) * | 2016-12-22 | 2017-06-20 | 安徽易有墙纸有限公司 | A kind of resistant oil resistant wallpaper and preparation method thereof |
CN106867372A (en) * | 2016-12-22 | 2017-06-20 | 安徽易有墙纸有限公司 | A kind of high-hardness water-proof wallpaper |
CN107245911A (en) * | 2017-08-02 | 2017-10-13 | 合肥市大卓电力有限责任公司 | A kind of preparation method of novel environment friendly wallpaper |
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Application publication date: 20181019 |