CN105331303A - Glutinous rice adhesive being easy to blend and convenient to construct and used for wallpaper pasting, and preparation method thereof - Google Patents
Glutinous rice adhesive being easy to blend and convenient to construct and used for wallpaper pasting, and preparation method thereof Download PDFInfo
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Abstract
The invention belongs to the wallpaper adhesive industry, and especially relates to a glutinous rice adhesive being easy to blend and convenient to construct and used for wallpaper pasting, and a preparation method thereof. The glutinous rice adhesive being easy to blend and convenient to construct and used for wallpaper pasting is mainly prepared from, by weight, 600-700 parts of deionized water, 20-60 parts of glutinous rice flour, 60-100 parts of waxy corn starch, 20-30 parts of corn starch, 30-60 parts of wheat starch, 20-40 parts of potato starch, 20-40 parts of cassava starch, 0.1-0.5 parts of a cross-linking agent, 10-18 parts of a cationic etherifying agent, 30-40 parts of an anionic etherifying agent, 30-50 parts of a catalyst, 2-5 parts of a wetting agent, 10-15 parts of a bactericide and 5-8 parts of a mildew inhibitor. The glutinous rice adhesive product used for wallpaper and wall cloth adhesion, prepared in the invention, has the advantages of easy blending, improvement of the construction adhesive blending preparation efficiency, good coating levelability, and facilitation of pattern splicing and joint aligning of wallpaper and wall cloth construction.
Description
Technical field
The invention belongs to wallpaper adhesive industry, particularly wallpaper stickup glutinous rice glue of constructing and preparation method thereof converted in a kind of easy tune.
Background technology
Along with continuous " intensification " of several years ago real estate market, the domestic environment potential safety hazard caused by house ornamentation attracts people's attention.From the data that can inquire about, it is pollute the third phase indicated that modern is entering with " room air pollution ".The toxic substance discharged in house decoration material has formaldehyde, toluene diisocyanate, organic volatile, asbestos, ammonia, radon etc., and wherein nearly kind more than 20 has been confirmed to be carcinogens and mutagen.New clothes are repaiied house indoor atmospheric pollution and are very likely had a strong impact on healthy even carcinogenic as can be seen here, and therefore selection material is comparatively crucial, wherein use wallpaper to be that the current constructional ornamental material market share takies larger house ornamentation means.
Through development nearly ten years, wallpaper progressively develops into weaving, nonwoven, environmental protection, ecology, green product from single product, put up wallpaper, wall cloth auxiliary material thereupon, tackiness agent, also towards function future developments such as health, ecology, environmental protection, substitutes the tackiness agent that tradition uses high-content white glue with vinyl completely.
Relative environmental protection on domestic market and to use more be starch conversion tackiness agent, but there is many deficiencies or problem: because this tackiness agent cools 30 DEG C by after certain starch and the hot gelatinization of treated starch, after add 30% low-solid content white glue with vinyl and stir, produce paste white glue with vinyl.Its production cost is high, and use when pasting wallpaper, wallpaper not easily moves, cannot parquets, to flower.Construction is overflow glue not easy cleaning, coheres and unevenly easily occurs bubble, bulge phenomenon.
Because product interpolation thickening white glue with vinyl is Chemicals, inadequate environmental protection, indoor extended residual chemical industry monomer smell, and do not add the viscosity that thickening white glue with vinyl can not ensure product.Especially in the high wallpaper such as high-grade pure paper, gold foil paper of processing requirement, wall cloth application, often cause because bonding effect is undesirable repeating construction, material resources waste, sharply add and rise cost, be difficult to meet user demand completely, restriction wallpaper industry is advanced and development.
Summary of the invention
The present invention is directed to the defect of prior art, provide a kind of easily tune to convert, coating good leveling property, final product is not containing formaldehyde, and nontoxic, the wallpaper stickup glutinous rice glue of constructing converted in the easy tune that high/low temperature stability is good.
The preparation method of the wallpaper stickup glutinous rice glue that the present invention also provides above-mentioned easy tune to convert to construct.
The technical solution adopted for the present invention to solve the technical problems is:
A wallpaper stickup glutinous rice glue of constructing converted in easy tune, and this glutinous rice glue is mainly made up of the raw material of following weight part:
Deionized water: 600 ~ 700,
Sticky rice flour: 20 ~ 60,
Waxy corn starch: 60 ~ 100,
W-Gum: 20 ~ 30,
Wheat starch: 30 ~ 60,
Yam starch: 20 ~ 40,
Tapioca (flour): 20 ~ 40,
Linking agent: 0.1 ~ 0.5,
Cationic etherifying agent: 10 ~ 18,
Negatively charged ion etherifying agent: 30 ~ 40,
Catalyzer: 30 ~ 50,
Wetting agent: 2 ~ 5,
Sterilant: 10 ~ 15,
Mould inhibitor: 5 ~ 8.
As preferably, linking agent is borax or non-iron aluminium sulfate.
As preferably, cationic etherifying agent is 3-chloro-2-hydroxypropyl-trimethyl ammonium chloride, and negatively charged ion etherifying agent is Mono Chloro Acetic Acid or sodium chloroacetate.
As preferably, catalyzer is any one or two or more combinations in sodium hydroxide, potassium hydroxide, sodium phosphate or sodium carbonate.
As preferably, wetting agent is any one or combination of Macrogol 200, poly(oxyethylene glycol) 400, propylene glycol, and mould inhibitor is any one or two or more combinations in Sodium dehydroacetate, sodium Diacetate, calcium propionate, tennecetin.
As preferably, sterilant is the combination of in glacial acetic acid, ethanol, M-nitro benzoic acid, potassium sorbate more than at least three kinds.As preferably, sterilant is glacial acetic acid: ethanol: M-nitro benzoic acid: the compound that potassium sorbate mixes with the weight proportion of 5:10:1-2:0-2.
The preparation method of the wallpaper stickup glutinous rice glue of constructing converted in a kind of described easy tune, the method is mainly: according to proportioning by after sticky rice flour, waxy corn starch, W-Gum, wheat starch, yam starch, tapioca (flour) premix, add wetting agent, linking agent and cationic etherifying agent and carry out crosslinked and the process of positively charged ion etherificate, add catalyzer more afterwards and negatively charged ion etherifying agent carries out carboxymethylation process, obtain composite modified starch breast, 40 ~ 120min is reacted, germicidal treatment discharging packing again after adding sterilant, mould inhibitor again.
As preferably, the method is mainly: according to proportioning by sticky rice flour, waxy corn starch, W-Gum, wheat starch, yam starch, after tapioca (flour) premix, add wetting agent, linking agent and cationic etherifying agent carry out crosslinked and the process of positively charged ion etherificate, dispersed with stirring heated up 35 ~ 50 DEG C after 30 minutes, constant temperature 3 hours ~ 5 hours, add catalyzer dispersion stirring 10 ~ 20 minutes afterwards, add negatively charged ion etherifying agent again and carry out carboxymethylation process, react and obtain composite modified starch breast after 40 ~ 60 minutes, add sterilant again, 40 ~ 120min is reacted after mould inhibitor, germicidal treatment discharging packing again.
The present invention a kind ofly adopts the ative starch materials such as natural glutinous rice starch, waxy corn starch, W-Gum, wheat starch, yam starch, tapioca (flour), by carrying out suitable compatibility to the category of ative starch and tret, carry out crosslinked denaturing treatment, positively charged ion etherificate denaturing treatment, the triple complex denaturation process of carboxymethyl etherification denaturing treatment again, effectively improve the shortcomings such as the viscosity stability that single variety raw material in the past exists is low, anti-shearing force is poor, resistance to deterioration, anti-microbe ability difference; Meanwhile, the stickup wallpaper glutinous rice glue of exploitation is made to have suitable initial viscosity, good levelling property and very strong cohesive strength; Meanwhile, by starch after complex denaturation process, there is gelatinization point low, close to normal temperature gelatinization, can energy efficient, reducing discharge, is the environment-friendly type wallpaper glue product of the cleaner production of the sustainable cycle development of environmental protection.
The invention has the beneficial effects as follows: wallpaper prepared by the present invention, wall cloth stickup glutinous rice glue product have easily to adjust to be converted, and improves construction impregnation efficiency; Coating good leveling property, is beneficial to the parquets opposite joint of wallpaper wall paper construction; Final product is not containing formaldehyde, nontoxic; Product high/low temperature stability is good, applied widelyly can meet different geographical, the wallpaper of Different climate, wall cloth construction usage require it is promote that industry is healthy, benign development, the good product of benefiting the nation and the people.
Embodiment
Below by specific embodiment, technical scheme of the present invention is described in further detail.Should be appreciated that enforcement of the present invention is not limited to the following examples, any pro forma accommodation make the present invention and/or change all will fall into scope.
In the present invention, if not refer in particular to, all parts, per-cent are weight unit, and the equipment adopted and raw material etc. all can be buied from market or this area is conventional.Method in following embodiment, if no special instructions, is the ordinary method of this area.
Cationic etherifying agent (3-chloro-2-hydroxypropyl-trimethyl ammonium chloride), Dow Chemical Company;
Negatively charged ion etherifying agent (Mono Chloro Acetic Acid or sodium chloroacetate), Shijiazhuang Bi De Chemical Co., Ltd.;
Embodiment 1
Deionized water: 650kg, sticky rice flour: 50kg, waxy corn starch: 80kg, W-Gum: 20kg, wheat starch: 30kg, yam starch: 50kg, tapioca (flour): 20kg, borax: 0.15kg, cationic etherifying agent: 18kg, sodium chloroacetate: 30kg, sodium carbonate: 20kg, sodium hydroxide: 30kg, Macrogol 200: 2kg, glacial acetic acid: 5kg, ethanol: 10kg, M-nitro benzoic acid: 2kg, calcium propionate: 2kg, sodium Diacetate: 1kg, tennecetin: 0.3kg, Sodium dehydroacetate: 0.4kg.
Preparation method: by deionized water, sticky rice flour (Henan Huangguo Grain Company Limited's production), waxy corn starch (production of Qinhuangdao Li Hua company), W-Gum (production of Zhucheng Xing Mao company), wheat starch (production of Anhui An Te company), yam starch (production of Great Northern Wilderness group company), tapioca (flour) (production of Guangxi Ming Yang company), polyoxyethylene glycol (production of Hai'an, Jiangsu petroleum chemical plant), borax (production of Yingkou Hong Taipeng magnesium company limited), cationic etherifying agent (Dow Chemical Company's production) adds in reaction vessel, dispersed with stirring heated up 35 ~ 50 DEG C after 30 minutes, constant temperature 3 hours ~ 5 hours, add sodium carbonate (production of Shandong Hai Hua company), sodium hydroxide (production of Shanghai Li Shan Chemical Co., Ltd.) dispersion stirring 10 ~ 20 minutes, add and to add glacial acetic acid (production of Tonghua, Zhengzhou Industrial Co., Ltd.) dispersion after sodium chloroacetate (production of Shijiazhuang Bi De Chemical Co., Ltd.) reacts 40 ~ 60 minutes afterwards and within 5 ~ 10 minutes, add M-nitro benzoic acid solution (M-nitro benzoic acid [productions of Zibo three good fortune chemical development company limited] 2 10 parts of edible ethanols dissolve) and disperse within 5 ~ 10 minutes, to add calcium propionate (Zhong Zheng Chemical Co., Ltd. of Tengzhou of Shandong Province), sodium Diacetate (production of Nantong Ao Kai company), (Nantong Ao Kai company produces dehydroacetic acid (DHA) sodium solution, dilute with the deionized water dissolving of 3 times of weight, this deionized water consumption is not counted in formula water consumption, lower same), (tennecetin [production of Qi Hong bio tech ltd] dilutes with the deionized water dissolving of 3 times of weight tennecetin solution, this deionized water consumption is not counted in formula water consumption, lower same) disperse stirring 40 ~ 60 minutes, 30 DEG C are cooled to after colloid modification, adopt pulse strong-light technology to carry out surface disinfection to colloid in discharging simultaneously, packaging can obtain easily adjusting converting, good construction, the wallpaper of high-environmental performance, wall cloth tackiness agent.
Product is beige pasty colloid, product viscosity 64000mpa.s; 180 ° of stripping strengths are 10.8N/25mm; Freeze-thaw stability > 10 freeze-thaw cycle; High-temperature stability > 120d; Product is adjusted and is converted conveniently, and good leveling property can meet all kinds of wallpaper, wall cloth is applied in different construction environments in coating.
Embodiment 2
Deionized water: 650kg, sticky rice flour: 40kg, waxy corn starch: 90kg, W-Gum: 25kg, wheat starch: 25kg, yam starch: 40kg, tapioca (flour): 30kg, borax: 0.2kg, cationic etherifying agent: 15kg, Mono Chloro Acetic Acid: 40kg, potassium hydroxide: 30kg, sodium phosphate: 25kg, poly(oxyethylene glycol) 400: 2kg, glacial acetic acid: 5kg, ethanol: 10kg, M-nitro benzoic acid: 1kg, potassium sorbate: 2kg, calcium propionate: 2kg, sodium Diacetate: 1kg, tennecetin: 0.3kg, Sodium dehydroacetate: 0.4kg.
Preparation method: by deionized water, sticky rice flour (Henan Huangguo Grain Company Limited's production), waxy corn starch (production of Qinhuangdao Li Hua company), W-Gum (production of Zhucheng Xing Mao company), wheat starch (production of Anhui An Te company), yam starch (production of Great Northern Wilderness group company), tapioca (flour) (production of Guangxi Ming Yang company), polyoxyethylene glycol (production of Hai'an, Jiangsu petroleum chemical plant), borax (production of Yingkou Hong Taipeng magnesium company limited), cationic etherifying agent (Dow Chemical Company's production) adds in reaction vessel, dispersed with stirring heated up 35 ~ 50 DEG C after 30 minutes, constant temperature 3 hours ~ 5 hours, add sodium phosphate (production of Shandong Zhenhua Industries, Inc), potassium hydroxide (production of Jiangsu You Lide Chemical Co., Ltd.) dispersion stirring 10 ~ 20 minutes, add and to add glacial acetic acid (production of Tonghua, Zhengzhou Industrial Co., Ltd.) dispersion after Mono Chloro Acetic Acid (production of Shijiazhuang Bi De Chemical Co., Ltd.) reacts 40 ~ 60 minutes afterwards and within 5 ~ 10 minutes, add M-nitro benzoic acid solution (M-nitro benzoic acid [productions of Zibo three good fortune chemical development company limited] 1 10 parts of edible ethanols dissolve) and disperse to add potassium sorbate in 5 ~ 10 minutes, calcium propionate (Zhong Zheng Chemical Co., Ltd. of Tengzhou of Shandong Province), sodium Diacetate (production of Nantong Ao Kai company), dehydroacetic acid (DHA) sodium solution (production of Nantong Ao Kai company), tennecetin solution (tennecetin [production of Qi Hong bio tech ltd] 3 ~ 5 parts of deionized water dissolvings dilute) dispersion stirring 40 ~ 60 minutes, 30 DEG C are cooled to after colloid modification, adopt pulse strong-light technology to carry out surface disinfection to colloid in discharging simultaneously, packaging can obtain easily adjusting converting, good construction, the wallpaper of high-environmental performance, wall cloth tackiness agent.
Product is beige pasty colloid, product viscosity 65000mpa.s; 180 ° of stripping strengths are 11.5N/25mm; Freeze-thaw stability > 12 freeze-thaw cycle; High-temperature stability > 120d; Product is adjusted and is converted conveniently, and good leveling property can meet all kinds of wallpaper, wall cloth is applied in different construction environments in coating.
Embodiment 3
Deionized water: 650kg, sticky rice flour: 40kg, waxy corn starch: 90kg, W-Gum: 25kg, wheat starch: 25kg, yam starch: 40kg, tapioca (flour): 30kg, borax: 0.2kg, cationic etherifying agent: 18kg, Mono Chloro Acetic Acid: 38kg, sodium carbonate: 30kg, sodium hydroxide: 25kg, poly(oxyethylene glycol) 400: 2kg, glacial acetic acid: 5kg, ethanol: 10kg, M-nitro benzoic acid: 1kg, potassium sorbate: 2kg, calcium propionate: 2kg, sodium Diacetate: 1kg, tennecetin: 0.3kg, Sodium dehydroacetate: 0.4kg.
Preparation method: by deionized water, sticky rice flour (Henan Huangguo Grain Company Limited's production), waxy corn starch (production of Qinhuangdao Li Hua company), W-Gum (production of Zhucheng Xing Mao company), wheat starch (production of Anhui An Te company), yam starch (production of Great Northern Wilderness group company), tapioca (flour) (production of Guangxi Ming Yang company), polyoxyethylene glycol (production of Hai'an, Jiangsu petroleum chemical plant) borax (production of Yingkou Hong Taipeng magnesium company limited), cationic etherifying agent (Dow Chemical Company's production) adds in reaction vessel, dispersed with stirring heated up 35 ~ 50 DEG C after 30 minutes, constant temperature 3 hours ~ 5 hours, add sodium carbonate (production of Shandong Hai Hua company), sodium hydroxide (production of Shanghai Li Shan Chemical Co., Ltd.) dispersion stirring 10 ~ 20 minutes, add and to add glacial acetic acid (production of Tonghua, Zhengzhou Industrial Co., Ltd.) dispersion after Mono Chloro Acetic Acid (production of Shijiazhuang Bi De Chemical Co., Ltd.) reacts 40 ~ 60 minutes afterwards and within 5 ~ 10 minutes, add M-nitro benzoic acid solution (M-nitro benzoic acid [productions of Zibo three good fortune chemical development company limited] 1 10 parts of edible ethanols dissolve) and disperse to add potassium sorbate in 5 ~ 10 minutes, calcium propionate (Zhong Zheng Chemical Co., Ltd. of Tengzhou of Shandong Province), sodium Diacetate (production of Nantong Ao Kai company), dehydroacetic acid (DHA) sodium solution (production of Nantong Ao Kai company), tennecetin solution (tennecetin [production of Qi Hong bio tech ltd] 3 ~ 5 parts of deionized water dissolvings dilute) dispersion stirring 40 ~ 60 minutes, 30 DEG C are cooled to after colloid modification, adopt pulse strong-light technology to carry out surface disinfection to colloid in discharging simultaneously, packaging can obtain easily adjusting converting, good construction, the wallpaper of high-environmental performance, wall cloth tackiness agent.
Product is beige pasty colloid, product viscosity 62000mpa.s; 180 ° of stripping strengths are 10.2N/25mm; Freeze-thaw stability > 12 freeze-thaw cycle; High-temperature stability > 150d; Product is adjusted and is converted conveniently, and good leveling property can meet all kinds of wallpaper, wall cloth is applied in different construction environments in coating.
Embodiment 4
Deionized water: 650kg, sticky rice flour: 50kg, waxy corn starch: 90kg, W-Gum: 20kg, wheat starch: 30kg, yam starch: 20kg, tapioca (flour): 50kg, borax: 0.2kg, cationic etherifying agent: 18kg, Mono Chloro Acetic Acid: 40kg, potassium hydroxide: 30kg, sodium phosphate: 25kg, propylene glycol: 2kg, glacial acetic acid: 5kg, ethanol: 10kg, M-nitro benzoic acid: 1kg, potassium sorbate: 2kg, calcium propionate: 2kg, sodium Diacetate: 1kg, tennecetin: 0.3kg, Sodium dehydroacetate: 0.4kg.
Preparation method: by deionized water, sticky rice flour (Henan Huangguo Grain Company Limited's production), waxy corn starch (production of Qinhuangdao Li Hua company), W-Gum (production of Zhucheng Xing Mao company), wheat starch (production of Anhui An Te company), yam starch (production of Great Northern Wilderness group company), tapioca (flour) (production of Guangxi Ming Yang company), propylene glycol (Dow Chemical Company's production) borax (production of Yingkou Hong Taipeng magnesium company limited), cationic etherifying agent (Dow Chemical Company's production) adds in reaction vessel, dispersed with stirring heated up 35 ~ 50 DEG C after 30 minutes, constant temperature 3 hours ~ 5 hours, add sodium phosphate (production of Shandong Zhenhua Industries, Inc), potassium hydroxide (production of Jiangsu You Lide Chemical Co., Ltd.) dispersion stirring 10 ~ 20 minutes, add and to add glacial acetic acid (production of Tonghua, Zhengzhou Industrial Co., Ltd.) dispersion after Mono Chloro Acetic Acid (production of Shijiazhuang Bi De Chemical Co., Ltd.) reacts 40 ~ 60 minutes afterwards and within 5 ~ 10 minutes, add M-nitro benzoic acid solution (M-nitro benzoic acid [productions of Zibo three good fortune chemical development company limited] 1 10 parts of edible ethanols dissolve) and disperse to add potassium sorbate in 5 ~ 10 minutes, calcium propionate (Zhong Zheng Chemical Co., Ltd. of Tengzhou of Shandong Province), sodium Diacetate (production of Nantong Ao Kai company), dehydroacetic acid (DHA) sodium solution (production of Nantong Ao Kai company), tennecetin solution (tennecetin [production of Qi Hong bio tech ltd] 3 ~ 5 parts of deionized water dissolvings dilute) dispersion stirring 40 ~ 60 minutes, 30 DEG C are cooled to after colloid modification, adopt pulse strong-light technology to carry out surface disinfection to colloid in discharging simultaneously, packaging can obtain easily adjusting converting, good construction, the wallpaper of high-environmental performance, wall cloth tackiness agent.
Product is beige pasty colloid, product viscosity 63000mpa.s; 180 ° of stripping strengths are 11.8N/25mm; Freeze-thaw stability > 10 freeze-thaw cycle; High-temperature stability > 130d; Product is adjusted and is converted conveniently, and good leveling property can meet all kinds of wallpaper, wall cloth is applied in different construction environments in coating.
Embodiment 5
Deionized water: 650kg, sticky rice flour: 50kg, waxy corn starch: 90kg, W-Gum: 20kg, wheat starch: 30kg, yam starch: 35kg, tapioca (flour): 35kg, borax: 0.2kg, cationic etherifying agent: 18kg, Mono Chloro Acetic Acid: 40kg, sodium hydroxide: 30kg, potassium hydroxide: 20kg, propylene glycol: 1kg, polyoxyethylene glycol: 1kg, glacial acetic acid: 5kg, ethanol: 10kg, M-nitro benzoic acid: 1kg, potassium sorbate: 2kg, calcium propionate: 1.5kg, sodium Diacetate: 1.5kg, tennecetin: 0.5kg, Sodium dehydroacetate: 0.3kg.
Preparation method: by deionized water, sticky rice flour (Henan Huangguo Grain Company Limited's production), waxy corn starch (production of Qinhuangdao Li Hua company), W-Gum (production of Zhucheng Xing Mao company), wheat starch (production of Anhui An Te company), yam starch (production of Great Northern Wilderness group company), tapioca (flour) (production of Guangxi Ming Yang company), propylene glycol (Dow Chemical Company's production) borax (production of Yingkou Hong Taipeng magnesium company limited), cationic etherifying agent (Dow Chemical Company's production) adds in reaction vessel, dispersed with stirring heated up 35 ~ 50 DEG C after 30 minutes, constant temperature 3 hours ~ 5 hours, add sodium hydroxide (production of Shanghai Li Shan Chemical Co., Ltd.)), potassium hydroxide (production of Jiangsu You Lide Chemical Co., Ltd.) dispersion stirring 10 ~ 20 minutes, add and to add glacial acetic acid (production of Tonghua, Zhengzhou Industrial Co., Ltd.) dispersion after Mono Chloro Acetic Acid (production of Shijiazhuang Bi De Chemical Co., Ltd.) reacts 40 ~ 60 minutes afterwards and within 5 ~ 10 minutes, add M-nitro benzoic acid solution (M-nitro benzoic acid [productions of Zibo three good fortune chemical development company limited] 1 10 parts of edible ethanols dissolve) and disperse to add potassium sorbate in 5 ~ 10 minutes, calcium propionate (Zhong Zheng Chemical Co., Ltd. of Tengzhou of Shandong Province), sodium Diacetate (production of Nantong Ao Kai company), dehydroacetic acid (DHA) sodium solution (production of Nantong Ao Kai company), tennecetin solution (tennecetin [production of Qi Hong bio tech ltd] 3 ~ 5 parts of deionized water dissolvings dilute) dispersion stirring 40 ~ 60 minutes, 30 DEG C are cooled to after colloid modification, adopt pulse strong-light technology to carry out surface disinfection to colloid in discharging simultaneously, packaging can obtain easily adjusting converting, good construction, the wallpaper of high-environmental performance, wall cloth tackiness agent.
Product is beige pasty colloid, product viscosity 68000mpa.s; 180 ° of stripping strengths are 12.5N/25mm; Freeze-thaw stability > 12 freeze-thaw cycle; High-temperature stability > 150d; Product is adjusted and is converted conveniently, and good leveling property can meet all kinds of wallpaper, wall cloth is applied in different construction environments in coating.
In order to compare judgement between existing like product, get glutinous rice glue that the present invention obtains and performance test is carried out in commercially available prod, concrete outcome is in table 1 and table 2.
Table 1 wallpaper glue stick product performance contrast table
Table 2 the present invention and conventional glutinous rice glue product contrast
From table 1 and table 2, the glutinous rice glue product that the present invention produces has applied widely, and construction is easily adjusted and converted, and product stability is good, and period of storage is long, can extend the wallpaper glue stick of shelf-life; Products material derives from the commodity crop of plantation capable of circulation, belongs to renewable resources, is the good product of Sustainable Production, meets the energy saving policy of country and the strategic type product of Sustainable development; Products production of the present invention, temperature of reaction is lower, production energy consumption is less, can effectively reduce production energy usage, and improve the plant factor of enterprises production, effectively can reduce customer using cost, be the good product that can promote the wallpaper adhesive industry of wallpaper industry healthy development, wide market.
Above-described embodiment is one of the present invention preferably scheme, not does any pro forma restriction to the present invention, also has other variant and remodeling under the prerequisite not exceeding the technical scheme described in claim.
Claims (9)
1. easily adjust and convert a wallpaper stickup glutinous rice glue of constructing, it is characterized in that this glutinous rice glue is mainly made up of the raw material of following weight part:
Deionized water: 600 ~ 700,
Sticky rice flour: 20 ~ 60,
Waxy corn starch: 60 ~ 100,
W-Gum: 20 ~ 30,
Wheat starch: 30 ~ 60,
Yam starch: 20 ~ 40,
Tapioca (flour): 20 ~ 40,
Linking agent: 0.1 ~ 0.5,
Cationic etherifying agent: 10 ~ 18,
Negatively charged ion etherifying agent: 30 ~ 40,
Catalyzer: 30 ~ 50,
Wetting agent: 2 ~ 5,
Sterilant: 10 ~ 15,
Mould inhibitor: 5 ~ 8.
2. the wallpaper stickup glutinous rice glue of constructing converted in easy tune according to claim 1, it is characterized in that: linking agent is borax or non-iron aluminium sulfate.
3. the wallpaper stickup glutinous rice glue of constructing converted in easy tune according to claim 1, and it is characterized in that: cationic etherifying agent is 3-chloro-2-hydroxypropyl-trimethyl ammonium chloride, negatively charged ion etherifying agent is Mono Chloro Acetic Acid or sodium chloroacetate.
4. the wallpaper stickup glutinous rice glue of constructing converted in easy tune according to claim 1, it is characterized in that: catalyzer is any one or two or more combinations in sodium hydroxide, potassium hydroxide, sodium phosphate or sodium carbonate.
5. the wallpaper stickup glutinous rice glue of constructing converted in easy tune according to claim 1, it is characterized in that: wetting agent is any one or combination of Macrogol 200, poly(oxyethylene glycol) 400, propylene glycol, mould inhibitor is any one or two or more combinations in Sodium dehydroacetate, sodium Diacetate, calcium propionate, tennecetin.
6. the wallpaper stickup glutinous rice glue of constructing converted in easy tune according to claim 1, it is characterized in that: sterilant is the combination of in glacial acetic acid, ethanol, M-nitro benzoic acid, potassium sorbate more than at least three kinds.
7. the wallpaper stickup glutinous rice glue of constructing converted in easy tune according to claim 6, it is characterized in that: sterilant is glacial acetic acid: ethanol: M-nitro benzoic acid: the compound that potassium sorbate mixes with the weight proportion of 5:10:1-2:0-2.
8. the preparation method of the wallpaper stickup glutinous rice glue of constructing converted in an easy tune according to claim 1, it is characterized in that the method mainly: according to proportioning by after sticky rice flour, waxy corn starch, W-Gum, wheat starch, yam starch, tapioca (flour) premix, add wetting agent, linking agent and cationic etherifying agent and carry out crosslinked and the process of positively charged ion etherificate, add catalyzer more afterwards and negatively charged ion etherifying agent carries out carboxymethylation process, obtain composite modified starch breast, 40 ~ 120min is reacted, germicidal treatment discharging packing again after adding sterilant, mould inhibitor again.
9. the preparation method of the wallpaper stickup glutinous rice glue of constructing converted in easy tune according to claim 8, it is characterized in that the method mainly: according to proportioning by sticky rice flour, waxy corn starch, W-Gum, wheat starch, yam starch, after tapioca (flour) premix, add wetting agent, linking agent and cationic etherifying agent carry out crosslinked and the process of positively charged ion etherificate, dispersed with stirring heated up 35 ~ 50 DEG C after 30 minutes, constant temperature 3 hours ~ 5 hours, add catalyzer dispersion stirring 10 ~ 20 minutes afterwards, add negatively charged ion etherifying agent again and carry out carboxymethylation process, react and obtain composite modified starch breast after 40 ~ 60 minutes, add sterilant again, 40 ~ 120min is reacted after mould inhibitor, germicidal treatment discharging packing again.
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| CN106281109A (en) * | 2016-08-26 | 2017-01-04 | 桐乡嘉力丰实业股份有限公司 | A kind of high stability mildew-resistant environmental protection Oryza glutinosa glue and preparation technology thereof |
| CN106349971A (en) * | 2016-08-26 | 2017-01-25 | 桐乡嘉力丰实业股份有限公司 | Natural environment-friendly mildew-proof and damp-proof glutinous rice glue and preparation process thereof |
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| CN108300378A (en) * | 2016-01-28 | 2018-07-20 | 嘉力丰科技股份有限公司 | The compound composition of glutinous rice glue and the preparation method of glutinous rice glue |
| CN108342182A (en) * | 2018-02-08 | 2018-07-31 | 杭州欢伯生物技术有限公司 | A kind of glutinous rice glue and preparation method thereof with healthcare function |
| CN109181635A (en) * | 2018-07-26 | 2019-01-11 | 合肥广民建材有限公司 | A kind of dedicated antibacterial glutinous rice glue of wallpaper and preparation method thereof |
| IT201700102009A1 (en) * | 2017-09-12 | 2019-03-12 | Promoitalia Group Spa | REGENERATING AND SMOOTHING COMPOSITION FOR THE TREATMENT OF SKIN INESTETISIS AND ITS PREPARATION PROCEDURE |
| CN109958002A (en) * | 2019-04-22 | 2019-07-02 | 四川轻化工大学 | Mildew inhibitor for white spirit packaging paper box and preparation method thereof |
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| CN106398584A (en) * | 2016-08-31 | 2017-02-15 | 桐乡嘉力丰实业股份有限公司 | Rose aroma type glutinous-rice wet adhesive and preparation method thereof |
| CN106700966A (en) * | 2016-12-14 | 2017-05-24 | 龚亚龙 | Adhesive and preparation method thereof |
| CN107384245A (en) * | 2017-08-28 | 2017-11-24 | 上海前引科技有限公司 | A kind of antibacterial and mouldproof anion glutinous rice adhesive |
| WO2019053606A1 (en) * | 2017-09-12 | 2019-03-21 | Promoitalia Group S.P.A. | Regenerating composition with smoothing action for treating skin imperfections and process for preparation thereof |
| IT201700102009A1 (en) * | 2017-09-12 | 2019-03-12 | Promoitalia Group Spa | REGENERATING AND SMOOTHING COMPOSITION FOR THE TREATMENT OF SKIN INESTETISIS AND ITS PREPARATION PROCEDURE |
| CN107964391A (en) * | 2017-12-07 | 2018-04-27 | 山东梦想与家智能科技有限公司 | A kind of bamboo charcoal odor-elimination wallpaper glue and preparation method thereof |
| CN108047990A (en) * | 2018-01-24 | 2018-05-18 | 合肥市大卓电力有限责任公司 | A kind of novel antibacterial glutinous rice glue and preparation method thereof |
| CN108342182A (en) * | 2018-02-08 | 2018-07-31 | 杭州欢伯生物技术有限公司 | A kind of glutinous rice glue and preparation method thereof with healthcare function |
| CN109181635A (en) * | 2018-07-26 | 2019-01-11 | 合肥广民建材有限公司 | A kind of dedicated antibacterial glutinous rice glue of wallpaper and preparation method thereof |
| CN109958002A (en) * | 2019-04-22 | 2019-07-02 | 四川轻化工大学 | Mildew inhibitor for white spirit packaging paper box and preparation method thereof |
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