CN106925228A - A kind of attapulgite deodorant for refrigerator and preparation method thereof - Google Patents
A kind of attapulgite deodorant for refrigerator and preparation method thereof Download PDFInfo
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- CN106925228A CN106925228A CN201710231056.1A CN201710231056A CN106925228A CN 106925228 A CN106925228 A CN 106925228A CN 201710231056 A CN201710231056 A CN 201710231056A CN 106925228 A CN106925228 A CN 106925228A
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/013—Deodorant compositions containing animal or plant extracts, or vegetable material
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- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
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- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
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- A61L2209/21—Use of chemical compounds for treating air or the like
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Abstract
The invention discloses a kind of attapulgite deodorant for refrigerator and preparation method thereof, it is related to attapulgite technical field, by weight including 1 ~ 5 part of 100 ~ 120 parts of attapulgite, 20 ~ 30 parts of pomelo peel, 20 ~ 30 parts of plant leaf blade, 10 ~ 20 parts of white cement, 2 ~ 6 parts of nano-scale silver powder, 2 ~ 6 parts of tourmaline fine powder and titanium dioxide.The present invention is with attapulgite as primary raw material, and low manufacture cost, deodorant and antibacterial effect is preferable, and hydrophobicity is strong, and service life is more long.
Description
Technical field
The present invention relates to attapulgite technical field, and in particular to a kind of attapulgite deodorant for refrigerator and its preparation side
Method.
Background technology
Attapulgite is also known as thread stone, thousand native kings etc..The world is multinational to be distributed.But China accounts for the 85% of whole allowable exploitations,
Total amount, up to 500,000,000 tons, is that this product production in enormous quantities is laid a good foundation.Attapulgite is in barreled structure, and its surface area is up to 9.6 ~ 36
㎡/g, has very strong adsorption capacity to various organic gas heresy taste.In the design, attapulgite composition fills up to 60 ~ 80%
Divide and make use of suction-operated of the attapulgite to various harmful components.Attapulgite also has preferable mildew resistance, suppresses microorganism
Growth, chemical inertness stabilization is never degenerated, non-toxic, there is reliable security to food.
Refrigerator has turned into the indispensable common electric of Modern Family.It is commonly used to store guaranteeing the quality for raw-food material and vegetables
It is fresh.Play the role of in daily life indispensable.After long-term use, some food debris are inevitably lost in refrigerator.
These being rich in nutrition materials are also the growth thing of microorganism, all kinds of bacteriums in refrigerator, virus is turned into food contaminant and people
The hazardous material of body health.These specks also produce some harmful materials, such as ammonia, amine, or even produce aspergillus flavus etc.
Carcinogenic substance.Common disease mushroom in the more refrigerator such as mould, yeast.But it is the space for storing food in refrigerator, it is impossible to gone out with sterilization
The medicine class dissipation of worm these microorganisms.
The content of the invention
It is main with attapulgite it is an object of the invention to provide a kind of attapulgite deodorant for refrigerator and preparation method thereof
Raw material, low manufacture cost, preferably, hydrophobicity is strong, and service life is more long for deodorant and antibacterial effect.
The invention provides following technical scheme：A kind of attapulgite deodorant for refrigerator, including following weight portion original
Material：100 ~ 120 parts of attapulgite, 20 ~ 30 parts of pomelo peel, 20 ~ 30 parts of plant leaf blade, 10 ~ 20 parts of white cement, nano-scale silver powder 2 ~
1 ~ 5 part of 6 parts, 2 ~ 6 parts of tourmaline fine powder and titanium dioxide.
Preferably, including following weight portion raw material：It is 110 parts of attapulgite, 25 parts of pomelo peel, 25 parts of plant leaf blade, white
3 parts of 15 parts of cement, 4 parts of nano-scale silver powder, 4 parts of tourmaline fine powder and titanium dioxide.
Preferably, the plant leaf blade is any in paulownia leaves, Poplar leaves, Folium Pterocaryae, Folium sophorae or Boston ivy leaf
Kind.
A kind of preparation method of attapulgite deodorant for refrigerator is also provided in the present invention, is comprised the following steps：
Step（1）, attapulgite is ground into the particle of 0.5 ~ 2mm of particle diameter；
Step（2）, by step（1）5 ~ 6h is carried during the middle attapulgite by grinding is soaked in 1 ~ 2% sodium hydroxide solution
Pure, filtration drying obtains attapulgite powder after purification；
Step（3）, by step（2）In attapulgite powder be added in ethanol solution, with 200 ~ 300r/min of rotating speed stir
35 ~ 45min, obtains attapulgite alcohol suspending liquid, at 25 ~ 35 DEG C, toward attapulgite alcohol suspending liquid, adds amino silicone
Oil, and continue to stir 1 ~ 2h with 100 ~ 200r/min of rotating speed, attapulgite's surface is modified upper amido silicon oil molecule, then will have
The liquid that machine modification is obtained is placed in and 2 ~ 3h is dried in 65 ~ 70 DEG C of oven conditions, and the powder that will be dried to obtain is ground
20 ~ 30min, obtains modified attapulgite powder end after grinding, standby；
Step（4）, take pomelo peel, be placed on after cleaning up ventilation drying, dry after be put into pulverizer crushing, crush
To shaddock peel powder, shaddock peel powder is mixed with water according to mass ratio 1: 5~1: 8,5~6h of heating and refluxing extraction, heating-up temperature control
60 ~ 70 DEG C are made as, shaddock ped essential oil is obtained, it is standby；
Step（5）, by plant leaf blade microwave irradiation, the leaf after microwave irradiation dries in the shade at shady and cool ventilation, after drying in the shade
Plant leaf blade is put into pulverizer crushing, crosses 80 ~ 100 mesh sieves, with mass concentration for 20 ~ 40% ethanol water is extracted 4 ~ 5 times,
The filtrate for merging extraction every time obtains plant leaf blade extract solution；
Step（6）, by the step（2）In the plant leaf blade extract solution that obtains be concentrated under reduced pressure, until it is small to detect ethanol content
Untill when 0.5%, then filtered, the impurity in filtrate, the filtrate that will be collected into are removed with macroporous adsorbent resin column chromatography
It is spray-dried, is obtained natural plants dry powder, it is standby；
Step（7）, by step（3）Modified attapulgite powder end, the step for obtaining（4）The shaddock ped essential oil that obtains and
Step（5）The natural plants dry powder blend for obtaining, and according to proportioning add nano-scale silver powder, white cement, tourmaline fine powder,
Titanium dioxide, the clear water for accounting for gross weight 25% ~ 30% is added after being well mixed, and is continued stirring and is mixed to get paste mixture；
Step（8）, by step（7）In the paste mixture that obtains insert in mould, it is molded after be put into electric dry oven,
When temperature is 8% ~ 10% to be baked to moisture at 100 DEG C ~ 110 DEG C, take out cool to normal temperature, obtain final product the attapulgite and remove
Smelly dose.
Preferably, the step（2）Middle drying temperature is 90 ~ 110 DEG C, and drying time is 2 ~ 3h.
Preferably, the step（3）The mass ratio of attapulgite powder and ethanol solution is 1：8~1：10, amido silicon oil and recessed
The mass ratio of convex rod soil alcohol suspending liquid is 1：50~1：60.
Preferably, the step（5）Middle microwave irradiation power is 10 ~ 70W/g, and plant leaf blade tiling thickness is 5 ~ 30mm,
Microwave frequency is 2450MHZ, and microwave irradiating time is 4 ~ 6min.
Preferably, the step（5）Middle plant leaf is 1: 10 ~ 1 with the weight ratio of ethanol water：15, extraction temperature
60 ~ 70 DEG C, 1 ~ 2h of extraction time.
Preferably, the step（6）In macroporous absorbent resin be non-polar resin.
Beneficial effects of the present invention：With attapulgite as primary raw material, low manufacture cost, deodorant and antibacterial effect is preferable,
Other hydrophobicity is strong, and service life is more long, specific as follows：
（1）, the present invention attapulgite is purified and is modified, bedding void increase, suction-operated enhancing, using amido silicon oil
Organic modification is carried out, hydrophobicity is made it have；
（2）, the present invention addition white cement, play a part of coagulator and supporter, because attapulgite is more open, be a granulated into
Type is more difficult, and white cement and attapulgite add water mixing granulation, increase the ventilated function of attapulgite, are conducive to attapulgite
Absorption pernicious gas and each quasi-microorganism carry out it is deodorant；
（3）, the present invention addition tourmaline, with peculiar smell in adsorbed gas and various pernicious gases, the effect of purify air；
（4）, the present invention addition titanium dioxide have sterilizing, self-cleaning function, titanium dioxide can also improve overall whiteness, make outward
Table is pure white attractive in appearance；
（5）, the present invention extracts the active principle of shaddock ped turns into Essential Oil From Citrus Grandis Peel, and preparing natural plant powder, makes the present invention
Deodorant in the low temperature environment of refrigerator sustained release delicate fragrance.
Specific embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments be merely to illustrate the present invention and without
In limitation the scope of the present invention.
Embodiment 1
A kind of attapulgite deodorant for refrigerator, including following weight portion raw material：100 parts of attapulgite, 20 parts of pomelo peel, plant
1 part of 20 parts of blade, 10 parts of white cement, 2 parts of nano-scale silver powder, 2 parts of tourmaline fine powder and titanium dioxide.
Wherein, the plant leaf blade is paulownia leaves.
A kind of preparation method of attapulgite deodorant for refrigerator is also provided in the present embodiment, is comprised the following steps：
Step（1）, attapulgite is ground into the particle of particle diameter 0.5mm；
Step（2）, by step（1）5h is purified during the middle attapulgite by grinding is soaked in 1% sodium hydroxide solution,
Filtration drying obtains attapulgite powder after purification；
Step（3）, by step（2）In attapulgite powder be added in ethanol solution, with rotating speed 200r/min stir
35min, obtains attapulgite alcohol suspending liquid, at 25 DEG C, toward attapulgite alcohol suspending liquid, adds amido silicon oil, and
Continue to stir 1h with rotating speed 100r/min, attapulgite's surface is modified upper amido silicon oil molecule, then by organic modification
The liquid for obtaining is placed in 65 DEG C of oven conditions and dries 2h, and the powder that will be dried to obtain is ground 20min, is obtained after grinding
Modified attapulgite powder end, it is standby；
Step（4）, take pomelo peel, be placed on after cleaning up ventilation drying, dry after be put into pulverizer crushing, crush
To shaddock peel powder, shaddock peel powder is mixed with water according to mass ratio 1: 5, heating and refluxing extraction 5h, heating and temperature control is 60 DEG C,
Shaddock ped essential oil is obtained, it is standby；
Step（5）, by plant leaf blade microwave irradiation, the leaf after microwave irradiation dries in the shade at shady and cool ventilation, after drying in the shade
Plant leaf blade is put into pulverizer crushing, crosses 80 mesh sieves, is extracted 4 times with the ethanol water that mass concentration is 20%, merges each
The filtrate of extraction obtains plant leaf blade extract solution；
Step（6）, by the step（2）In the plant leaf blade extract solution that obtains be concentrated under reduced pressure, until it is small to detect ethanol content
Untill when 0.5%, then filtered, the impurity in filtrate, the filtrate that will be collected into are removed with macroporous adsorbent resin column chromatography
It is spray-dried, is obtained natural plants dry powder, it is standby；
Step（7）, by step（3）Modified attapulgite powder end, the step for obtaining（4）The shaddock ped essential oil that obtains and
Step（5）The natural plants dry powder blend for obtaining, and add nanometer-level silver, white cement, tourmaline fine powder, titanium according to proportioning
White powder, the clear water for accounting for gross weight 25% is added after being well mixed, and is continued stirring and is mixed to get paste mixture；
Step（8）, by step（7）In the paste mixture that obtains insert in mould, it is molded after be put into electric dry oven,
When temperature is 8% to be baked to moisture at 100 DEG C, take out cool to normal temperature, obtain final product the attapulgite deodorant.
Wherein, the step（2）Middle drying temperature is 90 DEG C, and drying time is 2h.
Wherein, the step（3）The mass ratio of attapulgite powder and ethanol solution is 1：8, amido silicon oil and attapulgite
The mass ratio of alcohol suspending liquid is 1：50.
Wherein, the step（5）Middle microwave irradiation power is 10W/g, and plant leaf blade tiling thickness is 5mm, microwave frequency
It is 2450MHZ, microwave irradiating time is 4min.
Wherein, the step（5）Middle plant leaf is 1: 10 with the weight ratio of ethanol water, 60 DEG C of extraction temperature, leaching
Carry time 1h.
Wherein, the step（6）In macroporous absorbent resin be non-polar resin.
Embodiment 2
A kind of attapulgite deodorant for refrigerator, it is characterised in that by weight including 120 parts of attapulgite, 30 parts of pomelo peel,
5 parts of 30 parts of plant leaf blade, 20 parts of white cement, 6 parts of nano-scale silver powder, 6 parts of tourmaline fine powder and titanium dioxide.
Wherein, the plant leaf blade is Poplar leaves.
A kind of preparation method of attapulgite deodorant for refrigerator is also provided in the present embodiment, is comprised the following steps：
Step（1）, attapulgite is ground into the particle of particle diameter 2mm；
Step（2）, by step（1）6h is purified during the middle attapulgite by grinding is soaked in 2% sodium hydroxide solution,
Filtration drying obtains attapulgite powder after purification；
Step（3）, by step（2）In attapulgite powder be added in ethanol solution, with rotating speed 300r/min stir
45min, obtains attapulgite alcohol suspending liquid, at 35 DEG C, toward attapulgite alcohol suspending liquid, adds amido silicon oil, and
Continue to stir 2h with rotating speed 200r/min, attapulgite's surface is modified upper amido silicon oil molecule, then by organic modification
The liquid for obtaining is placed in 70 DEG C of oven conditions and dries 3h, and the powder that will be dried to obtain is ground 30min, is obtained after grinding
Modified attapulgite powder end, it is standby；
Step（4）, take pomelo peel, be placed on after cleaning up ventilation drying, dry after be put into pulverizer crushing, crush
To shaddock peel powder, shaddock peel powder is mixed with water according to mass ratio 1: 8, heating and refluxing extraction 6h, heating and temperature control is 60 ~ 70
DEG C, shaddock ped essential oil is obtained, it is standby；
Step（5）, by plant leaf blade microwave irradiation, the leaf after microwave irradiation dries in the shade at shady and cool ventilation, after drying in the shade
Plant leaf blade is put into pulverizer crushing, crosses 100 mesh sieves, is extracted 5 times with the ethanol water that mass concentration is 40%, merges each
The filtrate of extraction obtains plant leaf blade extract solution；
Step（6）, by the step（2）In the plant leaf blade extract solution that obtains be concentrated under reduced pressure, until it is small to detect ethanol content
Untill when 0.5%, then filtered, the impurity in filtrate, the filtrate that will be collected into are removed with macroporous adsorbent resin column chromatography
It is spray-dried, is obtained natural plants dry powder, it is standby；
Step（7）, by step（3）Modified attapulgite powder end, the step for obtaining（4）The shaddock ped essential oil that obtains and
Step（5）The natural plants dry powder blend for obtaining, and add nanometer-level silver, white cement, tourmaline fine powder, titanium according to proportioning
White powder, the clear water for accounting for gross weight 30% is added after being well mixed, and is continued stirring and is mixed to get paste mixture；
Step（8）, by step（7）In the paste mixture that obtains insert in mould, it is molded after be put into electric dry oven,
When temperature is 8% ~ 10% to be baked to moisture at 110 DEG C, take out cool to normal temperature, obtain final product the attapulgite deodorant.
Wherein, the step（2）Middle drying temperature is 110 DEG C, and drying time is 3h.
Wherein, the step（3）The mass ratio of attapulgite powder and ethanol solution is 1：10, amido silicon oil and attapulgite
The mass ratio of alcohol suspending liquid is 1：60.
Wherein, the step（5）Middle microwave irradiation power is 70W/g, and plant leaf blade tiling thickness is 30mm, microwave frequency
It is 2450MHZ, microwave irradiating time is 6min.
Wherein, the step（5）Middle plant leaf is 1 with the weight ratio of ethanol water：15,70 DEG C of extraction temperature, leaching
Carry time 2h.
Wherein, the step（6）In macroporous absorbent resin be non-polar resin.
Embodiment 3
A kind of attapulgite deodorant for refrigerator, by weight including 110 parts of attapulgite, 25 parts of pomelo peel, plant leaf blade 25
Part, 15 parts of white cement, 4 parts of nano-scale silver powder, 4 parts of tourmaline fine powder and 3 parts of titanium dioxide.
Wherein, the plant leaf blade is Folium sophorae.
A kind of preparation method of attapulgite deodorant for refrigerator is also provided in the present embodiment, is comprised the following steps：
Step（1）, attapulgite is ground into the particle of particle diameter 1mm；
Step（2）, by step（1）5.5h is carried during the middle attapulgite by grinding is soaked in 1.5% sodium hydroxide solution
Pure, filtration drying obtains attapulgite powder after purification；
Step（3）, by step（2）In attapulgite powder be added in ethanol solution, with rotating speed 250r/min stir
40min, obtains attapulgite alcohol suspending liquid, at 30 DEG C, toward attapulgite alcohol suspending liquid, adds amido silicon oil, and
Continue to stir 1.5h with rotating speed 150r/min, attapulgite's surface is modified upper amido silicon oil molecule, then change organic decoration
The liquid that property is obtained is placed in 68 DEG C of oven conditions and dries 2.5h, and the powder that will be dried to obtain is ground 25min, after grinding
Modified attapulgite powder end is obtained, it is standby；
Step（4）, take pomelo peel, be placed on after cleaning up ventilation drying, dry after be put into pulverizer crushing, crush
To shaddock peel powder, shaddock peel powder is mixed with water according to mass ratio 1: 6, heating and refluxing extraction 5.5h, heating and temperature control is 65
DEG C, shaddock ped essential oil is obtained, it is standby；
Step（5）, by plant leaf blade microwave irradiation, the leaf after microwave irradiation dries in the shade at shady and cool ventilation, after drying in the shade
Plant leaf blade is put into pulverizer crushing, crosses 90 mesh sieves, is extracted 4 times with the ethanol water that mass concentration is 30%, merges each
The filtrate of extraction obtains plant leaf blade extract solution；
Step（6）, by the step（2）In the plant leaf blade extract solution that obtains be concentrated under reduced pressure, until it is small to detect ethanol content
Untill when 0.5%, then filtered, the impurity in filtrate, the filtrate that will be collected into are removed with macroporous adsorbent resin column chromatography
It is spray-dried, is obtained natural plants dry powder, it is standby；
Step（7）, by step（3）Modified attapulgite powder end, the step for obtaining（4）The shaddock ped essential oil that obtains and
Step（5）The natural plants dry powder blend for obtaining, and add nanometer-level silver, white cement, tourmaline fine powder, titanium according to proportioning
White powder, the clear water for accounting for gross weight 27% is added after being well mixed, and is continued stirring and is mixed to get paste mixture；
Step（8）, by step（7）In the paste mixture that obtains insert in mould, it is molded after be put into electric dry oven,
When temperature is 9% to be baked to moisture at 105 DEG C, take out cool to normal temperature, obtain final product the attapulgite deodorant.
Wherein, the step（2）Middle drying temperature is 100 DEG C, and drying time is 2.5h.
Wherein, the step（3）The mass ratio of attapulgite powder and ethanol solution is 1：9, amido silicon oil and attapulgite
The mass ratio of alcohol suspending liquid is 1：55.
Wherein, the step（5）Middle microwave irradiation power is 40W/g, and plant leaf blade tiling thickness is 20mm, microwave frequency
It is 2450MHZ, microwave irradiating time is 5min.
Wherein, the step（5）Middle plant leaf is 1: 12 with the weight ratio of ethanol water, 65 DEG C of extraction temperature, leaching
Carry time 1.5h.
Wherein, the step（6）In macroporous absorbent resin be non-polar resin.
The present invention has been described in detail with reference to the foregoing embodiments, for a person skilled in the art, its according to
The technical scheme described in foregoing embodiments can so be modified, or which part technical characteristic is equally replaced
Change.All any modification, equivalent substitution and improvements within the spirit and principles in the present invention, made etc., should be included in the present invention
Protection domain within.
Claims (9)
1. a kind of attapulgite deodorant for refrigerator, it is characterised in that the raw material including following weight portion：Attapulgite 100 ~ 120
Part, 20 ~ 30 parts of pomelo peel, 20 ~ 30 parts of plant leaf blade, 10 ~ 20 parts of white cement, 2 ~ 6 parts of nano-scale silver powder, tourmaline fine powder 2 ~ 6
1 ~ 5 part of part and titanium dioxide.
2. attapulgite deodorant according to claim 1, it is characterised in that the raw material including following weight portion：It is concavo-convex
110 parts of rod soil, 25 parts of pomelo peel, 25 parts of plant leaf blade, 15 parts of white cement, 4 parts of nano-scale silver powder, 4 parts of tourmaline fine powder and titanium
3 parts of white powder.
3. attapulgite deodorant according to claim 1, it is characterised in that the plant leaf blade is paulownia leaves, willow
Any one in leaf, Folium Pterocaryae, Folium sophorae or Boston ivy leaf.
4. the preparation method of attapulgite deodorant of the one kind according to any one of claim 1 ~ 3, it is characterised in that including
Following steps：
Step（1）, attapulgite is ground into the particle of 0.5 ~ 2mm of particle diameter；
Step（2）, by step（1）5 ~ 6h is carried during the middle attapulgite by grinding is soaked in 1 ~ 2% sodium hydroxide solution
Pure, filtration drying obtains attapulgite powder after purification；
Step（3）, by step（2）In attapulgite powder be added in ethanol solution, with 200 ~ 300r/min of rotating speed stir
35 ~ 45min, obtains attapulgite alcohol suspending liquid, at 25 ~ 35 DEG C, toward attapulgite alcohol suspending liquid, adds amino silicone
Oil, and continue to stir 1 ~ 2h with 100 ~ 200r/min of rotating speed, attapulgite's surface is modified upper amido silicon oil molecule, then will have
The liquid that machine modification is obtained is placed in and 2 ~ 3h is dried in 65 ~ 70 DEG C of oven conditions, and the powder that will be dried to obtain is ground
20 ~ 30min, obtains modified attapulgite powder end after grinding, standby；
Step（4）, take pomelo peel, be placed on after cleaning up ventilation drying, dry after be put into pulverizer crushing, crush
To shaddock peel powder, shaddock peel powder is mixed with water according to mass ratio 1: 5~1: 8,5~6h of heating and refluxing extraction, heating-up temperature control
60 ~ 70 DEG C are made as, shaddock ped essential oil is obtained, it is standby；
Step（5）, by plant leaf blade microwave irradiation, the leaf after microwave irradiation dries in the shade at shady and cool ventilation, after drying in the shade
Plant leaf blade is put into pulverizer crushing, crosses 80 ~ 100 mesh sieves, with mass concentration for 20 ~ 40% ethanol water is extracted 4 ~ 5 times,
The filtrate for merging extraction every time obtains plant leaf blade extract solution；
Step（6）, by the step（2）In the plant leaf blade extract solution that obtains be concentrated under reduced pressure, until it is small to detect ethanol content
Untill when 0.5%, then filtered, the impurity in filtrate, the filtrate that will be collected into are removed with macroporous adsorbent resin column chromatography
It is spray-dried, is obtained natural plants dry powder, it is standby；
Step（7）, by step（3）Modified attapulgite powder end, the step for obtaining（4）The shaddock ped essential oil that obtains and
Step（5）The natural plants dry powder blend for obtaining, and according to proportioning add nano-scale silver powder, white cement, tourmaline fine powder,
Titanium dioxide, the clear water for accounting for gross weight 25 ~ 30% is added after being well mixed, and is continued stirring and is mixed to get paste mixture；
Step（8）, by step（7）In the paste mixture that obtains insert in mould, it is molded after be put into electric dry oven,
When temperature is 8 ~ 10% to be baked to moisture at 100 ~ 110 DEG C, take out cool to normal temperature, obtain final product the attapulgite deodorant
Agent.
5. the preparation method of attapulgite deodorant according to claim 4, it is characterised in that the step（2）In do
Dry temperature is 90 ~ 110 DEG C, and drying time is 2 ~ 3h.
6. the preparation method of attapulgite deodorant according to claim 4, it is characterised in that the step（3）It is concavo-convex
The mass ratio of rod soil powder and ethanol solution is 1：8~1：10, the mass ratio of amido silicon oil and attapulgite alcohol suspending liquid is 1：50
~1：60.
7. the preparation method of attapulgite deodorant according to claim 4, it is characterised in that the step（5）In it is micro-
Ripple irradiation power is 10 ~ 70W/g, and plant leaf blade tiling thickness is 5 ~ 30mm, and microwave frequency is 2450MHZ, microwave irradiating time
It is 4 ~ 6min.
8. the preparation method of attapulgite deodorant according to claim 4, it is characterised in that the step（5）Middle plant
Thing leaf is 1: 10 ~ 1 with the weight ratio of ethanol water：15,60 ~ 70 DEG C of extraction temperature, 1 ~ 2h of extraction time.
9. the preparation method of attapulgite deodorant according to claim 4, it is characterised in that the step（6）In
Macroporous absorbent resin is non-polar resin.
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