CN109181635A - A kind of dedicated antibacterial glutinous rice glue of wallpaper and preparation method thereof - Google Patents
A kind of dedicated antibacterial glutinous rice glue of wallpaper and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J199/00—Adhesives based on natural macromolecular compounds or on derivatives thereof, not provided for in groups C09J101/00 -C09J107/00 or C09J189/00 - C09J197/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
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Abstract
The invention discloses a kind of dedicated antibacterial glutinous rice glue of wallpaper, the raw material including following parts by weight: pretreatment 40~60 parts of glutinous rice, 10~20 parts of sweet potato, 15~25 parts of tapioca, 3~7 parts of alum, 6~11 parts of pentaerythrite, 2~4 parts of glucolactone, 8~12 parts of modification infusorial earth, 3~6 parts of sorbierite, 4~9 parts of the Chinese herbal medicine extract, 2~5 parts of thickener, 1~3 part of anionic additive, 1~2 part of nano-silver ionic fungicide.Proportion of the present invention by between control raw material and raw material, the product prepared does not discharge volatile organic matter, and non-toxic to humans, the caking property of glutinous rice glue is strong, has excellent bactericidal mould proof effect to the common mould of wallpaper, effectively improves its service life.
Description
Technical field
The invention belongs to glutinous rice glue technical fields, and in particular to a kind of dedicated antibacterial glutinous rice glue of wallpaper and preparation method thereof.
Background technique
Instantly, requirement of the people for finishing material is higher and higher, and the environmental-protecting performance of finishing material considers as many people
One of necessary condition.Plate etc. gradually replaces the materials such as traditional calcimine, paint, and wallpaper etc. is with its good use
The performances such as property, the feature of environmental protection and dicoration, are also increasingly widely used by people, and wallpaper is adhered on plate and is often made with
Adhesive glue is sticked together, and general adhesive glue can all will cause greatly human body largely using organic solvents such as formaldehyde substantially
Harm.
Glutinous rice glue is also referred to as glutinous rice glue, be with pure natural glutinous rice or glutinous rice is raw material, by glutinous rice purification, grinding, dry etc.
12 procedures and the environment-protective adhesive formed, applied widely, viscosity is long.
But traditional glutinous rice glue it is generally existing viscosity it is low, anti-aging bad, storage thickening is hardened phenomenon, and appearance is not
Good, frost resistance poorly causes viscosity to decline, high expensive and construction when impregnation it is laborious the problems such as.
The patent of application publication number CN107057603A discloses a kind of child room special environment protection glutinous rice rubber powder and its processing
Method is process by following step: steamed, HIGH PRESSURE TREATMENT, microwave treatment, immersion, primary drying, tabletting, redrying, close
Package dress.Child room special environment protection glutinous rice rubber powder provided by the invention, the raw material of use is environmentally protective, it is organic not discharge volatility
Object, non-toxic to humans, the caking property of glutinous rice rubber powder is strong, has excellent bactericidal mould proof effect to the common mould of wallpaper, has
Effect improves its service life.But preparation process is complicated, production efficiency is low.
Summary of the invention
The present invention provides dedicated antibacterial glutinous rice glues of a kind of wallpaper and preparation method thereof, solve asking in background technique
Topic, the proportion of the present invention by between control raw material and raw material, the product prepared does not discharge volatile organic matter, to people
Body is nontoxic, and the caking property of glutinous rice glue is strong, has excellent bactericidal mould proof effect to the common mould of wallpaper, effectively improving it makes
Use the service life.
It is of the existing technology in order to solve the problems, such as, it adopts the following technical scheme that
A kind of dedicated antibacterial glutinous rice glue of wallpaper, the raw material including following parts by weight: pretreatment 40~60 parts of glutinous rice, sweet potato 10~20
Part, 15~25 parts of tapioca, 3~7 parts of alum, 6~11 parts of pentaerythrite, 2~4 parts of glucolactone, modification infusorial earth 8
~12 parts, 3~6 parts of sorbierite, 4~9 parts of the Chinese herbal medicine extract, 2~5 parts of thickener, 1~3 part of anionic additive, nano silver
1~2 part of ion sterilizing agent.
Preferably, the dedicated antibacterial glutinous rice glue of the wallpaper, the raw material including following parts by weight: pretreatment glutinous rice 45~55
Part, 12~18 parts of sweet potato, 17~24 parts of tapioca, 4~6 parts of alum, 7~10 parts of pentaerythrite, glucolactone 2.9~
3.3 parts, 9~11 parts of modification infusorial earth, 4~5 parts of sorbierite, 5~8 parts of the Chinese herbal medicine extract, 3~4 parts of thickener, anion add
Add 1.5~2.6 parts of agent, 1.2~1.7 parts of nano-silver ionic fungicide.
Preferably, the dedicated antibacterial glutinous rice glue of the wallpaper, the raw material including following parts by weight: pretreatment 50 parts of glutinous rice, red
15 parts of potato, 22 parts of tapioca, 5 parts of alum, 9 parts of pentaerythrite, 3.1 parts of glucolactone, 10 parts of modification infusorial earth, sorb
4.8 parts of alcohol, 7 parts of the Chinese herbal medicine extract, 3.4 parts of thickener, 2.2 parts of anionic additive, 1.3 parts of nano-silver ionic fungicide.
Preferably, it is described pretreatment glutinous rice the preparation method is as follows:
By glutinous rice be put into glacial acetic acid it is molten in, be warming up to 45~60 DEG C, ultrasonication power be 800~1200W under conditions of
It handles 10~20min and obtains the pretreatment glutinous rice after taking-up is dried.
Preferably, the modification infusorial earth the preparation method is as follows:
First by diatomite temperature be 550~650 DEG C at calcine 2 hours, cool down after, ball milling crosses 100~200 meshes, then in
It after being impregnated 3 hours in 10% acetic acid solution, takes out, deionized water is washed to neutrality, and the mountain for being equivalent to diatom powder weight 3% is added
The smooth monoleate of pears, after mixing, drying is ground into nanometer powder to get the modification infusorial earth.
Preferably, the Chinese herbal medicine extract is wormwood extracting solution, camphor ball extracting solution, Flos Lonicerae extractive solution, kuh-seng mention
Take the mixture of liquid and garlic extract, the wormwood extracting solution, camphor ball extracting solution, Flos Lonicerae extractive solution, Radix Sophorae Flavescentis extractive liquid
And garlic extract 2:2:2:2:1.
Preferably, the thickener is hydroxyethyl ether cellulose or TYLOSE 30000.
Preferably, the anionic additive is inorganic mineral.
A method of preparing the dedicated antibacterial glutinous rice glue of the wallpaper, comprising the following steps:
(1) pretreatment glutinous rice, sweet potato, tapioca, alum, pentaerythrite, glucolactone, modification are weighed by above-mentioned formula
Diatomite, sorbierite, the Chinese herbal medicine extract, thickener, anionic additive, nano-silver ionic fungicide, it is spare；
(2) sweet potato washing is clean, bulk of the partial size less than 2 centimetres is cut into peeling, spare；
(3) glutinous rice will be pre-processed and sweet potato block, tapioca, alum mix, adding water into material water content is 40%, while stirring
Side heating is mixed, is warming up to 80 DEG C, insulated and stirred 1~2 hour, the heating process was as follows: first with the heating rate liter of 2 DEG C/min
Then temperature is warming up to 80 DEG C again to 50 DEG C with the heating rate of 1 DEG C/min；
(4) step (3) resulting product is mixed with pentaerythrite, glucolactone, sorbierite, is then gelatinized, is obtained
It is gelatinized product；
(5) gelatinization product is stirred with surplus material, then is cooled to room temperature, packs to get the dedicated antibacterial of the wallpaper
Glutinous rice glue.
Preferably, the speed stirred in the step (3) is 20r/min.
Compared with prior art, the present invention it has the advantages that
(1) present invention is using pretreatment glutinous rice, sweet potato, tapioca, alum, pentaerythrite, glucolactone, modified diatom
Soil, sorbierite, the Chinese herbal medicine extract, thickener, anionic additive, nano-silver ionic fungicide etc. are used as raw material, use
Raw material is environmentally protective, does not discharge volatile organic matter, non-toxic to humans, and the caking property for preparing glutinous rice glue is strong, to wallpaper
Common mould has excellent bactericidal mould proof effect, effectively improves its service life；
(2) present invention can have by the compounding of a variety of specified raw material glue such as pretreatment glutinous rice, sweet potato, tapioca, alum
Effect improves its adhesive property, also, further combined with pretreatment glutinous rice provided in the present invention, can preferably improve its bonding
Etc. performances；
(3) present invention is added to the Chinese herbal medicine extract in the feed, and the Chinese herbal medicine extract is wormwood extracting solution, camphor ball mentions
The mixture of liquid, Flos Lonicerae extractive solution, Radix Sophorae Flavescentis extractive liquid and garlic extract, and nano-silver ionic is taken mutually to act synergistically,
A variety of germs can be resisted, to improve the antibiotic property of product.
Specific embodiment
Present invention will be further explained below with reference to specific examples.These embodiments are merely to illustrate the present invention and do not have to
In limiting the scope of the invention.
Embodiment 1
The present embodiment is related to a kind of dedicated antibacterial glutinous rice glue of wallpaper, the raw material including following parts by weight: pretreatment 40 parts of glutinous rice, red
10 parts of potato, 15 parts of tapioca, 3 parts of alum, 6 parts of pentaerythrite, 2 parts of glucolactone, 8 parts of modification infusorial earth, sorbierite 3
Part, 4 parts of the Chinese herbal medicine extract, 2 parts of thickener, 1 part of anionic additive, 1 part of nano-silver ionic fungicide.
Wherein, it is described pretreatment glutinous rice the preparation method is as follows:
By glutinous rice be put into glacial acetic acid it is molten in, be warming up to 45 DEG C, ultrasonication power be 800W under conditions of handle 10min,
After taking-up is dried, the pretreatment glutinous rice is obtained.
Wherein, the modification infusorial earth the preparation method is as follows:
First by diatomite temperature be 550 DEG C at calcine 2 hours, cool down after, ball milling crosses 100~200 meshes, then in 10%
It after being impregnated 3 hours in acetic acid solution, takes out, deionized water is washed to neutrality, and the sorb that addition is equivalent to diatom powder weight 3% is smooth
Monoleate, after mixing, drying is ground into nanometer powder to get the modification infusorial earth.
Wherein, the Chinese herbal medicine extract is wormwood extracting solution, camphor ball extracting solution, Flos Lonicerae extractive solution, kuh-seng extraction
The mixture of liquid and garlic extract, the wormwood extracting solution, camphor ball extracting solution, Flos Lonicerae extractive solution, Radix Sophorae Flavescentis extractive liquid and
Garlic extract 2:2:2:2:1.
Wherein, the thickener is hydroxyethyl ether cellulose.
Wherein, the anionic additive is inorganic mineral.
A method of preparing the dedicated antibacterial glutinous rice glue of the wallpaper, comprising the following steps:
(1) pretreatment glutinous rice, sweet potato, tapioca, alum, pentaerythrite, glucolactone, modification are weighed by above-mentioned formula
Diatomite, sorbierite, the Chinese herbal medicine extract, thickener, anionic additive, nano-silver ionic fungicide, it is spare；
(2) sweet potato washing is clean, bulk of the partial size less than 2 centimetres is cut into peeling, spare；
(3) glutinous rice will be pre-processed and sweet potato block, tapioca, alum mix, adding water into material water content is 40%, while stirring
Side heating is mixed, is warming up to 80 DEG C, insulated and stirred 1 hour, the heating process was as follows: first being heated up with the heating rate of 2 DEG C/min
To 50 DEG C, 80 DEG C then are warming up to the heating rate of 1 DEG C/min again；
(4) step (3) resulting product is mixed with pentaerythrite, glucolactone, sorbierite, is then gelatinized, is obtained
It is gelatinized product；
(5) gelatinization product is stirred with surplus material, then is cooled to room temperature, packs to get the dedicated antibacterial of the wallpaper
Glutinous rice glue.
Wherein, the speed stirred in the step (3) is 20r/min.
Embodiment 2
The present embodiment is related to a kind of dedicated antibacterial glutinous rice glue of wallpaper, the raw material including following parts by weight: pretreatment 60 parts of glutinous rice, red
20 parts of potato, 25 parts of tapioca, 7 parts of alum, 11 parts of pentaerythrite, 4 parts of glucolactone, 12 parts of modification infusorial earth, sorb
6 parts of alcohol, 9 parts of the Chinese herbal medicine extract, 5 parts of thickener, 3 parts of anionic additive, 2 parts of nano-silver ionic fungicide.
Wherein, it is described pretreatment glutinous rice the preparation method is as follows:
By glutinous rice be put into glacial acetic acid it is molten in, be warming up to 60 DEG C, ultrasonication power be 1200W under conditions of handle 20min,
After taking-up is dried, the pretreatment glutinous rice is obtained.
Wherein, the modification infusorial earth the preparation method is as follows:
First by diatomite temperature be 650 DEG C at calcine 2 hours, cool down after, ball milling crosses 100~200 meshes, then in 10%
It after being impregnated 3 hours in acetic acid solution, takes out, deionized water is washed to neutrality, and the sorb that addition is equivalent to diatom powder weight 3% is smooth
Monoleate, after mixing, drying is ground into nanometer powder to get the modification infusorial earth.
Wherein, the Chinese herbal medicine extract is wormwood extracting solution, camphor ball extracting solution, Flos Lonicerae extractive solution, kuh-seng extraction
The mixture of liquid and garlic extract, the wormwood extracting solution, camphor ball extracting solution, Flos Lonicerae extractive solution, Radix Sophorae Flavescentis extractive liquid and
Garlic extract 2:2:2:2:1.
Wherein, the thickener is hydroxyethyl ether cellulose or TYLOSE 30000.
Wherein, the anionic additive is inorganic mineral.
A method of preparing the dedicated antibacterial glutinous rice glue of the wallpaper, comprising the following steps:
(1) pretreatment glutinous rice, sweet potato, tapioca, alum, pentaerythrite, glucolactone, modification are weighed by above-mentioned formula
Diatomite, sorbierite, the Chinese herbal medicine extract, thickener, anionic additive, nano-silver ionic fungicide, it is spare；
(2) sweet potato washing is clean, bulk of the partial size less than 2 centimetres is cut into peeling, spare；
(3) glutinous rice will be pre-processed and sweet potato block, tapioca, alum mix, adding water into material water content is 40%, while stirring
Side heating is mixed, is warming up to 80 DEG C, insulated and stirred 2 hours, the heating process was as follows: first being heated up with the heating rate of 2 DEG C/min
To 50 DEG C, 80 DEG C then are warming up to the heating rate of 1 DEG C/min again；
(4) step (3) resulting product is mixed with pentaerythrite, glucolactone, sorbierite, is then gelatinized, is obtained
It is gelatinized product；
(5) gelatinization product is stirred with surplus material, then is cooled to room temperature, packs to get the dedicated antibacterial of the wallpaper
Glutinous rice glue.
Wherein, the speed stirred in the step (3) is 20r/min.
Embodiment 3
The present embodiment is related to a kind of dedicated antibacterial glutinous rice glue of wallpaper, the raw material including following parts by weight: pretreatment 45 parts of glutinous rice, red
12 parts of potato, 17 parts of tapioca, 4 parts of alum, 7 parts of pentaerythrite, 2.9 parts of glucolactone, 9 parts of modification infusorial earth, sorb
4 parts of alcohol, 5 parts of the Chinese herbal medicine extract, 3 parts of thickener, 1.5 parts of anionic additive, 1.2 parts of nano-silver ionic fungicide.
Wherein, it is described pretreatment glutinous rice the preparation method is as follows:
By glutinous rice be put into glacial acetic acid it is molten in, be warming up to 50 DEG C, ultrasonication power be 900W under conditions of handle 12min,
After taking-up is dried, the pretreatment glutinous rice is obtained.
Wherein, the modification infusorial earth the preparation method is as follows:
First by diatomite temperature be 580 DEG C at calcine 2 hours, cool down after, ball milling crosses 100~200 meshes, then in 10%
It after being impregnated 3 hours in acetic acid solution, takes out, deionized water is washed to neutrality, and the sorb that addition is equivalent to diatom powder weight 3% is smooth
Monoleate, after mixing, drying is ground into nanometer powder to get the modification infusorial earth.
Wherein, the Chinese herbal medicine extract is wormwood extracting solution, camphor ball extracting solution, Flos Lonicerae extractive solution, kuh-seng extraction
The mixture of liquid and garlic extract, the wormwood extracting solution, camphor ball extracting solution, Flos Lonicerae extractive solution, Radix Sophorae Flavescentis extractive liquid and
Garlic extract 2:2:2:2:1.
Wherein, the thickener is TYLOSE 30000.
Wherein, the anionic additive is inorganic mineral.
A method of preparing the dedicated antibacterial glutinous rice glue of the wallpaper, comprising the following steps:
(1) pretreatment glutinous rice, sweet potato, tapioca, alum, pentaerythrite, glucolactone, modification are weighed by above-mentioned formula
Diatomite, sorbierite, the Chinese herbal medicine extract, thickener, anionic additive, nano-silver ionic fungicide, it is spare；
(2) sweet potato washing is clean, bulk of the partial size less than 2 centimetres is cut into peeling, spare；
(3) glutinous rice will be pre-processed and sweet potato block, tapioca, alum mix, adding water into material water content is 40%, while stirring
Side heating is mixed, is warming up to 80 DEG C, insulated and stirred 1.2 hours, the heating process was as follows: first with the heating rate liter of 2 DEG C/min
Then temperature is warming up to 80 DEG C again to 50 DEG C with the heating rate of 1 DEG C/min；
(4) step (3) resulting product is mixed with pentaerythrite, glucolactone, sorbierite, is then gelatinized, is obtained
It is gelatinized product；
(5) gelatinization product is stirred with surplus material, then is cooled to room temperature, packs to get the dedicated antibacterial of the wallpaper
Glutinous rice glue.
Wherein, the speed stirred in the step (3) is 20r/min.
Embodiment 4
The present embodiment is related to a kind of dedicated antibacterial glutinous rice glue of wallpaper, the raw material including following parts by weight: pretreatment 55 parts of glutinous rice, red
18 parts of potato, 24 parts of tapioca, 6 parts of alum, 10 parts of pentaerythrite, 3.3 parts of glucolactone, 11 parts of modification infusorial earth, mountain
5 parts of pears alcohol, 8 parts of the Chinese herbal medicine extract, 4 parts of thickener, 2.6 parts of anionic additive, 1.7 parts of nano-silver ionic fungicide.
Wherein, it is described pretreatment glutinous rice the preparation method is as follows:
By glutinous rice be put into glacial acetic acid it is molten in, be warming up to 52 DEG C, ultrasonication power be 1000W under conditions of handle 15min,
After taking-up is dried, the pretreatment glutinous rice is obtained.
Wherein, the modification infusorial earth the preparation method is as follows:
First by diatomite temperature be 600 DEG C at calcine 2 hours, cool down after, ball milling crosses 100~200 meshes, then in 10%
It after being impregnated 3 hours in acetic acid solution, takes out, deionized water is washed to neutrality, and the sorb that addition is equivalent to diatom powder weight 3% is smooth
Monoleate, after mixing, drying is ground into nanometer powder to get the modification infusorial earth.
Wherein, the Chinese herbal medicine extract is wormwood extracting solution, camphor ball extracting solution, Flos Lonicerae extractive solution, kuh-seng extraction
The mixture of liquid and garlic extract, the wormwood extracting solution, camphor ball extracting solution, Flos Lonicerae extractive solution, Radix Sophorae Flavescentis extractive liquid and
Garlic extract 2:2:2:2:1.
Wherein, the thickener is TYLOSE 30000.
Wherein, the anionic additive is inorganic mineral.
A method of preparing the dedicated antibacterial glutinous rice glue of the wallpaper, comprising the following steps:
(1) pretreatment glutinous rice, sweet potato, tapioca, alum, pentaerythrite, glucolactone, modification are weighed by above-mentioned formula
Diatomite, sorbierite, the Chinese herbal medicine extract, thickener, anionic additive, nano-silver ionic fungicide, it is spare；
(2) sweet potato washing is clean, bulk of the partial size less than 2 centimetres is cut into peeling, spare；
(3) glutinous rice will be pre-processed and sweet potato block, tapioca, alum mix, adding water into material water content is 40%, while stirring
Side heating is mixed, is warming up to 80 DEG C, insulated and stirred 1.5 hours, the heating process was as follows: first with the heating rate liter of 2 DEG C/min
Then temperature is warming up to 80 DEG C again to 50 DEG C with the heating rate of 1 DEG C/min；
(4) step (3) resulting product is mixed with pentaerythrite, glucolactone, sorbierite, is then gelatinized, is obtained
It is gelatinized product；
(5) gelatinization product is stirred with surplus material, then is cooled to room temperature, packs to get the dedicated antibacterial of the wallpaper
Glutinous rice glue.
Wherein, the speed stirred in the step (3) is 20r/min.
Embodiment 5
The present embodiment is related to a kind of dedicated antibacterial glutinous rice glue of wallpaper, the raw material including following parts by weight: pretreatment 50 parts of glutinous rice, red
15 parts of potato, 22 parts of tapioca, 5 parts of alum, 9 parts of pentaerythrite, 3.1 parts of glucolactone, 10 parts of modification infusorial earth, sorb
4.8 parts of alcohol, 7 parts of the Chinese herbal medicine extract, 3.4 parts of thickener, 2.2 parts of anionic additive, 1.3 parts of nano-silver ionic fungicide.
Wherein, it is described pretreatment glutinous rice the preparation method is as follows:
By glutinous rice be put into glacial acetic acid it is molten in, be warming up to 55 DEG C, ultrasonication power be 1100W under conditions of handle 18min,
After taking-up is dried, the pretreatment glutinous rice is obtained.
Wherein, the modification infusorial earth the preparation method is as follows:
First by diatomite temperature be 620 DEG C at calcine 2 hours, cool down after, ball milling crosses 100~200 meshes, then in 10%
It after being impregnated 3 hours in acetic acid solution, takes out, deionized water is washed to neutrality, and the sorb that addition is equivalent to diatom powder weight 3% is smooth
Monoleate, after mixing, drying is ground into nanometer powder to get the modification infusorial earth.
Wherein, the Chinese herbal medicine extract is wormwood extracting solution, camphor ball extracting solution, Flos Lonicerae extractive solution, kuh-seng extraction
The mixture of liquid and garlic extract, the wormwood extracting solution, camphor ball extracting solution, Flos Lonicerae extractive solution, Radix Sophorae Flavescentis extractive liquid and
Garlic extract 2:2:2:2:1.
Wherein, the thickener is TYLOSE 30000.
Wherein, the anionic additive is inorganic mineral.
A method of preparing the dedicated antibacterial glutinous rice glue of the wallpaper, comprising the following steps:
(1) pretreatment glutinous rice, sweet potato, tapioca, alum, pentaerythrite, glucolactone, modification are weighed by above-mentioned formula
Diatomite, sorbierite, the Chinese herbal medicine extract, thickener, anionic additive, nano-silver ionic fungicide, it is spare；
(2) sweet potato washing is clean, bulk of the partial size less than 2 centimetres is cut into peeling, spare；
(3) glutinous rice will be pre-processed and sweet potato block, tapioca, alum mix, adding water into material water content is 40%, while stirring
Side heating is mixed, is warming up to 80 DEG C, insulated and stirred 1.8 hours, the heating process was as follows: first with the heating rate liter of 2 DEG C/min
Then temperature is warming up to 80 DEG C again to 50 DEG C with the heating rate of 1 DEG C/min；
(4) step (3) resulting product is mixed with pentaerythrite, glucolactone, sorbierite, is then gelatinized, is obtained
It is gelatinized product；
(5) gelatinization product is stirred with surplus material, then is cooled to room temperature, packs to get the dedicated antibacterial of the wallpaper
Glutinous rice glue.
Wherein, the speed stirred in the step (3) is 20r/min.
Comparative example
A kind of child room special environment protection glutinous rice rubber powder and its processing method of the patent disclosure of application publication number CN107057603A.
Glutinous rice glue described in above-described embodiment 1~5, comparative example is detected into its wet viscosity according to JC/T548-2016 respectively
(when strip length is 300mm, moving distance), sliding property, 180 ° of peel strengths, 7d working life, 30d working life and 180d are suitable
With the phase, as a result as shown in the table.Wherein, not corrupt, not thinning, mildew be qualification.
| Wet viscosity (mm) | Sliding property (N) | 180oPeel strength (N/25mm) | 7d working life | 30d working life | 180d working life | |
| Embodiment 1 | 1.8 | 7.3 | 25 | It is qualified | It is qualified | It is qualified |
| Embodiment 2 | 2.1 | 6.8 | 22 | It is qualified | It is qualified | It is qualified |
| Embodiment 3 | 1.9 | 7.1 | 24 | It is qualified | It is qualified | It is qualified |
| Embodiment 4 | 2.2 | 6.9 | 23 | It is qualified | It is qualified | It is qualified |
| Embodiment 5 | 1.8 | 6.7 | 26 | It is qualified | It is qualified | It is qualified |
| Comparative example | 5 | 10.2 | 10 | It is qualified | There is slight mildew | There is part mildew |
As can be seen from the above table, the performance of glutinous rice glue of the present invention is better than comparative example.
In conclusion (1) present invention is using pretreatment glutinous rice, sweet potato, tapioca, alum, pentaerythrite, gluconic acid
Lactone, modification infusorial earth, sorbierite, the Chinese herbal medicine extract, thickener, anionic additive, nano-silver ionic fungicide etc. are made
For raw material, the raw material of use is environmentally protective, does not discharge volatile organic matter, non-toxic to humans, prepares the viscous of glutinous rice glue
Knot property is strong, has excellent bactericidal mould proof effect to the common mould of wallpaper, effectively improves its service life；
(2) present invention can have by the compounding of a variety of specified raw material glue such as pretreatment glutinous rice, sweet potato, tapioca, alum
Effect improves its adhesive property, also, further combined with pretreatment glutinous rice provided in the present invention, can preferably improve its bonding
Etc. performances；
(3) present invention is added to the Chinese herbal medicine extract in the feed, and the Chinese herbal medicine extract is wormwood extracting solution, camphor ball mentions
The mixture of liquid, Flos Lonicerae extractive solution, Radix Sophorae Flavescentis extractive liquid and garlic extract, and nano-silver ionic is taken mutually to act synergistically,
A variety of germs can be resisted, to improve the antibiotic property of product.
Specific embodiments of the present invention are described above.It is to be appreciated that the invention is not limited to above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring substantive content of the invention.
Claims (10)
1. a kind of dedicated antibacterial glutinous rice glue of wallpaper, which is characterized in that the raw material including following parts by weight: pretreatment glutinous rice 40~60
Part, 10~20 parts of sweet potato, 15~25 parts of tapioca, 3~7 parts of alum, 6~11 parts of pentaerythrite, glucolactone 2~4
Part, the addition of 8~12 parts of modification infusorial earth, 3~6 parts of sorbierite, 4~9 parts of the Chinese herbal medicine extract, 2~5 parts of thickener, anion
1~3 part of agent, 1~2 part of nano-silver ionic fungicide.
2. the dedicated antibacterial glutinous rice glue of wallpaper according to claim 1, which is characterized in that the raw material including following parts by weight:
Pre-process 45~55 parts of glutinous rice, 12~18 parts of sweet potato, 17~24 parts of tapioca, 4~6 parts of alum, 7~10 parts of pentaerythrite,
2.9~3.3 parts of glucolactone, 9~11 parts of modification infusorial earth, 4~5 parts of sorbierite, 5~8 parts of the Chinese herbal medicine extract, thickening
3~4 parts of agent, 1.5~2.6 parts of anionic additive, 1.2~1.7 parts of nano-silver ionic fungicide.
3. the dedicated antibacterial glutinous rice glue of wallpaper according to claim 1, which is characterized in that the raw material including following parts by weight:
50 parts of glutinous rice of pretreatment, 22 parts of tapioca, 5 parts of alum, 9 parts of pentaerythrite, 3.1 parts of glucolactone, changes 15 parts of sweet potato
Property 10 parts of diatomite, 4.8 parts of sorbierite, 7 parts of the Chinese herbal medicine extract, 3.4 parts of thickener, 2.2 parts of anionic additive, nano silver
1.3 parts of ion sterilizing agent.
4. the dedicated antibacterial glutinous rice glue of wallpaper according to claim 1, which is characterized in that the preparation side of the pretreatment glutinous rice
Method is as follows:
By glutinous rice be put into glacial acetic acid it is molten in, be warming up to 45~60 DEG C, ultrasonication power be 800~1200W under conditions of
It handles 10~20min and obtains the pretreatment glutinous rice after taking-up is dried.
5. the dedicated antibacterial glutinous rice glue of wallpaper according to claim 1, which is characterized in that the preparation side of the modification infusorial earth
Method is as follows:
First by diatomite temperature be 550~650 DEG C at calcine 2 hours, cool down after, ball milling crosses 100~200 meshes, then in
It after being impregnated 3 hours in 10% acetic acid solution, takes out, deionized water is washed to neutrality, and the mountain for being equivalent to diatom powder weight 3% is added
The smooth monoleate of pears, after mixing, drying is ground into nanometer powder to get the modification infusorial earth.
6. the dedicated antibacterial glutinous rice glue of wallpaper according to claim 1, which is characterized in that the Chinese herbal medicine extract is wormwood
Extracting solution, camphor ball extracting solution, Flos Lonicerae extractive solution, Radix Sophorae Flavescentis extractive liquid and garlic extract mixture, the wormwood extracts
Liquid, camphor ball extracting solution, Flos Lonicerae extractive solution, Radix Sophorae Flavescentis extractive liquid and garlic extract 2:2:2:2:1.
7. the dedicated antibacterial glutinous rice glue of wallpaper according to claim 1, which is characterized in that the thickener is hydroxy ethyl fiber
Plain ether or TYLOSE 30000.
8. the dedicated antibacterial glutinous rice glue of wallpaper according to claim 1, which is characterized in that the anionic additive is inorganic
Minerals.
9. a kind of method for preparing any one of claim 1~8 dedicated antibacterial glutinous rice glue of wallpaper, which is characterized in that including
Following steps:
(1) pretreatment glutinous rice, sweet potato, tapioca, alum, pentaerythrite, glucolactone, modification are weighed by above-mentioned formula
Diatomite, sorbierite, the Chinese herbal medicine extract, thickener, anionic additive, nano-silver ionic fungicide, it is spare；
(2) sweet potato washing is clean, bulk of the partial size less than 2 centimetres is cut into peeling, spare；
(3) glutinous rice will be pre-processed and sweet potato block, tapioca, alum mix, adding water into material water content is 40%, while stirring
Side heating is mixed, is warming up to 80 DEG C, insulated and stirred 1~2 hour, the heating process was as follows: first with the heating rate liter of 2 DEG C/min
Then temperature is warming up to 80 DEG C again to 50 DEG C with the heating rate of 1 DEG C/min；
(4) step (3) resulting product is mixed with pentaerythrite, glucolactone, sorbierite, is then gelatinized, is obtained
It is gelatinized product；
(5) gelatinization product is stirred with surplus material, then is cooled to room temperature, packs to get the dedicated antibacterial of the wallpaper
Glutinous rice glue.
10. preparation method according to claim 9, which is characterized in that the speed stirred in the step (3) is 20r/
min。
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112571909A (en) * | 2020-12-28 | 2021-03-30 | 滁州卷烟材料厂 | Composite moisture-proof aluminum foil paper |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105331303A (en) * | 2015-09-14 | 2016-02-17 | 桐乡嘉力丰实业股份有限公司 | Glutinous rice adhesive being easy to blend and convenient to construct and used for wallpaper pasting, and preparation method thereof |
| CN105623551A (en) * | 2014-11-28 | 2016-06-01 | 曹燕 | Antibiotic and mildew-resistant starch adhesive for wallpaper, and preparation method thereof |
| CN106281109A (en) * | 2016-08-26 | 2017-01-04 | 桐乡嘉力丰实业股份有限公司 | A kind of high stability mildew-resistant environmental protection Oryza glutinosa glue and preparation technology thereof |
| CN106381089A (en) * | 2016-08-31 | 2017-02-08 | 桐乡嘉力丰实业股份有限公司 | Edible environmentally-friendly glutinous rice glue composition used for pasting wallpapers, and production method thereof |
| CN107629726A (en) * | 2017-09-26 | 2018-01-26 | 芜湖县双宝建材有限公司 | A kind of glutinous rice glue preparation method for wallpaper |
| CN107652915A (en) * | 2017-09-26 | 2018-02-02 | 芜湖县双宝建材有限公司 | A kind of wallpaper bonds mould proof glutinous rice glue with high |
| CN108047990A (en) * | 2018-01-24 | 2018-05-18 | 合肥市大卓电力有限责任公司 | A kind of novel antibacterial glutinous rice glue and preparation method thereof |
| CN108219708A (en) * | 2018-03-21 | 2018-06-29 | 合肥广民建材有限公司 | A kind of preparation method of environmental protection glutinous rice glue |
-
2018
- 2018-07-26 CN CN201810831407.7A patent/CN109181635A/en not_active Withdrawn
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105623551A (en) * | 2014-11-28 | 2016-06-01 | 曹燕 | Antibiotic and mildew-resistant starch adhesive for wallpaper, and preparation method thereof |
| CN105331303A (en) * | 2015-09-14 | 2016-02-17 | 桐乡嘉力丰实业股份有限公司 | Glutinous rice adhesive being easy to blend and convenient to construct and used for wallpaper pasting, and preparation method thereof |
| CN106281109A (en) * | 2016-08-26 | 2017-01-04 | 桐乡嘉力丰实业股份有限公司 | A kind of high stability mildew-resistant environmental protection Oryza glutinosa glue and preparation technology thereof |
| CN106381089A (en) * | 2016-08-31 | 2017-02-08 | 桐乡嘉力丰实业股份有限公司 | Edible environmentally-friendly glutinous rice glue composition used for pasting wallpapers, and production method thereof |
| CN107629726A (en) * | 2017-09-26 | 2018-01-26 | 芜湖县双宝建材有限公司 | A kind of glutinous rice glue preparation method for wallpaper |
| CN107652915A (en) * | 2017-09-26 | 2018-02-02 | 芜湖县双宝建材有限公司 | A kind of wallpaper bonds mould proof glutinous rice glue with high |
| CN108047990A (en) * | 2018-01-24 | 2018-05-18 | 合肥市大卓电力有限责任公司 | A kind of novel antibacterial glutinous rice glue and preparation method thereof |
| CN108219708A (en) * | 2018-03-21 | 2018-06-29 | 合肥广民建材有限公司 | A kind of preparation method of environmental protection glutinous rice glue |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112571909A (en) * | 2020-12-28 | 2021-03-30 | 滁州卷烟材料厂 | Composite moisture-proof aluminum foil paper |
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Application publication date: 20190111 |