CN108047990A - A kind of novel antibacterial glutinous rice glue and preparation method thereof - Google Patents
A kind of novel antibacterial glutinous rice glue and preparation method thereof Download PDFInfo
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- CN108047990A CN108047990A CN201810066221.7A CN201810066221A CN108047990A CN 108047990 A CN108047990 A CN 108047990A CN 201810066221 A CN201810066221 A CN 201810066221A CN 108047990 A CN108047990 A CN 108047990A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/02—Starch; Degradation products thereof, e.g. dextrin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K2003/387—Borates
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Abstract
The invention discloses a kind of novel antibacterial glutinous rice glue, include the raw material of following parts by weight：30~50 parts of glutinous rice flour, 15~27 parts of potato starch, 12~25 parts of wheaten starch, 3~5 parts of lignin, 1~4 part of citric acid, 1~2 part of catalyst, 6~12 parts of modified organo montmorillonite, 2~3 parts of photocatalyst, 4~8 parts of calcium propionate, 5~10 parts of Traditional Chinese drug mixture, 2~5 parts of alum, 1~2 part of antifoaming agent, 2~3 parts of anion natural mineral powder, 150~200 parts of deionized water.The present invention uses glutinous rice flour, potato starch and wheaten starch, and for raw material, raw material sources are extensive, at low cost, and the glutinous rice glue prepared is safe and non-toxic, has no irritating odor, and will not generate and go mouldy, and favorable moth-proof is capable of purifying air.
Description
Technical field
The invention belongs to environment-friendly materials technical fields, and in particular to a kind of novel antibacterial glutinous rice glue and preparation method thereof.
Background technology
Wallpaper is as a kind of house decorative material, because it is with color is various, safety and environmental protection, easy for construction, Ke Yishi
It the features such as different occasions, is accepted extensively by masses.The wallpaper material of safety and environmental protection be subject to everybody approve, but for
Wallpaper, the security of auxiliary material are also the problem of can not be ignored.
At present, on the market, the glue pasted for wallpaper substantially has rubber powder, rubber cement, wet glue etc., and the raw material of general rubber cement is
Formaldehyde is a kind of chemical reagent being harmful to human body, and rubber powder can coordinate rubber cement to use or be used alone, but it is environmentally friendly
Performance is relatively poor.At present, at home, the glutinous rice glue in wet glue is the first choice of house decoration, is the high property that a kind of wallpaper is pasted
It can glue.
Glutinous rice glue is most risen early in Japan, and incoming various countries, therefore is also known as " Japanese glue ", it can firmly cling wall
Surface wallpaper, also, house is allowed to become comfortable, durable and environmentally friendly.Because glutinous rice glue uses the material of natural plants, it is susceptible to and goes mouldy
Or the problems such as damaging by worms, also become the hot spot of research.
The content of the invention
The present invention provides a kind of novel antibacterial glutinous rice glues and preparation method thereof, solve asking in above-mentioned background technology
Topic, the present invention uses glutinous rice flour, potato starch and wheaten starch, and for raw material, raw material sources are extensive, at low cost, and for preparing is glutinous
Rice glue is safe and non-toxic, has no irritating odor, and will not generate and go mouldy, and favorable moth-proof is capable of purifying air.
It is existing in the prior art in order to solve the problems, such as, it adopts the following technical scheme that：
A kind of novel antibacterial glutinous rice glue includes the raw material of following parts by weight：30~50 parts of glutinous rice flour, potato starch 15~27
Part, 12~25 parts of wheaten starch, 3~5 parts of lignin, 1~4 part of citric acid, 1~2 part of catalyst, modified organo montmorillonite 6~
12 parts, 2~3 parts of photocatalyst, 4~8 parts of calcium propionate, 5~10 parts of Traditional Chinese drug mixture, 2~5 parts of alum, 1~2 part of antifoaming agent, bear from
Sub- 2~3 parts of natural mineral powder, 150~200 parts of deionized water.
Preferably, the novel antibacterial glutinous rice glue includes the raw material of following parts by weight：35~45 parts of glutinous rice flour, potato
18~23 parts of starch, 15~22 parts of wheaten starch, 3.4~4.6 parts of lignin, 2~3 parts of citric acid, 1.3~1.8 parts of catalyst,
7~11 parts of modified organo montmorillonite, 2.1~2.9 parts of photocatalyst, 5~7 parts of calcium propionate, 6~9 parts of Traditional Chinese drug mixture, alum 3~4
Part, 1.3~1.8 parts of antifoaming agent, 2.2~2.9 parts of anion natural mineral powder, 173~186 parts of deionized water.
Preferably, the novel antibacterial glutinous rice glue includes the raw material of following parts by weight：40 parts of glutinous rice flour, potato starch
20 parts, 21 parts of wheaten starch, 4 parts of lignin, 2.5 parts of citric acid, 1.6 parts of catalyst, 8 parts of modified organo montmorillonite, photocatalyst
2.7 parts, 6 parts of calcium propionate, 8 parts of Traditional Chinese drug mixture, 3.3 parts of alum, 1.5 parts of antifoaming agent, 2.4 parts of anion natural mineral powder,
180 parts of deionized water.
Preferably, the modified organo montmorillonite is made using following methods：
First by montmorillonite, ammonium lauryl sulfate and deionized water in mass ratio 1:0.2:12 mixing are placed in reaction kettle, then are added
Heat when insulated and stirred reaction 2~3 is small, is subsequently cooled to room temperature, filters to 70~80 DEG C, and filter cake drying, grinding cross 40~80
Mesh sieve obtains organic modification montmonrillonite.
Preferably, the Traditional Chinese drug mixture for purslane, thyme, spina date seed, Chinese gall, Chinese cassia tree, the mixture of ginger,
Wherein purslane, thyme, spina date seed, Chinese gall, Chinese cassia tree, the mass ratio of ginger are 2:1:3:1:1:2.
Preferably, the anion natural mineral powder includes the raw material of following part meter：10 parts of tourmaline, lanthanide rare are multiple
Close 5 parts of 9 parts of salt and titanium dioxide.
A kind of method for preparing the novel antibacterial glutinous rice glue, includes the following steps：
（1）By above-mentioned formula weigh glutinous rice flour, potato starch, wheaten starch, lignin, citric acid, catalyst, modification it is organic
Montmorillonite, photocatalyst, calcium propionate, Traditional Chinese drug mixture, alum, antifoaming agent, anion natural mineral powder, it is spare；
（2）Traditional Chinese drug mixture is cleaned up, is crushed, crosses 100~200 mesh sieves, it is small to be subsequently placed in immersion 3~5 in deionized water
When, then high heat decoction extremely boiling, it is then cooked by slow fire 30~60 minutes；
（3）First glutinous rice flour, potato starch and wheaten starch are uniformly mixed, then are placed in step（2）It is soaked in the mixed liquor of gained
When bubble 10~20 is small, then addition alum, catalyst are uniformly mixed, and are placed in 90~100 DEG C of high temperature and are gelatinized 10~20 minutes,
Product must be gelatinized；
（4）By step（3）The mixture of gained is cooled to 70~80 DEG C, adds in lignin, citric acid and acrylic acid, insulated and stirred
When reaction 1~2 is small, modified organo montmorillonite, photocatalyst, antifoaming agent, anion natural mineral powder are then sequentially added, is stirred
It is uniformly mixed to get the novel antibacterial glutinous rice glue.
It is preferably, described that be uniformly mixed process as follows：First using 50~100r/min of the slow-speed of revolution premixing 10~
After 15min, then 30~45min is mixed in high 200~300r/min of rotating speed.
Compared with prior art, the present invention it has the advantages that：
Novel antibacterial glutinous rice glue of the present invention uses glutinous rice flour, potato starch and wheaten starch as raw material, raw material sources
Extensively, at low cost, the glutinous rice glue prepared is safe and non-toxic, has no irritating odor, and will not generate and go mouldy, and favorable moth-proof can be net
It is specific as follows to change air：
（1）Novel antibacterial glutinous rice glue of the present invention uses glutinous rice flour, potato starch and wheaten starch as raw material, glutinous rice
Powder, potato starch and wheaten starch are natural plants, safety and environmental protection, it is nontoxic, have no irritating odor, and derive from a wealth of sources,
It is at low cost；
（2）Photocatalyst is with the addition of in novel antibacterial glutinous rice glue raw material of the present invention, photocatalyst can produce oxidability pole
Strong free hydroxy and active oxygen has the function of very strong photoredox, oxidable to decompose various organic compounds and portion
Point inorganic matter can destroy the cell membrane of bacterium and cure the protein of virus, can kill bacterium and decomposing organic pollutant, having
Organic pollutants resolve into free of contamination water and carbon dioxide, and therefore, photocatalyst can effectively degrade toxic and harmful gas in air,
Various bacteria can be effectively killed, antibiotic rate is up to 99.99%, and bacterium or fungi can be released to toxin decomposition and innoxious place
Reason, while it is also equipped with the functions such as deodorization, anti-pollution；
（3）Novel antibacterial glutinous rice glue of the present invention is with the addition of Traditional Chinese drug mixture, has the function of anti-mildew, and can rise
To the effect of tranquilizing the mind, beneficial to people's health.
Specific embodiment
With reference to specific embodiment, the present invention is further explained.These embodiments are merely to illustrate the present invention and do not have to
In limiting the scope of the invention.
Embodiment 1
The present embodiment is related to a kind of novel antibacterial glutinous rice glue, includes the raw material of following parts by weight：30 parts of glutinous rice flour, potato starch
15 parts, 12 parts of wheaten starch, 3 parts of lignin, 1 part of citric acid, 1 part of catalyst, 6 parts of modified organo montmorillonite, 2 parts of photocatalyst,
4 parts of calcium propionate, 5 parts of Traditional Chinese drug mixture, 2 parts of alum, 1 part of antifoaming agent, 2 parts of anion natural mineral powder, deionized water 150
Part.
Wherein, the modified organo montmorillonite is made using following methods：
First by montmorillonite, ammonium lauryl sulfate and deionized water in mass ratio 1:0.2:12 mixing are placed in reaction kettle, then are added
Heat when insulated and stirred reaction 2 is small, is subsequently cooled to room temperature, filters to 70 DEG C, and filter cake drying, grinding, crossing 40~80 mesh sieves must have
Machine modified montmorillonoid.
Wherein, the Traditional Chinese drug mixture for purslane, thyme, spina date seed, Chinese gall, Chinese cassia tree, the mixture of ginger,
Middle purslane, thyme, spina date seed, Chinese gall, Chinese cassia tree, the mass ratio of ginger are 2:1:3:1:1:2.
Wherein, the anion natural mineral powder includes the raw material of following part meter：10 parts of tourmaline, lanthanide rare are compound
5 parts of 9 parts of salt and titanium dioxide.
A kind of method for preparing the novel antibacterial glutinous rice glue, includes the following steps：
（1）By above-mentioned formula weigh glutinous rice flour, potato starch, wheaten starch, lignin, citric acid, catalyst, modification it is organic
Montmorillonite, photocatalyst, calcium propionate, Traditional Chinese drug mixture, alum, antifoaming agent, anion natural mineral powder, it is spare；
（2）Traditional Chinese drug mixture is cleaned up, crush, cross 100~200 mesh sieves, be subsequently placed in deionized water impregnate 3 it is small when,
Again then high heat decoction is cooked by slow fire 30 minutes to seething with excitement；
（3）First glutinous rice flour, potato starch and wheaten starch are uniformly mixed, then are placed in step（2）It is soaked in the mixed liquor of gained
Steep 10 it is small when, then add in alum, catalyst and be uniformly mixed, be placed in 90 DEG C of high temperature and be gelatinized 10 minutes, obtain gelatinization product；
（4）By step（3）The mixture of gained is cooled to 70 DEG C, adds in lignin, citric acid and acrylic acid, insulated and stirred reaction
1 it is small when, then sequentially add modified organo montmorillonite, photocatalyst, antifoaming agent, anion natural mineral powder, be stirred
It is even to get the novel antibacterial glutinous rice glue.
It is wherein, described that be uniformly mixed process as follows：After being first pre-mixed 10min using slow-speed of revolution 50r/min, Ran Hou
High rotating speed 200r/min mixing 30min.
Embodiment 2
The present embodiment is related to a kind of novel antibacterial glutinous rice glue, includes the raw material of following parts by weight：50 parts of glutinous rice flour, potato starch
27 parts, 25 parts of wheaten starch, 5 parts of lignin, 4 parts of citric acid, 2 parts of catalyst, 12 parts of modified organo montmorillonite, 3 parts of photocatalyst,
8 parts of calcium propionate, 10 parts of Traditional Chinese drug mixture, 5 parts of alum, 2 parts of antifoaming agent, 3 parts of anion natural mineral powder, deionized water 200
Part.
Wherein, the modified organo montmorillonite is made using following methods：
First by montmorillonite, ammonium lauryl sulfate and deionized water in mass ratio 1:0.2:12 mixing are placed in reaction kettle, then are added
Heat when insulated and stirred reaction 3 is small, is subsequently cooled to room temperature, filters to 80 DEG C, and filter cake drying, grinding, crossing 40~80 mesh sieves must have
Machine modified montmorillonoid.
Wherein, the Traditional Chinese drug mixture for purslane, thyme, spina date seed, Chinese gall, Chinese cassia tree, the mixture of ginger,
Middle purslane, thyme, spina date seed, Chinese gall, Chinese cassia tree, the mass ratio of ginger are 2:1:3:1:1:2.
Wherein, the anion natural mineral powder includes the raw material of following part meter：10 parts of tourmaline, lanthanide rare are compound
5 parts of 9 parts of salt and titanium dioxide.
A kind of method for preparing the novel antibacterial glutinous rice glue, includes the following steps：
（1）By above-mentioned formula weigh glutinous rice flour, potato starch, wheaten starch, lignin, citric acid, catalyst, modification it is organic
Montmorillonite, photocatalyst, calcium propionate, Traditional Chinese drug mixture, alum, antifoaming agent, anion natural mineral powder, it is spare；
（2）Traditional Chinese drug mixture is cleaned up, crush, cross 100~200 mesh sieves, be subsequently placed in deionized water impregnate 5 it is small when,
Again then high heat decoction is cooked by slow fire 60 minutes to seething with excitement；
（3）First glutinous rice flour, potato starch and wheaten starch are uniformly mixed, then are placed in step（2）It is soaked in the mixed liquor of gained
Steep 20 it is small when, then add in alum, catalyst and be uniformly mixed, be placed in 100 DEG C of high temperature and be gelatinized 20 minutes, obtain gelatinization product；
（4）By step（3）The mixture of gained is cooled to 80 DEG C, adds in lignin, citric acid and acrylic acid, insulated and stirred reaction
2 it is small when, then sequentially add modified organo montmorillonite, photocatalyst, antifoaming agent, anion natural mineral powder, be stirred
It is even to get the novel antibacterial glutinous rice glue.
It is wherein, described that be uniformly mixed process as follows：After being first pre-mixed 15min using slow-speed of revolution 100r/min, then
In high rotating speed 300r/min mixing 45min.
Embodiment 3
The present embodiment is related to a kind of novel antibacterial glutinous rice glue, includes the raw material of following parts by weight：35 parts of glutinous rice flour, potato starch
18 parts, 15 parts of wheaten starch, 3.4 parts of lignin, 2 parts of citric acid, 1.3 parts of catalyst, 7 parts of modified organo montmorillonite, photocatalyst
2.1 parts, 5 parts of calcium propionate, 6 parts of Traditional Chinese drug mixture, 3 parts of alum, 1.3 parts of antifoaming agent, 2.2 parts of anion natural mineral powder, go
173 parts of ionized water.
Wherein, the modified organo montmorillonite is made using following methods：
First by montmorillonite, ammonium lauryl sulfate and deionized water in mass ratio 1:0.2:12 mixing are placed in reaction kettle, then are added
Heat when insulated and stirred reaction 2.3 is small, is subsequently cooled to room temperature, filters to 72 DEG C, and filter cake drying, grinding are crossed 40~80 mesh sieves and obtained
Organic modification montmonrillonite.
Wherein, the Traditional Chinese drug mixture for purslane, thyme, spina date seed, Chinese gall, Chinese cassia tree, the mixture of ginger,
Middle purslane, thyme, spina date seed, Chinese gall, Chinese cassia tree, the mass ratio of ginger are 2:1:3:1:1:2.
Wherein, the anion natural mineral powder includes the raw material of following part meter：10 parts of tourmaline, lanthanide rare are compound
5 parts of 9 parts of salt and titanium dioxide.
A kind of method for preparing the novel antibacterial glutinous rice glue, includes the following steps：
（1）By above-mentioned formula weigh glutinous rice flour, potato starch, wheaten starch, lignin, citric acid, catalyst, modification it is organic
Montmorillonite, photocatalyst, calcium propionate, Traditional Chinese drug mixture, alum, antifoaming agent, anion natural mineral powder, it is spare；
（2）Traditional Chinese drug mixture is cleaned up, is crushed, crosses 100~200 mesh sieves, it is small to be subsequently placed in immersion 3.5 in deionized water
When, then high heat decoction extremely boiling, it is then cooked by slow fire 35 minutes；
（3）First glutinous rice flour, potato starch and wheaten starch are uniformly mixed, then are placed in step（2）It is soaked in the mixed liquor of gained
Steep 12 it is small when, then add in alum, catalyst and be uniformly mixed, be placed in 93 DEG C of high temperature and be gelatinized 11 minutes, obtain gelatinization product；
（4）By step（3）The mixture of gained is cooled to 73 DEG C, adds in lignin, citric acid and acrylic acid, insulated and stirred reaction
1.2 it is small when, then sequentially add modified organo montmorillonite, photocatalyst, antifoaming agent, anion natural mineral powder, be stirred
Uniformly to get the novel antibacterial glutinous rice glue.
It is wherein, described that be uniformly mixed process as follows：After being first pre-mixed 12min using slow-speed of revolution 70r/min, Ran Hou
High rotating speed 210r/min mixing 35min.
Embodiment 4
The present embodiment is related to a kind of novel antibacterial glutinous rice glue, includes the raw material of following parts by weight：45 parts of glutinous rice flour, potato starch
23 parts, 22 parts of wheaten starch, 4.6 parts of lignin, 3 parts of citric acid, 1.8 parts of catalyst, 11 parts of modified organo montmorillonite, photocatalyst
2.9 parts, 7 parts of calcium propionate, 9 parts of Traditional Chinese drug mixture, 4 parts of alum, 1.8 parts of antifoaming agent, 2.9 parts of anion natural mineral powder, go
186 parts of ionized water.
Wherein, the modified organo montmorillonite is made using following methods：
First by montmorillonite, ammonium lauryl sulfate and deionized water in mass ratio 1:0.2:12 mixing are placed in reaction kettle, then are added
Heat when insulated and stirred reaction 2.5 is small, is subsequently cooled to room temperature, filters to 75 DEG C, and filter cake drying, grinding are crossed 40~80 mesh sieves and obtained
Organic modification montmonrillonite.
Wherein, the Traditional Chinese drug mixture for purslane, thyme, spina date seed, Chinese gall, Chinese cassia tree, the mixture of ginger,
Middle purslane, thyme, spina date seed, Chinese gall, Chinese cassia tree, the mass ratio of ginger are 2:1:3:1:1:2.
Wherein, the anion natural mineral powder includes the raw material of following part meter：10 parts of tourmaline, lanthanide rare are compound
5 parts of 9 parts of salt and titanium dioxide.
A kind of method for preparing the novel antibacterial glutinous rice glue, includes the following steps：
（1）By above-mentioned formula weigh glutinous rice flour, potato starch, wheaten starch, lignin, citric acid, catalyst, modification it is organic
Montmorillonite, photocatalyst, calcium propionate, Traditional Chinese drug mixture, alum, antifoaming agent, anion natural mineral powder, it is spare；
（2）Traditional Chinese drug mixture is cleaned up, crush, cross 100~200 mesh sieves, be subsequently placed in deionized water impregnate 4 it is small when,
Again then high heat decoction is cooked by slow fire 45 minutes to seething with excitement；
（3）First glutinous rice flour, potato starch and wheaten starch are uniformly mixed, then are placed in step（2）It is soaked in the mixed liquor of gained
Steep 15 it is small when, then add in alum, catalyst and be uniformly mixed, be placed in 95 DEG C of high temperature and be gelatinized 15 minutes, obtain gelatinization product；
（4）By step（3）The mixture of gained is cooled to 75 DEG C, adds in lignin, citric acid and acrylic acid, insulated and stirred reaction
1.5 it is small when, then sequentially add modified organo montmorillonite, photocatalyst, antifoaming agent, anion natural mineral powder, be stirred
Uniformly to get the novel antibacterial glutinous rice glue.
It is wherein, described that be uniformly mixed process as follows：After being first pre-mixed 13min using slow-speed of revolution 75r/min, Ran Hou
High rotating speed 250r/min mixing 38min.
Embodiment 5
The present embodiment is related to a kind of novel antibacterial glutinous rice glue, includes the raw material of following parts by weight：40 parts of glutinous rice flour, potato starch
20 parts, 21 parts of wheaten starch, 4 parts of lignin, 2.5 parts of citric acid, 1.6 parts of catalyst, 8 parts of modified organo montmorillonite, photocatalyst
2.7 parts, 6 parts of calcium propionate, 8 parts of Traditional Chinese drug mixture, 3.3 parts of alum, 1.5 parts of antifoaming agent, 2.4 parts of anion natural mineral powder,
180 parts of deionized water.
Wherein, the modified organo montmorillonite is made using following methods：
First by montmorillonite, ammonium lauryl sulfate and deionized water in mass ratio 1:0.2:12 mixing are placed in reaction kettle, then are added
Heat when insulated and stirred reaction 2.7 is small, is subsequently cooled to room temperature, filters to 78 DEG C, and filter cake drying, grinding are crossed 40~80 mesh sieves and obtained
Organic modification montmonrillonite.
Wherein, the Traditional Chinese drug mixture for purslane, thyme, spina date seed, Chinese gall, Chinese cassia tree, the mixture of ginger,
Middle purslane, thyme, spina date seed, Chinese gall, Chinese cassia tree, the mass ratio of ginger are 2:1:3:1:1:2.
Wherein, the anion natural mineral powder includes the raw material of following part meter：10 parts of tourmaline, lanthanide rare are compound
5 parts of 9 parts of salt and titanium dioxide.
A kind of method for preparing the novel antibacterial glutinous rice glue, includes the following steps：
（1）By above-mentioned formula weigh glutinous rice flour, potato starch, wheaten starch, lignin, citric acid, catalyst, modification it is organic
Montmorillonite, photocatalyst, calcium propionate, Traditional Chinese drug mixture, alum, antifoaming agent, anion natural mineral powder, it is spare；
（2）Traditional Chinese drug mixture is cleaned up, is crushed, crosses 100~200 mesh sieves, it is small to be subsequently placed in immersion 4.5 in deionized water
When, then high heat decoction extremely boiling, it is then cooked by slow fire 50 minutes；
（3）First glutinous rice flour, potato starch and wheaten starch are uniformly mixed, then are placed in step（2）It is soaked in the mixed liquor of gained
Steep 19 it is small when, then add in alum, catalyst and be uniformly mixed, be placed in 98 DEG C of high temperature and be gelatinized 17 minutes, obtain gelatinization product；
（4）By step（3）The mixture of gained is cooled to 78 DEG C, adds in lignin, citric acid and acrylic acid, insulated and stirred reaction
1.7 it is small when, then sequentially add modified organo montmorillonite, photocatalyst, antifoaming agent, anion natural mineral powder, be stirred
Uniformly to get the novel antibacterial glutinous rice glue.
It is wherein, described that be uniformly mixed process as follows：After being first pre-mixed 14min using slow-speed of revolution 90/min, Ran Hou
High rotating speed 280r/min mixing 40min.
Specific embodiments of the present invention are described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (8)
1. a kind of novel antibacterial glutinous rice glue, which is characterized in that include the raw material of following parts by weight：30~50 parts of glutinous rice flour, Ma Ling
15~27 parts of sweet potato starch, 12~25 parts of wheaten starch, 3~5 parts of lignin, 1~4 part of citric acid, 1~2 part of catalyst, modification have
6~12 parts of machine montmorillonite, 2~3 parts of photocatalyst, 4~8 parts of calcium propionate, 5~10 parts of Traditional Chinese drug mixture, 2~5 parts of alum, antifoaming agent
1~2 part, 2~3 parts of anion natural mineral powder, 150~200 parts of deionized water.
2. novel antibacterial glutinous rice glue according to claim 1, which is characterized in that include the raw material of following parts by weight：Glutinous rice
35~45 parts of powder, 18~23 parts of potato starch, 15~22 parts of wheaten starch, 3.4~4.6 parts of lignin, 2~3 parts of citric acid,
1.3~1.8 parts of catalyst, 7~11 parts of modified organo montmorillonite, 2.1~2.9 parts of photocatalyst, 5~7 parts of calcium propionate, Chinese medicine mixing
6~9 parts of object, 3~4 parts of alum, 1.3~1.8 parts of antifoaming agent, 2.2~2.9 parts of anion natural mineral powder, deionized water 173
~186 parts.
3. novel antibacterial glutinous rice glue according to claim 1, which is characterized in that include the raw material of following parts by weight：Glutinous rice
40 parts of powder, 20 parts of potato starch, 21 parts of wheaten starch, 4 parts of lignin, 2.5 parts of citric acid, 1.6 parts of catalyst, modification are organic
8 parts of montmorillonite, 2.7 parts of photocatalyst, 6 parts of calcium propionate, 8 parts of Traditional Chinese drug mixture, 3.3 parts of alum, 1.5 parts of antifoaming agent, anion day
Right 2.4 parts of minerals powder, 180 parts of deionized water.
4. novel antibacterial glutinous rice glue according to claim 1, which is characterized in that the modified organo montmorillonite is using following
Method is made：
First by montmorillonite, ammonium lauryl sulfate and deionized water in mass ratio 1:0.2:12 mixing are placed in reaction kettle, then are added
Heat when insulated and stirred reaction 2~3 is small, is subsequently cooled to room temperature, filters to 70~80 DEG C, and filter cake drying, grinding cross 40~80
Mesh sieve obtains organic modification montmonrillonite.
5. novel antibacterial glutinous rice glue according to claim 1, which is characterized in that the Traditional Chinese drug mixture is purslane, hundred
In perfume, spina date seed, Chinese gall, Chinese cassia tree, the mixture of ginger, wherein purslane, thyme, spina date seed, Chinese gall, Chinese cassia tree, life
The mass ratio of ginger is 2:1:3:1:1:2.
6. novel antibacterial glutinous rice glue according to claim 1, which is characterized in that the anion natural mineral powder includes
The raw material of following part meter：5 parts of 10 parts of tourmaline, 9 parts of lanthanide rare composite salt and titanium dioxide.
A kind of 7. method for preparing any one of the claim 1~6 novel antibacterial glutinous rice glue, which is characterized in that including as follows
Step：
（1）By above-mentioned formula weigh glutinous rice flour, potato starch, wheaten starch, lignin, citric acid, catalyst, modification it is organic
Montmorillonite, photocatalyst, calcium propionate, Traditional Chinese drug mixture, alum, antifoaming agent, anion natural mineral powder, it is spare；
（2）Traditional Chinese drug mixture is cleaned up, is crushed, crosses 100~200 mesh sieves, it is small to be subsequently placed in immersion 3~5 in deionized water
When, then high heat decoction extremely boiling, it is then cooked by slow fire 30~60 minutes；
（3）First glutinous rice flour, potato starch and wheaten starch are uniformly mixed, then are placed in step（2）It is soaked in the mixed liquor of gained
When bubble 10~20 is small, then addition alum, catalyst are uniformly mixed, and are placed in 90~100 DEG C of high temperature and are gelatinized 10~20 minutes,
Product must be gelatinized；
（4）By step（3）The mixture of gained is cooled to 70~80 DEG C, adds in lignin, citric acid and acrylic acid, insulated and stirred
When reaction 1~2 is small, modified organo montmorillonite, photocatalyst, antifoaming agent, anion natural mineral powder are then sequentially added, is stirred
It is uniformly mixed to get the novel antibacterial glutinous rice glue.
8. preparation method according to claim 7, which is characterized in that described to be uniformly mixed process as follows：First use
After 50~100r/min of the slow-speed of revolution is pre-mixed 10~15min, then 30~45min is mixed in high 200~300r/min of rotating speed.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108587494A (en) * | 2018-07-26 | 2018-09-28 | 合肥广民建材有限公司 | A kind of glutinous rice glue and preparation method thereof with sedative action |
| CN109181635A (en) * | 2018-07-26 | 2019-01-11 | 合肥广民建材有限公司 | A kind of dedicated antibacterial glutinous rice glue of wallpaper and preparation method thereof |
| CN112759799A (en) * | 2020-12-29 | 2021-05-07 | 芜湖信诺教育设备有限公司 | Automobile manufacturing practical training glue product capable of being recycled repeatedly |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105331303A (en) * | 2015-09-14 | 2016-02-17 | 桐乡嘉力丰实业股份有限公司 | Glutinous rice adhesive being easy to blend and convenient to construct and used for wallpaper pasting, and preparation method thereof |
| CN106281051A (en) * | 2016-08-31 | 2017-01-04 | 桐乡嘉力丰实业股份有限公司 | Mildew-resistant flavouring wallpaper glue stick and preparation method thereof |
| CN106349971A (en) * | 2016-08-26 | 2017-01-25 | 桐乡嘉力丰实业股份有限公司 | Natural environment-friendly mildew-proof and damp-proof glutinous rice glue and preparation process thereof |
| CN106916551A (en) * | 2017-04-06 | 2017-07-04 | 合肥欧克斯新型建材有限公司 | A kind of Wall paper adhesive and preparation method thereof |
-
2018
- 2018-01-24 CN CN201810066221.7A patent/CN108047990A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105331303A (en) * | 2015-09-14 | 2016-02-17 | 桐乡嘉力丰实业股份有限公司 | Glutinous rice adhesive being easy to blend and convenient to construct and used for wallpaper pasting, and preparation method thereof |
| CN106349971A (en) * | 2016-08-26 | 2017-01-25 | 桐乡嘉力丰实业股份有限公司 | Natural environment-friendly mildew-proof and damp-proof glutinous rice glue and preparation process thereof |
| CN106281051A (en) * | 2016-08-31 | 2017-01-04 | 桐乡嘉力丰实业股份有限公司 | Mildew-resistant flavouring wallpaper glue stick and preparation method thereof |
| CN106916551A (en) * | 2017-04-06 | 2017-07-04 | 合肥欧克斯新型建材有限公司 | A kind of Wall paper adhesive and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108587494A (en) * | 2018-07-26 | 2018-09-28 | 合肥广民建材有限公司 | A kind of glutinous rice glue and preparation method thereof with sedative action |
| CN109181635A (en) * | 2018-07-26 | 2019-01-11 | 合肥广民建材有限公司 | A kind of dedicated antibacterial glutinous rice glue of wallpaper and preparation method thereof |
| CN112759799A (en) * | 2020-12-29 | 2021-05-07 | 芜湖信诺教育设备有限公司 | Automobile manufacturing practical training glue product capable of being recycled repeatedly |
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